共查询到20条相似文献,搜索用时 15 毫秒
1.
Negin Ashrafi Azmah Hanim Mohamed Ariff Dong-Won Jung Masoud Sarraf Javad Foroughi Shamsuddin Sulaiman Tang Sai Hong 《Materials》2022,15(12)
An investigation into the addition of different weight percentages of Fe3O4 nanoparticles to find the optimum wt.% and its effect on the microstructure, thermal, magnetic, and electrical properties of aluminum matrix composite was conducted using the powder metallurgy method. The purpose of this research was to develop magnetic properties in aluminum. Based on the obtained results, the value of density, hardness, and saturation magnetization (Ms) from 2.33 g/cm3, 43 HV and 2.49 emu/g for Al-10 Fe3O4 reached a maximum value of 3.29 g/cm3, 47 HV and 13.06 emu/g for the Al-35 Fe3O4 which showed an improvement of 41.2%, 9.3%, and 424.5%, respectively. The maximum and minimum coercivity (Hc) was 231.87 G for Al-10 Fe3O4 and 142.34 G for Al-35 Fe3O4. Moreover, the thermal conductivity and electrical resistivity at a high weight percentage (35wt.%) were 159 w/mK, 9.9 × 10−4 Ω·m, and the highest compressive strength was 133 Mpa. 相似文献
2.
This work describes the thermal stability and magnetic properties of polyvinylidene fluoride (PVDF)/magnetite nanocomposites fabricated using the solution mixing technique. The image of transmission electron microscopy for PVDF/magnetite nanocomposites reveals that the 13 nm magnetite nanoparticles are well distributed in PVDF matrix. The electroactive β-phase and piezoelectric responses of PVDF/magnetite nanocomposites are increased as the loading of magnetite nanoparticles increases. The piezoelectric responses of PVDF/magnetite films are extensively increased about five times in magnitude with applied strength of electrical field at 35 MV/m. The magnetic properties of PVDF/magnetite nanocomposites exhibit supermagnetism with saturation magnetization in the range of 1.6 × 10−3–3.1 × 10−3 emu/g, which increases as the amount of magnetite nanoparticles increases. The incorporation of 2 wt % magnetite nanoparticles into the PVDF matrix improves the thermal stability about 25 °C as compared to that of PVDF. The effect of magnetite particles on the isothermal degradation behavior of PVDF is also investigated. 相似文献
3.
Nursyafiqah Zaini Norzilawati Mohamad Saiful Amri Mazlan Siti Aishah Abdul Aziz Seung-Bok Choi Norhiwani Mohd Hapipi Nur Azmah Nordin Nurhazimah Nazmi Ubaidillah Ubaidillah 《Materials》2021,14(23)
Common sensors in many applications are in the form of rigid devices that can react according to external stimuli. However, a magnetorheological plastomer (MRP) can offer a new type of sensing capability, as it is flexible in shape, soft, and responsive to an external magnetic field. In this study, graphite (Gr) particles are introduced into an MRP as an additive, to investigate the advantages of its electrical properties in MRPs, such as conductivity, which is absolutely required in a potential sensor. As a first step to achieve this, MRP samples containing carbonyl iron particles (CIPs) and various amounts of of Gr, from 0 to 10 wt.%, are prepared, and their magnetic-field-dependent electrical properties are experimentally evaluated. After the morphological aspect of Gr–MRP is characterized using environmental scanning electron microscopy (ESEM), the magnetic properties of MRP and Gr–MRP are evaluated via a vibrating sample magnetometer (VSM). The resistivities of the Gr–MRP samples are then tested under various applied magnetic flux densities, showing that the resistivity of Gr–MRP decreases with increasing of Gr content up to 10 wt.%. In addition, the electrical conductivity is tested using a test rig, showing that the conductivity increases as the amount of Gr additive increases, up to 10 wt.%. The conductivity of 10 wt.% Gr–MRP is found to be highest, at 178.06% higher than the Gr–MRP with 6 wt.%, for a magnetic flux density of 400 mT. It is observed that with the addition of Gr, the conductivity properties are improved with increases in the magnetic flux density, which could contribute to the potential usefulness of these materials as sensing detection devices. 相似文献
4.
Wei Jin Jiaan Liu Zhili Wang Yonghua Wang Zheng Cao Yaohui Liu Xianyong Zhu 《Materials》2015,8(11):7511-7518
Open-celled aluminum foams with different pore sizes were fabricated. A plasma electrolytic oxidation (PEO) treatment was applied on the aluminum foams to create a layer of ceramic coating. The sound absorption coefficients of the foams were measured by an impedance tube and they were calculated by a transfer function method. The experimental results show that the sound absorption coefficient of the foam increases gradually with the decrease of pore size. Additionally, when the porosity of the foam increases, the sound absorption coefficient also increases. The PEO coating surface is rough and porous, which is beneficial for improvement in sound absorption. After PEO treatment, the maximum sound absorption of the foam is improved to some extent. 相似文献
5.
Porous materials hold great potential in the field of sound absorption, but the most abundantly used materials, such as Polyurethane (PU) foam and polyvinyl chloride (PVC) foam, would inevitably bring environmental harms during fabrication. In this study, the nontoxic addition-molded room temperature vulcanized silicone rubber is chosen as the matrix, and NaCl particles are chosen as the pore forming agent to prepare open cell foams via the dissolve-separating foaming method. The effect of different amounts of NaCl (0–100 phr) on the cell structure, mechanical and sound absorption properties is investigated and analyzed. The results indicate that the cell structure could be tailored via changing the addition amount of NaCl, and open cell silicon rubber foams could be achieved with more than 20 phr NaCl addition. Open cell silicon foams show the most effective sound absorption for sound waves in middle frequency (1000–2000 Hz), which should be attributed to the improved impedance matching caused by the open cell structures. Additionally, the mechanical properties, including hardness, tensile strength and corresponding elastic properties, gradually decay to a steady value with the increasing addition amount of NaCl. Therefore, open cell silicone rubber foams are capable of sound absorption in middle frequency. 相似文献
6.
Seyed Nourallah Attyabi Seyed Mohammad Ali Radmanesh Seyyed Ali Seyyed Ebrahimi Hossein Dehghan Zahra Lalegani Bejan Hamawandi 《Materials》2022,15(22)
Mn52Al45.7C2.3 flakes with different sizes were prepared with two distinct surfactant-assisted ball-milling methods using cylindrical and barrel containers. Different microstructure and magnetic properties were measured based on the sequence of the container shape and different ball-milling times (2, 5, and 10 h). Morphology investigations showed that for powders milled in a barrel container, the amount of τ-phase was more compared to the samples milled in a cylindrical container. Moreover, in the powders milled with barrel containers, considerably higher magnetic properties were obtained in terms of saturation magnetization (Ms) and remanent magnetization (Mr) compared to those powders milled with cylindrical containers. Magnetic properties were found to be a function of the ball-milling time. High remanent magnetization and saturation magnetization have been found for powders milled in barrel containers, whereas only mediocre remanent magnetization and saturation magnetization have been measured in the case of milling in cylindrical containers. The highest Ms = 52.49 emu g−1 and Mr = 24.10 emu g−1 were obtained for the powders milled in barrel containers for 2 h. The higher magnetic properties taken from the milling in barrel containers is due to the higher shear stress and more uniform strain distribution induced by the barrel configuration, resulting in the stable τ-phase at a reasonably low-strain microstructure. 相似文献
7.
Xiaocui Yang Fei Yang Xinmin Shen Enshuai Wang Xiaonan Zhang Cheng Shen Wenqiang Peng 《Materials》2022,15(17)
For the common difficulties of noise control in a low frequency region, an adjustable parallel Helmholtz acoustic metamaterial (APH-AM) was developed to gain broad sound absorption band by introducing multiple resonant chambers to enlarge the absorption bandwidth and tuning length of rear cavity for each chamber. Based on the coupling analysis of double resonators, the generation mechanism of broad sound absorption by adjusting the structural parameters was analyzed, which provided a foundation for the development of APH-AM with tunable chambers. Different from other optimization designs by theoretical modeling or finite element simulation, the adjustment of sound absorption performance for the proposed APH-AM could be directly conducted in transfer function tube measurement by changing the length of rear cavity for each chamber. According to optimization process of APH-AM, The target for all sound absorption coefficients above 0.9 was achieved in 602–1287 Hz with normal incidence and that for all sound absorption coefficients above 0.85 was obtained in 618–1482 Hz. The distributions of sound pressure for peak absorption frequency points were obtained in the finite element simulation, which could exhibit its sound absorption mechanism. Meanwhile, the sound absorption performance of the APH-AM with larger length of the aperture and that with smaller diameter of the aperture were discussed by finite element simulation, which could further show the potential of APH-AM in the low-frequency sound absorption. The proposed APH-AM could improve efficiency and accuracy in adjusting sound absorption performance purposefully, which would promote its practical application in low-frequency noise control. 相似文献
8.
Rusila Zamani Abdul Rashid Nurul Azhani Yunus Saiful Amri Mazlan Norhasnidawani Johari Siti Aishah Abdul Aziz Nur Azmah Nordin Muntaz Hana Ahmad Khairi Mohd Aidy Faizal Johari 《Materials》2022,15(7)
Temperature is one of the most influential factors affecting the performance of elastomer matrix in magnetorheological elastomer (MRE). Previous studies have utilized silica as a reinforcing filler in polymer composite and as a coating material in MRE to improve the thermal stability of the base material. However, the usage of silica as an additive in the thermal stability of MRE has not been explored. Thus, in this study, the effect of silica as an additive on the temperature-dependent mechanical and rheological properties of ethylene propylene diene monomer (EPDM)-based MREs was investigated by using 30 wt.% carbonyl iron particles (CIPs) as the main filler, with different contents of silica nanoparticles (0 to 11 wt.%). The microstructure analysis was examined by using field-emission scanning electron microscopy (FESEM), while the thermal characterizations were studied by using a thermogravimetric analyzer and differential scanning calorimetry. The tensile properties were conducted by using Instron Universal Testing Machine in the absence of magnetic field at various temperatures. Meanwhile, the rheological properties were analyzed under oscillatory loadings in the influence of magnetic field, using a rotational rheometer at 25 to 65 °C. The results revealed that the temperature has diminished the interfacial interactions between filler and matrix, thus affecting the properties of MRE, where the tensile properties and MR effect decrease with increasing temperature. However, the presence of silica capable improved the thermal stability of EPDM-based MRE by enhancing the interactions between filler and matrix, thus reducing the interfacial defects when under the influence of temperature. Consequently, the incorporation of silica nanoparticles as an additive in EPDM-based MRE requires more exploration, since it has the potential to sustain the properties of MRE devices in a variety of temperature conditions. Thus, the study on the temperature-dependent mechanical and rheological properties of MRE is necessary, particularly regarding its practical applications. 相似文献
9.
Ern Kuzmann Israel Felner Laura Szirki Sndor Stichleutner Zoltn Homonnay Mahmoud R. El-Sharif Colin U. Chisholm 《Materials》2022,15(9)
Sn-Fe-Ni-Co quaternary alloys, in the composition range of 37–44 at% Sn, 35–39 at% Fe, 6–8 at% Ni and 13–17 at% Co, were prepared by direct current (DC) and pulse plating (PP) electrodeposition. The alloy deposits were characterized by XRD, 57Fe and 119Sn conversion electron Mössbauer spectroscopy, SEM-EDX and magnetization measurements. XRD revealed the amorphous character of the quaternary alloy deposits. The dominant ferromagnetic character of the deposits was shown by magnetization and Mössbauer spectroscopy measurements. Room temperature Mössbauer spectra showed minor paramagnetic phases, where their occurrences (~3–20%) are correlated to the electrodeposition parameters (Jdep from −16 to −23 mA/cm2 for DC, Jpulse from −40 to −75 mA/cm2 for PP), the composition and the saturation magnetization (~52–73 emu/g). A considerable difference was found in the magnetization curves applying parallel or perpendicular orientation of the applied fields, indicating magnetic anisotropy both in DC and pulse plated alloy coatings. 相似文献
10.
Yoon-Ji Yim Jae Jun Lee Alexandre Tugirumubano Sun Ho Go Hong Gun Kim Lee Ku Kwac 《Materials》2021,14(14)
In this study, soft magnetic metal was coated on carbon fibers (CFs) using an electroless FeCoNi-plating method to enhance the electromagnetic interference (EMI) shielding properties of CFs. Scanning electron microscopy, X-ray diffraction, and a vibrating sample magnetometer were employed to determine the morphologies, structural properties, and magnetic properties of the FeCoNi-CFs, respectively. The EMI shielding behavior of the FeCoNi-CFs was investigated in the frequency range of 300 kHz to 3 GHz through vector network analysis. The EMI shielding properties of the FeCoNi-CFs were significantly enhanced compared with those of the as-received CFs. The highest EMI shielding effectiveness of the 60-FeCoNi-CFs was approximately 69.4 dB at 1.5 GHz. The saturation magnetization and coercivity of the 60-FeCoNi-CFs were approximately 103.2 emu/g and 46.3 Oe, respectively. This indicates that the presence of FeCoNi layers on CFs can lead to good EMI shielding due to the EMI adsorption behavior of the magnetic metal layers. 相似文献
11.
FeSiBCCr amorphous powders were produced by a novel gas–water combined atomization process, and the corresponding MPCs (magnetic powder cores) were subsequently fabricated by phosphating treatment (0.4~1.6 wt.%), cold pressing (550~2350 MPa), and annealing (423~773 K), respectively. The results showed that the powders had high circularity, excellent thermal stability (ΔT = 59 K), and high saturation magnetization (0.83 T), which could provide raw powders for high-performance MPCs. With increasing phosphoric acid concentrations, despite the increase in DC-bias%, the uniformity of the insulation layers deteriorated, which led to a decrease in permeability and an increase in core loss. With increasing compaction pressures, the core loss increased continuously, and the permeability and DC-bias% first increased and then decreased. When annealing below the crystallization temperature, with increasing annealing temperatures, the permeability increased, and the core loss and DC-bias% decreased continuously. Under the optimized process of 0.4 wt.% phosphating concentration, 550 MPa pressure, and 773 K annealing temperature, the MPCs had a permeability of 21.54 ± 1.21, DC-bias% of 90.3 ± 0.2, and a core loss (Bm = 50 mT, f = 100 kHz) of 103.0 ± 26.3 mW cm−3. The MPCs had excellent high-frequency low-loss characteristics and showed great application potential under the development trends of high current, high power, and high frequency of electronic components. 相似文献
12.
Geovana L. Santana Murilo C. Crovace Ernesto E. Mazn Adilson J. A. de Oliveira Theo Z. Pavan Edgar D. Zanotto 《Materials》2022,15(9)
Magnetic hyperthermia (MHT) is a therapy that uses the heat generated by a magnetic material for cancer treatment. Magnetite nanoparticles are the most used materials in MHT. However, magnetite has a high Curie temperature (Tc~580 °C), and its use may generate local superheating. To overcome this problem, strontium-doped lanthanum manganite could replace magnetite because it shows a Tc near the ideal range (42–45 °C). In this study, we developed a smart composite formed by an F18 bioactive glass matrix with different amounts of Lanthanum-Strontium Manganite (LSM) powder (5, 10, 20, and 30 wt.% LSM). The effect of LSM addition was analyzed in terms of sinterability, magnetic properties, heating ability under a magnetic field, and in vitro bioactivity. The saturation magnetization (Ms) and remanent magnetization (Mr) increased by the LSM content, the confinement of LSM particles within the bioactive glass matrix also caused an increase in Tc. Calorimetry evaluation revealed a temperature increase from 5 °C (composition LSM5) to 15 °C (LSM30). The specific absorption rates were also calculated. Bioactivity measurements demonstrated HCA formation on the surface of all the composites in up to 15 days. The best material reached 40 °C, demonstrating the proof of concept sought in this research. Therefore, these composites have great potential for bone cancer therapy and should be further explored. 相似文献
13.
Maria Kuraska Roman Barczewski Mateusz Barczewski Aleksander Prociak Krzysztof Polaczek 《Materials》2020,13(24)
The main goal of this work was to evaluate the thermal insulation and sound absorption properties of open-cell rigid polyurethane foams synthesized with different contents of cooking oil-based polyol. The content of the applied bio-polyol as well as flame retardant (triethyl phosphate) in the foam formulation had a significant influence on the cellular structures of the materials. The open-cell polyurethane foams were characterized by apparent densities in the range 16–30 kg/m3. The sound absorption coefficients of the polyurethanes with various contents of bio-polyol were determined using the standing wave method (Kundt’s tube) in the frequency range of 100–6300 Hz. The effect of the content of the bio-polyol and flame retardant on the coefficient of thermal conductivity (at average temperatures of 0, 10 and 20 °C) as well as the compressive strength (at 20 and −10 °C) was analyzed. Different trends were observed in terms of the thermal insulation properties and sound absorption ability of the open-cell polyurethanes due to the addition of bio-polyol. In conclusion, it is necessary to use systems containing both petrochemical and bio-based raw materials. 相似文献
14.
Rui Pedro Silva Rui Soares Rui Neto Ana Reis Ricardo Paiva Rui Madureira Jos Silva 《Materials》2022,15(6)
The effect of the application of a rotating magnetic field on the average grain size of IN718 castings was experimentally studied. For the purpose, four parts were produced by investment casting and characterized. The first casting was produced without application of RMF for comparison. The remaining ones were submitted to different RMF frequencies for 15 min and subsequently to the pouring of the nickel-based superalloy. In these three castings, the RMF frequencies applied were, respectively, 15 Hz, 75 Hz and 150 Hz. All the other process parameters were kept constant during the execution of the experimental procedure. The average grain size of the samples was determined according to the ASTM E112-13 standard, using intercept methods. Macro hardness measurements, tensile testing and SEM-EDS analysis were conducted in order to evaluate the casting’s mechanical properties and microstructures. The results demonstrate a noticeable grain size reduction in the samples submitted to rotating magnetic field. An average grain area reduction, greater than 96%, was achieved in the castings where RMF frequencies of 75 Hz and 150 Hz were applied. The application of RMF also caused a morphological change in the casting’s dendrites from cellular to almost equiaxed. Additionally, it originated the decrease of the size and amount of needle-like δ phase. Regarding mechanical properties of the cast parts, no major differences were verified. 相似文献
15.
纳米级磁性多柔比星脂质体的制备 总被引:1,自引:0,他引:1
目的制备纳米级磁性多柔比星脂质体(DOX—MLP)。方法用反相蒸发法制备纳米级DOX-MLP,以正交实验设计确定最佳制备工艺。电镜观察脂质体形态,zetapal粒度分析仪测量其粒径,紫外sephadex G-50法测定其包封率,磁测仪测量其磁响应性。结果DOX-MLP呈圆形或椭圆形,粒径为(293.4±20.6)nm,包封率为30.8%±3.27%,磁响应性(50.28±7.8)emu。结论用反相蒸发法制备的磁性多柔比星脂质体平均粒径小,磁响应性高,达到纳米级标准。 相似文献
16.
Beatriz C. Ribeiro Cristina A. R. Alvarez Brbara C. Alves Juliana M. Rodrigues Maria Joo R. P. Queiroz Bernardo G. Almeida Ana Pires Andr M. Pereira Joo P. Araújo Paulo J. G. Coutinho Ana Rita O. Rodrigues Elisabete M. S. Castanheira 《Materials》2022,15(5)
The development of stimuli-sensitive drug delivery systems is a very attractive area of current research in cancer therapy. The deep knowledge on the microenvironment of tumors has supported the progress of nanosystems’ ability for controlled and local fusion as well as drug release. Temperature and pH are two of the most promising triggers in the development of sensitive formulations to improve the efficacy of anticancer agents. Herein, magnetic liposomes with fusogenic sensitivity to pH and temperature were developed aiming at dual cancer therapy (by chemotherapy and magnetic hyperthermia). Magnetic nanoparticles of mixed calcium/manganese ferrite were synthesized by co-precipitation with citrate and by sol–gel method, and characterized by X-ray diffraction (XRD), scanning electron microscopy in transmission mode (STEM), and superconducting quantum interference device (SQUID). The citrate-stabilized nanoparticles showed a small-sized population (around 8 nm, determined by XRD) and suitable magnetic properties, with a low coercivity and high saturation magnetization (~54 emu/g). The nanoparticles were incorporated into liposomes of dipalmitoylphosphatidylcholine/cholesteryl hemisuccinate (DPPC:CHEMS) and of the same components with a PEGylated lipid (DPPC:CHEMS:DSPE-PEG), resulting in magnetoliposomes with sizes around 100 nm. Dynamic light scattering (DLS) and electrophoretic light scattering (ELS) measurements were performed to investigate the pH-sensitivity of the magnetoliposomes’ fusogenic ability. Two new antitumor thienopyridine derivatives were efficiently encapsulated in the magnetic liposomes and the drug delivery capability of the loaded nanosystems was evaluated, under different pH and temperature conditions. 相似文献
17.
Dhayalini Balasubramanian Senthil Rajendran Bhuvanesh Srinivasan Nirmalakumari Angamuthu 《Materials》2020,13(22)
The current study deals with the analysis of sound absorption characteristics of foxtail millet husk powder. Noise is one the most persistent pollutants which has to be dealt seriously. Foxtail millet is a small seeded cereal cultivated across the world and its husk is less explored for its utilization in polymer composites. The husk is the outer protective covering of the seed, rich in silica and lingo-cellulose content making it suitable for sound insulation. The acoustic characterization is done for treated foxtail millet husk powder and polypropylene composite panels. The physical parameters like fiber mass content, density, and thickness of the composite panel were varied and their influence over sound absorption was mapped. The influence of porosity, airflow resistance, and tortuosity was also studied. The experimental result shows that 30-mm thick foxtail millet husk powder composite panel with 40% fiber mass content, 320 kg/m3 density showed promising sound absorption for sound frequency range above 1000 Hz. We achieved noise reduction coefficient (NRC) value of 0.54. In view to improve the performance of the panel in low-frequency range, we studied the efficiency of incorporating air gap and rigid backing material to the designed panel. We used foxtail millet husk powder panel of density 850 kg/m3 as rigid backing material with varying air gap thickness. Thus the composite of 320 kg/m3 density, 30-mm thick when provided with 35-mm air gap and backing material improved the composite’s performance in sound frequency range 250 Hz to 1000 Hz. The overall sound absorption performance was improved and the NRC value and average sound absorption coefficient (SAC) were increased to 0.7 and 0.63 respectively comparable with the commercial acoustic panels made out of the synthetic fibers. We have calculated the sound absorption coefficient values using Delany and Bezlay model (D&B model) and Johnson–Champoux–Allard model (JCA model) and compared them with the measured sound absorption values. 相似文献
18.
Siti Aishah Abdul Aziz Saiful Amri Mazlan Ubaidillah Ubaidillah Norzilawati Mohamad Michal Sedlacik Nur Azmah Nordin Nurhazimah Nazmi 《Materials》2021,14(17)
Polymer composites have been widely used as damping materials in various applications due to the ability of reducing the vibrations. However, the environmental and surrounding thermal exposure towards polymer composites have affected their mechanical properties and lifecycle. Therefore, this paper presents the effect of material-temperature dependence on the loss factor and phase shift angle characteristics. Two types of unageing and aging silicone-rubber-based magnetorheological elastomer (SR-MRE) with different concentrations of carbonyl iron particles (CIPs), 30 and 60 wt%, are utilized in this study. The morphological, magnetic, and rheological properties related to the loss factor and phase shift angle are characterized using a low-vacuum scanning electron microscopy, and vibrating sample magnetometer and rheometer, respectively. The morphological analysis of SR-MRE consisting of 30 wt% CIPs revealed a smoother surface area when compared to 60 wt% CIPs after thermal aging due to the improvement of CIPs dispersion in the presence of heat. Nevertheless, the rheological analysis demonstrated inimitable rheological properties due to different in-rubber structures, shear deformation condition, as well as the influence of magnetic field. No significant changes of loss factor occurred at a low CIPs concentration, whilst the loss factor increased at a higher CIPs concentration. On that basis, it has been determined that the proposed changes of the polymer chain network due to the long-term temperature exposure of different concentrations of CIPs might explain the unique rheological properties of the unaged and aged SR-MRE. 相似文献
19.
Eduard V. Monaico Vadim Morari Maksim Kutuzau Veaceslav V. Ursaki Kornelius Nielsch Ion M. Tiginyanu 《Materials》2022,15(18)
Uniform nanogranular NiFe layers with Ni contents of 65%, 80%, and 100% have been electroplated in the potentiostatic deposition mode on both planar substrates and arrays of nanowires prepared by the anodization of GaAs substrates. The fabricated planar and coaxial core-shell ferromagnetic structures have been investigated by means of scanning electron microscopy (SEM) and vibrating sample magnetometry (VSM). To determine the perspectives for applications, a comparative analysis of magnetic properties, in terms of the saturation and remanence moment, the squareness ratio, and the coercivity, was performed for structures with different Ni contents. 相似文献
20.
Milena Leszczyska Elbieta Malewska Joanna Ryszkowska Maria Kuraska Micha Gloc Micha K. Leszczyski Aleksander Prociak 《Materials》2021,14(7)
The reported study concerns the introduction of renewable raw materials into the formulation of rigid polyurethane foams in the quest for the sustainable development of polymer composites. In this study, rigid polyurethane foam composites were prepared using 75 wt.% of rapeseed oil-based polyol and 15 parts per hundred parts of polyol (php) of natural fillers such as chokeberry pomace, raspberry seeds, as well as hazelnut and walnut shells. The influence of the used raw materials on the foaming process, structure, and properties of foams was investigated using a FOAMAT analyzer and a wide selection of characterization techniques. The introduction of renewable raw materials limited reactivity of the system, which reduced maximum temperature of the foaming process. Moreover, foams prepared using renewable raw materials were characterized by a more regular cell structure, a higher share of closed cells, lower apparent density, lower compressive strength and glass transition temperature, low friability (<2%), low water absorption (<1%), high dimensional stability (<±0.5%) and increased thermal stability. The proper selection and preparation of the renewable raw materials and the rational development of the polyurethane recipe composition allow for the preparation of environmentally-friendly foam products with beneficial application properties considering the demands of the circular economy in the synthesis of rigid foams. 相似文献