Environment-friendly magnetic Fe–Ce–W catalyst for the selective catalytic reduction of NOx with NH3: influence of citric acid content on its activity-structure relationship

The influence of the citric acid content on the structural and redox properties of a magnetic iron–cerium–tungsten mixed oxide catalyst prepared through a microwave-assisted citric acid sol–gel method is investigated via TG–DTG–DSC, XRD, N₂ adsorption–desorption, XPS, H₂-TPR and NH₃-TPD. Additionally, the NH₃-SCR activity of the magnetic FeCeW-m (m = 0.25, 0.5 and 1.0) catalysts are also studied. The results indicate that an increase in citric acid content strengthens the sol–gel reaction between citric acid and metal ions and promotes the formation of the γ-Fe₂O₃ crystallite not α-Fe₂O₃. Meanwhile, it decreases the BET surface area and pore volume of the catalyst. Furthermore, the surface concentration of iron species on the catalyst is enhanced when the molar ratio of citric acid/(Fe + Ce + W) increases from 0.25 to 1.0, but its surface absorbed oxygen and total oxygen concentration decrease. The magnetic FeCeW-0.5 catalyst shows the best reducibility at temperatures below 790 °C. The increase in the citric acid content inhibits the formation of acid sites in the catalyst, thus the magnetic FeCeW-0.25 catalyst possesses the most Lewis acid sites and Brønsted acid sites among the catalysts. The enhancement in citric acid content is beneficial to improve the SCR reaction rates normalized by the surface area of the catalyst. This catalyst exhibits high anti-SO₂ and H₂O poisoning, and the molar ratio of citric acid/(Fe + Ce + W) affects the adsorption of NO_x species on its surface.

The enhancement of critic acid amount strengthened the sol–gel reaction between critic acid and metal ions, showed an important role on the structure properties of magnetic Fe–Ce–W mixed oxide catalyst, thereby affected its NH₃-SCR activity.     

Hydrophobic mesoporous silicon dioxide for improving foam stability

In this study, mesoporous SiO₂ nanoparticles (MSNs) were synthesized via a sol–gel method and modified with (3-chloropropyl) trimethoxysilane to make them hydrophobic (MMSNs). The material was characterized via SEM, TEM, FT-IR, DLS, BET and contact angle measurements. The MMSNs have good foam stability, so that the foam properties of the added particles have been increased by 38.4% in an oil/SDS solution. Simultaneously, it becomes a promising material for foam stabilization in order to enhance the oil recovery because it is bio-compatibile and environment friendly. Also, it provides a novel application-stable foam for mesoporous materials.

In this study, mesoporous SiO₂ nanoparticles (MSNs) were synthesized via a sol–gel method and modified with (3-chloropropyl) trimethoxysilane to make them hydrophobic (MMSNs).     

Facile and rapid synthesis of a novel spindle-like heterojunction BiVO4 showing enhanced visible-light-driven photoactivity

A spindle-like monoclinic–tetragonal heterojunction BiVO₄ was successfully synthesized by a pressure-controllable microwave method. The as-prepared BiVO₄ samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectroscopy (DRS), photoluminescence (PL) spectroscopy, transient photocurrent responses and electrochemical impedance spectroscopy (EIS). The visible-light-driven photocatalytic activity of the BiVO₄ samples was evaluated for the degradation of Rhodamine B (RhB) and tetracycline (TC). The synthesis process needs microwave irradiation for only 10 min without the addition of any auxiliary reagent, pH adjustment, and calcination. The as-prepared spindle-like monoclinic–tetragonal heterojunction BiVO₄ exhibits excellent photocatalytic activity for the degradation of both RhB and TC. The photocatalytic degradation rates of RhB and TC over spindle-like BiVO₄ are 1.77 and 1.64 times higher, respectively, than that measured over monoclinic BiVO₄. The enhanced photocatalytic activity is mainly attributed to the fact that the existence of a heterojunction effectively promotes the separation of photo-generated carriers and extends the visible-light absorption of BiVO₄.

A novel spindle-like monoclinic–tetragonal BiVO₄ heterojunction is rapidly synthesized via a pressure-controllable microwave method.     

Organic–inorganic hybridization for the synthesis of robust in situ hydrophobic polypropylsilsesquioxane aerogels with fast oil absorption properties

In situ hydrophobic polypropylsilsesquioxane aerogels (PSAs) were successfully synthesized via an organic–inorganic hybridization method by a sol–gel process, in which propyltriethoxysilane (PTES) and tetraethylorthosilicate (TEOS) were used as co-precursors. ²⁹Si NMR and FTIR analyses indicated the high degree of condensation of the precursors and proved the attachment of propyl (–C₃H₇) groups in PSAs, respectively. By means of incorporating propyl groups, both mechanical robustness and in situ hydrophobicity were obtained. Meanwhile, the mechanical strength, contact angle and density obviously increased with the increase in propyl groups. Under optimized conditions, as-prepared PSA could endure up to a 70% maximum linear compression with few cracks. Benefiting from the robust structure and in situ hydrophobicity, PSAs showed high absorption capacities (8–10 times that of its own weight) and fast absorption properties (<20 s) for a wide range of organic solvents and could be reused at least 5 times.

In situ hydrophobic and mechanically robust polypropylsilsesquioxane aerogels (PSAs) were successfully synthesized via an organic–inorganic hybridization method by a sol–gel process.     

Role of annealing temperature on the sol–gel synthesis of VO2 nanowires with in situ characterization of their metal–insulator transition

Among the techniques to create VO₂ nanostructures, the sol–gel method is the most facile and benefits from simple, manipulable synthetic parameters. Here, by utilizing various TEM techniques, we report the sequential morphological evolution of VO₂ nanostructures in a sol–gel film spin-coated on a customized TEM grid, which underwent oxygen reduction as the annealing temperature increased. In situ TEM dark-field imaging and Raman spectroscopy allowed us to confirm the sharp phase transition behavior of an individual nanowire by illustrating the effect of electrode-clamping-induced tensile stress on the nucleation of the R phase from the M1 phase. The electrical transport properties of a single-nanowire device fabricated on a customized TEM grid showed excellent control of the stoichiometry and crystallinity of the wire. These results offer critical information for preparing tailored VO₂ nanostructures with advanced transition properties by the sol–gel method to enable the fabrication of scalable flexible devices.

The single-VO₂ nanowire device synthesized via sequential morphological evolutions with oxygen reduction during annealing features a sharp metal-insulator transition.     

Synthesis of highly crystalline LaFeO3 nanospheres for phenoxazinone synthase mimicking activity

LaFeO₃ nanospheres with an orthorhombic perovskite structure were synthesized by a sol–gel autocombustion method in the presence of different citric acid ratios (x = 2, 4, 8, and 16) and utilized for the photocatalytic conversion of o-aminophenol (OAP) to 2-aminophenoxazine-3-one (APX) for the first time. OAP is one of the most toxic phenolic derivatives used as a starting material in many industries; however, the dimerization product APX has diverse therapeutic properties. Photocatalytic conversion was carried out in ethanol/water and acetonitrile/water mixtures in the absence and presence of molecular oxygen at ambient temperature via the oxidative coupling reaction that mimics phenoxazinone synthase-like activity. The LaFeO₃ samples showed a superior photocatalytic activity of OAP to APX with rate constants of 0.43 and 0.92 min⁻¹ in the absence and presence of molecular oxygen, respectively. Thus, the LaFeO₃ nanozymes could be used as promising candidates in industrial water treatment and phenoxazinone synthase-like activity.

LaFeO₃ nanospheres were synthesized by a facile sol–gel autocombustion method and explored for the photocatalytic transformation of o-aminophenol to 2-aminophenoxazine-3-one.     

A novel MnO–CrN nanocomposite based non-enzymatic hydrogen peroxide sensor

A MnO–CrN composite was obtained via the ammonolysis of the low-cost nitride precursors Cr(NO₃)₃·9H₂O and Mn(NO₃)₂·4H₂O at 800 °C for 8 h using a sol–gel method. The specific surface area of the synthesized powder was measured via BET analysis and it was found to be 262 m² g⁻¹. Regarding its application, the electrochemical sensing performance toward hydrogen peroxide (H₂O₂) was studied via applying cyclic voltammetry (CV) and amperometry (i–t) analysis. The linear response range was 0.33–15 000 μM with a correlation coefficient (R²) value of 0.995. Excellent performance toward H₂O₂ was observed with a limit of detection of 0.059 μM, a limit of quantification of 0.199 μM, and sensitivity of 2156.25 μA mM⁻¹ cm⁻². A short response time of within 2 s was achieved. Hence, we develop and offer an efficient approach for synthesizing a new cost-efficient material for H₂O₂ sensing.

A MnO–CrN composite was obtained via the ammonolysis of the low-cost nitride precursors Cr(NO₃)₃·9H₂O and Mn(NO₃)₂·4H₂O at 800 °C for 8 h using a sol–gel method.     

Synthesis of a hierarchical carbon fiber@cobalt ferrite@manganese dioxide composite and its application as a microwave absorber

In this study, a novel hierarchical carbon fiber@cobalt ferrite@manganese dioxide (CF@CoFe₂O₄@MnO₂) composite was facilely prepared via a sol–gel method and hydrothermal reaction. The morphology, structure, chemical and element composition, crystal form, elemental binding energy, magnetic behavior and microwave absorbing performance of the composite were carefully investigated. According to its hysteresis loops, the composite exhibits a typical soft magnetic behavior, with a M_s value of 30.2 emu g⁻¹. Besides, the as-synthesized CF@CoFe₂O₄@MnO₂ composite exhibits superior microwave absorption performance mainly due to reasonable electromagnetic matching, and its minimum reflection loss value can reach −34 dB with a sample thickness of just 1.5 mm. The composite can be regarded as an ideal microwave absorber.

In this study, a novel hierarchical carbon fiber@cobalt ferrite@manganese dioxide (CF@CoFe₂O₄@MnO₂) composite was facilely prepared via a sol–gel method and hydrothermal reaction.     

The preparation of MgO nanopowders synthesized via an improved polyacrylamide gel method

In order to address the issue of metal ion incorporation during polymerization, citric acid was used as a chelating agent to improve the polyacrylamide gel route. In the present work, MgO nanoparticles were synthesized via this improved method. The calcination temperature of the gel precursor containing magnesium nitrate was determined by thermogravimetry and differential scanning calorimetry (TG-DSC). The phases and microstructures of MgO nanopowders were identified via X-ray diffraction (XRD), transmission electron microscopy (TEM) and specific surface area measurements (BET). The results showed that the nanoparticles synthesized under 600 °C were pure, globular and about 5–20 nm in size with a narrow distribution. Furthermore, the coalescence and growth of the MgO nanograins were amazingly observed with increasing calcination temperatures and calcination time. The influence of calcination temperature on the morphology and growth behavior is greater than that of the calcination duration. The activation energy for grain growth was estimated to be 31.43 kJ mol⁻¹, and the dominant growth mechanism was predicted to be related to the grain-rotation-induced grain coalescence (GRIGC) mechanism.

In order to address the issue of metal ion incorporation during polymerization, citric acid was used as a chelating agent to improve the polyacrylamide gel route.     

Mechanistic insight into the non-hydrolytic sol–gel process of tellurite glass films to attain a high transmission

The development of amorphous films with a wide transmission window and high refractive index is of growing significance due to the strong demand of integrating functional nanoparticles for the next-generation hybrid optoelectronic films. High-index TeO₂-based glass films made via the sol–gel process are particularly suitable as their low temperature preparation process promises high compatibility with a large variety of nanoparticles and substrates that suffer from low thermal stability. However, due to the lack of in-depth understanding of the mechanisms of the formation of undesired metallic-Te (highly absorbing species) in the films, the preparation of high-transmission TeO₂-based sol–gel films has been severely hampered. Here, by gaining insight into the mechanistic chemistry of metallic-Te formation at different stages during the non-hydrolytic sol–gel process, we identify the chemical route to prevent the generation of metallic-Te in a TeO₂-based film. The as-prepared TeO₂-based film exhibits a high transmission that is close to the theoretical limit. This opens up a new avenue for advancing the performance of hybrid optoelectronic films via incorporating a large variety of unique nanoparticles.

This work develops a high-transparency amorphous film with a wide transmission window and high refractive index, which can potentially meet the strong demand of integrating functional nanoparticles for the next-generation hybrid optoelectronic films.     

In situ synthesis of C-doped BiVO4 with natural leaf as a template under different calcination temperatures

In this work, a series of C-doped BiVO₄ (BiVO₄-T) with natural leaf structures were synthesized by a dipping-calcination method with the leaf of Chongyang wood seedling as a template under different calcination temperatures. The structures and morphologies of BiVO₄-T were observed by FE-SEM observations. The doped carbon in BiVO₄-T was formed in situ from the natural leaf during the calcination process and the amount of doping could be regulated from 0.51–1.16 wt% by controlling the calcination temperature. It was found that the sample calcined at 600 °C (BiVO₄-600) with a C-doping content of 1.16 wt% showed the best photocatalytic degradation activity. After 120 min visible light irradiation, the photocatalytic decomposition efficiency of RhB for BiVO₄-600 is 2.2 times higher than that of no template BiVO₄. The enhanced photocatalytic performance is ascribed to the combined action of the unique morphology and doped-carbon. It is considered that the unique structures and carbon doping of BiVO₄-600 are in favor of the enhancement of visible light absorption, which was supported by UV-vis DRS. Furthermore, the C-doping can enhance the efficient separation and transfer of the photo-generated electron–hole pairs, as proved by PL measurements. This study provides a simple dipping-calcination method and found the best calcination temperature to fabricate a high-performance BiVO₄, which simultaneously achieves morphology and C-doping control in one step.

A series of C-doped BiVO₄ with natural leaf as a template were synthesized under different calcination temperatures by the dipping-calcination method, which simultaneously achieves morphology and C-doping control in one step.     

Efficient charge separation and transfer of a TaON/BiVO4 heterojunction for photoelectrochemical water splitting

The separation and transfer of photogenerated electron–hole pairs in semiconductors is the key point for photoelectrochemical (PEC) water splitting. Here, an ideal TaON/BiVO₄ heterojunction electrode was fabricated via a simple hydrothermal method. As BiVO₄ and TaON were in well contact with each other, high performance TaON/BiVO₄ heterojunction photoanodes were constructed. The photocurrent of the 2-TaON/BiVO₄ electrode reached 2.6 mA cm⁻² at 1.23 V vs. RHE, which is 1.75 times as that of the bare BiVO₄. TaON improves the PEC performance by simultaneously promoting the photo-generated charge separation and surface reaction transfer. When a Co-Pi co-catalyst was integrated onto the surface of the 2-TaON/BiVO₄ electrode, the surface water oxidation kinetics further improved, and a highly efficient photocurrent density of 3.6 mA cm⁻² was achieved at 1.23 V vs. RHE. The largest half-cell solar energy conversion efficiency for Co-Pi/TaON/BiVO₄ was 1.19% at 0.69 V vs. RHE, corresponding to 6 times that of bare BiVO₄ (0.19% at 0.95 V vs. RHE). This study provides an available strategy to develop photoelectrochemical water splitting of BiVO₄-based photoanodes.

TaON/BiVO₄ heterojunction electrodes exhibited significant enhancement in the photoelectrochemical water oxidation.     

Bimetallic phosphide decorated Mo–BiVO4 for significantly improved photoelectrochemical activity and stability

Bismuth vanadate photoanode has shown great potential for photoelectrochemical (PEC) catalysis, but it needs to be further modified because of its relatively low charge-separation efficiency and poor stability. Herein, the bimetallic phosphide NiCoP decorated Mo–BiVO₄ is fabricated through the electrodeposition and drop-casting method, which significantly improves the charge separation and surface oxidation reaction. Therefore, the fabricated NiCoP/Mo–BiVO₄ photoanode exhibits a low onset potential of 0.21 V (vs. RHE) and high photocurrent of 3.21 mA cm⁻² at 1.23 V (vs. RHE), which is 3.12 times higher than that of pure BiVO₄. Importantly, the decoration of NiCoP significantly improve the stability of BiVO₄ photoanode.

Bimetallic phosphide NiCoP decorated Mo–BiVO₄ photoanode was fabricated, and showed significantly improved photoelectrochemical activity and stability.     

Regenerable g-C3N4–chitosan beads with enhanced photocatalytic activity and stability

In this study, a series of regenerable graphitic carbon nitride–chitosan (g-C₃N₄–CS) beads were successfully synthesized via the blend crosslinking method. The prepared beads were characterized by scanning electron microscopy (SEM), thermogravimetric analysis (TGA), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), diffuse reflectance spectroscopy (DRS), photoluminescence (PL) spectroscopy, and X-ray photoelectron spectroscopy (XPS). The structural characterization results indicate that the g-C₃N₄ granules were uniformly distributed on the surface of the chitosan matrix, and the structures of g-C₃N₄ and CS are maintained. In addition, the prepared g-C₃N₄–CS beads exhibited efficient MB degradation and stability. The optimum photocatalytic activity of our synthesized g-C₃N₄–CS beads was higher than that of the bulk g-C₃N₄ by a factor of 1.78 for MB. The improved photocatalytic activity was predominantly attributed to the synergistic effect between in situ adsorption and photocatalytic degradation. In addition, the reacted g-C₃N₄–CS beads can be regenerated by merely adding sodium hydroxide and hydrogen peroxide. Additionally, the regenerated g-C₃N₄–CS beads exhibit excellent stability after four runs, while the mass loss is less than 10%. This work might provide guidance for the design and fabrication of easily regenerated g-C₃N₄-based photocatalysts for environmental purification.

In this study, a series of regenerable graphitic carbon nitride–chitosan (g-C₃N₄–CS) beads were successfully synthesized via the blend crosslinking method.     

The utilization of Fe-doped g-C3N4 in a heterogeneous photo-Fenton-like catalytic system: the effect of different parameters and a system mechanism investigation

In this study, a series of Fe-doped g-C₃N₄ (Fe–C₃N₄) samples was synthesized and characterized via X-ray powder diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflection spectroscopy (UV-vis DRS), and photoluminescence (PL) spectroscopy. The photocatalytic activity of the synthesized Fe–C₃N₄ was investigated toward methylene blue (MB) degradation with hydrogen peroxide (H₂O₂) assistance. The results showed that the Fe–C₃N₄ heterogeneous photo-Fenton-like system showed excellent catalytic performance when the pH value was varied from 3.0 to 9.0. Evaluating the effects of various inorganic anions in the Fe–C₃N₄ heterogeneous photo-Fenton-like system, HCO₃⁻ showed a dual effect on MB degradation, and Cl⁻ and NO₃⁻ showed an inhibitory effect on MB degradation. Evaluating the effects of inorganic cations, Al³⁺, Mg²⁺, and Ca²⁺ strongly inhibited MB degradation. Recycling experiments demonstrated that Fe–C₃N₄ possesses good reusability and stability. Quenching experiments were carried out, and it was found that hydroxyl radicals (·OH) were the primary active species in the system. Besides, nine intermediates were identified via LC/MS, and a possible MB degradation pathway in the system was proposed. This study could promote the application of this Fe–C₃N₄ heterogeneous photo-Fenton-like system in realistic dye wastewater.

The influence of reaction parameters, especially the presence of inorganic ions, on the activity of a Fe–C₃N₄ photo-Fenton system has been systematically studied.     

Fabrication,characterization and high photocatalytic activity of Ag–ZnO heterojunctions under UV-visible light

Pure ZnO and Ag–ZnO nanocomposites were fabricated via a sol–gel route, and the obtained photocatalysts were characterized by XRD, SEM, TEM, BET, XPS, PL and DRS. The results showed that Ag⁰ nanoparticles deposit on the ZnO surface and Ag modification has negligible impact on the crystal structure, surface hydroxyl group content and surface area of ZnO. However, the recombination of photogenerated electrons and holes was suppressed effectively by Ag loading. The photocatalytic activity was investigated by evaluating the degradation of MB under xenon lamp irradiation as the UV-visible light source, and the results show that the photocatalytic activity of ZnO significantly improved after Ag modification. Ag–ZnO photocatalysts exhibit higher photocatalytic activity than commercial photocatalyst P25. The degradation degree of MB for 1%Ag–ZnO was 97.1% after 15 min. ˙O₂⁻ radicals are the main active species responsible for the photodegradation process, and Ag–ZnO heterojunctions generate more ˙O₂⁻ radicals, which is the primary reason for the improved photocatalytic performance.

Ag–ZnO heterojunction promotes the separation of photogenerated pairs and thus exhibits high catalytic activity under UV-visible light.     

Z-scheme BiVO4/Ag/Ag2S composites with enhanced photocatalytic efficiency under visible light

The Z-scheme BiVO₄/Ag/Ag₂S photocatalyst was fabricated via a two-step route. The as-prepared samples were characterized by XRD, FE-SEM, HRTEM, XPS and UV-vis diffuse reflectance spectroscopy. The results of PL and photocurrent response tests demonstrate that the ternary BiVO₄/Ag/Ag₂S composites had a high separation and migration efficiency of photoexcited carriers. As a result, the ternary photocatalyst exhibits enhanced photocatalytic activity for decomposing Rhodamine B (RhB) under LED light (420 nm) irradiation. The results of trapping experiments demonstrate both h⁺ and ˙OH play crucial roles in decomposing RhB molecules. Additionally, the energy band structures and density of states (DOS) of BiVO₄ and Ag₂S were investigated via the density functional theory (DFT) method. Finally, a Z-scheme electron migration mechanism of BiVO₄ → Ag → Ag₂S was proposed based on the experimental and calculated results.

The Z-scheme BiVO₄/Ag/Ag₂S photocatalyst was fabricated via a two-step route.     

The design and growth of peanut-like CuS/BiVO4 composites for photoelectrochemical sensing

In this study, the CuS/BiVO₄-X (where X represents the mass percentage of CuS associated with CuS/BiVO₄; X = 2%, 5% and 7%) p–n heterostructures were fabricated using a two-step hydrothermal method. The structural and morphological features were ascertained in great detail using several physical characterization processes. According to the results of the photoelectrochemical (PEC) experimental processes, the PEC properties of CuS/BiVO₄-5% were much more obvious as compared to those of pure BiVO₄, CuS and CuS/BiVO₄-X. Moreover, the photoluminescence (PL) and UV-vis diffuse reflection spectra (DRS) affirmed that the CuS/BiVO₄-5% demonstrates an excellent capacity for absorbing visible light and low electron recombination rate as compared with the other composites. Accordingly, PEC sensors with CuS/BiVO₄-5% were fabricated for the detection of dopamine (DA) and bisphenol A (BPA) with outstanding selectivity and stability. For DA, it implied a broad linear range from 0.01–10 μM and 10–120 μM, and for BPA, the broad linear range was 0.01–90 μM. Thus, the PEC sensor has significant potential application when it comes to DA and BPA detection.

In this study, the CuS/BiVO₄-X (where X represents the mass percentage of CuS associated with CuS/BiVO₄; X = 2%, 5% and 7%) p–n heterostructures were fabricated using a two-step hydrothermal method.     

Co2+ substituted for Bi3+ in BiVO4 and its enhanced photocatalytic activity under visible LED light irradiation

We investigated the fabrication of Co-doped BiVO₄ (Bi_1−xCo_xVO_4+δ, 0.05 < x < 0.5) by the substitution of Co ions for Bi sites in BiVO₄. The X-ray diffraction (XRD), Raman, and X-ray photoelectron spectroscopy (XPS) results indicated that the substitution of Co²⁺ ions for Bi³⁺ sites in BiVO₄ was successful, although a change in the crystal phase of BiVO₄ did not occur. UV-vis DRS and PL results suggested that the Co-incorporation could slightly improve the visible light absorption of BiVO₄ and induce the separation of photoinduced electron–hole pairs; therefore, a significant enhancement of photocatalytic performance was achieved. The Bi_0.8Co_0.2VO_4+δ sample showed superior photocatalytic activity in comparison with other samples, achieving 96.78% methylene blue (MB) removal within 180 min. In addition, the proposed mechanism of improved photocatalytic activities and the stability of the catalyst were also investigated.

We investigated the fabrication of Co-doped BiVO₄ (Bi_1−xCo_xVO_4+δ, 0.05 < x < 0.5) by the substitution of Co ions for Bi sites in BiVO₄.     

Visible light assisted photocatalytic degradation of crystal violet dye and electrochemical detection of ascorbic acid using a BiVO4/FeVO4 heterojunction composite

A BiVO₄/FeVO₄ nanocomposite photocatalyst was successfully synthesized via a hydrothermal method. The prepared heterojunction photocatalyst was characterized physically and chemically using XRD, SEM, EDX, XPS, BET, FT-IR, Raman, UV-vis DRS, EPR and photoluminescence techniques. BiVO₄/FeVO₄ was explored for its photocatalytic activity by the decomposition of crystal violet (CV) organic dye under visible radiation. This experiment showed that BiVO₄/FeVO₄ at a ratio of 2 : 1 completely degrades CV within 60 min. In addition, BiVO₄/FeVO₄ was investigated for the electrochemical detection of the useful analyte ascorbic acid using electrochemical impedance spectroscopy (EIS) and cyclic voltammetry techniques. This work reveals the potential of the BiVO₄/FeVO₄ nanocomposite for applications in environmental disciplines as well as in biosensing.

A highly pure BiVO₄/FeVO₄ heterojunction nanocomposite photocatalyst was synthesized by a facile hydrothermal method. The simple and economical manufacturing process allows easier industrial scale-up and the results contribute to the design of more effective photocatalysts.