共查询到20条相似文献,搜索用时 31 毫秒
1.
A three-dimensional reduced graphene oxide nanomaterial with β-cyclodextrin modified glassy carbon electrode (3D-rGO/β-CD/GCE) was constructed and used to detect the electrochemical behavior of dopamine (DA). The nanocomposite materials were characterized by scanning electron microscopy (SEM), infrared spectrometry (FT-IR), Raman spectrogram and thermogravimetric analysis (TGA), which showed that β-CD was well modified on 3D graphene with a porous structure. The electrochemical properties of different modified electrodes were investigated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), proving the highest electron transfer rate of the 3D-rGO/β-CD modified electrode. The experimental conditions such as scan rate, pH, enrichment time and layer thickness were optimized. Under the best experimental conditions, DA was detected by differential pulse voltammetry (DPV) by 3D-rGO/β-CD/GCE with excellent electrocatalytic ability and satisfactory recognition ability, resulting in a wide linear range of 0.5–100 μM and a low detection limit (LOD) of 0.013 μM. The modified electrode based on 3D-rGO/β-CD nanocomposites is promising in the field of electrochemical sensors due to its high sensitivity and other excellent properties.A 3D-rGO/β-CD nanocomposite was successfully synthesized and further modified onto the surface of GCE to construct a new biosensor for electrochemically sensing DA. 相似文献
2.
Behzad Mirzaei Ali Zarrabi Abdollah Noorbakhsh Abbas Amini Pooyan Makvandi 《RSC advances》2021,11(14):7862
Curcumin is a polyphenolic compound with anti-oxidative and anti-cancer properties that is obtained from turmeric plants. Several studies have demonstrated that cancer cells are not killed unless they are exposed to 5–50 mM of curcumin. Consequently, it is vital to control the concentration of curcumin in cancer therapy. In this study, a sensitive electrochemical sensor was fabricated based on a beta-cyclodextrin–reduced graphene oxide (β-CD–rGO) nanocomposite for measuring curcumin concentration. The effects of experimental factors were investigated and the optimum parametric conditions were determined using the Taguchi optimization method. The β-CD–rGO modified electrode exhibited good electrochemical properties for curcumin detection. The results of differential pulse voltammetry experiments unveiled that the sensor shows a linear response to curcumin concentration over the range of 0.05–10 mM with a detection limit of 33 nM and sensitivity of 4.813 μA μM−1. The fabricated sensor exhibited selectivity in the presence of other electroactive species, e.g., propranolol, clomipramine and clonazepam.In this study, a sensitive electrochemical sensor was fabricated based on a beta-cyclodextrin–reduced graphene oxide (β-CD–rGO) nanocomposite for measuring curcumin concentration. 相似文献
3.
In this study, a novel tetrabromobisphenol A (TBBPA) sensor was fabricated based on a CTAB-capped gold nanoparticle (AuNPs)-thio-β-cyclodextrin (SH-β-CD)/graphene oxide modified glassy carbon electrode (GCE). The peak current of TBBPA was dramatically enhanced by the AuNPs with a diameter of 6.2 nm on the modified electrodes compared with the other sized particles (10.1 or 16.1 nm). To further improve the electrochemical performance of the modified electrode, the influence of pH of the buffer solution and the accumulation time on the determination were investigated. The optimum pH and accumulation time were 7.0 and 180 s, respectively. The developed sensor exhibited good reproducibility, and excellent sensitivity and selectivity, showing a low detection limit (1.2 × 10−9 mol L−1) and a linear range from 1.5 × 10−8 to 7 × 10−6 mol L−1. In addition, a possible oxidization mechanism of TBBPA was also discussed. Finally, this sensor was successfully applied to detect TBBPA in water samples, and the results were consistent with those acquired by high-performance liquid chromatography.In this study, a novel tetrabromobisphenol A (TBBPA) sensor was fabricated based on a CTAB-capped gold nanoparticle (AuNP)-thio-β-cyclodextrin (SH-β-CD)/graphene oxide modified glassy carbon electrode (GCE). 相似文献
4.
Vijay Kumar Rajeev Kumar Gupta Ravi Kumar Gundampati Devendra Kumar Singh Sweta Mohan Syed Hadi Hasan Manisha Malviya 《RSC advances》2018,8(2):619
The current study aims at the development of an electrochemical sensor based on a silver nanoparticle–reduced graphene oxide–polyaniline (AgNPs–rGO–PANI) nanocomposite for the sensitive and selective detection of hydrogen peroxide (H2O2). The nanocomposite was fabricated by simple in situ synthesis of PANI at the surface of rGO sheet which was followed by stirring with AEC biosynthesized AgNPs to form a nanocomposite. The AgNPs, GO, rGO, PANI, rGO–PANI, and AgNPs–rGO–PANI nanocomposite and their interaction were studied by UV-vis, FTIR, XRD, SEM, EDX and XPS analysis. AgNPs–rGO–PANI nanocomposite was loaded (0.5 mg cm−2) on a glassy carbon electrode (GCE) where the active surface area was maintained at 0.2 cm2 for investigation of the electrochemical properties. It was found that AgNPs–rGO–PANI–GCE had high sensitivity towards the reduction of H2O2 than AgNPs–rGO which occurred at −0.4 V vs. SCE due to the presence of PANI (AgNPs have direct electronic interaction with N atom of the PANI backbone) which enhanced the rate of transfer of electron during the electrochemical reduction of H2O2. The calibration plots of H2O2 electrochemical detection was established in the range of 0.01 μM to 1000 μM (R2 = 0.99) with a detection limit of 50 nM, the response time of about 5 s at a signal-to-noise ratio (S/N = 3). The sensitivity was calculated as 14.7 μA mM−1 cm−2 which indicated a significant potential as a non-enzymatic H2O2 sensor.The current study aims at the development of an electrochemical sensor based on a silver nanoparticle–reduced graphene oxide–polyaniline (AgNPs–rGO–PANI) nanocomposite for the sensitive and selective detection of hydrogen peroxide (H2O2). 相似文献
5.
High-performance electrode modification materials play a crucial role in improving the sensitivity of sensor detection in electrochemical determination of heavy metals. In this study, a rGO/MoS2/CS nanocomposite modified glassy carbon electrode (GCE) was used to construct a sensitive sensor for detecting lead ions in tobacco leaves. The reduced graphene oxide (rGO) was used to increase the conductivity of the sensor, and the nano-flowered MoS2 could provide a large reaction specific surface area and a certain active site for heavy metal reaction. Chitosan (CS) was used to improve the enrichment ability of heavy metals and increase the electrocatalytic activity of electrode. Thus, an electrochemical sensor with excellent performance in reproducibility, stability and anti-interference ability was established. The stripping behavior of Pb(ii) and the application conditions of the sensor were studied by square wave anodic stripping voltammetry (SWASV). The investigation indicated that the sensor exhibited high detection sensitivity in the range of 0.005–0.05–2.0 μM, and the limit of detection (LOD) was 0.0016 μM. This work can provide a fast and effective method for determination of Pb(ii) in samples with low content, such as tobacco leaves.High-performance electrode modification materials play a crucial role in improving the sensitivity of sensor detection in electrochemical determination of heavy metals. 相似文献
6.
Kai Kang Beibei Wang Xueping Ji Yuheng Liu Wenrui Zhao Yaqing Du Zhiyong Guo Jujie Ren 《RSC advances》2021,11(4):2446
This study reports a new type of artificial nanozyme based on Hemin-doped-HKUST-1 (HKUST-1, also referred to as MOF-199; a face-centered-cubic MOF containing nanochannels) as a redox mediator for the detection of dopamine (DA). Hemin-doped-HKUST-1 was successfully synthesized by one-pot hydrothermal method, which was combined with reduced graphene oxide (rGO) modified on a glassy carbon electrode (GCE) to construct a sensor (Hemin-doped HKUST-1/rGO/GCE). The morphology and structure of Hemin-doped-HKUST-1 were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM) and infrared spectra (IR) techniques. The Hemin-doped HKUST-1/rGO nanozyme showed an excellent electrocatalytic activity for DA oxidation, which is due to the enhanced Hemin activity through the formation of a metal–organic framework (MOFs) and the synergy between the Hemin-doped HKUST-1 and rGO in nanozyme. The resulted sensor exhibited a high sensitivity of 1.224 μA μM−1, with a lower detection limit of 3.27 × 10−8 M (S/N = 3) and a wide linear range of 0.03–10 μM for DA detection. In addition, due to the stabilizing effect of MOFs on heme, the sensor showed satisfactory stability and has been successfully applied to the detection of DA in serum samples, indicating that this work has potential value in clinical work.Hemin-doped-HKUST-1 nanozyme has been successfully synthesized and used for dopamine detection with excellent reproducibility, stability and anti-interference. 相似文献
7.
Nadzirah Sofia Anuar Wan Jeffrey Basirun Md. Shalauddin Shamima Akhter 《RSC advances》2020,10(29):17336
A platinum–silver graphene (Pt–Ag/Gr) nanocomposite modified electrode was fabricated for the electrochemical detection of dopamine (DA). Electrochemical studies of the Pt–Ag/Gr nanocomposite towards DA detection were performed by cyclic voltammetry (CV) and differential pulse voltammetry (DPV). The CV analysis showed that Pt–Ag/Gr/GCE had enhanced electrocatalytic activity towards DA oxidation due to the synergistic effects between the platinum–silver nanoparticles and graphene. The DPV results showed that the modified sensor demonstrated a linear concentration range between 0.1 and 60 μM with a limit of detection of 0.012 μM. The Pt–Ag/Gr/GCE presented satisfactory results for reproducibility, stability and selectivity. The prepared sensor also showed acceptable recoveries for a real sample study.A platinum–silver graphene nanocomposite was synthesized and characterized. A nanocomposite modified electrode was fabricated in order to investigate the electrochemical detection of dopamine. 相似文献
8.
Lignosulfonate (LS), a biomass by-product from sulfite pulping and the paper-making industry, which has many excellent characteristics, such as renewable, environmentally friendly, amphiphilic nature, and especially the abundant content of hydrophilic functional groups in its architecture, making it highly reactive and can be used as a sensitive material in sensors to show changes in electrical signals. Herein, we report a one-step in situ method to fabricate lignosulfonate-modified reduced graphene oxide (LS–rGO) green biosensors, which can be used for the sensitive electrochemical detection of dopamine without interference from uric acid and ascorbic acid. The modified LS molecular layers act as chemical-sensing layers, while the rGO planar sheets function as electric-transmitting layers in the as-assembled dopamine biosensors. After the in situ-decoration of the LS modifier, the sensing performance of LS–rGO for the detection of dopamine was much higher than that of the pure rGO electrode, and the highest current response of the biosensor toward dopamine greatly improved from 11.2 μA to 52.07 μA. The electrochemical sensitivity of the modified biosensor was optimized to be 0.43 μA μM−1, and the detection limit was as low as 0.035 μM with a wide linear range (0.12–100 μM), which is better than that of most previously reported metal- and organic-based modified graphene electrodes. The newly designed biosensor has unique advantages including rapid, stable, sensitive and selective detection of dopamine without interference, providing a facile pathway for the synthesis of green resource-derived sensing materials instead of the traditional toxic and expensive modifiers.One-step situ method to fabricate lignosulfonate modified reduced graphene oxide sensors for sensitive, selective and highly repetitive electrochemical detection of dopamine. 相似文献
9.
In this paper, Ag–Pd bimetallic nanoparticles uniformly distributed on reduced graphene oxide (rGO) were synthesized by redox reaction between Pd2+, Ag+and GO, and were characterized by X-ray diffractometry, field emission scanning electron microscopy, electrochemical impedance spectroscopy and thermal gravimetric analyses. A novel electrochemical sensor was constructed based on these nanocomposites using glassy carbon as a substrate. Under optimal conditions, the linear ranges were 0.50–300.00 μM for PA and 1.00–300.00 μM for 4-AP, with the detection limits of 0.23 μM for PA and 0.013 μM for 4-AP, respectively. This sensor was successfully applied to the determination of PA in pharmaceutical formulations and gave satisfactory results with a lower detection limit, wider linear range and good reproducibility.Simultaneous detection of acetaminophen and 4-aminophenol with a highly sensitive electrochemical sensor based on silver–palladium bimetal nanoparticles and reduced graphene oxide. 相似文献
10.
Reduced graphene oxide (rGO) integrated with iron oxide nanoparticles (α-Fe2O3/rGO) composites with different morphologies were successfully obtained through the in situ synthesis and mechanical agitation methods. It was found that the α-Fe2O3 was densely and freely dispersed on the rGO layer. By comparing electrochemical properties, the sheet-like α-Fe2O3/rGO composites demonstrate excellent electrochemical performance: the highest specific capacitance, and excellent cycling stability and rate capacity. The specific capacitance is 970 F g−1 at a current density of 1 A g−1 and the capacitance retention is 75% after 2000 cycles with the current density reaching 5 A g−1. It is mainly due to the synergistic effect between the α-Fe2O3 and rGO, and the high conductivity of the rGO offers a fast channel for the movement of electrons.Preparation of α-Fe2O3/rGO composites for supercapacitor application using in situ synthesis and a mechanical agitation method. 相似文献
11.
In the present study, thiol β-cyclodextrin (SH-CD) and ethylenediamine β-cyclodextrin (NH2-β-CD) were simultaneously grafted on the same interface of an Au NP deposited carboxyl SiC (Au@CSiC) nanocomposite. An electrochemical sensor for the simultaneous determination of nitrophenol isomers (o-nitrophenol, o-NP; p-nitrophenol, p-NP) using SH-CD and NH2-β-CD functionalized Au@SiC (Au@CSiC-SH/NH2-CD) nanocomposite was successfully constructed. Differential pulse voltammetry was used to quantify o-NP and p-NP within the concentration range of 0.01–150 μM under the optimal conditions. The detection limit (S/N = 3) of the sensor was 0.019 and 0.023 μM for o-NP and p-NP, respectively, indicating a low detection limit. Interference study results demonstrated that the sensor was not affected in the presence of similar aromatic compounds during the determination of NP isomers, showing high selectivity. The proposed electrochemical sensing platform was successfully used to determine NP isomers in tap water. The low detection limit and high selectivity of the proposed electrochemical sensor were caused by the high surface area, the excellent conductivity, and the more recognized (enriched) NP isomer molecules by SH-β-CD and NH2-β-CD of the Au@CSiC-SH/NH2-CD nanocomposite.An illustration of simultaneous electrochemical determination of nitrophenol isomers using β-cyclodextrin derivative-functionalized silicon carbide. 相似文献
12.
A zeolitic imidazolate framework-8 (ZIF-8)/reduced graphene oxide (rGO) nanocomposite was formed by using an efficient synthetic method. The morphology and structure of the ZIF-8/rGO nanocomposite were characterized by scanning electron spectroscopy (SEM), X-ray diffraction (XRD) and thermogravimetric analysis (TGA) mapping. The ZIF-8/rGO nanocomposites were immobilized on a carbon paste electrode (CPE) to construct a high-performance nonenzymatic electrochemical H2O2 sensor. A cyclic voltammetry (CV) study showed that the ZIF-8/rGO nanocomposites displayed better electrocatalytic activity toward H2O2 reduction compared to that of ZIF-8. An amperometric study indicated that the H2O2 sensor displayed high performance, which offered a low detection limit (0.05 μM) (S/N = 3), a high sensitivity (4.01 μA mM−1 cm−2), and a wide linear range (from 1.0 to 625 μM). An electrochemical reaction mechanism was proposed for H2O2 reduction on the ZIF-8/rGO/CPE. Importantly, the as-fabricated H2O2 sensor exhibited good reproducibility and excellent selectivity. Furthermore, the constructed high-performance sensor was utilized to monitor the H2O2 levels in real samples, and satisfactory results were obtained. These results demonstrated that the ZIF-8/rGO nanocomposite can be used as a good electrochemical sensor material in practical applications.A zeolitic imidazolate framework-8 (ZIF-8)/reduced graphene oxide (rGO) nanocomposite was formed by using an efficient synthetic method. 相似文献
13.
Shuaihui Li Yashen Ma Yongkang Liu Gu Xin Minghua Wang Zhihong Zhang Zhongyi Liu 《RSC advances》2019,9(6):2997
A three dimensional (3D) nanostructured composite based on the self-assembly of MoS2 nanospheres and polyaniline (PANI) loaded on reduced graphene oxide (denoted by 3D MoS2-PANI/rGO) was prepared via a feasible one-pot hydrothermal process. The 3D MoS2-PANI/rGO nanocomposite not only exhibits good functionality and bioaffinity but also displays high electrochemical catalytic activity. As such, the developed 3D MoS2-PANI/rGO nanocomposite can be employed as the sensing platform for simultaneously detecting small biomolecules, i.e., ascorbic acid (AA), dopamine (DA), and uric acid (UA). The peak currents obtained from the differential pulse voltammetry (DPV) measurements depended linearly on the concentrations in the wide range from 50 μM to 8.0 mM, 5.0 to 500 μM, and 1.0 to 500 μM, giving low detection limits of 22.20, 0.70, and 0.36 μM for AA, DA, and UA, respectively. Furthermore, the 3D MoS2-PANI/rGO-based electrochemical sensor also exhibited high selectivity, good reproducibility and stability toward small molecule detection. The present sensing strategy based on 3D MoS2-PANI/rGO suggests a good reliability in the trace determination of electroactive biomolecules.A three dimensional (3D) nanostructured composite based on the self-assembly of MoS2 nanospheres and polyaniline (PANI) loaded on reduced graphene oxide (denoted by 3D MoS2-PANI/rGO) was prepared via a feasible one-pot hydrothermal process. 相似文献
14.
The peripheral and non-peripheral substitution of 4-trifluoromethylphenoxy groups in the design of gas sensing phthalocyanine cobalt/reduced graphene oxide (rGO) hybrids with two different positions of the substituents was realized. Tetra-α(β)-(4-trifluoromethylphenoxy)phthalocyanine cobalt/reduced graphene oxide (3(4)-cF3poPcCo/rGO) hybrids were prepared through noncovalent interaction, and were analyzed by FT-IR, UV-vis, TGA and SEM. The gas sensing performance of the cF3poPcCo/rGO hybrid gas sensors towards ppb hydrogen sulfide (H2S) was measured at room temperature. The results show that the 4-cF3poPcCo/rGO sensor has better sensitivity, selectivity and reproducibility than the 3-cF3poPcCo/rGO sensor, as well as a perfect linear response to the concentration of H2S. For the 4-cF3poPcCo/rGO sensor, the response sensitivity to 1 ppm H2S is as high as 46.58, the response and recovery times are 600 s and 50 s for 1 ppm H2S, and the detection limit is as low as 11.6 ppb. This is mainly due to the loose and porous structure of the cF3poPcCo/rGO hybrids, the fact that graphene is an excellent conductive agent, and the fact that the electron-withdrawing capability of the trifluoromethyl group can increase the holes of rGO and PcCo. In addition, through electrochemical impedance spectroscopy (EIS) and I–V curves, and density functional theory, the influence of different positions of the substituents of cF3poPcCo/rGO on the sensing performance and the sensing mechanism for improving sensitivity were discussed and confirmed in detail.Highly sensitive gas sensing materials are of great importance for environmental pollution monitoring. 相似文献
15.
In this paper, a hybrid nanocomposite (MB-rGO) was synthesized based on the π–π stacking interactions between methylene blue (MB) and reduced graphene oxide (rGO). The as-synthesized nanocomposite was characterized by SEM, TEM, XRD, FTIR, UV-vis and XPS spectra. UV-vis spectroscopy and electrochemical tests suggested the MB-rGO modified on the electrode exhibited glucose oxidase-mimetic catalytic activity towards glucose, and displayed excellent electrocatalytic performance for electrochemical detection of glucose with a wide linear range from 1.04 to 17.44 mM, a low detection limit of 45.8 μM and a large sensitivity of 13.08 μA mM−1 cm−2. The proposed glucose sensor also showed high stability, reproducibility and good abilities of anti-interference to dopamine, ascorbic acid and uric acid. Moreover, the modified electrode was used to determine glucose concentration in human blood serum samples with satisfactory results.A novel electrochemical glucose sensor based on methylene blue-reduced graphene oxide nanocomposite was constructed, and the sensor exhibited good glucose oxidase-mimetic electrocatalytic activity towards glucose and practical applicability. 相似文献
16.
Heavy metal pollution can be toxic to humans and wildlife, thus it is of great significance to develop rapid and sensitive methods to detect heavy metal ions. Here, a novel type of electrochemical sensor for the simultaneous detection of heavy metal ions has been prepared by using poly(l-glutamic acid) (PGA) and graphene oxide (GO) composite materials to modify the glassy carbon electrode (GCE). Due to the good binding properties of poly(l-glutamic acid) (PGA) for the heavy metal ions (such as Cu2+, Cd2+, and Hg2+) as well as good electron conductivity of graphene oxide (GO), the heavy metal ions, Cu2+, Cd2+, and Hg2+ in aqueous solution can be accurately detected by using differential pulse anodic stripping voltammetry method (DPASV). Under the optimized experiment conditions, the modified GCE shows excellent electrochemical performance toward Cu2+, Cd2+, and Hg2+, and the linear range of PG/GCE for Cu2+, Cd2+, and Hg2+ is 0.25–5.5 μM, and the limits of detection (LODs, S/N ≥ 3) Cu2+, Cd2+, and Hg2+ are estimated to be 0.024 μM, 0.015 μM and 0.032 μM, respectively. Moreover, the modified GCE is successfully applied to the determination of Cu2+, Cd2+, and Hg2+ in real samples. All obtained results show that the modified electrode not only has the advantages of simple preparation, high sensitivity, and good stability, but also can be applied in the field of heavy metal ion detection.A novel electrochemical sensor with high stability and good reproducibility for the simultaneous detection of heavy metal ions was prepared by using PGA/GO to modify the GCE, showing high sensitivity of superior to most of the reported values. 相似文献
17.
The sensitive and specific detection of tumor biomarkers is crucial for early diagnosis and treatment of malignant melanoma. Immunoassay with a simple sensing interface and high sensitivity is highly desirable. In this work, a simple electrochemical immunosensor based on a chitosan/reduced graphene oxide (CS–rGO) nanocomposite was developed for sensitive determination of an S-100B protein, a tumor marker of malignant melanoma. CS–rGO nanocomposite were prepared by chemical reduction of graphene oxide in the presence of chitosan and modified on glassy carbon electrode (GCE) to provide a biofriendly, conductive, and easily chemically modified matrix for further immobilization of antibodies. Anti-S-100B antibodies were grafted onto the chitosan molecules to fabricate the immunorecognition interface by a simple glutaraldehyde cross-linking method. Electrochemical determination of S-100B was achieved by measuring the decreased current signal of solution phase electrochemical probes, which originated from the increased steric hindrance and insulation caused by the formation of antigen–antibody complexes at the electrode interface. Due to the good conductivity, high surface area, excellent biocompatibility, and good film-forming ability of CS–rGO, the constructed immunosensor exhibited good stability, high selectivity and sensitivity, a wide dynamic range from 10 fg mL−1 to 1 ng mL−1 and a low limit of detection of 1.9 pg mL−1 (S/N = 3). Moreover, the sensor was also applicable for the sensitive detection of S-100B protein in real human serum samples.Simple electrochemical immunosensor is easily fabricated based on chitosan/reduce graphene oxide nanocomposite for sensitive determination of a tumor marker of malignant melanoma. 相似文献
18.
Ningthoujam Somorjit Singh Franco Mayanglambam Harshal B. Nemade P. K. Giri 《RSC advances》2021,11(16):9488
A combination of low-cost synthetic route and simplified exfoliation technique to develop high-quality graphene-based sheets with very large lateral dimensions, which are viable to scale up, remains a challenging problem. Herein, super-large graphene oxide (GO) sheets with lateral size up to 104 μm with a surface area of 6831 μm2 have been developed based on a simple approach using mild heating conditions, and subsequent deoxygenation yields reduced graphene oxide (rGO) sheets. With the decrease in number of layers (<10, <5, bi-layer and mono-layer) in GO, the Raman intensity ratio, ID/IG value increases systematically from 0.73 to 0.97. The efficacy of reducing oxygen-containing functional groups from GO to rGO is confirmed from Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, UV-visible absorption spectroscopy, photoluminescence, and thermogravimetric analysis. Current–voltage measurements revealed substantial improvement of current by three orders of magnitude upon reduction of GO to rGO, which is consistent with the significant decrease in charge transfer resistance in rGO, as revealed from the electrochemical impedance spectra. The large-area GO and rGO sheets when applied in surface-enhanced Raman scattering (SERS) exhibited a large enhancement factor of 104 and high detection capability down to a concentration of 10 nM for Rhodamine B. Furthermore, the rGO incorporated hybrid rGO–SnO2 demonstrated ∼50% improvement in sensitivity for CO2 gas sensing as compared to the commercial SnO2 based gas sensor. The higher sensitivity in the rGO case is ascribed to its high surface area, as revealed from the BET analysis. Therefore, the present simplified and economical approach of large-area graphene oxide could potentially open up a new strategy for industrial-scale production in the future.Super-large lateral size of graphene-based sheets by mild heating and their applications in SERS and CO2 gas sensing. 相似文献
19.
1,4-Dioxane is a carcinogenic, non-biodegradable, organic water pollutant which is used as a solvent in various industries. It is also formed as an undesired by-product in the cosmetic and pharmaceutical industry. Given its carcinogenicity and ability to pollute, it is desirable to develop a sensitive and selective sensor to detect it in drinking water and other water bodies. Current works on this sensor are very few and involve complex metal oxide composite systems. A sensitive electrochemical sensor for 1,4-dioxane was developed by modifying a glassy carbon electrode (GCE) with a reduced graphene oxide–curcumin (rGO–CM) nanocomposite synthesized by a simple solution approach. The prepared rGO–CM was characterized by X-ray Diffraction (XRD), Fourier Transform Infrared (FTIR) Spectroscopy, Raman spectroscopy, UV-Vis spectroscopy, and Scanning Electron Microscopy (SEM). The rGO–CM/GCE sensor was employed for the detection of 1,4-dioxane in the range of 0.1–100 μM. Although, the detection range is narrower compared to reported literature, the sensitivity obtained for the proposed sensor is far superior. Moreover, the limit of detection (0.13 μM) is lower than the dioxane detection target defined by the World Health Organization (0.56 μM). The proposed rGO–CM/GCE also showed excellent stability and good recovery values in real sample (tap water and drinking water) analysis.Reduced graphene oxide–curcumin (rGO–CM) nanocomposite was prepared from graphite oxide using curcumin. The rGO–CM/GCE was used for highly sensitive 1,4-dioxane detection. The LOD obtained (0.13 μM) was lower than the WHO guideline value. 相似文献
20.
Sedigheh Akbari Shohreh Jahani Mohammad Mehdi Foroughi Hadi Hassani Nadiki 《RSC advances》2020,10(63):38532
The present research synthesized manganese dioxide nano-flowers (β-MnO2-NF) via a simplified technique for electro-catalytic utilization. Moreover, morphological characteristics and X-ray analyses showed Mn in the oxide form with β-type crystallographic structure. In addition, the research proposed a new efficient electro-chemical sensor to detect methadone at the modified glassy carbon electrode (β-MnO2-NF/GCE). It has been found that oxidizing methadone is irreversible and shows a diffusion controlled procedure at the β-MnO2-NF/GCE. Moreover, β-MnO2-NF/GCE was considerably enhanced in the anodic peak current of methadone related to the separation of morphine and methadone overlapping voltammetric responses with probable difference of 510 mV. In addition, a linear increase has been observed between the catalytic peak currents gained by the differential pulse voltammetry (DPV) of morphine and methadone and their concentrations in the range between 0.1–200.0 μM and 0.1–250.0 μM, respectively. Furthermore, the limits of detection (LOD) for methadone and morphine were found to be 5.6 nM and 8.3 nM, respectively. It has been found that our electrode could have a successful application for detecting methadone and morphine in the drug dose form, urine, and saliva samples. Thus, this condition demonstrated that β-MnO2-NF/GCE displays good analytical performances for the detection of methadone.Electrochemical sensor based on β-MnO2 nanoflower-modified glassy carbon electrode for the simultaneous detection of methadone and morphine was fabricated. 相似文献