Pt–Nix alloy nanoparticles: a new strategy for cocatalyst design on a CdS surface for photo-catalytic hydrogen generation

Solar photocatalytic water splitting for the production of hydrogen has been a core aspect for decades. A highly active and durable photocatalyst is crucial for the success of the renewable hydrogen economy. To date, the development of highly effective photocatalysts has been seen by the contemporary research community as a grand challenge. Thus, herein we put forward a sincere attempt to use a Pt–Ni_x alloy nanoparticle (NP) cocatalyst loaded CdS photocatalyst ((Pt–Ni_x)/CdS) for photocatalytic hydrogen production under visible light. The Pt–Ni_x alloy NP cocatalyst was synthesized using a one-pot solvothermal method. The cocatalyst nanoparticles were deposited onto the surface of CdS, forming a Pt–Ni_x/CdS photocatalyst. Photocatalytic hydrogen production was carried out using a 300 W Xe light equipped with a 420 nm cut-off filter. The H₂ evolution rate of the Pt–Ni₃/CdS photocatalyst can reach a value as high as 48.96 mmol h⁻¹ g⁻¹ catalyst, with a quantum efficiency of 44.0% at 420 nm. The experimental results indicate that this Pt–Ni₃/CdS photocatalyst is a prospective candidate for solar hydrogen generation from water-splitting.

In this report, PtNi_x alloy NPs coupled with a CdS photocatalyst for photocatalytic hydrogen generation under visible light have been explored.     

Photocatalytic-induced bubble-propelled isotropic g-C3N4-coated carbon microsphere micromotors for dynamic removal of organic pollutants

An isotropic bubble-propelled graphitic carbon nitride coated carbon microsphere (g-C₃N₄@CMS) micromotor that displays efficient self-propulsion powered by visible light irradiation and offers effective dynamic removal of organic pollutants for environmental applications is described. Its morphology, structure, and composition were systematically characterized, confirming the successful coating of g-C₃N₄ on the CMS surface and a core–shell structure. The photocatalytic-induced bubble propulsion of g-C₃N₄@CMS micromotors essentially stems from the asymmetrical photocatalytic redox reactions of g-C₃N₄ on the symmetrical surface of micromotors under visible light illumination. The stacking effect of g-C₃N₄ on the CMS surface results in a microporous structure that provides a highly reactive photocatalytic layer, which also leads to effective bubble evolution and propulsion at remarkable speeds of over 167.97 μm s⁻¹ under 250 mW cm⁻² visible light in the presence of 30% H₂O₂ fuel. The velocity can be easily and effectively adjusted by H₂O₂ fuel and the intensity of visible light. Furthermore, the motion state can be reversibly and wirelessly controlled by “switching on/off” light. Such coupling of the high photocatalytic activity of the porous g-C₃N₄ shell with the rapid movement of these light-driven micromotors, along with the corresponding fluid dynamics and mixing, result in greatly accelerated organic pollutant degradation. The adsorption kinetics have also been investigated and shown to follow pseudo-second-order kinetics. The strategy proposed here would inspire the designing of light-driven symmetrical micromotors because of the low cost, single component, and simple structure as well as facile and large-scale fabrication, which make them suitable for practical applications.

An isotropic bubble-propelled g-C₃N₄@CMS micromotor that displays efficient self-propulsion powered by visible light irradiation and offers effective dynamic removal of organic pollutants for environmental applications is described.     

Two dimensional Ni2P/CdS photocatalyst for boosting hydrogen production under visible light irradiation

Two-dimensional (2D) semiconductor materials have attracted considerable attention in the field of photocatalysis due to the high interfacial charge separation efficiency and abundant surface active sites. Herein, we have fabricated 2D/2D sheets of Ni₂P/CdS heterostructure for photocatalytic H₂ evolution. The microscopic and photocatalytic activity results suggested that Ni₂P nanosheets were coupled with snowflake CdS. The optimal hydrogen production rate reached 58.33 mmol h⁻¹ g⁻¹ (QE = 34.38%, λ = 420 nm) over 5 wt% Ni₂P, which is equivalent to that of 1 wt% Pt/CdS. Compared with pure CdS, Ni₂P/CdS presented lower fluorescence intensity and stronger photocurrent density, which demonstrated that the 2D/2D Ni₂P/CdS heterojunction photocatalyst significantly improved the separation efficiency of photogenerated electrons and holes. The excellent performance of Ni₂P/CdS clearly indicated that Ni₂P was an excellent cocatalyst and could provide abundant active sites for hydrogen evolution.

The mechanism of photogenerated charges separation and hydrogen production of 2D/2D structure Ni₂P/CdS.     

New insights into the surface plasmon resonance (SPR) driven photocatalytic H2 production of Au–TiO2

The Surface Plasmon Resonance (SPR) driven photocatalytic H₂ production upon visible light illumination (≥500 nm) was investigated on gold-loaded TiO₂ (Au–TiO₂). It has been clearly shown that the Au-SPR can directly lead to photocatalytic H₂ evolution under illumination (≥500 nm). However, there are still some open issues about the underlying mechanism for the SPR-driven photocatalytic H₂ production, especially the explanation of the resonance energy transfer (RET) theory and the direct electron transfer (DET) theory. In this contribution, by means of the EPR and laser flash photolysis spectroscopy, we clearly showed the signals for different species formed by trapped electrons and holes in TiO₂ upon visible light illumination (≥500 nm). However, the energy of the Au-SPR is insufficient to overcome the bandgap of TiO₂. The signals of the trapped electrons and holes originate from two distinct processes, rather than the simple electron–hole pair excitation. Results obtained by Laser Flash Photolysis spectroscopy evidenced that, due to the Au-SPR effect, Au NPs can inject electrons to the conduction band of TiO₂ and the Au-SPR can also initiate e⁻/h⁺ pair generation (interfacial charge transfer process) upon visible light illumination (≥500 nm). Moreover, the Density Functional Theory (DFT) calculation provided direct evidence that, due to the Au-SPR, new impurity energy levels occurred, thus further theoretically elaborating the proposed mechanisms.

The Surface Plasmon Resonance (SPR) driven photocatalytic H₂ production upon visible light illumination (≥500 nm) was investigated on gold-loaded TiO₂ (Au–TiO₂).     

The effect of stoichiometry on the structural,thermal and electronic properties of thermally decomposed nickel oxide

A thermal decomposition route with different sintering temperatures was employed to prepare non-stoichiometric nickel oxide (Ni_1−δO) from Ni(NO₃)₂·6H₂O as a precursor. The non-stoichiometry of samples was then studied chemically by iodometric titration, wherein the concentration of Ni³⁺ determined by chemical analysis, which is increasing with increasing excess of oxygen or reducing the sintering temperature from the stoichiometric NiO; it decreases as sintering temperature increases. These results were corroborated by the excess oxygen obtained from the thermo-gravimetric analysis (TGA). X-ray diffraction (XRD) and Fourier transformed infrared (FTIR) techniques indicate the crystalline nature, Ni–O bond vibrations and cubic structural phase of Ni_1−δO. The change in oxidation state of nickel from Ni³⁺ to Ni²⁺ were seen in the X-ray photoelectron spectroscopy (XPS) analysis and found to be completely saturated in Ni²⁺ as the sintering temperature reaches 700 °C. This analysis accounts for the implication of non-stoichiometric on the magnetization data, which indicate a shift in antiferromagnetic ordering temperature (T_N) due to associated increased magnetic disorder. A sharp transition in the specific heat capacity at T_N and a shift towards lower temperature are also evidenced with respect to the non-stoichiometry of the system.

A thermal decomposition route with different sintering temperatures was employed to prepare non-stoichiometric nickel oxide (Ni_1−δO) from Ni(NO₃)₂·6H₂O as a precursor.     

Low temperature fabrication of Fe2O3 nanorod film coated with ultra-thin g-C3N4 for a direct z-scheme exerting photocatalytic activities

We engineered high aspect ratio Fe₂O₃ nanorods (with an aspect ratio of 17 : 1) coated with g-C₃N₄ using a sequential solvothermal method at very low temperature followed by a thermal evaporation method. Here, the high aspect ratio Fe₂O₃ nanorods were directly grown onto the FTO substrate under relatively low pressure conditions. The g-C₃N₄ was coated onto a uniform Fe₂O₃ nanorod film as the heterostructure, exhibiting rational band conduction and a valence band that engaged in surface photoredox reactions by a direct z-scheme mechanism. The heterostructures, particularly 0.75g-C₃N₄@Fe₂O₃ nanorods, exhibited outstanding photocatalytic activities compared to those of bare Fe₂O₃ nanorods. In terms of 4-nitrophenol degradation, 0.75g-C₃N₄@Fe₂O₃ nanorods degraded all of the organic pollutant within 6 h under visible irradiation at a kinetic constant of 12.71 × 10⁻³ min⁻¹, about 15-fold more rapidly than bare Fe₂O₃. Further, the hydrogen evolution rate was 37.06 μmol h⁻¹ g⁻¹, 39-fold higher than that of bare Fe₂O₃. We suggest that electron and hole pairs are efficiently separated in g-C₃N₄@Fe₂O₃ nanorods, thus accelerating surface photoreaction via a direct z-scheme under visible illumination.

The engineered high aspect ratio of Fe₂O₃ nanorods coated with g-C₃N₄ demonstrates z-scheme mechanism, showing the best performance in 4-nitrophenol photodegradation and H₂ evolution.     

Efficient solar light-driven hydrogen generation using an Sn3O4 nanoflake/graphene nanoheterostructure

Herein, we report Sn₃O₄ and Sn₃O₄ nanoflake/graphene for photocatalytic hydrogen generation from H₂O and H₂S under natural “sunlight” irradiation. The Sn₃O₄/graphene composites were prepared by a simple hydrothermal method at relatively low temperatures (150 °C). The incorporation of graphene in Sn₃O₄ exhibits remarkable improvement in solar light absorption, with improved photoinduced charge separation due to formation of the heterostructure. The highest photocatalytic hydrogen production rate for the Sn₃O₄/graphene nanoheterostructure was observed as 4687 μmol h⁻¹ g⁻¹ from H₂O and 7887 μmol h⁻¹ g⁻¹ from H₂S under natural sunlight. The observed hydrogen evolution is much higher than that for pure Sn₃O₄ (5.7 times that from H₂O, and 2.2 times from H₂S). The improved photocatalytic activity is due to the presence of graphene, which acts as an electron collector and transporter in the heterostructure. More significantly, the Sn₃O₄ nanoflakes are uniformly and parallel grown on the graphene surface, which accelerates the fast transport of electrons due to the short diffusion distance. Such a unique morphology for the Sn₃O₄ along with the graphene provides more adsorption sites, which are effective for photocatalytic reactions under solar light. This work suggests an effective strategy towards designing the surfaces of various oxides with graphene nanoheterostructures for high performance of energy-conversion devices.

Herein, we have demonstrated the synthesis of the two-dimensional hierarchical Sn₃O₄/graphene nanostructure by a facile solvothermal method. The nanostructure has been used as a photocatalyst for hydrogen production under solar light.     

Graphitic carbon nitride with thermally-induced nitrogen defects: an efficient process to enhance photocatalytic H2 production performance

Graphitic carbon nitride (g-C₃N₄, CN) with nitrogen vacancies was synthesized by a controlled thermal etching method in a semi-closed air-conditioning system. The defect-modified g-C₃N₄ shows an excellent photocatalytic performance demonstrated by water splitting under visible light irradiation. With proper heat-treatment durations such as 2 h (CN2) and 4 h (CN4) at 550 °C, the hydrogen production rates significantly increase to 100 μmol h⁻¹ and 72 μmol h⁻¹, which are 11 times and 8 times the rate of the pristine CN (8.8 μmol h⁻¹) respectively. The excellent hydrogen production performance of nitrogen defect modified CN2 is due to the synergy effect of the decreased band gap, enlarged specific surface area and increased separation/migration efficiency of photoinduced charge carriers. This simple defect engineering method provides a good paradigm to improve the photocatalytic performance by tailoring the electronic and physical structures of g-C₃N₄.

An efficient thermal-treatment method was developed for the preparation of defect modified g-C₃N₄ with excellent photocatalytic H₂ production performance.     

Synergetic effect of photocatalysis and peroxymonosulfate activated by MFe2O4 (M = Co,Mn, or Zn) for enhanced photocatalytic activity under visible light irradiation

Nanosized MFe₂O₄ (M = Co, Mn, or Zn) photocatalysts were synthesized via a simple sol–gel method. MFe₂O₄ photocatalysts exhibited lower photocatalytic activity for the degradation of levofloxacin hydrochloride under visible light irradiation. For enhancement of photocatalytic activity, MFe₂O₄ was used to activate peroxymonosulfate and degrade levofloxacin hydrochloride under visible light irradiation. The influences of peroxymonosulfate dosage, levofloxacin hydrochloride concentration, pH value, and temperature on peroxymonosulfate activation to degrade levofloxacin hydrochloride were investigated in detail. The mechanism of activation of peroxymonosulfate by MFe₂O₄ was proposed and proved by radical quenching experiments, electron spin resonance analysis, X-ray photoelectron spectroscopy, electrochemical impedance spectroscopy, and transient photocurrent responses. The combined activation effects of photogenerated e⁻/h⁺ and transition metals on peroxymonosulfate to produce sulfate radical clearly enhanced the degradation efficiency.

The combined activation effects of photogenerated e⁻/h⁺, Fe, Co, Mn, and Zn on peroxymonosulfate to produce SO₄˙⁻ clearly enhanced the degradation efficiency.     

Homojunction and defect synergy-mediated electron–hole separation for solar-driven mesoporous rutile/anatase TiO2 microsphere photocatalysts

The photocatalytic hydrogen evolution of TiO₂ is deemed to be one of the most promising ways of converting solar energy to chemical energy; however, it is a challenge to improve the photo-generated charge separation efficiency and enhance solar utilization. Herein, black mesoporous rutile/anatase TiO₂ microspheres with a homojunction and surface defects have been successfully synthesized by an evaporation-induced self-assembly, solvothermal and high-temperature surface hydrogenation method. The H500-BMR/ATM (HX-BMR/ATM, where X means the different hydrogen calcination temperatures) materials not only possess a mesoporous structure and relatively high specific surface area of 39.2 m² g⁻¹, but also have a narrow bandgap (∼2.87 eV), which could extend the photoresponse to the visible light region. They exhibit high photocatalytic hydrogen production (6.4 mmol h⁻¹ g⁻¹), which is much higher (approximately 1.8 times) than that of pristine mesoporous rutile/anatase TiO₂ microspheres (3.58 mmol h⁻¹ g⁻¹). This enhanced photocatalytic hydrogen production property is attributed to the synergistic effect of the homojunction and surface defects in improving efficient electron–hole separation and high utilization of solar light. This work proposes a new approach to improve the performance of photocatalytic hydrogen production and probably offers a new insight into fabricating other high-performance photocatalysts.

Mesoporous rutile/anatase TiO₂ microspheres with surface defects are fabricated and exhibit excellent solar-driven photocatalytic performance due to synergistic effect of the homojunction and surface defects favoring efficient e–h separation.     

Enhanced photocatalytic H2 evolution over covalent organic frameworks through an assembled NiS cocatalyst

Covalent organic frameworks (COFs) have been investigated in the field of photocatalysts for H₂ evolution because of their crystalline structure and diversity. However, most of them need the help of noble metals as co-catalysts to realize a high hydrogen evolution. Herein, we chose typical COFs as a platform and constructed NiSX-BD (X: weight fraction of NiS) composites by assembling NiS at room temperature. The NiS nanoparticles are shown to tightly adhere to the COFs surface. Under visible light irradiation (wavelength > 420 nm), the optimized sample with 3 wt% NiS loading exhibits a photocatalytic H₂ evolution rate of 38.4 μmol h⁻¹ (3840 μmol h⁻¹ g⁻¹), which is about 120 folds higher than that of the pure TpBD-COF and better than TpBD-COF/Pt with the same Pt loading (3 wt%). NiS3-BD shows stable hydrogen evolution in at least six consecutive cycle tests totaling 18 h. Further investigation reveals that the loaded NiS can facilitate the transfer of photogenerated electrons from TpBD-COF to the co-catalyst, leading to efficient and high photocatalytic activity. Combining the significant feature of COFs, this study opens up a feasible avenue to boost the photocatalytic H₂ performance by constructing the synergetic effects between COFs and cost-effective material.

We constructed a novel hybrid photocatalyst by assembling NiS through a milder method. Under visible light irradiation, controlled NiS/TpBD-COF composites can readily optimize photocatalytic performances without a noble cocatalyst.     

Reduced graphene oxide-supported Ag-loaded Fe-doped TiO2 for the degradation mechanism of methylene blue and its electrochemical properties

Graphene oxide-based composites have been developed as cheap and effective photocatalysts for dye degradation and water splitting applications. Herein, we report reduced graphene oxide (rGO)/Ag/Fe-doped TiO₂ that has been successfully prepared using a simple process. The resulting composites were characterized by a wide range of physicochemical techniques. The photocatalytic activities of the composite materials were studied under visible light supplied by a 35 W Xe arc lamp. The rGO/Ag/Fe-doped TiO₂ composite demonstrated excellent degradation of methylene blue (MB) in 150 min and 4-nitrophenol (4-NP) in 210 min under visible light irradiation, and trapping experiments were carried out to explain the mechanism of photocatalytic activity. Moreover, electrochemical studies were carried out to demonstrate the oxygen evolution reaction (OER) activity on rGO/Ag/Fe-doped TiO₂ in 1 M of H₂SO₄ electrolyte, with a scan rate of 50 mV s⁻¹. The reductions in overpotential are due to the d-orbital splitting in Fe-doped TiO₂ and rGO as an electron collector and transporter.

Graphene oxide-based composites have been developed as cheap and effective photocatalysts for dye degradation and water splitting applications.     

Unique hierarchical SiO2@ZnIn2S4 marigold flower like nanoheterostructure for solar hydrogen production

The novel marigold flower like SiO₂@ZnIn₂S₄ nano-heterostructure was fabricated using an in situ hydrothermal method. The nanoheterostructure exhibits hexagonal structure with marigold flower like morphology. The porous marigold flower assembly was constructed using ultrathin nanosheets. Interestingly, the thickness of the nanopetal was observed to be 5–10 nm and tiny SiO₂ nanoparticles (5–7 nm) are decorated on the surface of the nanopetals. As the concentration of SiO₂ increases the deposition of SiO₂ nanoparticles on ZnIn₂S₄ nanopetals increases in the form of clusters. The optical study revealed that the band gap lies in the visible range of the solar spectrum. Using X-ray photoelectron spectroscopy (XPS), the chemical structure and valence states of the as-synthesized SiO₂@ZnIn₂S₄ nano-heterostructure were confirmed. The photocatalytic activities of the hierarchical SiO₂@ZnIn₂S₄ nano-heterostructure for hydrogen evolution from H₂S under natural sunlight have been investigated with regard to the band structure in the visible region. The 0.75% SiO₂@ZnIn₂S₄ showed a higher photocatalytic activity (6730 μmol⁻¹ h⁻¹ g⁻¹) for hydrogen production which is almost double that of pristine ZnIn₂S₄. Similarly, the hydrogen production from water splitting was observed to be 730 μmol⁻¹ h⁻¹ g⁻¹. The enhanced photocatalytic activity is attributed to the inhibition of charge carrier separation owing to the hierarchical morphology, heterojunction and crystallinity of the SiO₂@ZnIn₂S₄.

The novel marigold flower like SiO₂@ZnIn₂S₄ nano-heterostructure was fabricated using an in situ hydrothermal method.     

Synthesis and characterization of nickel-doped ceria nanoparticles with improved surface reducibility

Nickel-doped ceria nanoparticles (Ni_0.1Ce_0.9O_2−x NPs) were fabricated from Schiff-base complexes and characterized by various microscopic and spectroscopic methods. Clear evidence is provided for incorporation of nickel ions in the ceria lattice in the form of Ni³⁺ species which is considered as the hole trapped state of Ni²⁺. The Ni_0.1Ce_0.9O_2−x NPs exhibit enhanced reducibility in H₂ as compared to conventional ceria-supported Ni particles, while in O₂ the dopant nickel cations are oxidized at higher valence than the supported ones.

Nickel-doped ceria nanoparticles (Ni_0.1Ce_0.9O_2−x NPs) were fabricated from Schiff-base complexes and characterized by various microscopic and spectroscopic methods.     

Plasmonic Ag decorated CdMoO4 as an efficient photocatalyst for solar hydrogen production

The synthesis of Ag-nanoparticle-decorated CdMoO₄ and its photocatalytic activity towards hydrogen generation under sunlight has been demonstrated. The CdMoO₄ samples were synthesized by a simple hydrothermal approach in which Ag nanoparticles were in situ decorated on the surface of CdMoO₄. A morphological study showed that 5 nm spherical Ag nanoparticles were homogeneously distributed on the surface of CdMoO₄ particles. The UV/DRS spectra show that the band gap of CdMoO₄ was narrowed by the incorporation of a small amount of Ag nanoparticles. The surface plasmonic effect of Ag shows broad absorption in the visible region. The enhanced photocatalytic hydrogen production activities of all the samples were evaluated by using methanol as a sacrificial reagent in water under natural sunlight conditions. The results suggest that the rate of photocatalytic hydrogen production using CdMoO₄ can be significantly improved by loading 2% Ag nanoparticles: i.e. 2465 μmol h⁻¹ g⁻¹ for a 15 mg catalyst. The strong excitation of surface plasmon resonance (SPR) absorption by the Ag nanoparticles was found in the Ag-loaded samples. In this system, the role of Ag nanoparticles on the surface of CdMoO₄ has been discussed. In particular, the SPR effect is responsible for higher hydrogen evolution under natural sunlight because of broad absorption in the visible region. The current study could provide new insights for designing metal/semiconductor interface systems to harvest solar light for solar fuel generation.

Plasmonic enhancement of photocatalytic hydrogen generation is demonstrated using hierarchical Ag decorated CdMoO₄ synthesized using a hydrothermal method.     

Synthesis of SrTiO3 submicron cubes with simultaneous and competitive photocatalytic activity for H2O splitting and CO2 reduction

Single crystalline strontium titanate (SrTiO₃) submicron cubes have been synthesized based on a molten salt method. The submicron cubes showed superior photocatalytic activity towards both water splitting and carbon dioxide reduction, in which methane (CH₄) and hydrogen (H₂) were simultaneously produced. The average production rate of methane up to 8 h is 4.39 μmol g⁻¹ h⁻¹ but drops to 0.46 μmol g⁻¹ h⁻¹. However, the average production rate of hydrogen is 14.52 before 8 h but then increases to 120.23 μmol g⁻¹ h⁻¹ after 8 h. The rate change of the two processes confirms the competition between the H₂O splitting and CO₂ reduction reactions. Band structure and surface characteristics of the SrTiO₃ submicron cubes were characterized by diffuse reflective UV-Vis spectroscopy, Mott–Schottky analysis, X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR). The results reveal that the simultaneous and competitive production of methane and hydrogen is due to a thermodynamics factor, as well as the competition between the adsorption of carbon dioxide and water molecules on the surface of the faceted SrTiO₃. This work demonstrates that SrTiO₃ photocatalysts are efficient in producing sustainable fuels via water splitting and carbon dioxide reduction reactions.

There is a clear competitive relationship between water splitting and photocatalytic reduction of carbon dioxide in the whole process of photocatalytic reduction of carbon dioxide with the prepared cubic SrTiO₃ as a photocatalyst.     

A dual polymer composite of poly(3-hexylthiophene) and poly(3,4-ethylenedioxythiophene) hybrid surface heterojunction with g-C3N4 for enhanced photocatalytic hydrogen evolution

A surface heterojunction catalyst of g-C₃N₄–PEDOT/P3HT with P3HT and PEDOT as the polymer sensitizer and hole transport pathway is successfully prepared. The as constructed g-C₃N₄–PEDOT/P3HT composite exhibits a photocatalyst H₂ evolution rate up to 427703.3 μmol h⁻¹ g⁻¹ which is 1059 times higher than that of g-C₃N₄, 118 times higher than that of g-C₃N₄–PEDOT with ascorbic acid as sacrificial reagents. What''s more, the g-C₃N₄–PEDOT/P3HT can even show an obviously enhanced photocatalytic H₂ evolution rate which is 6.1 times higher than that of pure g-C₃N₄ in pure water without any sacrificial reagent. Combining the experimental results and molecular dynamic (MD) simulation results, a possible mechanism can be drawn that the existed PEDOT possesses relatively higher hole mobility and can be used as a hole conductor between g-C₃N₄ and P3HT. Then, the photogenerated holes migration can be accelerated by PEDOT from the VB of g-C₃N₄ to the VB of P3HT. All those factors may benefit the synergy among g-C₃N₄, PEDOT and P3HT, which finally facilitates the rapid migration of photoinduced electron–hole pairs and eventually improves the photocatalytic H₂ activity process of g-C₃N₄–PEDOT/P3HT with visible light. The present work may provide useful insights for designing a surface heterojunction composite photocatalyst with high photocatalytic activity for H₂ production.

A surface heterojunction catalyst of g-C₃N₄-PEDOT/P3HT with P3HT and PEDOT as the polymer sensitizer and hole transport pathway is successfully prepared. The as prepared photocatalyst with much improved photocatalytic activity for H₂ production.     

Immobilizing a visible light-responsive photocatalyst on a recyclable polymeric composite for floating and suspended applications in water treatment

A visible light responsive TiO₂/Ag₃PO₄ (10 : 1) nanocomposite was prepared and successfully immobilized (12 wt%) in a spherical polymeric matrix consisting of polysulfone and alginate (10 : 6). The resulted beads featured a sponge-like structure with interconnected macrovoids and micropores, and showed high adsorption and visible-light photocatalytic activity towards various wastewater pollutants, including the widely used dye – methylene blue (k = 0.0321 min⁻¹), and two emerging pharmaceutical contaminants – diclofenac (k = 0.018 min⁻¹) and triclosan (k = 0.052 min⁻¹). As determined, the ˙OH radical and h⁺ are the primary reactive oxygen species responsible for the photodegradation. The composite photocatalytic beads are also effective in bacterial inactivation and degradation of acyl-homoserine lactones (AHLs), the bacterial quorum sensing autoinducers triggering biofilms, thus exhibiting a promising future in wastewater disinfection and biofilm retardation. Additionally, these beads could be used in inter-switchable suspended or buoyant forms, and be effectively regenerated by H₂O₂ treatment, and used for multiple cycles without any significant loss in photoactivity. With these unique features, the prepared visible-light photocatalytic beads could be easily applied in large-scale water and wastewater treatment systems.

A recyclable visible light-responsive nanocomposite was prepared and immobilized in a spherical polymeric matrix having inter-switchable suspended or buoyant forms for wastewater treatment.     

In situ constructed oxygen-vacancy-rich MoO3−x/porous g-C3N4 heterojunction for synergistically enhanced photocatalytic H2 evolution

A simple method was developed for enhanced synergistic photocatalytic hydrogen evolution by in situ constructing of oxygen-vacancy-rich MoO_3−x/porous g-C₃N₄ heterojunctions. Introduction of a MoO_3−x precursor (Mo(OH)₆) solution into g-C₃N₄ nanosheets helped to form a porous structure, and nano-sized oxygen-vacancy-rich MoO_3−xin situ grew and formed a heterojunction with g-C₃N₄, favorable for charge separation and photocatalytic hydrogen evolution (HER). Optimizing the content of the MoO_3−x precursor in the composite leads to a maximum photocatalytic H₂ evolution rate of 4694.3 μmol g⁻¹ h⁻¹, which is approximately 4 times higher of that of pure g-C₃N₄ (1220.1 μmol g⁻¹ h⁻¹). The presence of oxygen vacancies (OVs) could give rise to electron-rich metal sites. High porosity induced more active sites on the pores'' edges. Both synergistically enhanced the photocatalytic HER performance. Our study not only presented a facile method to form nano-sized heterojunctions, but also to introduce more active sites by high porosity and efficient charge separation from OVs.

In situ growth method to construct a nano-sized oxygen-vacancy-rich MoO_3−x/porous g-C₃N₄ heterojunction. MoO_3−x derived OV traps and porous g-C₃N₄ nanosheet derived short migration distance and plentiful edge active sites.     

Flower-like hydrogen titanate nanosheets: preparation,characterization and their photocatalytic hydrogen production performance in the presence of Pt cocatalyst

Flower-like hydrogen titanate nanosheets were prepared by a hydrothermal method and an assembling process. Then the Pt nanoparticles as cocatalysts were supported on the hydrogen titanate nanosheets through a photoreduction method. The samples were characterized by XRD, TG-DTA, ICP, SEM, TEM, XPS and UV-vis DRS. Their photocatalytic activity for H₂ production was also evaluated. The TEM results revealed that the as-prepared H₂Ti₂O₅·H₂O was with flower-like structure in which nanosheets were interlaced together. The formation mechanism of flower-like H₂Ti₂O₅·H₂O nanosheets was briefly proposed. With Pt cocatalyst, the flower-like H₂Ti₂O₅·H₂O had better photocatalytic activity (hydrogen production rate: 9.28 mmol g⁻¹ h⁻¹) and good cycling stability than original H₂Ti₂O₅·H₂O and commercial P25 under the same conditions. It was also found that the amount of cocatalyst Pt was positively correlated with photocatalytic performance.

Hydrogen titanate nanosheets were assembled into the flower-like hydrogen titanate nanosheets to obtain high photocatalytic performance.