Enhanced visible-light photodegradation of fluoroquinolone-based antibiotics and E. coli growth inhibition using Ag–TiO2 nanoparticles

Antibiotics in wastewater represent a growing and worrying menace for environmental and human health fostering the spread of antimicrobial resistance. Titanium dioxide (TiO₂) is a well-studied and well-performing photocatalyst for wastewater treatment. However, it presents drawbacks linked with the high energy needed for its activation and the fast electron–hole pair recombination. In this work, TiO₂ nanoparticles were decorated with Ag nanoparticles by a facile photochemical reduction method to obtain an increased photocatalytic response under visible light. Although similar materials have been reported, we advanced this field by performing a study of the photocatalytic mechanism for Ag–TiO₂ nanoparticles (Ag–TiO₂ NPs) under visible light taking in consideration also the rutile phase of the TiO₂ nanoparticles. Moreover, we examined the Ag–TiO₂ NPs photocatalytic performance against two antibiotics from the same family. The obtained Ag–TiO₂ NPs were fully characterised. The results showed that Ag NPs (average size: 23.9 ± 18.3 nm) were homogeneously dispersed on the TiO₂ surface and the photo-response of the Ag–TiO₂ NPs was greatly enhanced in the visible light region when compared to TiO₂ P25. Hence, the obtained Ag–TiO₂ NPs showed excellent photocatalytic degradation efficiency towards the two fluoroquinolone-based antibiotics ciprofloxacin (92%) and norfloxacin (94%) after 240 min of visible light irradiation, demonstrating a possible application of these particles in wastewater treatment. In addition, it was also proved that, after five Ag–TiO₂ NPs re-utilisations in consecutive ciprofloxacin photodegradation reactions, only a photocatalytic efficiency drop of 8% was observed. Scavengers experiments demonstrated that the photocatalytic mechanism of ciprofloxacin degradation in the presence of Ag–TiO₂ NPs is mainly driven by holes and ˙OH radicals, and that the rutile phase in the system plays a crucial role. Finally, Ag–TiO₂ NPs showed also antibacterial activity towards Escherichia coli (E. coli) opening the avenue for a possible use of this material in hospital wastewater treatment.

Ag nanoparticles decorated-TiO₂ P25 are a viable alternative for the degradation, through a rutile-mediated mechanism, of fluoroquinolone-based antibiotics under visible light irradiation and, at the same time, for bacteria inactivation in water.     

Z-scheme BiVO4/Ag/Ag2S composites with enhanced photocatalytic efficiency under visible light

The Z-scheme BiVO₄/Ag/Ag₂S photocatalyst was fabricated via a two-step route. The as-prepared samples were characterized by XRD, FE-SEM, HRTEM, XPS and UV-vis diffuse reflectance spectroscopy. The results of PL and photocurrent response tests demonstrate that the ternary BiVO₄/Ag/Ag₂S composites had a high separation and migration efficiency of photoexcited carriers. As a result, the ternary photocatalyst exhibits enhanced photocatalytic activity for decomposing Rhodamine B (RhB) under LED light (420 nm) irradiation. The results of trapping experiments demonstrate both h⁺ and ˙OH play crucial roles in decomposing RhB molecules. Additionally, the energy band structures and density of states (DOS) of BiVO₄ and Ag₂S were investigated via the density functional theory (DFT) method. Finally, a Z-scheme electron migration mechanism of BiVO₄ → Ag → Ag₂S was proposed based on the experimental and calculated results.

The Z-scheme BiVO₄/Ag/Ag₂S photocatalyst was fabricated via a two-step route.     

Novel TiO2/GO/CuFe2O4 nanocomposite: a magnetic,reusable and visible-light-driven photocatalyst for efficient photocatalytic removal of chlorinated pesticides from wastewater

A TiO₂/GO/CuFe₂O₄ heterostructure photocatalyst is fabricated by a simple and low-cost ball-milling pathway for enhancing the photocatalytic degradation of chlorinated pesticides under UV light irradiation. Based on the advantages of graphene oxide, TiO₂, and CuFe₂O₄, the nanocomposite exhibited visible light absorption, magnetic properties, and adsorption capacity. Integrated analyses using XRD, SEM, TEM, and UV-visible techniques demonstrated that the nanocomposite exhibited a well-defined crystalline phase, sizes of 10–15 nm, and evincing a visible light absorption feature with an optical bandgap energy of 2.4 eV. The photocatalytic degradations of 17 different chlorinated pesticides (persistent organic pollutants) were assayed using the prepared photocatalyst. The photocatalytic activity of the nanocomposite generated almost 96.5% photocatalytic removal efficiency of typical pesticide DDE from water under UV irradiation. The superior photocatalytic performance was exhibited by the TiO₂/GO/CuFeO₄ catalyst owing to its high adsorption performance and separation efficiency of photo-generated carriers. The photocatalyst was examined in 5 cycles for treating uncolored pesticides with purposeful separation using an external magnetic field.

A TiO₂/GO/CuFe₂O₄ heterostructure photocatalyst is fabricated by a simple and low cost ball milling pathway for enhancing the photocatalytic degradation of chlorinated pesticides under UV light irradiation.     

Construction of H4xK2xSn2−xS4+x/TiO2 nanocomposites with enhanced visible light-driven photocatalytic performance

In this paper, a new photocatalyst with TiO₂ nanospheres decorated on ultrathin layered thiostannate H_4xK_2xSn_2−xS_4+x (X = 0.5–0.6, HKTS) nanosheets was successfully synthesized by a facile solvothermal method combined with the hydrolysis of tetrabutyl titanate and it was denoted as HKTS/TiO₂. By adjusting the content of tetrabutyl titanate, composites with different Sn/Ti molar ratios were prepared. The composites were applied for RhB degradation under visible light irradiation, and the optimum proportion of HKTS/TiO₂ was obtained. The results of X-ray diffraction, Raman spectroscopy, Fourier transform infrared spectroscopy and scanning electron microscopy confirmed that TiO₂ was successfully decorated on HKTS nanosheets. The combination of TiO₂ and HKTS extended the absorption wavelength of TiO₂ from UV to visible light range, and the separation efficiency of photoexcited electron–hole pairs was also enhanced. The photocatalytic degradation rate of RhB over HKTS/TiO₂-1.0 was almost 97.9% after 60 min illumination, which was higher than those of HKTS and pure TiO₂. The photocatalyst exhibited excellent reusability and stability as the degradation rate of RhB was 95.7% even after three cycles. The photocatalytic mechanism experiment indicated that ·O₂⁻ and h⁺ played a dominant role in the photocatalytic process. All these results indicate that the newly fabricated HKTS/TiO₂ composites provide a high-performance photocatalyst for waste water treatment, and the application of thiostannate can be extended to the field of photocatalytic materials.

The enhanced visible light photocatalytic performance of a newly fabricated nanostructure combined TiO₂ with HKTS.     

Surface plasmon-driven photoelectrochemical water splitting of a Ag/TiO2 nanoplate photoanode

A silver/titanium dioxide nanoplate (Ag/TiO₂ NP) photoelectrode was designed and fabricated from vertically aligned TiO₂ nanoplates (NP) decorated with silver nanoparticles (NPs) through a simple hydrothermal synthesis and electrodeposition route. The electrodeposition times of Ag NPs on the TiO₂ NP were crucial for surface plasmon-driven photoelectrochemical (PEC) water splitting performance. The Ag/TiO₂ NP at the optimal deposition time of 5 min with a Ag element content of 0.53 wt% demonstrated a remarkably high photocurrent density of 0.35 mA cm⁻² at 1.23 V vs. RHE under AM 1.5G illumination, which was 5 fold higher than that of the pristine TiO₂ NP. It was clear that the enhanced light absorption properties and PEC performance for Ag/TiO₂ NP could be effectively adjusted by simply controlling the loading amounts of metallic Ag NPs (average size of 10–30 nm) at different electrodeposition times. The superior PEC performance of the Ag/TiO₂ NP photoanode was attributed to the synergistic effects of the plasmonic Ag NPs and the TiO₂ nanoplate. Interestingly, the plasmonic effect of Ag NPs not only increased the visible-light response (λ_max = 570 nm) of TiO₂ but also provided hot electrons to promote photocurrent generation and suppress charge recombination. Importantly, this study offers a potentially efficient strategy for the design and fabrication of a new type of TiO₂ hybrid nanostructure with a plasmonic enhancement for PEC water splitting.

A hybrid nanostructure Ag/TiO₂ photoelectrode for PEC water splitting with a remarkable high photocurrent density, 0.35 mA cm⁻² (5 fold higher than that of the pristine TiO₂ photoeletrode) was fabricated by a facile one-pot hydrothermal and electrodeposition method.     

Fabrication of Ag3PO4/GO/NiFe2O4 composites with highly efficient and stable visible-light-driven photocatalytic degradation of rhodamine B

Effective visible-light-driven Ag₃PO₄/GO/NiFe₂O₄Z-scheme magnetic composites were successfully fabricated by a simple ion-exchange deposition method. The Ag₃PO₄/GO/NiFe₂O₄ (8%) composite exhibited excellent photocatalytic activity (degradation efficiency was ∼96% within 15 min and kinetic constant reached 0.1956 min⁻¹) and stability when compared to Ag₃PO₄, NiFe₂O₄, and Ag₃PO₄/NiFe₂O₄ for rhodamine B (RhB) degradation. Furthermore, by electrochemical and fluorescence measurements, the Ag₃PO₄/GO/NiFe₂O₄ (8%) material also showed larger transient photocurrent, lower impedance, and longer fluorescence lifetime (7.82 ns). Comparing the activity result dependence with characterization results, it was indicated that photocatalytic activity depended on fast charge transfer from Ag₃PO₄ to NiFe₂O₄ through GO sheet. The h⁺ and ·O₂⁻ species played important roles in RhB degradation under visible-light. A possible Z-scheme mechanism is proposed over the Ag₃PO₄/GO/NiFe₂O₄ (8%) composite. This study might provide a promising visible light responsive photocatalyst for the photocatalytic degradation of organic dyes in wastewater.

Effective visible-light-driven Ag₃PO₄/GO/NiFe₂O₄Z-scheme magnetic composites were successfully fabricated by a simple ion-exchange deposition method. The composites exhibited excellent photocatalytic activity and stability for RhB degradation.     

A one-pot synthesis of AgBr/Ag3PO4 composite photocatalysts

In this study, an AgBr/Ag₃PO₄ (ABAP) photocatalyst has been prepared via a facile one-pot anion-exchange method. SEM, XRD, XPS and UV-Vis DRS characterization techniques are carried out to study the structural and physicochemical characteristics of the AgBr/Ag₃PO₄ composites. The ABAP photocatalyst exhibited outstanding photocatalytic capability for the photodegradation of rhodamine B (RhB) under visible light irradiation. The optimal ABAP-48% composite displayed the highest photocatalytic activity; a complete degradation was attained in 25 min under visible light irradiation. The excellent stability and reusability of ABAP catalysts were examined by five subsequent runs. A probable degradation mechanism of ABAP composites was carefully surveyed. Furthermore, radical trapping experiments confirmed that the ˙O₂⁻ radical was the main active species in the photodegradation reaction.

In this study, an AgBr/Ag₃PO₄ (ABAP) photocatalyst has been prepared via a facile one-pot anion-exchange method.     

TiO2 nanofibres decorated with green-synthesized PAu/Ag@CQDs for the efficient photocatalytic degradation of organic dyes and pharmaceutical drugs

Organic pollutants such as dyes and pharmaceutical drugs have become an environmental menace, particularly in water bodies owing to their unregulated discharge. It is thus required to develop an economically viable and environment-friendly approach for their degradation in water bodies. In this study, for the first time, we report green route-synthesized plasmonic nanostructures (P_M-CQDs (where M: Au and Ag)) decorated onto TiO₂ nanofibers for the treatment of toxic dye- and pharmaceutical drug-based wastewater. P_M-CQDs are efficaciously synthesized using carbon quantum dots (CQDs) as the sole reducing and capping agent, wherein CQDs are derived via a green synthesis approach from Citrus limetta waste. The characteristic electron-donating property of CQDs played a key role in the reduction of Au³⁺ to Au⁰ and Ag⁺ to Ag⁰ under visible light irradiation to obtain P_Au-CQDs and P_Ag-CQDs, respectively. Thus, the obtained CQDs, P_Au-CQDs, and P_Ag-CQDs are loaded onto TiO₂ nanofibers to obtain a P_M-CQD/TiO₂ nanocomposite (NC), and are further probed via transmission electron microscopy, scanning electron microscopy and UV-visible spectrophotometry. The degradation of organic pollutants and pharmaceutical drugs using methylene blue and erythromycin as model pollutants is mapped with UV-vis and NMR spectroscopy. The results demonstrate the complete MB dye degradation in 20 minutes with 1 mg mL⁻¹ of P_Au-CQD/TiO₂ NC, which otherwise is 30 minutes for P_Ag@CQD/TiO₂ dose under visible light irradiation. Similarly, the pharmaceutical drug was found to degrade in 150 minutes with P_Au-CQD/TiO₂ photocatalysts. These findings reveal the enhanced photocatalytic performance of the green-synthesized Au decorated with TiO₂ nanofibers and are attributed to the boosted SPR effect and aqueous-phase stability of Au nanostructures. This study opens a new domain of utilizing waste-derived and green-synthesized plasmonic nanostructures for the degradation of toxic/hazardous dyes and pharmaceutical pollutants in water.

Citrus limetta waste-derived plasmonic nanostructures for photocatalytic degradation of toxic dyes and pharmaceutical pollutants in water.     

Ag2O-decorated electrospun BiVO4 nanofibers with enhanced photocatalytic performance

Semiconductor photocatalysts are emerging as tools for pollutant degradation in industrial wastewater, air purification, antibacterial applications, etc. due to their use of visible light, which is abundant in sunlight. Here, we report a new type of p–n junction Ag₂O/BiVO₄ heterogeneous nanostructured photocatalyst with enhanced photocatalytic performance. P-type Ag₂O nanoparticles were in situ reduced and assembled on the surface of electrospun BiVO₄ nanofibers using ultraviolet (UV) irradiation; this process hindered the recombination of localized photogenerated electron–hole pairs, and hence resulted in the enhanced photocatalytic activity of the BiVO₄/Ag₂O nanocomposites. The photocatalytic activities of the obtained BiVO₄ and BiVO₄/Ag₂O nanocomposites were assessed by measuring the degradation of rhodamine B (RhB) under visible light. The 10 wt% Ag₂O/BiVO₄ sample yielded the optimum degradation of RhB (98.47%), much higher than that yielded by pure BiVO₄ nanofibers (64.67%). No obvious change in the XRD pattern of an Ag₂O/BiVO₄ sample occurred as a result of its use in the photocatalytic reaction, indicating its excellent stability. The high photocatalytic performance observed was attributed to the large surface-to-volume ratio of the essentially one-dimensional electrospun BiVO₄ nanofibers and to the in situ growth of p-type Ag₂O on the surface of the n-type BiVO₄ nanofibers.

Ag₂O doped electrospun BiVO₄ nanofibers with p–n junction heterogeneous structures show enhanced photocatalytic activity under visible light (photocatalytic efficiency: 98.47% within 100 min) and good cycling stability.     

Fabrication of Ag/AgBr/Ag3VO4 composites with high visible light photocatalytic performance

Herein, Ag/AgBr/Ag₃VO₄ composites were synthesized by a simple continuous precipitation method. The obtained composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectroscopy and photoluminescence spectroscopy (PL). Photocatalytic performance of the composites was assessed by the degradation of methyl orange (MO) and tetracycline hydrochloride (TC) under visible light, and the effects of different nominal mass ratios of AgBr and Ag₃VO₄ on the photocatalytic activity were investigated. The results showed that after 20 min of visible light irradiation (λ > 420 nm), the removal rate of MO in the presence of a 5 : 1 sample reached 98.6%. The EIS and photocurrent results demonstrated that the enhancement of the visible light photocatalytic activity was attributed to the efficient electron–hole pair separation. In addition, the scavenging reactions conducted via the addition of different scavengers confirmed that h⁺ and ·O²⁻ were the main active species in the reaction. The present study offers potential for the degradation of contaminants.

Ag/AgBr/Ag₃VO₄ composites were synthesized by a simple continuous precipitation method, which were used to degrade organic pollutants and found to have excellent photocatalytic properties.     

ZnO/Ag/Ag2WO4 photo-electrodes with plasmonic behavior for enhanced photoelectrochemical water oxidation

Ag-based compounds are excellent co-catalyst that can enhance harvesting visible light and increase photo-generated charge carrier separation owing to its surface plasmon resonance (SPR) effect in photoelectrochemical (PEC) applications. However, the PEC performance of a ZnO/Ag/Ag₂WO₄ heterostructure with SPR behavior has not been fully studied so far. Here we report the preparation of a ZnO/Ag/Ag₂WO₄ photo-electrode with SPR behavior by a low temperature hydrothermal chemical growth method followed by a successive ionic layer adsorption and reaction (SILAR) method. The properties of the prepared samples were investigated by different characterization techniques, which confirm that Ag/Ag₂WO₄ was deposited on the ZnO NRs. The Ag₂WO₄/Ag/ZnO photo-electrode showed an enhancement in PEC performance compared to bare ZnO NRs. The observed enhancement is attributed to the red shift of the optical absorption spectrum of the Ag₂WO₄/Ag/ZnO to the visible region (>400 nm) and to the SPR effect of surface metallic silver (Ag⁰) particles from the Ag/Ag₂WO₄ that could generate electron–hole pairs under illumination of low energy visible sun light. Finally, we proposed the PEC mechanism of the Ag₂WO₄/Ag/ZnO photo-electrode with an energy band structure and possible electron–hole separation and transportation in the ZnO/Ag/Ag₂WO₄ heterostructure with SPR effect for water oxidation.

Ag-based compounds are excellent co-catalyst that can enhance harvesting visible light and increase photo-generated charge carrier separation owing to its surface plasmon resonance (SPR) effect in photoelectrochemical (PEC) applications.     

Immobilized Ag3PO4/GO on 3D nickel foam and its photocatalytic degradation of norfloxacin antibiotic under visible light

In this study, a series of Ag₃PO₄/graphene oxide (GO) films were dip-coated on a metal nickel foam. The immobilized catalysts were characterized by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, ultraviolet-visible spectroscopy, Raman spectroscopy, high-resolution transmission electron microscopy and photoluminescence spectroscopy. The results show that Ag₃PO₄/GO was successfully supported on a nickel foam. The photocatalytic activity of the film catalyst under visible light was investigated by the degradation of norfloxacin, an antibiotic. Photocatalytic stability of this catalyst was also investigated. An optimized film exhibited superior activity and stability, the degradation rate of norfloxacin was about 83.68% in 100 min and the reaction rate constant k was 1.9 times that of pristine Ag₃PO₄. Further investigation found that photo-generated holes (h⁺) and superoxide anion radicals (·O₂⁻) are the main active species in the photodegradation process. The result indicates that the addition of GO inhibits the recombination of photogenerated electron–hole pairs, and thus has improved the photocatalytic activity and cyclic stability under visible light. The photocatalytic mechanism of the film catalyst was proposed. The prepared Ag₃PO₄/GO film catalyst is a promising candidate for treatment of wastewater containing antibiotics.

A series of Ag₃PO₄/graphene oxide catalysts were dip-coated onto 3D nickel foam for photocatalytic degradation of norfloxacin antibiotics.     

Enhanced photocatalytic activity of TiO2/UiO-67 under visible-light for aflatoxin B1 degradation

TiO₂ has great potential in photocatalytic degradation of organic pollutants, but poor visible light response and low separation efficiency of photogenerated electron–hole pairs limit its wide applications. In this study, we have successfully prepared TiO₂/UiO-67 photocatalyst through an in situ solvothermal method. The degradation rate of aflatoxin B1 (AFB1) is 98.9% in only 80 min, which is superior to the commercial P25, commercial TiO₂ and most of reported photocatalysts under visible light irradiation. In addition, the TiO₂/UiO-67 photocatalyst showed excellent recyclability. We demonstrated that the enhanced photocatalytic mechanism was owing to the heterojunction between TiO₂ and UiO-67, which enhanced effectively the separation photogenerated charge carriers and visible light response. The free radical trapping tests demonstrated that superoxide radicals (˙O₂⁻), holes (h⁺) and hydroxyl radicals (˙OH) were the main active species and then oxidized AFB1 to some small molecules.

Enhanced photocatalytic activity of TiO₂/UiO-67 under visible-light for aflatoxin B1 degradation.     

A hybrid design of Ag-decorated ZnO on layered nanomaterials (MgAC) with photocatalytic and antibacterial dual-functional abilities

In this work, Ag@ZnO and Ag@ZnO/MgAC photocatalysts were synthesized using a simple two-step electrochemical method by the addition of magnesium aminoclay (MgAC) as a great stabilizer and a Lewis base, which could donate electrons for reduction of Ag⁺ and Zn²⁺ ions, facilitating uniform formation as well as effective inhibition of aggregation of Ag@ZnO nanoparticles (NPs) on the MgAC matrix. Ag@ZnO and Ag@ZnO/MgAC were investigated for photocatalytic degradation of MB and their antibacterial efficiencies. Ag@ZnO/MgAC showed excellent photocatalytic MB degradation with a performance of 98.56% after 80 min of visible-light irradiation and good antibacterial activity against Salmonella (Sal) and Staphylococcus aureus (S. aureus) bacterial strains, providing promising high application potential. Herein, different from the bare ZnO NPs, for Ag@ZnO/MgAC nanocomposites, Ag@ZnO NPs functioned as an effective photocatalyst under visible light illumination, in which, incorporated Ag atoms in the ZnO crystal structure caused the increase in a larger number of lattice defect sites. Benefiting from the strong surface plasmon resonance (SPR) effect of Ag and energy band matching between ZnO and Ag, the visible light absorption capacity and the separation of the photogenerated charge carriers were promoted. Therefore, the MB degradation efficiency of Ag@ZnO/MgAC was considerably accelerated in the presence of produced radicals from visible light illumination.

Dual-functional Ag@ZnO/MgAC nanocomposites for photocatalytic and antibacterial applications synthesized by a simple two-step electrochemical method.     

Versatility of CoPcS in CoPcS/TiO2 for MB degradation: photosensitization,charge separation and oxygen activation

In this report, a composite photocatalyst consisting of cobalt phthalocyanine sulfate (CoPcS) and TiO₂ was prepared by a facile synthesis. Careful characterizations and measurements indicate a covalent grafting of CoPcS onto TiO₂ through Ti–O–S linkages, acquiring an intimate heterojunction between TiO₂ and CoPcS. The obtained composite was evaluated for its photocatalytic activity toward the degradation of methyl blue (MB) under visible light irradiation. The evaluation showed a significantly enhanced degradation rate of MB by CoPcS/TiO₂. The improved photocatalytic performance of CoPcS/TiO₂ was attributed to the photosensitization of TiO₂ by CoPcS, charge separation by electron transfer at the interface of the heterojunction formed between CoPcS and TiO₂, and oxygen activation via CoPcS. A synergetic mechanism in improving the photocatalytic performance of TiO₂ by CoPcS was investigated.

In this report, a composite photocatalyst consisting of cobalt phthalocyanine sulfate (CoPcS) and TiO₂ was prepared by a facile synthesis.     

The structure and self-regeneration performance of Salix psammophila-activated carbon modified by Ag and N co-doped TiO2

In this study, Salix psammophila activated carbon (AC) was modified by immersing it in an AgNO₃ solution and coating it with an N-doped TiO₂ film to improve its self-regeneration performance in visible light. Ag⁺ was adsorbed and reduced to Ag nanoparticles by AC. Ti element only existed as Ti⁴⁺, and N element was incorporated into TiO₂ mainly in the form of interstitial nitrogen. The photodegradation of Ag-N-TiO₂-AC (AC coated with Ag and N co-modified TiO₂) was enhanced under visible light irradiation because of its three inherent structures: (1) Ag and N co-modified TiO₂ had a smaller average crystal size; (2) with a low bandgap (1.59 eV), the photoresponse region of Ag and N co-modified TiO₂ was greatly extended; (3) the lifetime of the photogenerated holes was increased. With the increase in the AgNO₃ dosage, the Ag-N-TiO₂-AC photodegradation increased, while its adsorption decreased. Because of these synergistic effects, 0.05Ag-0.1N-TiO₂-AC (where 0.05 is the dosage of AgNO₃, g) presented the best self-regeneration performance under visible light irradiation.

In this study, Salix psammophila activated carbon (AC) was modified by immersing it in an AgNO₃ solution and coating it with an N-doped TiO₂ film to improve its self-regeneration performance in visible light.     

A green approach for the synthesis of novel Ag3PO4/SnO2/porcine bone and its exploitation as a catalyst in the photodegradation of lignosulfonate into alkyl acids

A novel Ag₃PO₄/SnO₂/porcine bone composite photocatalyst was successfully prepared via an ion exchange method, which can convert lignin derivatives into small molecular acids upon exposure to visible light at room temperature at ambient pressure. The composition characterization, optical absorption properties and photocatalytic activities of the Ag₃PO₄/SnO₂/porcine bone composites were thoroughly investigated. The certain role of each component of the composites in the degradation reaction was discussed: Ag₃PO₄ acted as the major active component, while SnO₂ and porcine bone as cocatalyst contributed to improve the photocatalytic activity and stability of Ag₃PO₄. The enhanced activity of the Ag₃PO₄/SnO₂/porcine bone composite may be attributed to the synergistic effect including the matched energy band structures of Ag₃PO₄ and SnO₂ for the decrease in the probability of electron–hole recombination and improved performance in the presence of hierarchical porous porcine bone (hydroxyapatite). This paper also analyzed the change of the molecular weight and structure of sodium lignin sulfonate in the photocatalytic reaction and discussed the possible photocatalytic mechanism of the photocatalyst composite, indicating that the benzene rings of guaiacol were oxidized into different alkyl acids (maleic acid, oxalic acid, formic acid and methoxy acetic acid).

A novel Ag₃PO₄/SnO₂/porcine bone photocatalyst was synthesized for mild depolymerization of lignosulfonate, providing a green approach to utilize lignin derivatives.     

Preparation and visible-light photocatalytic properties of the floating hollow glass microspheres – TiO2/Ag3PO4 composites

A novel floating visible-light photocatalyst (HGMs–TiO₂/Ag₃PO₄) composite was prepared using amino modified low-density hollow glass microspheres (HGMs) as carriers to disperse and support TiO₂ and Ag₃PO₄ photocatalysts. The surface morphology, crystal structure and optical properties of the HGMs–TiO₂/Ag₃PO₄ composites were characterized and the Ag₃PO₄ content on the surface of the microspheres was determined by atomic absorption spectrometry (AAS). Methylene blue (MB) was chose as the organic pollutant to investigate the visible-light catalytic properties of the HGMs–TiO₂/Ag₃PO₄ composites. For HGM composite photocatalysts, when the theoretical mass ratio of TiO₂ to Ag₃PO₄ on the surface of HGMs is 1 : 1.5, the visible-light catalytic activity of the composite is superior to pure Ag₃PO₄ and a TiO₂/Ag₃PO₄ photocatalyst with a mass ratio of 1 : 1.5 under the same conditions, due to the increased light-contact area and the photocatalytic active sites, since the TiO₂ and Ag₃PO₄ particles can be well dispersed on the surface of the floating HGMs. Furthermore, the deposits of TiO₂ and Ag₃PO₄ on the HGM surface form a heterostructure, facilitating the separation of electron–hole (e⁻ – h⁺) in the energy band, and elevating the photocatalytic activity and cycle stability of Ag₃PO₄. This work indicates that floating HGMs–TiO₂/Ag₃PO₄ composites could become a promising photocatalyst for organic dye removal due to the low cost and high visible-light responsiveness.

The amino modified low-density hollow glass microspheres were used as carriers of TiO₂ and Ag₃PO₄ photocatalysts to prepare the floating visible-light photocatalyst composite.     

Rational design of a polypyrrole-based competent bifunctional magnetic nanocatalyst

The combination of conducting polymers with semiconductors for the fabrication of organic/inorganic hybrid nanocatalysts is one of the most promising research areas for many applications. In this work, the synthesized nanocomposite combines several advantages such as the photoresponse shift from the UV region toward visible light by narrowing the band gap of the semiconductor, magnetic separation ability and dual applications including the catalytic reduction of p-nitrophenol (PNP) and the photocatalytic degradation of methylene blue (MB) dye. In addition to the core magnetite nanoparticles (NPs), the synthesized nanocomposite contains polypyrrole (PPY) and TiO₂ shells that are decorated with silver metal NPs to prevent electron–hole recombination and to enhance the catalytic performance. Indeed, the catalytic PNP reduction experiments reveal that the synthesized nanocomposite exhibits significantly high catalytic activity with a rate constant of 0.1169 min⁻¹. Moreover, the photocatalytic experiments show that the synthesized nanophotocatalyst has a boosting effect toward MB dye degradation under normal daytime visible light irradiation with a rate constant of 6.38 × 10⁻² min⁻¹. The synergetic effect between silver NPs, PPY and TiO₂ is thought to play a fundamental role in enhancing the photocatalytic activity.

An efficient method to synthesize a magnetic nanocomposite with dual catalytic activities with a synergetic effect between Ag nanoparticles, polypyrrole and TiO₂ is described.     

Visible-light-driven Ag/Bi3O4Cl nanocomposite photocatalyst with enhanced photocatalytic activity for degradation of tetracycline

In this study, a novel Ag/Bi₃O₄Cl photocatalyst has been synthesized by a facile photodeposition process. Its photocatalytic performance was evaluated from the degradation of tetracycline (TC) under visible light irradiation (λ > 420 nm). The 1.0 wt% Ag/Bi₃O₄Cl photocatalyst could significantly enhance the degradation of TC compared with pure Bi₃O₄Cl, with the degradation level reaching 94.2% in 120 minutes. The enhancement of photocatalytic activity could be attributed to the synergetic effect of the photogenerated electrons (e⁻) of Bi₃O₄Cl and the surface plasmon resonance (SPR) caused by Ag nanoparticles, which could improve the absorption capacity of visible light and facilitate the separation of photogenerated electron–hole pairs. In addition, electron spin resonance (ESR) analysis and trapping experiments demonstrated that the superoxide radicals (˙O²⁻), hydroxyl radicals (˙OH) and holes (h⁺) played crucial roles in the photocatalytic process of TC degradation. The present work provides a promising approach for the development of highly efficient photocatalysts to address current environmental pollution, energy issues and other related areas.

A novel Ag/Bi₃O₄Cl photocatalyst has been synthesized by a facile photodeposition process. The Ag/Bi₃O₄Cl photocatalyst exhibited excellent photocatalytic activity for the degradation of tetracycline.