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1.
This paper presents a comprehensive evaluation on self-compacting (SC) mortars incorporating 0, 1, 3, and 5% alumina nanoparticles (NA) as well as 0% and 30% rice husk ash (RHA) used as Portland cement replacement. To evaluate the workability, mechanical, and durability performance of SC mortars incorporating NA and RHA, the fresh properties (slump flow diameter and V-funnel flow time), hardened properties (compressive strength, flexural strength, and ultrasonic pulse velocity), and durability properties (water absorption, rapid chloride permeability, and electrical resistivity) were determined. The results indicated that the addition of NA and RHA has negligible effect on the workability and water absorption rate of the SC mortars. However, significant compressive and flexural strength development was observed in the SC mortars treated with NA or the combination of NA and RHA. The introduction of RHA and NA also reduced the rapid chloride permeability and enhanced the electrical resistivity of the SC mortars significantly. It is concluded that the coexistence of 30% RHA and 3% NA as cement replacement in SC mortars can provide the best mechanical and durability performance.  相似文献   

2.
Superabsorbent polymers (SAPs) are used as internal curing agents in cementitious materials, which reduce autogenous shrinkage in concrete as they have a low water-to-cement ratios and improve the freeze–thaw resistance. However, the compressive strength of concrete may also be reduced due to additional voids in the hydrated cement matrix. In this study, we fabricated a delayed absorption type of SAP (I-SAP) composed of cross-linked modified acrylate and studied its absorption characteristics and effect on compressive strength after 28 days. Furthermore, the effect of curing conditions on the strength of concrete and hydrated cement paste with SAP were investigated. The absorption capacity of I-SAP in the synthetic pore solution and deionised water was examined and compared with that of a conventional SAP, and the former was absorbed more by I-SAP. The results revealed that the compressive strength of concrete increased with the addition of I-SAP, particularly with the curing condition of 60% RH. Although the compressive strength of hydrated cement paste with I-SAP reduced in water or sealed curing conditions, no loss of strength in the paste cured at 60% RH was seen. The cement matrix densification due to hydration of belite around the SAP surface is the main mechanism for strength development in concrete cured at sealed and 60% RH. However, the voids formed by SAP control the compressive strength of hydrated paste.  相似文献   

3.
In order to solve the problem of lack of natural river sand, crushed waste oyster shells (WOS) were used to replace river sand. By replacing 20% river sand, WOS mortar with different particle sizes of WOS were made for the experiment. Through experimental observation, the initial slump and slump flow loss rate were studied. The effects of different particle sizes and curing times on the compressive strength, flexural strength, static elastic modulus, and dry shrinkage of WOS mortar were analyzed. The relationship formulas between the compressive strength, flexural strength, particle size, and curing age were proposed. The results showed that the setting time and slump flow decreased with a decrease in the particle size of WOS. It was also found that the mortar with fine crushed WOS had high compressive strength, flexural strength, and static elastic modulus at both early and long-term curing age. A formula was proposed to describe the development of the compressive strength with the particle size of WOS and curing time, and the relations among these mechanical properties were discussed. Furthermore, drying shrinkage increased when WOS was used and could not satisfy the standard requirement of 0.075%. In contrast, the addition of fine WOS and double-dose sulfonated naphthalene-formaldehyde superplasticizer (SNF SP) reduced the shrinkage rate of the mortar by 8.35% and provided better workability and mechanical properties for mortar.  相似文献   

4.
This study focuses on the effects of superabsorbent polymers (SAP) and belite-rich Portland cement (BPC) on the compressive strength, autogenous shrinkage (AS), and micro- and macroscopic performance of sustainable, ultra-high-performance paste (SUHPP). Several experimental studies were conducted, including compressive strength, AS, isothermal calorimetry, X-ray diffraction (XRD), thermogravimetric analysis (TGA), attenuated total reflectance (ATR)–Fourier-transform infrared spectroscopy (FTIR), ultra-sonic pulse velocity (UPV), and electrical resistivity. The following conclusions can be made based on the experimental results: (1) a small amount of SAP has a strength promotion effect during the first 3 days, while BPC can significantly improve the strength over the following 28 days. (2) SAP slows down the internal relative humidity reduction and effectively reduces the development of AS. BPC specimens show a lower AS than other specimens. The AS shows a linear relationship with the internal relative humidity. (3) Specimens with SAP possess higher cumulative hydration heat than control specimens. The slow hydration rate in the BPC effectively reduces the exothermic heat. (4) With the increase in SAP, the calcium hydroxide (CH) and combined water content increases, and SAP thus improves the effect on cement hydration. The contents of CH and combined water in BPC specimens are lower than those in the ordinary Portland cement (OPC) specimen. (5) All samples display rapid hydration of the cement in the first 3 days, with a high rate of UPV development. Strength is an exponential function of UPVs. (6) The electrical resistivity is reduced due to the increase in porosity caused by the release of water from SAP. From 3 to 28 days, BPC specimens show a greater increment in electrical resistivity than other specimens.  相似文献   

5.
This work aims to investigate the effects of multi-walled carbon nanotubes (MWCNTs) on the strength and electrical properties of cement mortar. MWCNTs were added to cement mortar in four different concentrations: 0.00 wt.%, 0.01 wt.%, 0.015 wt.%, and 0.02 wt.% by the mass of cement. The consistency, density, setting time and compressive and flexural strength of mixes were tested and analyzed at 28 and 90 days curing time. Mechanical performance tests confirm an increase of 25% and 20% in the ultimate compressive and flexural strength respectively, which results from MWCNT 0.02 wt.% loading at 90 days curing time. The resistivity measurements in mortars with 0.01 and 0.015 wt.% MWCNT loading result up to 10% decrement at both 28 and 90 days curing. Activation energy calculations show fully accordance with these statements, resuming that 0.01 wt.% MWCNT appears to be the most effective loading scheme to produce certain conductivity enhancement in cement mortar.  相似文献   

6.
In this paper, an ultrahigh-strength marine concrete containing coral aggregates is developed. Concrete fabricated from marine sources is considered an effective and economical alternative for marine engineering and the construction of remote islands. To protect sea coral ecosystems, the coral aggregates used for construction are only efflorescent coral debris. To achieve the expected mechanical performance from the studied concrete, an optimal mixture design is conducted to determine the optimal proportions of components, in order to optimize the compressive strength. The mechanical properties and the autogenous shrinkage, as well as the heat flow of early hydration reactions, are measured. The hydration products fill up the pores of coral aggregates, endowing our concrete with flowability and self-compacting ability. The phases in the marine concrete are identified via X-ray diffraction analysis. The 28-day compressive and flexural strength of the developed marine concrete achieve 116.76 MPa and 18.24 MPa, respectively. On account of the lower cement content and the internal curing provided by coral aggregates, the volume change resulting from autogenous shrinkage is only 63.11% of that of ordinary reactive powder concrete.  相似文献   

7.
The substitution of river sand with glass aggregate (GA) and cement with glass powder (GP) is a mainstream method to recycle waste glass. Traditionally, standard curing was widely used for glass-based mortars. However, it is time-consuming and cannot address low mechanical strengths of the early-age mortars. Therefore, the effect of water curing at 80 °C on the properties of GA mortars is investigated. Furthermore, the effect of the GP size is also considered. Results show that compared with the expansion of alkali-silica reaction (ASR), water curing at 80 °C has a negligible effect on the volume change. Moreover, the compressive strength of GA mortars under 1-day water curing at 80 °C is comparable with that under 28-day water curing at 20 °C. Therefore, the 1-day water curing at 80 °C is proposed as an accelerated curing method for GA mortars. On the other hand, the addition of GP with the mean size of 28.3 and 47.9 μm can effectively mitigate the ASR expansion of GA mortars. Compared with the size of 28.3 μm, GA mortars containing GP (47.9 μm) always obtain higher compressive strength. In particular, when applying the 1-day water curing at 80 °C, GA mortars containing GP (47.9 μm) can even gain higher strength than those containing fly ash.  相似文献   

8.
Ultra-High Performance Concretes (UHPC) are cement-based materials with a very low water-to-binder ratio that present a very-high compressive strength, high tensile strength and ductility as well as excellent durability, making them very interesting for various civil engineering applications. However, one drawback of UHPC is their pretty high autogenous shrinkage stemming from their very low water-to-binder ratio. There are several options to reduce UHPC shrinkage, such as the use of fibers (steel fibers, polypropylene fibers, wollastonite microfibers), shrinkage-reducing admixtures (SRA), expansive admixtures (EA), saturated lightweight aggregates (SLWA) and superabsorbent polymers (SAP). Other factors related to curing conditions, such as humidity and temperature, also affect the shrinkage of UHPC. The aim of this paper is to investigate the impact of various SRA, different mixing and curing conditions (low to moderate mixing temperatures, moderate to high relative humidity and water immersion) as well as different curing starting times and durations on the shrinkage of UHPC. The major importance of the initial mixing and curing conditions has been clearly demonstrated. It was shown that the shrinkage of the UHPC was reduced by more than 20% at early-age and long-term when the fresh UHPC temperature was closer to 20 °C. In addition, curing by water immersion led to drastic reductions in shrinkage of up to 65% and 30% at early-age and long-term, respectively, in comparison to a 20% reduction for fog curing at early-age. Finally, utilization of a liquid polyol-based SRA allowed for reductions of 69% and 63% of early-age and long-term shrinkages, respectively, while a powder polyol-based SRA provided a decrease of 47% and 35%, respectively.  相似文献   

9.
The effect of the dosage of sulphur-containing tailings (STs) and curing temperature on the properties of M32.5 cement mortar was studied in this work. An experimental study was conducted to evaluate the effects of STs with different substitution ratios (0, 10%, 20%, 30%, 40%) on the compressive strength experiment, fluidity, expansion ratio, and pore structure of M32.5 cement mortar. The results showed that the addition of STs reduced the fluidity of mortar, and the fluidity decreased with the increase of the STs dosage. The compressive strength of mortars increased at a lower substitution rate (0~20%) but decreased at a higher substitution rate (>20%). Ettringite peaks and new sulfate peaks were found by X-ray diffraction (XRD) analysis. Scanning electron microscope (SEM) observation of the microstructure showed that a large number of hydrated products, such as ettringite, formed and filled in the interstitial space, which was conducive to the development of strength. The optimal STs replacement ratio of river sand was 10%. Then, the performance of mortar at curing temperatures of 23 ± 1, 40, 60, and 80 °C was further investigated under the optimal STs replacement ratio. Under high-temperature curing conditions, the early strength of M32.5 cement mortar with STs increased greatly, but the late strength decreased gradually with the increase in curing temperature. The early strength development of the mortar mainly depended on the high speed of hydration reaction, and the late strength variation was mainly affected by hydration products and the pore size distribution. After comprehensive consideration, the optimal curing temperature of M32.5 cement mortar with STs was 40 °C.  相似文献   

10.
The effects of mono (single type) and hybrid (mixed types) fibres on the workability, compressive strength, flexural strength, and toughness parameters of fly ash geopolymer mortar were studied. The ratio of sand to geopolymer paste of the mortar was 2.75. It was found that workability of mortar decreased more with the use of PP fibres due to its higher dispersion into individual filaments in geopolymer mortar compared to the bundled ARG and PVA fibres. Compressive strength increased by 14% for using 1% steel with 0.5% PP fibres compared to that of the control mixture, which was 48 MPa. However, 25 to 30% decrease of compressive strength was observed in the mortars using the low-modulus fibres. Generally, flexural strength followed the trend of compressive strength. Deflection hardening behaviours in terms of the ASTM C1609 toughness indices, namely I5, I10 and I20 were exhibited by the mortars using 1% steel mono fibres, 0.5% ARG with 0.5% steel and 1% PVA with 0.5% steel hybrid fibres. The toughness indices and residual strength factors of the mortars using the other mono or hybrid fibres at 1 or 1.5% dosage were relatively low. Therefore, multiple cracking and deflection hardening behaviours could be achieved in fly ash geopolymer mortars of high sand to binder ratio by using steel fibres in mono or hybrid forms with ARG and PVA fibres.  相似文献   

11.
The reduction of the moisture content of concrete during the drying process reduces the concrete’s volume and causes it to shrink. In general, concrete shrinkage is a phenomenon that causes concrete volume to dwindle and can lead to durability problems. There are different types of this phenomenon, among them chemical shrinkage, autogenous shrinkage, drying shrinkage including free shrinkage and restrained shrinkage, and thermal contraction. Shrinkage-reducing admixtures are commercially available in different forms. The present study investigates the effect of liquid propylene glycol ether on mechanical properties and free shrinkage induced by drying at different water-cement (w/c) ratios. Furthermore, the effect of shrinkage-reducing admixtures on the properties of hardened concrete such as compressive and tensile strength, electrical resistivity, modulus of elasticity, free drying shrinkage, water absorption, and depth of water penetration was investigated. The results indicated that shrinkage reducing agents performed better in a low w/c ratio and resulted in up to 50% shrinkage reduction, which was due to the surface reduction of capillary pores. The prediction of free shrinkage due to drying was also performed using an artificial neural network.  相似文献   

12.
Self-healing cementitious materials are a promising means for ensuring sustainable concrete infrastructure and promoting long-term service lives. To obtain microcapsules that are versatile in varying environments, in this study, absorbing microcapsules with calcium alginate as the shell and epoxy resin as the core were prepared. The absorbing microcapsules exhibit self-healing and can reduce the shrinkage of cementitious materials. Volume changes of the microcapsules in the hardened paste with increasing hydration age were observed using three-dimensional X-ray computed tomography. In the hardened cement paste with a water-cement ratio of 0.29, the absorption of the microcapsules lasted for several days, and the release of water lasted for 28 days. The absorption of microcapsules affected the fluidity of cement paste, and it was significantly weakened and delayed due to the lower absorption rate. The addition of absorbing microcapsules significantly reduced the autogenous and drying shrinkage of mortars. For microcapsules with a core content of 55% added at 3.5% of cement weight, autogenous shrinkage was almost eliminated. Most importantly, the addition of absorbing microcapsules could achieve a certain degree of recovery of compressive strength as well as satisfactory recovery of impermeability in dry and wet environments.  相似文献   

13.
The influence of four naturally occurring mineral additives (zeolite, diatomite, trass and bentonite) on the hydration and properties of cement pastes and mortars was investigated. The materials change the phase composition, heat of hydration (determined by calorimetry) and mechanical properties of composites. After 28 days, the amount of Ca(OH)2 was reduced by up to 23% and up to 35% more C-S-H was formed, as proved by TG measurements. Differences were observed in the kinetics of heat release, especially for 25% of the addition. In the calorimetric curves, an additional exothermic effect is observed, related to the alteration in the hydration of C3A in cement. From the point of view of beneficial influence on mechanical properties of mortars, the additives could be ranked as follows: bentonite < diatomite, zeolite < trass after 2 days and bentonite < diatomite < trass < zeolite after 28 days of curing. The highest compressive strength (58.5 MPa) was observed for the sample with a 10% addition of zeolite. Zeolite, trass, bentonite and diatomite are all pozzolanic materials; however, their activity varies to an extent due to the differences in their specific surface area and the content of the amorphous phase, responsible for the pozzolanic reaction.  相似文献   

14.
Coral sand cement (CSC) mortar is increasingly used in reef projects, which is prepared by mixing coral sand with cement and water in certain proportions. Considering that early-age hydration behavior is closely related to the strength and durability of the mortar, the early-age hydration process and micro-morphology of CSC mortars with various water–cement ratios (W/C) and sand–cement ratios (S/C) were studied. A monitoring system based on FBG is proposed in this paper, which uses the high sensitivity and conformability of optical fiber to measure the hydration temperature and internal shrinkage strain simultaneously and continuously. The standard sand cement (SSC) mortar with the same sand gradation and mix proportion is also prepared for comparison. The micro-morphology is observed by a scanning electron microscope (SEM) for measurement results’ explanation. The results show that the variation of the hydration temperature and shrinkage strain with hydration time of both CSC mortars and SSC mortars follow a unimodal function. Differently, the peak hydration temperature for CSC is obviously lower than that of SSC. The peak temperature of CSC mortar decreases linearly with the increase in S/C, and the decrease rate of the peak temperature is higher for CSC with small W/C than that with higher W/C. For mortars with lower W/C, the peak shrinkage strain of CSC is larger than that of SSC. Meanwhile, for mortars with higher W/C, the peak shrinkage strain of CSC changes to be lower than that of SSC, which is attributed to the significant water absorption characteristic of CSC. Therefore, as an eco-friendly lightweight aggregate, CS is more suitable than SS for the design of high W/C and alleviating the hydration heat of mass concrete under the meeting of strength.  相似文献   

15.
In recent years, partial replacement of cement with bagasse ash has been given attention for construction application due to its pozzolanic characteristics. Sugarcane bagasse ash and fine bagasse particles are abundant byproducts of the sugar industries and are disposed of in landfills. Our study presents the effect of burning bagasse at different temperatures (300 °C and 600 °C) on the compressive strength and physical properties of bagasse ash-blended mortars. Experimental results have revealed that bagasse produced more amorphous silica with very low carbon contents when it was burned at 600 °C/2 h. The compressive strength of mortar was improved when 5% bagasse ash replaced ordinary portland cement (OPC) at early curing ages. The addition of 10% bagasse ash cement also increased the compressive strength of mortars at 14 and 28 days of curing. However, none of the bagasse ash-blended portland pozzolana cement (PPC) mortars have shown improvement on compressive strength with the addition of bagasse ash. Characterization of bagasse ash was done using XRD, DTA-TGA, SEM, and atomic absorption spectrometry. Moreover, durability of mortars was checked by measuring water absorption and apparent porosity for bagasse ash-blended mortars.  相似文献   

16.
Concrete undergoes shrinkage regardless of the influence of external forces. The deformation of concrete is crucial for the structural stability of high-rise and large-scale buildings. In this study, the shrinkage and compressive creep of 70–90 MPa high-strength concrete used in high-rise buildings were evaluated based on the curing conditions (sealed/unsealed), and the existing prediction models were examined. It was observed that the curing condition does not significantly affect the mechanical properties of high-strength concrete, but the use of limestone coarse aggregate increases the elastic modulus when compared to granite coarse aggregate. The autogenous shrinkage of high-strength concrete is greater than that of normal-strength concrete owing to self-desiccation, resulting in a large variation from the value predicted by the model. The drying shrinkage was observed to be similar to that predicted by the model. Compressive creep was affected by the curing conditions, compressive strength, loading level, and loading age. The compressive creep of high-strength concrete varied significantly from the prediction results of ACI 209; ACI 209 was modified based on the measured values. The shrinkage and compressive creep characteristics of high-strength concrete must be reflected to predict the deformation of an actual structure exposed to various conditions.  相似文献   

17.
This research investigates the mechanism of metakaolin for mitigating the autogenous and drying shrinkages of alkali-activated slag with regard to the activator parameters, including concentration and modulus. The results indicate that the incorporation of metakaolin can decrease the initial viscosity and setting time. Increasing activator concentration can promote the reaction process and shorten the setting time. An increase in the metakaolin content induces a decrease in compressive strength due to reduced formation of reaction products. However, increasing activator dosage and modulus can improve the compressive strength of alkali-activated slag containing 30% metakaolin. The inclusion of metakaolin can mitigate the autogenous and drying shrinkage of alkali-activated slag by coarsening the pore structure. On the other hand, increases in activator concentration and modulus result in an increase in magnitude of the autogenous and drying shrinkage of alkali-activated slag containing metakaolin. The influence of the activator modulus on the shrinkage behavior of alkali-activated slag-metakaolin binary system should be further investigated.  相似文献   

18.
Nowadays, effective and eco-friendly ways of using waste materials that could replace natural resources (for example, sand) in the production of concrete composites are highly sought. The article presents the results of research on geopolymer composites produced from two types of waste materials—hemp and fine fractions recovered from recycled cement concrete, which were both used as a replacement for standard sand. A total of two research experiments were conducted. In the first experiment, geopolymer mortars were made using the standard sand, which was substituted with recycled fines, from 0% to 30% by weight. In the second study, geopolymers containing organic filler were designed, where the variables were (i) the amount of hemp and the percent of sand by volume (0%, 2.5%, and 5%) and(ii) the amount of hydrated lime and the percent of fly ash (by weight) (0%, 2%, and 4%) that were prepared. In both cases, the basic properties of the prepared composites were determined, including their flexural strength, compressive strength, volume density in a dry and saturated state, and water absorption by weight. Observations of the microstructure of the geopolymers using an electron and optical microscope were also conducted. The test results show that both materials (hemp and recycled fines) and the appropriate selection of the proportions of mortar components and can produce composites with better physical and mechanical properties compared to mortars made of only natural sand. The detailed results show that recycled fines (RF) can be a valuable substitute for natural sand. The presence of 30% recycled fines (by weight) as a replacement for natural sand in the alkali-activated mortar increased its compressive strength by 26% and its flexural strength by 9% compared to control composites (compared to composites made entirely of sand without its alternatives). The good dispersion of both materials in the geopolymer matrix probably contributed to filling of the pores and reducing the water absorption of the composites. The use of hemp as a sand substitute generally caused a decrease in the strength properties of geopolymer mortar, but satisfactory results were achieved with the substitution of 2.5% hemp (by volume) as a replacement for standard sand (40 MPa for compressive strength, and 6.3MPa for flexural strength). Both of these waste materials could be used as a substitute for natural sand and are examples of an eco-friendly and sustainable substitution to save natural, non-renewable resources.  相似文献   

19.
Carbon dioxide is the main component of greenhouse gases, which are responsible for an increase in global temperature. The utilization of carbon dioxide in cement-based materials is an effective way to capture this gas. In this paper, the influence of carbon dioxide curing on the setting time, the electrical resistivity, dry shrinkage ratio, water absorption by unit area and mechanical strengths (flexural and compressive strengths) were determined. The scanning electron microscope, X-ray diffraction and thermogravimetric analysis were obtained to investigate the mechanism of carbonation reaction of cement paste. Water–cement ratios of cement paste were selected to be 0.3, 0.4 and 0.5. Results showed that carbon dioxide curing could accelerate the setting of cement paste. The electrical resistivity decreased with the increasing water–cement ratio and increased with the carbon dioxide curing. Moreover, the evaluation function for the curing age and dry shrinkage rate or the mechanical strengths fit well with the positive correlation quadratic function. The water absorption by unit area increased linearly with the testing time. The carbon dioxide curing led to increasing the mechanical strengths and the dry shrinkage ratio. Meanwhile, the carbon dioxide curing demonstrated a decreasing effect on the water absorption by unit area. The mechanical strengths were improved by the carbon dioxide curing and increased in the form of quadratic function with the curing age. As obtained from the microscopic findings, that the carbon dioxide curing could accelerate the reaction of cement and improve the compactness of cement paste.  相似文献   

20.
The increasing annual emissions of iron ore tailings have proved a great threat to the natural environment, and the shortage of natural river sand, as well as the pursuit of sustainable development materials, provides motivation to reuse iron ore tailings as a fine aggregate in concrete. Due to the significantly different properties of iron tailings sand compared with natural river sand—such as the higher density, higher content of limestone particles smaller than 75 μm and its rough and angular shape—concretes prepared with iron tailings sand show remarkably higher shrinkage. This study presents the shrinkage characterization and shrinkage-reducing efficiency of three different methods on iron tailings, sand concrete and river sand concrete. The internal humidity was also monitored to reveal the shrinkage-reducing mechanism. The obtained results indicated that the autogenous and total shrinkage of iron tailings sand concrete were 9.8% and 13.3% higher than the river sand concrete at the age of 90 d, respectively. The shrinkage reducing agent (SRA) was the most effective shrinkage reducing method for river sand concrete, while for iron tailings sand concrete, super absorbent polymer (SAP) and controlled permeable formwork liner (CPFL) it worked best on autogenous shrinkage and drying shrinkage, respectively. Furthermore, the shrinkage mitigation strategies worked earlier for the drying shrinkage behavior of iron tailings sand concrete, while no such condition could be found for autogenous shrinkage.  相似文献   

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