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1.
Cement production is environmentally unsustainable due to the high anthropogenic carbon emissions produced. Supplementary cementitious materials (SCMs), derived from the by-products of different industries, have been deemed an effective way to reduce carbon emissions. The reduction in carbon emissions is achieved by lowering the clinker factor of cement, through a partial replacement with an SCM. Sugarcane Bagasse Ash (SCBA) is produced as an agricultural waste from the sugarcane industry and has gained a lot of attention for being a feasible and readily available pozzolanic material, underutilised as an SCM. This study evaluates alkali-activated sugarcane bagasse ash’s mechanical and durability performance, at varied contents, in binary blended cement concrete and ternary blended cement concrete containing silica fume (SF). Potassium Hydroxide (KOH), used as the alkali activator, is intended to enhance the reactivity of the ash, with the possibility of a high-volume SCBA content. The mechanical performance was investigated by compressive and split tensile strength tests, and durability performance was investigated using the Oxygen Permeability Index (OPI) test. In addition, a micro-CT porosity test was conducted to assess how the microstructure and porosity of the concrete affect the mechanical and durability performance. The results indicated that using SCBA in a ternary blend with SF can significantly improve the overall performance and create less porous concrete. At 30% SCBA and 10% SF replacement, the performance tests revealed the highest mechanical strength and the lowest permeability, outperforming the control concrete and the binary blended cement concrete containing only SCBA.  相似文献   

2.
Cracks in typical mortar constructions enhance water permeability and degrade ions into the structure, resulting in decreased mortar durability and strength. In this study, mortar samples are created that self-healed their cracks by precipitating calcium carbonate into them. Bacillus subtilus bacterium (10−7, 10−9 cells/mL), calcium lactate, fine aggregate, OPC-cement, water, and bagasse ash were used to make self-healing mortar samples. Calcium lactates were prepared from discarded eggshells and lactic acid to reduce the cost of self-healing mortars, and 5% control burnt bagasse ash was also employed as an OPC-cement alternative. In the presence of moisture, the bacterial spores in mortars become active and begin to feed the nutrient (calcium lactate). The calcium carbonate precipitates and plugs the fracture. Our experimental results demonstrated that cracks in self-healing mortars containing bagasse ash were largely healed after 3 days of curing, but this did not occur in conventional mortar samples. Cracks up to 0.6 mm in self-healing mortars were filled with calcite using 10−7 and 10−9 cell/mL bacteria concentrations. Images from an optical microscope, X-ray Diffraction (XRD), and a scanning electron microscope (SEM) were used to confirm the production of calcite in fractures. Furthermore, throughout the pre- and post-crack-development stages, self-healing mortars have higher compressive strength than conventional mortars. The precipitated calcium carbonates were primed to compact the samples by filling the void spaces in hardened mortar samples. When fissures developed in hardened mortars, bacteria became active in the presence of moisture, causing calcite to precipitate and fill the cracks. The compressive strength and flexural strength of self-healing mortar samples are higher than conventional mortars before cracks develop in the samples. After the healing process of the broken mortar parts (due to cracking), self-healing mortars containing 5% bagasse ash withstand a certain load and have greater flexural strength (100 kPa) than conventional mortars (zero kPa) at 28 days of cure. Self-healing mortars absorb less water than typical mortar samples. Mortar samples containing 10−7 bacteria cells/mL exhibit greater compressive strength, flexural strength, and self-healing ability. XRD and SEM were used to analyze mortar samples with healed fractures. XRD, FTIR, and SEM images were also used to validate the produced calcium lactate. Furthermore, the durability of mortars was evaluated using DTA-TGA analysis and water absorption tests.  相似文献   

3.
In this work, sugarcane bagasse fiber, a waste product of agroindustry, was added to mortar mixes at different proportions looking to seal porosities so as to improve the resistance of concrete to carbonation and to improve its mechanical properties. To evaluate the behavior of bagasse fibers in the alkaline media typical of mortars, bagasse fibers were subjected to solutions with alkaline pH values, and their chemical structure and morphological behavior was evaluated using FTIR (Fourier transform infrared spectroscopy) and SEM (Scanning Electron Microscopy). Using mortar cylinders in an accelerated carbonation chamber to obtain results in short lapses, the compressive strength and the carbonation were evaluated. The FTIR analysis results indicate that pH values of 11 and 12 causes a delignification, while at pH 9 and 10, a swelling of the molecule occurs because of the addition of hydroxyl ions, behavior that is confirmed with SEM images. A clear effect of the fiber addition on the performance of concrete was observed as the carbonation front of 35 mm for the sample without fibers was reduced to 2 mm for the sample with 2% fiber addition, resulting in an increase of 5 MPa in compressive strength. These results indicate that in the range of mortar pH, chemical changes occured over the sugarcane surface that could cause the growth of fibers and could partially seal the porosity in the mortars, thus enhancing its performance.  相似文献   

4.
Bagasse ash (BA) and rice husk ash (RHA) are by-products from electricity power plants. Ground calcium carbonate waste (GCW) is the by-product of the mining of calcium carbonate (CaCO3) in the color pigment manufacturing industry. Both BA and RHA are classified as low-quality pozzolanic materials, differing from GCW, which contains a high calcium oxide (CaO) content that leads to products equivalent to the hydration reaction. Therefore, GCW is likely able to improve the properties of self-consolidating concrete (SCC) incorporating BA and RHA. This paper discusses the production of green self-consolidating concrete (gSCC) and identifies the benefit of using GCW in gSCC prepared by triple combined GCW (10 and 20 wt%), BA (10, 20, and 30 wt%), and RHA (20 wt%). The results indicate that the majority of the gSCC retain acceptable flowability. The differences in the levels of gSCC substitution and the V-funnel flow results show general correlations with the increase in GCW. The gSCC prepared by 10 wt% GCW associated with 10 wt% BA and 20 wt% RHA was improved significantly. The filling and passing abilities of the gSCC were improved by using GCW. In addition, gSCC achieved mechanical property development and was able to minimize the consumption of OPC by up to 40%.  相似文献   

5.
Blast furnace slag (BFS)/sugar cane bagasse ash (SCBA) blends were assessed for the production of alkali-activated pastes and mortars. SCBA was collected from a lagoon in which wastes from a sugar cane industry were poured. After previous dry and grinding processes, SCBA was chemically characterized: it had a large percentage of organic matter (ca. 25%). Solutions of sodium hydroxide and sodium silicate were used as activating reagents. Different BFS/SCBA mixtures were studied, replacing part of the BFS by SCBA from 0 to 40% by weight. The mechanical strength of mortar was measured, obtaining values about 60 MPa of compressive strength for BFS/SCBA systems after 270 days of curing at 20 °C. Also, microstructural properties were assessed by means of SEM, TGA, XRD, pH, electrical conductivity, FTIR spectroscopy and MIP. Results showed a good stability of matrices developed by means of alkali-activation. It was demonstrated that sugar cane bagasse ash is an interesting source for preparing alkali-activated binders.  相似文献   

6.
With the trend toward taller and larger structures, the demand for high-strength and lightweight cement concrete has increased in the construction industry. Equipment for transporting ready-mixed concrete is frequently used to bring concrete to construction sites, and washing this equipment generates a large amount of recycled water, which is an industrial by-product. In this study, we recycled this water as the pre-wetting water for lightweight aggregate and as mixing water, and we substituted blast furnace slag powder (BS) and fly ash (FA) as cementitious materials (Cm). In addition, we evaluated the fluidity, compressive strength, tensile strength, drying shrinkage, and accelerated carbonation depth of lightweight ternary cementitious mortars (TCMs) containing artificial lightweight aggregate and recycled water. The 28-day compressive strengths of the lightweight TCM specimens with BS and FA were ~47.2–51.7 MPa, except for the specimen with 20% each of BS and FA (40.2 MPa), which was higher than that of the control specimen with 100% OPC (45.9 MPa). Meanwhile, the 28-day tensile strengths of the lightweight TCM specimens containing BS and FA were ~2.81–3.20 MPa, which are ~13.7–29.5% higher than those of the control specimen. In this study, the TCM specimen with 5% each of BS and FA performed the best in terms of the combination of compressive strength, tensile strength, and carbonation resistance.  相似文献   

7.
The use of repair mortars for concrete structures repair with no or limited resistance to the impact caused by freeze and thaw cycles is often the primary repair failure cause. This is particularly important in Poland. Due to the geographical location of the country, there is a large temperature difference between summer and winter. The number of passes through the threshold temperature of 0 °C throughout the year in the winter season exceeds 100. The article presents a comparison of the frost resistance results of tests of repair mortars. The first method was performed according to the Polish Guidelines (without the use of de-icing salts) and the second method according to PN-EN 1504-3 (with the use of de-icing salts). The results obtained were inconsistent in many areas. In particular, significant differences in the results for the change in compressive strength and the change in bending strength were observed. In the case of the frost resistance testing without the use of de-icing salts, a decrease in compressive strength was usually accompanied by a decrease in bending strength. In the case of frost resistance tests with the use of de-icing salts, an increase in the bending strength of mortars was observed (even by a dozen or so percent) with a decrease in the compressive strength of mortars (even by several dozen percent).  相似文献   

8.
The paper presents results of research on the impact of fly ash from fluidized bed combustion (FBC) of lignite, used in quantities of 30 and 45% by mass, and the mixture of FBC and silicious fly ash in amount of 45% by mass, on properties of cement–ash mortars. Mortars were exposed to aggressive environment of 1, 3, and 5% HCl solutions for 2 years. Mortars containing 45% FBC exposed to 1% HCl solution (pH = 2) showed the highest durability from among other mortars. The growth of their strength observed after 90 days of testing in 1% HCl environment, as well as the lowest drop of strength after 730 days of exposure to this environment, resulted from the reduced amount of large pores from 20 to 200 nm in mortars containing fly ash, with simultaneous growth of smaller pores of <20 nm during testing. A beneficial effect has been demonstrated of FBC addition to cement on properties of cement–ash mortars exposed to the aggressive impact of the HCl. Mortars with FBC fly-ash content increased to 45% by mass showed higher strength values, smaller differences in linear and mass changes, and increased durability in an aggressive environment observed during 730 days of testing.  相似文献   

9.
Setting time and mechanical properties are key metrics needed to assess the properties of municipal solid waste incineration (MSWI) bottom ash alkali-activated samples. This study investigated the solidification law, polymerization, and strength development mechanism in response to NaOH and liquid sodium silicate addition. Scanning electron microscopy and X-ray diffraction were used to identify the formation rules of polymerization products and the mechanism of the underlying polymerization reaction under different excitation conditions. The results identify a strongly alkaline environment as the key factor for the dissolution of active substances as well as for the formation of polymerization products. The self-condensation reaction of liquid sodium silicate in the supersaturated state (caused by the loss of free water) is the major reason for the rapid coagulation of alkali-activated samples. The combination of both NaOH and liquid sodium silicate achieves the optimal effect, because they play a compatible coupling role.  相似文献   

10.
Destruction of cement composites occurs due to the alternate or simultaneous effects of aggressive media, resulting in the destruction of concrete under the influence of chemical and physical factors. This article presents the results of changes in the measurement of linear strains of samples and changes in the microstructure of cement after 30 freezing and thawing cycles and immersed in 5% sodium sulfate solution. The compressive strengths ratios were carried out at the moment when the samples were moved to the sulfate solution after 30 cycles and at the end of the study when the samples showed visual signs of damage caused by the effect of 5% Na2SO4. The composition of the mixtures was selected based on the Gibbs triangle covering the area up to 40% replacement of Portland cement with low and high-calcium fly ashes or their mixture. Air-entrained and non-air entrained mortars were made of OPC, in which 20%, 26.6%, and 40% of Portland cement were replaced with low and/or high-calcium fly ash. Initial, freezing and thawing cycles accelerated the destruction of non- air-entrained cement mortars immersed in 5% sodium sulfate solution. The sulfate resistance, after the preceding frost damage, decreased along with the increase in the amount of replaced fly ash in the binder. Air-entrained mortars in which 20% of cement was replaced with high-calcium fly ash showed the best resistance to the action of sodium sulfate after 30 freezing and thawing cycles.  相似文献   

11.
This present study evaluates the effect of silica modulus (Ms) and curing temperature on strengths and the microstructures of binary blended alkali-activated volcanic ash and limestone powder mortar. Mortar samples were prepared using mass ratio of combined Na2SiO3(aq)/10 M NaOH(aq) of 0.5 to 1.5 at an interval of 0.25, corresponding to Ms of 0.52, 0.72, 0.89, 1.05 and 1.18, respectively, and sole 10 M NaOH(aq). Samples were then subjected to ambient room temperature, and the oven-cured temperature was maintained from 45 to 90 °C at an interval of 15 °C for 24 h. The maximum achievable 28-day strength was 27 MPa at Ms value of 0.89 cured at 75 °C. Samples synthesised with the sole 10 M NaOH(aq) activator resulted in a binder with a low 28-day compressive strength (15 MPa) compared to combined usage of Na2SiO3(aq)/10 M NaOH(aq) activators. Results further revealed that curing at low temperatures (25 °C to 45 °C) does not favour strength development, whereas higher curing temperature positively enhanced strength development. More than 70% of the 28-day compressive strength could be achieved within 12 h of curing with the usage of combined Na2SiO3(aq)/10 M NaOH(aq). XRD, FTIR and SEM + EDX characterisations revealed that activation with combined Na2SiO3(aq)/10 M NaOH(aq) leads to the formation of anorthite (CaAl2Si2O8), gehlenite (CaO.Al2O3.SiO2) and albite (NaAlSi3O8) that improve the amorphosity, homogeneity and microstructural density of the binder compared to that of samples synthesised with sole 10 M NaOH(aq).  相似文献   

12.
In line with the trend of using waste raw materials in the technology of building materials, experimental studies of cement mortars containing various amounts of fine-grained waste aggregate were carried out. The waste aggregate was based on an incinerated municipal sewage sludge which was mechanically crushed to an appropriate grading. Chemical and physical properties of the waste aggregate are presented. Mortars with varying amounts of waste aggregate as a replacement for natural sand were prepared. Study determines compressive strength and flexural strength up to 56 days. Properties such as capillary action, air content and thermal conductivity were determined. The results of the tests has shown that the incinerated waste sludge can be used as a partial or total replacement for natural aggregate. In mortars with waste aggregate, a favorable relation between flexural and compressive strengths was observed, which translates into increased strength of the interfacial transition zone. A significant increase in water absorption was observed for mortars containing high amounts of waste aggregate, which is directly related to its porous structure. Conducted studied prove that the aggregate obtained from incineration of the municipal sewage sludge can a feasible alternative for natural aggregates in production of masonry and rendering mortars for construction purposes.  相似文献   

13.
Recently, with increasingly stringent environmental regulations and the depletion of natural aggregate resources, high-quality aggregates have become scarce. Therefore, significant efforts have been devoted by the construction industry to improve the quality of concrete and achieve sustainable development by utilizing industrial by-products and developing alternative aggregates. In this study, we use amorphous metallic fibers (AMFs) to enhance the performance of mortar with steel slag aggregate. Testing revealed that the 28-day compressive strength of the sample with steel slag aggregate and AMFs was in the range of 48.7–50.8 MPa, which was equivalent to or higher than that of the control sample (48.7 MPa). The AMFs had a remarkable effect on improving the tensile strength of the mortar regardless of the use of natural aggregates. With AMFs, the drying shrinkage reduction rate of the sample with 100% steel slag aggregate was relatively higher than that of the sample with 50% natural fine aggregate. Furthermore, the difference in the drying shrinkage with respect to the amount of AMFs was insignificant. The findings can contribute to sustainable development in the construction industry.  相似文献   

14.
Biomass combustion is a significant new source of green energy in the European Union. The adequate utilization of byproducts created during that process is a growing challenge for the energy industry. Biomass fly ash could be used in cement composite production after appropriate activation of that material. This study had been conducted to assess the usefulness of mechanical and physical activation methods (grinding and sieving), as well as activation through the addition of active silica in the form of silica fume, as potential methods with which to activate biomass fly ash. Setting time, compressive strength, water absorption and bulk density tests were performed on fresh and hardened mortar. While all activation methods influenced the compressive strength development of cement mortar with fly ash, sieving of the biomass fly ash enhanced the early compressive strength of cement mortar. The use of active silica in the form of silica fume ensured higher compressive strength results than those of control specimens throughout the entire measurement period.  相似文献   

15.
Unfired admixed soil blocks are made up of soil plus stabilizers such as binders, fibers, or a combination of both. Soil is abundant on Earth, and it has been used to provide shelter to millions of people. The manufacturing and usage of cement and cement blocks raise several environmental and economic challenges. Due to disposal issues, agricultural and industrial waste is currently the biggest hazard to the environment and humanity in the world. Consequently, environmental degradation brought on by agricultural waste harms the ecology. As a result, researchers are attempting to develop an alternative to cement blocks, and various tests on unfired admixed soil blocks have been done. This investigation uses agricultural waste (i.e., paddy straw fiber and sugarcane bagasse ash) and industrial waste (i.e., marble dust) in manufacturing unfired admixed soil blocks. Under this investigation, the applicability of unfired soil blocks admixed with marble dust, paddy straw fiber, and bagasse ash was studied. The marble dust level ranged from 25% to 35%, bagasse ash content ranged from 7.5% to 12.5%, and the content of paddy straw fiber ranged from 0.8% to 1.2% by soil dry weight. Various tests were conducted on the 81 mix designs of the prepared unfired admixed soil blocks to find out the physical properties of the block followed by modeling and optimization. The findings demonstrate that the suggested method is a superior alternative to burned bricks for improving the physical properties of admixed soil blocks without firing.  相似文献   

16.
This article presents research on selected physical and mechanical properties of cement-based plasters and masonry mortars with consistency-improving additives, namely, traditional hydrated lime and a plasticizing and aerating mixture (APA), which, in practice, is often considered to be a lime substitute. Comparative analysis of the properties of mortars with alternative additives—lime or APA—was carried out, taking into consideration possible effects of cement, as two types of Portland cement were used for the research. For fresh mortar, mixture consistency, air content, resistance to segregation, and water retention were determined. Tests on hardened mortars included tests of porosity and impermeability, depth of penetration of water under pressure, drying shrinkage, as well as compressive and bending strength, modulus of elasticity, and adhesion of mortars to the base. In addition, research has shown that cement–lime mortars and cement mortars with APA admixture of similar consistency in the fresh state are characterized by significantly different properties. The results show, in most of the features analyzed, more favorable properties of mortars with the use of traditional lime. For shrinkage only, the use of admixture turned out to be more advantageous.  相似文献   

17.
This paper presents the results of research on the influence of polymer modifiers: styrene-acrylic copolymer, vinyl acetate/ethylene (EVA), vinyl acetate/acrylic copolymer (VAAc), and VA/VeoVa/acrylic terpolymer on the water permeability and adhesion of cement-containing waterproofing mortars in concrete. The content of the polymers in the composition of the mortars was 15, 20 and 26% (m/m) in relation to the weight of the dry ingredients. Using microscopic methods, an attempt was made to analyse the relationship between the microstructure of the mortars and the properties of these polymers. The EVA and the vinyl acetate/acrylic copolymer, which were used in the form of dry powders, had the most favourable effect on water permeability and adhesion to the concrete substrate. They may prove to be useful for the production of one-component cement-containing waterproofing mortars. On the other hand, the VA/VeoVa/acrylic terpolymer modifier had the least favourable effect on the tested properties. For mortars with this modifier, the desired water-permeability parameters were not achieved. Depending on the amount of polymer modifier, the mortars were characterized by differences in watertightness, as established on the basis of changes in porosity and differences in the adhesion of the cement-polymer paste to the surface of aggregate grains. It was determined that the type of polymer and its dispergation properties influence the water permeability of mortars, as well as their adhesion to concrete substrates.  相似文献   

18.
Recycled aggregate concrete (RAC) is a sort of green, low carbon, environmental protection building material, its application is of great significance to the low carbonization of the construction industry. The performance and strength of RAC are much lower than natural aggregate concrete (NAC), which are the key factors restricting its application. Class F fly ash is a cementitious material that is considered environmentally hazardous. In this paper, appropriate water-binder (w/b) ratios were found through a mortar expansion test at first. The compressive strength of recycled mortar incorporated with class F fly ash was further studied. On this basis, the mechanical properties of nine groups of fully recycled aggregate concrete (FRAC) with a w/b ratio of 0.3, 0.35, and 0.4, and fly ash replacement ratios of 0, 20%, and 40%, were studied. The influence of the w/b ratio and fly ash replacement ratio on mechanical properties was analyzed and compared with previous research results. In addition, the conversion formulas between the splitting tensile strength, flexural strength, and compressive strength of FRAC were fitted and established. The research results have a certain guiding significance for the mixture design of FRAC and further application of class F fly ash.  相似文献   

19.
Granite is a well-known building and decorative material, and, therefore, the amount of produced waste in the form of granite powder is a problem. Granite powder affects the health of people living near landfills. Dust particles floating in the air, which are blown by gusts of wind, can lead to lung silicosis and eye infections, and can also affect the immune system. To find an application for this kind of waste material, it was decided to study the effect of partially replacing cement with waste granite powder on the properties of fresh and hardened mortars intended for masonry applications. The authors planned to replace 5%, 10%, and 15% of cement with waste material. Series of mortar with the addition of granite powder achieved 50% to 70% of the compressive strength of the reference series, and 60% to 76% of the bending strength of the reference series. The partial replacement of cement with the granite powder significantly increased the water sorption coefficient. The consistency of the fresh mortar, and its density and water absorption also increased when compared to the reference series. Therefore, Granite powder can be used as a partial replacement of cement in masonry mortars.  相似文献   

20.
In this article, the effect of cement type on selected properties of plastering mortars containing a cellulose ether admixture was studied. In the research, commercial CEM I Portland cement, CEM II and CEM III, differing in the type and amount of mineral additives, and cement class, were used as binders. Tests of consistency, bulk density, water retention value (WRV), mechanical properties and calorimetric tests were performed. It was proved that the type of cement had no effect on water retention, which is regulated by the cellulose ether. All mortars modified with the admixture were characterized by WRV of about 99%. High water retention is closely related to the action of the cellulose ether admixture. As a result of the research, the possibility of using cement with additives as components of plasters was confirmed. However, attention should be paid to the consistency, mechanical properties of the tested mortars and changes in the pastes during the hydration process. Different effects of additives resulted from increasing or decreasing the consistency of mortars; the flow was in the range from 155 mm to 169 mm. Considering the compressive strength, all plasters can be classified as category III or IV, because the mortars attained the strength required by the standard, of at least 3.5 MPa. The processes of hydration of pastes were carried out with different intensity. In conclusion, the obtained results indicate the possibility of using CEM II and CEM III cements to produce plastering mortars, without changing the effect of water retention.  相似文献   

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