A nickel nanoparticle engineered CoFe2O4@GO–Kryptofix 22 composite: a green and retrievable catalytic system for the synthesis of 1,4-benzodiazepines in water

A composite of Ni nanoparticles incorporated in Kryptofix 22 conjugated magnetic nano-graphene oxide, CoFe₂O₄@GO–K 22·Ni, was synthesized via the grafting of Kryptofix 22 moieties on the magnetic nano-graphene oxide surface, followed by reaction of the nanocomposite with nickel nitrate. The Kryptofix 22 host material unit cavities can stabilize the Ni nanoparticles effectively and prevent their aggregation and separation from the surface. Characterization of the catalysts by FT-IR, FE-SEM, TGA, ICP, EDX, XRD, VSM and BET aided understanding the catalyst structure and morphology. This catalyst was efficiently applied for the synthesis of 1,4-benzodiazepine derivatives. The main advantages of the method are mild reaction conditions, inexpensive catalyst, it is environmentally benign, has high to excellent yields and shorter reaction times. This organometallic catalyst can be easily separated from a reaction mixture and was successfully examined for six runs with a slight loss of catalytic activity.

In this study, a competent and efficient methodology for the synthesis of benzodiazepine over magnetically retrievable novel CoFe₂O₄@GO–K 22 anchored Ni is reported.     

Solvothermal synthesis of octahedral and magnetic CoFe2O4–reduced graphene oxide hybrids and their photo-Fenton-like behavior under visible-light irradiation

We report a facile solvothermal synthesis of novel octahedral CoFe₂O₄–reduced graphene oxide (RGO) hybrid and pure CoFe₂O₄ that were used as heterogeneous photo-Fenton catalysts for the degradation of organic dyes in water. We investigated the structures, morphologies and catalytic activity of both the CoFe₂O₄ nanoparticles and CoFe₂O₄–RGO hybrids. The morphology of CoFe₂O₄ nanoparticles displays size-dependent shapes changing from granular (or sheet) to octahedral shapes with the introduction of RGO. Compared with bare CoFe₂O₄, the octahedral CoFe₂O₄–RGO hybrids serve as novel bifunctional materials displaying higher saturation magnetization values and excellent heterogeneous activation of H₂O₂ at nearly neutral pH. The high saturation magnetization (41.98 emu g⁻¹) of CoFe₂O₄–RGO hybrids aids their separation from the reaction mixture. In addition, the remarkable enhancement in the photo-Fenton activity of the CoFe₂O₄–RGO hybrids under visible light irradiation was attributed to the graphene/CoFe₂O₄ heterojunction, which aided the separation of excited electrons and holes. Furthermore, the CoFe₂O₄–RGO hybrids exhibited better removal efficiency for cationic methylene blue (MB) dye than for anionic methyl orange (MO) dye. Meanwhile, the CoFe₂O₄–RGO hybrids displayed acceptable photocatalytic stability, and we proposed an activation mechanism of H₂O₂ by the octahedral CoFe₂O₄–RGO hybrids.

Schematic illustration of an active heterogeneous photo-Fenton mechanism based on CoFe₂O₄–RGO hybrids.     

Magnetic CoFe2O4 nanoparticles supported on graphene oxide (CoFe2O4/GO) with high catalytic activity for peroxymonosulfate activation and degradation of rhodamine B

Herein, we report the preparation of magnetic CoFe₂O₄ nanoparticles and CoFe₂O₄/graphene oxide (GO) hybrids and evaluate their catalytic activity as heterogeneous peroxymonosulfate (PMS) activators for the decomposition of rhodamine B. The surface morphologies and structures of both CoFe₂O₄ nanoparticles and CoFe₂O₄/GO hybrids were investigated by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), Fourier transform infrared spectroscopy (FTIR) and nitrogen adsorption–desorption isotherms. The magnetic properties of the samples were assessed using a SQUID magnetometer at 298 K. Catalytic oxidation experiments demonstrated that CoFe₂O₄/GO hybrids exhibited much better catalytic activity than CoFe₂O₄ nanoparticles or CoFe₂O₄/reduced graphene oxide (rGO) hybrids, suggesting that GO plays an important role in CoFe₂O₄/GO hybrids in the decomposition of rhodamine B. The influence of various reaction conditions such as temperature, concentration of PMS, pH and decomposition time of rhodamine B over the CoFe₂O₄/GO catalyst were investigated and optimized. The rhodamine B degradation process was found to fit a pseudo-first order kinetics model. The catalyst could be easily separated from the reaction mixture by applying an external magnet. In particular, the as-prepared CoFe₂O₄/GO hybrid exhibited good reusability and stability in successive degradation experiments in PMS solution.

Herein, we report the preparation of magnetic CoFe₂O₄ nanoparticles and CoFe₂O₄/graphene oxide (GO) hybrids and evaluate their catalytic activity as heterogeneous peroxymonosulfate (PMS) activators for the decomposition of rhodamine B.     

CoFe2O4 nanoparticles decorated MoS2-reduced graphene oxide nanocomposite for improved microwave absorption and shielding performance

Magnetic CoFe₂O₄ nanoparticles decorated onto the surface of a MoS₂-reduced graphene oxide (MoS₂-rGO/CoFe₂O₄) nanocomposite were synthesized by a simple two-step hydrothermal method. The electromagnetic (EM) wave absorption performance and electromagnetic interference (EMI) shielding effectiveness of the materials were examined in the frequency range of 8.0–12.0 GHz (X-band). The MoS₂-rGO/CoFe₂O₄ nanocomposite was characterized by various tools such as X-ray diffraction, Raman spectroscopy, scanning electron microscopy, and transmission electron microscopy. High-resolution transmission electron microscopy results confirmed the decoration of magnetic nanoparticles onto the surface of the MoS₂-rGO nanocomposite with a diameter of 8–12 nm. The multiple interfacial polarization, moderate impedance matching, and defect dipole polarization improve the dielectric and magnetic loss of the materials, which leads to strong attenuation loss ability of incident EM energy within the shield. The pure MoS₂-rGO nanocomposite represents total shielding effectiveness (SE_T ∼16.52 dB), while the MoS₂-rGO/CoFe₂O₄ nanocomposite exhibits total shielding effectiveness (SE_T ∼19.26 dB) over the entire frequency range. It may be explained that the magnetic nanoparticles (CoFe₂O₄) serve as excellent conductive and magnetic fillers with a large surface area, leading to the migration of charge carriers at multi-interfaces.

Magnetic CoFe₂O₄ nanoparticles decorated onto the surface of a MoS₂-reduced graphene oxide (MoS₂-rGO/CoFe₂O₄) nanocomposite were synthesized by a simple two-step hydrothermal method.     

Barium promoted Ni/Sm2O3 catalysts for enhanced CO2 methanation

Low temperature CO₂ methanation is a favorable pathway to achieve high selectivity to methane while increasing the stability of the catalysts. A Ba promoted Ni/Sm₂O₃ catalyst was investigated for CO₂ methanation at atmospheric pressure with the temperature ranging from 200–450 °C. 5Ni–5Ba/Sm₂O₃ showed significant enhancement of CO₂ conversion particularly at temperatures ≤ 300 °C compared to Ni/Sm₂O₃. Incorporation of Ba into 5Ni/Sm₂O₃ improved the basicity of the catalysts and transformed the morphology of Sm₂O₃ from random structure into uniform groundnut shape nanoparticles. The uniformity of Sm₂O₃ created interparticle porosity that may be responsible for efficient heat transfer during a long catalytic reaction. Ba is also postulated to catalyze oxygen vacancy formation on Sm₂O₃ under a reducing environment presumably via isomorphic substitution. The disappearance of a high temperature (∼600 °C) reduction peak in H₂-TPR analysis revealed the reducibility of NiO following impregnation with Ba. However, further increasing the Ba loading to 15% formed BaNiO₃–BaNiO_2.36 phases which consequently reduced the activity of the Ni–Ba/Sm₂O₃ catalyst at low temperature. Ni was suggested to segregate from BaNiO₃–BaNiO_2.36 at high temperature thus exhibiting comparable activity with Ni/Sm₂O₃ at 450 °C.

Low temperature CO₂ methanation on 5Ni–5Ba/Sm₂O₃ is a favorable pathway to achieve high selectivity to methane while increasing the stability of the catalysts.     

Thermal stability,electrochemical and structural characterization of hydrothermally synthesised cobalt ferrite (CoFe2O4)

Monophasic nano-crystalline CoFe₂O₄ (CFO) nanoparticles of high purity have been synthesised through a low temperature hydrothermal route, which does not involve hazardous chemicals, or conditions. The easy, green procedure involves a hydrothermal treatment at 135 °C of an aqueous suspension of the oxalate salts of the precursors. No further purification or annealing procedure was necessary to obtain the crystalline nano-structured oxide. The nanoparticles were characterized structurally and chemically by powder X-ray diffraction (PXRD), Inductively Coupled Plasma Spectrometry (ICP-MS) and Scanning Electron Microscopy (SEM), thus confirming the successful synthesis of the CoFe₂O₄ particles with the expected crystal phase and stoichiometry and an almost complete inverse spinel structure. From the nanoparticles pellets were pressed to investigate the electronic conduction properties using electrochemical impedance spectroscopy (EIS). At low temperatures, the conductivity measurements reveal a semiconducting behavior originating from hopping between Co sites and a total conductivity dominated by the grain boundary contribution. At higher temperatures (T > 400 °C) a metallic–insulator transition occurs, which is attributed to additional hopping of electrons between the Fe sites.

Monophasic nano-crystalline CoFe₂O₄ (CFO) nanoparticles of high purity have been synthesised through a low temperature hydrothermal route, which does not involve hazardous chemicals, or conditions.     

Magnesium surface enrichment of CoFe2O4 magnetic nanoparticles immobilized with gold: reusable catalysts for green oxidation of benzyl alcohol

Gold nanoparticles have shown excellent activity for selective oxidation of alcohols; such catalytic systems are highly dependent on the initial activation of the substrates, which must occur on the catalyst surface in heterogeneous catalysts. In many cases, an extra base addition is required, although the basicity of the support may also be of significant importance. Here, we explored the intrinsic basicity of magnesium-based enrichments on CoFe₂O₄ magnetic nanoparticles for the oxidation of benzyl alcohol using molecular oxygen as oxidant. The MgO and Mg(OH)₂ enrichments enabled gold impregnation, which was not possible on the bare CoFe₂O₄ nanoparticles. The Au/MgO/CoFe₂O₄ and Au/Mg(OH)₂/CoFe₂O₄ catalysts reached 42% and 18% conversion, respectively without base promotion, in 2.5 hour and 2 bar of O₂. When the catalysts were tested with sub-stoichiometric amounts of base, they became more active (>70% of conversion) and stable in successive recycling experiments without metal leaching, under the same reaction conditions. We also showed the oxide phases of the enrichments performed using Rietveld refinements and how the Mg(OH)₂ phase interferes with the activity of MgO-based materials.

Gold nanoparticles have shown excellent activity for selective oxidation of alcohols; such catalytic systems are highly dependent on the initial activation of the substrates, which must occur on the catalyst surface in heterogeneous catalysts.     

A facile synthesis of nanostructured CoFe2O4 for the electrochemical sensing of bisphenol A

This work reports a novel, highly sensitive and cost-effective electrochemical sensor for the detection of bisphenol A in environmental water samples. Attractive non-noble transition metal oxide CoFe₂O₄ nanoparticles were successfully synthesized using a sol–gel combustion method and further characterized by X-ray diffraction, scanning electron microscopy and X-ray photoelectron spectroscopy. Under optimal conditions, the CoFe₂O₄ nanoparticle modified glassy carbon electrode exhibits high electrochemical activity and good catalytic performance for the detection of bisphenol A. The linear calibration curves are obtained within a wide concentration range from 0.05 μmol L⁻¹ to 10 μmol L⁻¹, and the limit of detection is 3.6 nmol L⁻¹ for bisphenol A. Moreover, this sensor also demonstrates excellent reproducibility, stability, and good anti-interference ability. The sensor was successfully applied to determine bisphenol A in practical samples, and the satisfactory recovery rate was between 95.5% and 102.0%. Based on the great electrochemical properties and practical application results, this electrochemical sensor has broad application prospects in the sensing of bisphenol A.

A new electrochemical sensor for bisphenol A is reported. CoFe₂O₄ nanoparticles were synthesized by a sol–gel combustion method. A nanoparticle-modified glassy carbon electrode exhibited outstanding electrochemical performance for the detection of bisphenol A.     

Effect of cobalt addition on the structure and properties of Ni–MCM-41 for the partial oxidation of methane to syngas

A one-step hydrothermal crystallization method was used to synthesize Co–Ni–MCM-41 catalysts for the partial oxidation of methane to syngas reaction. Co was added as an assistant in the synthesis process. The formation of a Ni–Co alloy decreased the damage of Ni ions to the framework of MCM-41. The Ni–Co alloy introduced more Ni into the channel exposing more active sites. The properties of the synthesized catalysts were characterized by XRD, N₂ adsorption–desorption, TEM, ICP, FT-IR, H₂-TPR, XPS and TGA techniques. Co–Ni–MCM-41 catalysts showed superior catalytic performance and sintering resistance than Ni–MCM-41 catalyst without Co. The Ni–Co alloy inhibited the formation of the NiO, thus reducing the sintering of the catalyst. The result was attributed to higher metal dispersion and more regular pore structure of the Co–Ni–MCM-41 catalysts. When the Co content was 1%, a conversion of 88% and selectivity of 87% was achieved.

The Ni–Co alloy confined within MCM-41 improved dispersibility and the stability of Ni.     

Engineered N-doped graphene quantum dots/CoFe2O4 spherical composites as a robust and retrievable catalyst: fabrication,characterization, and catalytic performance investigation in microwave-assisted synthesis of quinoline-3-carbonitrile derivatives

Nitrogen-doped graphene quantum dots (N-GQDs), which are less than 10 nm in size, are an interesting member of the nanocarbon materials family. N-GQDs nanostructures have been broadly applied in various fields, such as drug-gene delivery systems, photocatalytic reactions, and catalysts, owing to their unique properties. However, N-GQDs have rarely been introduced as a catalyst in organic synthesis. Herein, CoFe₂O₄ nanocomposites with diverse morphologies are fabricated in various conditions (e.g. green routes, various pH adjusters, temperatures). Due to further active sites on the surface of the nanocomposites, morphology engineering can be effective in catalytic activities. Following the synthesis, the catalytic activity of the engineered CoFe₂O₄ nanocomposites was screened, and it presented the order of spherical > rod > prism > cubic. The uniform spherical morphology provides more accessible active sites. Then, the novel nano-sized N-GQDs/CoFe₂O₄ magnetic spherical composite was readily fabricated by a green, low-cost, and easy hydrothermal route. The engineered composite was applied as an efficient magnetic nanocatalyst for the MW-assisted one-pot synthesis of new and known quinoline-3-carbonitrile derivatives (83–96%) in the shortest reaction time (60–90 s). Furthermore, the green route, easy separation of the nanocatalyst, and reusability (7 runs) without noticeable loss of catalytic efficiency are other advantages.

Sustainable fabrication of spherical N-GQDs/CoFe₂O₄ nanocomposites as a novel magnetically retrievable catalyst for the synthesis of quinoline-3-carbonitrile derivatives has been developed.     

Effect of Re promoter on the structure and catalytic performance of Ni–Re/Al2O3 catalysts for the reductive amination of monoethanolamine

In this paper, Ni/Al₂O₃ catalysts (15 wt% Ni) with different Re loadings were prepared to investigate the effect of Re on the structure and catalytic performance of Ni–Re/Al₂O₃ catalysts for the reductive amination of monoethanolamine. Reaction results reveal that the conversion and ethylenediamine selectivity increase significantly with increasing Re loading up to 2 wt%. Ni–Re/Al₂O₃ catalysts show excellent stability during the reductive amination reaction. The characterization of XRD, DR UV-Vis spectroscopy, H₂-TPR, and acidity–basicity measurements indicates that addition of Re improves the Ni dispersion, proportion of octahedral Ni²⁺ species, reducibility, and acid strength for Ni–Re/Al₂O₃ catalysts. The Ni15 and Ni15–Re2 catalysts were chosen for in-depth study. The results from SEM-BSE, TEM, and CO-TPD indicate that smaller Ni⁰ particle size and higher Ni⁰ surface area are obtained in the reduced Ni–Re/Al₂O₃ catalysts. Results from in situ XPS and STEM-EDX line scan suggest that Re species show a mixture of various valances and have a tendency to aggregate on the surface of Ni⁰ particles. During reaction, the Ni⁰ particles on the Al₂O₃ support are stabilized and the sintering process is effectively suppressed by the incorporation of Re. It could be concluded that sufficient Ni⁰ sites, the collaborative effect of Ni–Re, and brilliant stability contribute to the excellent catalytic performance of Ni–Re/Al₂O₃ catalysts for the reductive amination of monoethanolamine.

Re promoters improve the catalyst performance and stability of Ni–Re/Al₂O₃ catalysts for the reductive amination of monoethanolamine.     

Effect of the coexistence of albumin and H2O2 on the corrosion of biomedical cobalt alloys in physiological saline

The corrosion of Co–28Cr–6Mo and Co–35Ni–20Cr–10Mo, as biomedical alloys, has been investigated for effects of typical species (albumin and H₂O₂) in physiological saline, with their coexistence explored for the first time. Electrochemical and long term immersion tests were carried out. It was found that Co alloys were not sensitive to the presence of albumin alone, which slightly promoted anodic dissolution of Co–35Ni–20Cr–10Mo without noticeably affecting Co–28Cr–6Mo and facilitated oxide film dissolution on both alloys. H₂O₂ led to a clear drop in corrosion resistance, favouring metal release and surface oxide formation and inducing much thicker but less compact oxide films for both alloys. The coexistence of both species resulted in the worst corrosion resistance and most metal release, while the amount and composition of surface oxide remained at a similar level as in the absence of both. The effect of H₂O₂ inducing low compactness of surface oxides should prevail on deciding the poor corrosion protection ability of passive film, while albumin simultaneously promoted dissolution or inhibited formation of oxides due to H₂O₂. Corrosion resistance was consistently lower for Co–35Ni–20Cr–10Mo under each condition, the only alloy where the synergistic effect of both species was clearly demonstrated. This work suggests that the complexity of the environment must be considered for corrosion resistance evaluation of biomedical alloys.

Corrosion of biomedical Co alloys were firstly studied in the presence of both albumin and H₂O₂.     

Synthesis of a three-dimensional cross-linked Ni–V2O5 nanomaterial in an ionic liquid for lithium-ion batteries

A three-dimensional cross-linked Ni–V₂O₅ nanomaterial with a particle size of 250–300 nm was successfully prepared in a 1-butyl-3-methylimidazole bromide ionic liquid (IL). The formation of this structure may follow the rule of dissolution–recrystallization and the ionic liquid, as both a dissolution and structure-directing agent, plays an important role in the formation of the material. After calcination of the precursor, the active material (Ni–V₂O₅–IL) was used as an anode for lithium-ion batteries. The designed anode exhibited excellent electrochemical performance with 765 mA h g⁻¹ at a current density of 0.3 A g⁻¹ after 300 cycles, which is much higher than that of a NiVO–W material prepared via a hydrothermal method (305 mA h g⁻¹). These results show the remarkable superiority of this novel electrode material synthesized in an ionic liquid.

A three-dimensional cross-linked Ni–V₂O₅ nanomaterial with a particle size of 250–300 nm was successfully prepared in a 1-butyl-3-methylimidazole bromide ionic liquid (IL).     

Copper based on diaminonaphthalene-coated magnetic nanoparticles as robust catalysts for catalytic oxidation reactions and C–S cross-coupling reactions

In this work, the immobilization of copper(ii) on the surface of 1,8-diaminonaphthalene (DAN)-coated magnetic nanoparticles provides a highly active catalyst for the oxidation reaction of sulfides to sulfoxides and the oxidative coupling of thiols to disulfides using hydrogen peroxide (H₂O₂). This catalyst was also applied for the one-pot synthesis of symmetrical sulfides via the reaction of aryl halides with thiourea as the sulfur source in the presence of NaOH instead of former strongly basic and harsh reaction conditions. Under optimum conditions, the synthesis yields of sulfoxides, symmetrical sulfides, and disulfides were about 99%, 95%, and 96% respectively with highest selectivity. The heterogeneous copper-based catalyst has advantages such as the easy recyclability of the catalyst, the easy separation of the product and the less wastage of products during the separation of the catalyst. This heterogeneous nanocatalyst was characterized by FESEM, FT-IR, VSM, XRD, EDX, ICP and TGA. Furthermore, the recycled catalyst can be reused for several runs and is economically effective.

This green-based catalyst with non-toxic materials and high efficiency is used in organic reactions.     

Novel mesoporous Ag@SiO2 nanospheres as a heterogeneous catalyst with superior catalytic performance for hydrogenation of aromatic nitro compounds

Mesoporous core–shell structure Ag@SiO₂ nanospheres are constructed to prevent Ag nanoparticles from aggregation during the hydrogenation reaction. The prepared catalyst shows superior catalytic performance for hydrogenation of nitro compounds with 100% conversion and selectivity without any by-products, which also indicates good recycling performance for several times use.

Mesoporous core–shell structure Ag@SiO₂ nanospheres are constructed to prevent Ag nanoparticles from aggregation during the hydrogenation reaction.     

N-doped graphene/CoFe2O4 catalysts for the selective catalytic reduction of NOx by NH3

In this paper, CoFe₂O₄/graphene catalysts and N-doped graphene/CoFe₂O₄ (CoFe₂O₄/graphene-_N) catalysts were prepared using the hydrothermal crystallization method for the selective catalytic reduction of NO_x by NH₃. The results of the test showed that CoFe₂O₄/graphene catalysts exhibited the best denitrification activity when the loading was at 4% and the conversion rate of NO_x reached 99% at 250–300 °C. CoFe₂O₄/graphene-_N catalysts presented a better denitrification activity at low temperature than CoFe₂O₄/graphene catalysts, and the conversion rate of NO_x reached more than 95% at 200–300 °C. The intrinsic mechanism of CoFe₂O₄/graphene-_N catalysts in promoting SCR activity was preliminarily explored. The physicochemical properties of the samples were characterized using XRD, TEM, N₂ adsorption, XPS, NH₃-TPD, and H₂-TPR. The results indicated that nitrogen doping can improve the dispersion of CoFe₂O₄, and it also increased the acidic sites and the redox performance conducive to improving the denitrification activity of the catalysts. In addition, CoFe₂O₄/graphene-_N catalysts demonstrated a better resistance to water and sulfur than CoFe₂O₄/graphene catalysts.

N-doped graphene/CoFe₂O₄ presented better denitrification activity than CoFe₂O₄/graphene due to the more uniform distribution of CoFe₂O₄ and acidic sites etc.     

Assessing the potential biological activities of TiO2 and Cu,Ni and Cr doped TiO2 nanoparticles

Nanoparticles are like magic bullets and nanomaterials exhibit appealing properties. Their size and morphology can be switched by dopants for certain biological activities. Nanoparticles in combination with certain drugs enhance the antibiotic effects and may be valuable in combating bacterial resistance. The antimicrobial potency of nanoparticles depends upon their ability to bind to the surface of microbial cell membranes resulting in modulation of basic cell functions such as respiration. We report herein the antibacterial, antifungal and antioxidant activities of pure TiO₂ and TiO₂ doped with 4% Cu, Ni and Cr. The performance of pure and doped nanoparticles has been compared with reference compounds. A comparison of the antifungal activities of the samples doped with TiO₂ reveals that Cu–TiO₂ exhibits improved performance against A. fumigatus but lower antifungal activity against Mucor sp. and F. solani. Cu–TiO₂ and Ni–TiO₂ showed good antibacterial action against B. bronchiseptica, while Cr–TiO₂ nanoparticles displayed better activity against S. typhimurium as compared to pure TiO₂. Moreover, pristine TiO₂ and Ni–TiO₂ nanoparticles were found to demonstrate maximum total antioxidant capacity.

Nanoparticles bind to the surface of the cell membranes of microbes altering their basic cell functions and resulting in cell death.     

CoFe2O4/Cu(OH)2 magnetic nanocomposite: an efficient and reusable heterogeneous catalyst for one-pot synthesis of β-hydroxy-1,4-disubstituted-1,2,3-triazoles from epoxides

A magnetically separable CoFe₂O₄/Cu(OH)₂ nanocomposite was prepared and characterized by various techniques such as FESEM, EDS, TEM, XRD, VSM and FT-IR. This novel composite was used as a heterogeneous catalyst for the regioselective synthesis of β-hydroxy-1,4-disubstituted-1,2,3-triazoles from sodium azide, terminal alkynes and structurally different epoxides in water at 60 °C. The formation of the product proceeds in one pot through a mechanism that involves an in situ generated organic azide intermediate, followed by rapid ring closure with the alkyne component. The simple procedure, short reaction times, perfect regioselectivity, high product yields, and use of a benign solvent and nontoxic catalyst are among the considerable advantages of this protocol. Furthermore, the catalyst was easily separated using an external magnet and reused several times without any significant loss of catalytic activity or magnetic properties.

Magnetically separable CoFe₂O₄/Cu(OH)₂ nanocomposite was prepared and used as a novel heterogeneous catalyst for synthesis of β-hydroxy-1,4-disubstituted-1,2,3-triazoles from epoxides.     

Facile synthesis of a hollow Ni–Fe–B nanochain and its enhanced catalytic activity for hydrogen generation from NaBH4 hydrolysis

A hollow Ni–Fe–B nanochain is successfully synthesized by a galvanic replacement method using a Fe–B nanocomposite and a NiCl₂ solution as the template and additional reagent, respectively. Both the concentration of Ni and the morphology of the resulting Ni–Fe–B alloy are controlled by varying the duration of the replacement process during the synthesis. The Ni–Fe–B sample synthesized for 60 min (Ni–Fe–B-60) shows the best catalytic activity at 313 K, with a hydrogen production rate of 4320 mL min⁻¹ g_cat⁻¹ and an activation energy for the NaBH₄ hydrolysis reaction of 33.7 kJ mol⁻¹. The good performance of Ni–Fe–B-60 towards the hydrolysis of NaBH₄ can be ascribed to both hollow nanochain structural and electronic effects. Furthermore, the effects of temperature, catalyst amount, and concentration of NaOH and NaBH₄ on the hydrolysis process are systematically studied, and an overall kinetic rate equation is obtained. The hollow Ni–Fe–B nanochain catalyst also shows good reusability characteristics and maintained its initial activity after 5 consecutive cycles.

A hollow Ni–Fe–B nanochain is successfully synthesized by a galvanic replacement method using a Fe–B nanocomposite and a NiCl₂ solution as the template and additional reagent, respectively.     

Highly efficient reduction of 4-nitrophenolate to 4-aminophenolate by Au/γ-Fe2O3@HAP magnetic composites

In this article, the catalyst Au/γ-Fe₂O₃@hydroxyapatite (Au/γ-Fe₂O₃@HAP) consisting of Au nanoparticles supported on the core–shell structure γ-Fe₂O₃@HAP was prepared through a deposition–precipitation method. The catalyst was characterized by transmission electron microscopy, X-ray powder diffraction, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, N₂ adsorption–desorption and atomic absorption spectrometry. The as-prepared Au/γ-Fe₂O₃@HAP exhibited excellent performance for the reduction of 4-nitrophenolate (4-NP) to 4-aminophenolate (4-AP) in the presence of NaBH₄ at room temperature. Thermodynamic and kinetic data on the reduction of 4-NP to 4-AP catalyzed by the as-prepared catalyst were studied. The as-prepared catalyst could be easily separated by a magnet and recycled 6 times with over 92% conversion of 4-NP to 4-AP. In addition, the as-prepared catalyst showed excellent catalytic performance on other nitrophenolates. The TOF value of this work on the reduction of 4-NP to 4-AP was 241.3 h⁻¹. Au/γ-Fe₂O₃@HAP might have a promising potential application on the production of 4-AP and its derivatives.

In this article, the catalyst Au/γ-Fe₂O₃@hydroxyapatite (Au/γ-Fe₂O₃@HAP) consisting of Au nanoparticles supported on the core–shell structure γ-Fe₂O₃@HAP was prepared through a deposition–precipitation method.