Corrosion Properties of Cr27Fe24Co18Ni26Nb5 Alloy in 1 N Sulfuric Acid and 1 N Hydrochloric Acid Solutions

The composition of the Cr₂₇Fe₂₄Co₁₈Ni₂₆Nb₅ high-entropy alloy was selected from the FCC phase in a CrFeCoNiNb alloy. The alloy was melted in an argon atmosphere arc-furnace, followed by annealing in an air furnace. The dendrites of the alloy were in the FCC phase, and the eutectic interdendrites of the alloy comprised HCP and FCC phases. The microstructures and hardness of this alloy were examined; the results indicated that this alloy was very stable. This microstructure and hardness of the alloy almost remained the same after annealing at 1000 °C for 24 h. The polarization behaviors of Cr₂₇Fe₂₄Co₁₈Ni₂₆Nb₅ alloy in 1 N sulfuric acid and 1 N hydrochloric acid solutions were measured. Both the corrosion potential and the corrosion current density of the Cr₂₇Fe₂₄Co₁₈Ni₂₆Nb₅ alloy increased with increasing test temperatures. The activation energies of the Cr₂₇Fe₂₄Co₁₈Ni₂₆Nb₅ alloy in these two solutions were also calculated.     

Microstructures of FeCoNiMo and CrFeCoNiMo Alloys,and the Corrosion Properties in 1 M Nitric Acid and 1 M Sodium Chloride Solutions

FeCoNiMo and CrFeCoNiMo equimolar alloys were prepared by arc-melting. The microstructures of the as-cast alloys were examined by SEM, HREM and XRD; and a potentiodynamic polarization test of the as-cast alloys was undertaken to evaluate the corrosion resistance in the solutions. Results showed that both of FeCoNiMo and CrFeCoNiMo equimolar alloys had a dendritic structure. The dendrites of these two alloys were a single phase which was a simple cubic (SC) structure with large lattice constant; and the interdendrities of these two alloys had a dual-phased eutectic structure in which the phases were face-centered cubic (FCC) and simple cubic (SC). The hardness of CrFeCoNiMo alloy was higher than that of FeCoNiMo alloy. Additionally, the potentiodynamic polarization test showed that CrFeCoNiMo alloy was better than FeCoNiMo alloy in 1 M nitric acid and 1 M sodium chloride solutions. Adding chromium into FeCoNiMo alloy could increase corrosion resistance in these two solutions. All of the results indicated that the CrFeCoNiMo alloy surpassed FeCoNiMo alloy.     

The Microstructure Evolution and Electrochemical Corrosion Behavior of 7A46 Aluminum Alloy in Different Quenching Conditions

The quenching condition of aluminum alloy can affect the mechanical property and corrosion resistance of the profile. This paper is aimed at the low quench sensitivity of aluminum alloys. Scanning electron microscopy and transmission electron microscopy were used to analyze precipitate behaviors of the 7A46 aluminum alloy under different isothermal cooling conditions and microstructure evolutions of quench-induced precipitations. The effect of the different isothermal time on the corrosion resistance of the alloy, and the relationship between microstructure and corrosion resistance after quenching were revealed through electrochemical impedance spectroscopy and potentiodynamic polarization tests. Results show that corrosion sensitivity of the quenching-aged alloy is much higher than that of the double-aged (DA) alloy, and the corrosion resistance of the quenched alloy decreases firstly and then increases. Due to the high density of the matrix precipitates, the increased content of the impurity element, the discontinuity of the grain boundary precipitates and the widening of the precipitates free zone, the most serious degree of corrosion performance among the quenched alloys is 295 °C at 800 s, and the self-corrosion potential and self-current density is −0.919 V and 2.371 μA/cm², respectively.     

The Effect of Increasing Nickel Content on the Microstructure,Hardness, and Corrosion Resistance of the CuFeTiZrNix High-Entropy Alloys

In recent years, high-entropy alloys (HEAs) that contain fine grains of intermetallic compounds (IMCs) have gained increasing attention as they have been shown to exhibit both high mechanical strength and strong corrosion resistance. One such class of HEAs is that of CuFeTiZrNi alloys. In this study, we have investigated the effect of increasing Ni content on the microstructure, hardness, and corrosion resistance of the CuFeTiZrNi_x alloys (where x = 0.1, 0.3, 0.5, 0.8, 1.0 in a molar ratio). The alloys used in this study were prepared in an arc melting furnace and then annealed at 900 °C. First-principles calculations of the bulk modulus were also performed for each alloy. The results revealed that increasing the Ni content had several effects. Firstly, the microstructure of the CuFeTiZrNi_x alloys changed from B2_BCC and Laves_C14 in the CuFeTiZrNi_0.1 and CuFeTiZrNi_0.3 alloys to FCC, B2_BCC, and Laves_C14 in the CuFeTiZrNi_0.5 alloys; and to FCC, B2_BCC, Cu₅₁Zr₁₄, and Laves_C14 in the CuFeTiZrNi_0.8 and CuFeTiZrNi_1.0 alloys. Secondly, IMCs arising from a combination of the refractory elements (Ti and Zr) and atomic size differences were found in the interdendritic region. Thirdly, as the Ni content in the CuFeTiZrNi_x alloys increased, the hardness decreased, but the corrosion resistance increased.     

Corrosion Behavior of the AlCoCrFeNi2.1 Eutectic High-Entropy Alloy in Chloride-Containing Sulfuric Acid Solutions at Different Temperatures

In this work, the influence of temperature on the corrosion behavior of AlCoCrFeN_i2.1 eutectic high-entropy alloy in a chloride-containing sulfuric acid solution was investigated using electrochemical measurement, X-ray photoelectron spectroscopy, and scanning electron microscopy. Results show that the passive film of AlCoCrFeN_i2.1 is stable in chloride-containing sulfuric acid solutions at low temperatures, while an unstable film forms on the alloy at high temperatures. Furthermore, temperature changes the proportion of hydroxide and oxide in Fe and Cr, but it has no noticeable effect on Al and Ni, which is a significant factor on the passive behavior. L12 phase exhibits good corrosion resistance at different temperatures. Pitting occurred on B2 phase in the chloride-containing sulfuric acid solution at a low temperature of 5 °C, while pitting and dissolution take place on AlCoCrFeNi_2.1 in the acid solution at room temperature and above.     

The Inhibition of Aluminum Corrosion in Sulfuric Acid by Poly(1-vinyl-3-alkyl-imidazolium Hexafluorophosphate)

Compounds of poly(ionic liquid)s (PILs), derived from imidazole with different alkylic chain lengths located in the third position of the imidazolium ring (poly(1-vinyl-3-dodecyl-imidazolium) (PImC₁₂), poly(1-vinyl-3-octylimidazolium) (PImC₈) and poly(1-vinyl-3-butylimidazolium) (PImC₄) hexafluorophosphate) were synthesized. These compounds were tested as corrosion inhibitors on aluminum alloy AA6061 in diluted sulfuric acid (0.1–1 M H₂SO₄) by weight loss tests, polarization resistance measurements and inductively coupled plasma optical emission spectroscopy. Langmuir’s isotherms suggested film formation on bare alloy while standard free energy indicated inhibition by a physisorption process. However, compound efficiencies as inhibitors ranked low (PImC₁₂ > PImC₈ > PImC₄) to reach 61% for PImC₁₂ in highly diluted acidic solution. Apparently, the high mobility of sulfates favored their adsorption in comparison to PILs. The surface film displayed general corrosion, and pitting occurred as a consequence of PILs’ partial inhibition along with a continuous dissolution of defective patchy film on formation. A slight improvement in efficiency was displayed by compounds having high molecular weight and a long alkyl chain, as a consequence of steric hindrance and PIL interactions.     

Plasma Electrolytic Polishing—An Ecological Way for Increased Corrosion Resistance in Austenitic Stainless Steels

Plasma electrolytic polishing (PEP) is an environment-friendly alternative to the conventional electrochemical polishing (EP), giving optimal surface properties and improved corrosion resistance with minimum energy and time consumption, which leads to both economic and environmental benefits. This paper is focused on the corrosion behavior of PEP treated AISI 316L stainless steel widely used as a biomaterial. Corrosion resistance of plasma electrolytic polished surfaces without/with chemical pretreatment (acid cleaning) is evaluated and compared with original non-treated (as received) surfaces by three independent test methods: electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PP), and exposure immersion test. All corrosion tests are carried out in the 0.9 wt.% NaCl solution at a temperature of 37 ± 0.5 °C to simulate the internal environment of a human body. The quality of tested surfaces is also characterized by optical microscopy and by the surface roughness parameters. The results obtained indicated high corrosion resistance of PEP treated surfaces also without chemical pretreatment, which increases the ecological benefits of PEP technology.     

Corrosion Resistance of AISI 316L Stainless Steel Biomaterial after Plasma Immersion Ion Implantation of Nitrogen

Plasma immersion ion implantation (PIII) of nitrogen is low-temperature surface technology which enables the improvement of tribological properties without a deterioration of the corrosion behavior of austenitic stainless steels. In this paper the corrosion properties of PIII-treated AISI 316L stainless steel surfaces are evaluated by electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PP) and exposure immersion tests (all carried out in the 0.9 wt. % NaCl solution at 37 ± 0.5 °C) and compared with a non-treated surface. Results of the three performed independent corrosion tests consistently confirmed a significant increase in the corrosion resistance after two doses of PIII nitriding.     

Corrosion Behavior and Susceptibility to Stress Corrosion Cracking of Leaded and Lead-Free Brasses in Simulated Drinking Water

Duplex α + β’ brasses are widely used in drinking water distribution systems for tube fittings, valves, and ancillaries because they are low cost, easy to fabricate, and exhibit high mechanical strength. However, depending on application conditions and alloy composition, they may undergo dealloying and stress corrosion cracking. In this research, three different brass types, two leaded (CW617N and CW602N) alloys and one lead-free brass (CW724R), were investigated to assess their corrosion behavior and susceptibility to stress corrosion cracking (SCC) in simulated drinking water (SDW) solutions containing different chloride concentrations, compatible with drinking water composition requirements according to Moroccan standard NM 03.7.001. The corrosion behavior was assessed by electrochemical tests such as polarization curve recording and electrochemical impedance spectroscopy (EIS) monitoring, coupled to SEM-EDS surface observations. The susceptibility to SCC was investigated by slow strain rate tests (SSRT). The tests showed that corrosion was mainly under diffusion control and chlorides slightly accelerated corrosion rates. All alloys, and particularly CW617N, were affected by SCC under the testing conditions adopted and in general the SCC susceptibility increased at increasing chloride concentration.     

Effect of ECAP Route Type on the Microstructural Evolution,Crystallographic Texture,Electrochemical Behavior and Mechanical Properties of ZK30 Biodegradable Magnesium Alloy

In this study, billets of the ZK30 (Mg-3Zn-0.6 Zr-0.4 Mn, wt%) alloy were Equal Channel Angle Pressing (ECAP) processed for up to four passes of routes Bc (with rotating the sample 90° in the same direction between the subsequent passes), A (without sample rotation), and C (with sample rotating 180°) after each pass at a temperature of 250 °C and a ram speed of 10 mm/min using a die with an internal channel angle of 90°. The microstructural evolution and the crystallographic texture were investigated using a Scanning Electron Microscope (SEM) equipped with the Electron Back-Scatter Diffraction (EBSD) technique. Corrosion measurements were conducted in ringer lactate which is a simulated body fluid. The Vickers microhardness test and tensile tests were conducted for the alloy before and after processing. The as-annealed billets exhibited a bimodal structure as fine grains (more than 3.39 µm) coexisted with almost-equiaxed coarse grains (less than 76.73 µm); the average grain size was 26.69 µm. Further processing until four passes resulted in enhanced grain refinement and full Dynamic Recrystallization (DRX). ECAP processing through 4-Bc, 4-A, and 4-C exhibited significant reductions in grain size until they reached 1.94 µm, 2.89 µm, and 2.25 µm, respectively. Four-pass processing also resulted in the transformation of low-angle grain boundaries into high-angle grain boundaries. The previous conclusion was drawn from observing the simultaneous decrease in the fraction of low-angle grain boundaries and an increase in the fraction of high-angle grain boundaries. The pole figures revealed that 4-Bc, 4-A, and 4-C reduced the maximum texture intensity of the as-annealed billets. The potentiodynamic polarization findings revealed that route Bc is the most effective route in improving the corrosion rate, whereas the Electrochemical Impedance Spectroscopy (EIS) revealed that routes A and Bc improved the corrosion resistance with nearly identical values. Finally, 4-Bc resulted in the highest increase in Vickers hardness, yield stress, and ultimate tensile strength with values of 80.8%, 19.3%, and 44.5%, alongside a 31% improvement in ductility, all compared to the AA condition.     

Effect of Sulfate Ions on Galvanized Post-Tensioned Steel Corrosion in Alkaline Solutions and the Interaction with Other Ions

Zinc protection of galvanized steel is initially dissolved in alkaline solutions. However, a passive layer is formed over time which protects the steel from corrosion. The behavior of galvanized steel exposed to strong alkaline solutions (pH values of 12.7) with a fixed concentration of sulfate ions of 0.04 M is studied here. Electrochemical measurement techniques such as corrosion potential, linear polarization resistance and electrochemical impedance spectroscopy are used. Synergistic effects of sulfate ions are also studied together with other anions such as chloride Cl⁻ or bicarbonate ion HCO₃⁻ and with other cations such as calcium Ca²⁺, ammonium NH₄⁺ and magnesium Mg²⁺. The presence of sulfate ions can also depassivate the steel, leading to a corrosion current density of 0.3 µA/cm² at the end of the test. The presence of other ions in the solution increases this effect. The increase in corrosion current density caused by cations and anions corresponds to the following orders (greater to lesser influence): NH₄⁺ > Ca²⁺ > Mg²⁺ and HCO₃⁻ > Cl⁻ > SO₄²⁻.     

Investigation of the Structure and Corrosion Resistance of Novel High-Entropy Alloys for Potential Biomedical Applications

High-entropy alloys are a new generation of materials that have attracted the interest of numerous scientists because of their unusual properties. It seems interesting to use these alloys in biomedical applications. However, for this purpose, the basic condition of corrosion resistance must be fulfilled. In this article, selected corrosion properties of self-composed high-entropy alloys are investigated and compared with conventional biomedical alloys, that is titanium alloys and stainless steels. Corrosive parameters were determined using the potentiodynamic method. X-ray diffraction studies were performed to characterize the crystal structures. Microstructures of the prepared materials were examined using a scanning electron microscope, and surface hardness was measured by the Vickers method. The results show that investigated high-entropy alloys are characterized by simple structures. Three out of four tested high-entropy alloys had better corrosion properties than conventional implant alloys used in medicine. The Al_0.7CoCrFeNi alloy was characterized by a corrosion potential of −224 mV and a corrosion current density of 0.9 μA/cm²; CoCrFeNiCu by −210 mV and 1.1 μA/cm²; TiAlFeCoNi by −435 mV and 4.6 μA/cm²; and Mn_0.5TiCuAlCr by −253 mV and 1.3 μA/cm², respectively. Therefore, the proposed high-entropy alloys can be considered as potential materials for biomedical applications, but this requires more studies to confirm their biocompatibility.     

Corrosion Inhibition of Mild Steel and 304 Stainless Steel in 1 M Hydrochloric Acid Solution by Tea Tree Extract and Its Main Constituents

Tea tree extract, containing antioxidant constituents α-terpineol, terpinen-4-ol, and α-terpinene, has a wide range of applications in the cosmetic, food, and pharmaceutical industries. In this study, tea tree extract showed an anticorrosive effect under 1 M HCl solution on mild steel (MS) and 304 stainless steel (STS). Uniform corrosion for MS and pitting corrosion for STS at 298 K were retarded, with inhibition efficiencies of 77% and 86%, respectively. The inhibition of uniform and pitting corrosion was confirmed by scanning electron microscopy and laser scanning confocal microscopy in terms of surface roughness and pitting morphologies. The most effective constituent contributing to the inhibitory performance of tea tree extract was revealed to be α-terpineol, with an inhibition efficiency of 83%. The adsorption of tea tree extract was confirmed by surface characterization analysis using Fourier transform infrared spectroscopy, Raman spectroscopy, and Electrochemical impedance spectroscopy. Interestingly, G- and D-peaks of Raman spectra were detected from the inhibited steels, and this finding is the first example in the corrosion inhibition field. The anticorrosion mechanism can be explained by the formation of organic-Fe complexes on the corroded steel surface via electron donor and acceptor interactions in the presence of an oxygen atom of the hydroxyl group or ether of organic inhibitors.     

Characterization and Comparison of Corrosion Layer Microstructure between Cement Mortar and Alkali-Activated Fly Ash/Slag Mortar Exposed to Sulfuric Acid and Acetic Acid

In this study, we investigated the formation and evolution of the corrosion layers in alkali-activated mortar and ordinary Portland cement mortar exposed to sulfuric acid and acetic acid environments with different pH values, and explored the differences in the deterioration mechanisms. The experimental results indicated that ordinary Portland cement (OPC) mortars experienced more severe deterioration in terms of appearance, mass loss, and strength loss as compared with alkali-activated mortars exposed to an acetic acid environment, but their neutralization depths were smaller. Alkali-activated fly ash (AAF) mortar had a the relatively intact appearance but the greatest neutralization depth, which was due to its stable three-dimensional network but highly porous structure. To sum up, alkali-activated fly ash/slag (AFS) mortar had the best resistance to acid attack. In addition, the mortars exposed to acetic acid suffered greater deterioration than those exposed to sulfuric acid with the same pH values, which was mainly due to the highly porous corrosion layer formed in acetic acid, whereas crystallization of gypsum in sulfuric acid had a pore filling effect. However, for alkali-activated slag (AAS) and OPC mortars exposed to a sulfuric acid environment, extensive gypsum resulted in the formation of micro-cracks, and the corrosion layer of OPC mortar was more prone to fall off. OPC mortar also had the greatest resistance difference values of the continuously connected micro-pores before and after acid corrosion, followed by AAS, AAF, and AFS mortars, and these values for all the specimens were smaller in sulfuric acid. Furthermore, the gaps between acetic and sulfuric acid attacks increased with increased calcium content in binders, which were 7%, 13%, 21%, and 29% for AAF, AFS, AAS, and OPC mortars, respectively. Thus, it can be inferred that an appropriate amount of gypsum existed in the corrosion layer which could act as a barrier to some extent ina sulfuric acid environment.     

Changes in the Structure and Corrosion Protection Ability of Porous Anodic Oxide Films on Pure Al and Al Alloys by Pore Sealing Treatment

It is well known that corrosion protection of pure Al is enormously improved by the formation of porous anodic oxide films and by pore sealing treatment. However, the effects of anodizing and pore sealing on corrosion protection for Al alloys are unclear, because the alloying elements included in Al alloys affect the structure of anodic oxide films. In the present study, porous anodic oxide films are formed on pure Al, 1050-, 3003- and 5052-Al alloys, and pore sealing was carried out in boiling water. Changes in the structure and corrosion protection ability of porous anodic oxide films on pure Al and the Al alloys by pore sealing, were examined by scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS). SEM observation showed that anodic oxide films formed on pure Al have a smooth surface after pore sealing, and that cracks are formed in anodic oxide films on 1050-, 3003- and 5052-aluminum alloys, after pore sealing. Corrosion protection after pore sealing increased with anodizing time on pure Al, but only slightly increased with anodizing time on the Al alloys.     

Effect of Cr on Aqueous and Atmospheric Corrosion of Automotive Carbon Steel

This study investigated the effect of Cr alloying element on the corrosion properties of automotive carbon steel (0.1C, 0.5Si, 2.5Mn, Fe Bal., composition given in wt.%) in aqueous and atmospheric conditions using electrochemical measurement and cyclic corrosion tests. Three steels with 0, 0.3, and 0.5 wt.% Cr were studied by electrochemical impedance spectroscopy. Polarization resistance (R_p) of 0.3 Cr and 0.5 Cr steels was higher than that of 0 Cr steel, and the R_p also increased as the Cr content increased. Therefore, Cr increases the corrosion resistance of automotive carbon steel immersed in a chloride ion (Cl⁻)-containing aqueous solution. In the cyclic corrosion test results, Cl⁻ was concentrated at the metal/rust interface in all of the steels regardless of Cr content. The Cl⁻ was uniformly concentrated and distributed on the 0 Cr steel, but locally and non-uniformly concentrated on the Cr-added steels. The inner rust layer consisted of β-FeOOH containing Cl⁻ and Cr-goethite, while the outer rust layer was composed of amorphous iron oxyhydroxide mixed with various types of rust. FeCl₂ and CrCl₃ are formed from the Cl⁻ nest developed in the early stage, and the pitting at CrCl₃-formed regions are locally accelerated because Cr is strongly hydrolyzed to a very low pH.     

Structure and Superconductivity of Tin-Containing HfTiZrSnM (M = Cu,Fe, Nb,Ni) Medium-Entropy and High-Entropy Alloys

In an attempt to incorporate tin (Sn) into high-entropy alloys composed of refractory metals Hf, Nb, Ti and Zr with the addition of 3d transition metals Cu, Fe, and Ni, we synthesized a series of alloys in the system HfTiZrSnM (M = Cu, Fe, Nb, Ni). The alloys were characterized crystallographically, microstructurally, and compositionally, and their physical properties were determined, with the emphasis on superconductivity. All Sn-containing alloys are multi-phase mixtures of intermetallic compounds (in most cases four). A common feature of the alloys is a microstructure of large crystalline grains of a hexagonal (Hf, Ti, Zr)₅Sn₃ partially ordered phase embedded in a matrix that also contains many small inclusions. In the HfTiZrSnCu alloy, some Cu is also incorporated into the grains. Based on the electrical resistivity, specific heat, and magnetization measurements, a superconducting (SC) state was observed in the HfTiZr, HfTiZrSn, HfTiZrSnNi, and HfTiZrSnNb alloys. The HfTiZrSnFe alloy shows a partial SC transition, whereas the HfTiZrSnCu alloy is non-superconducting. All SC alloys are type II superconductors and belong to the Anderson class of “dirty” superconductors.     

Glass-Forming Ability and Corrosion Resistance of Al88Y8−xFe4+x (x = 0, 1, 2 at.%) Alloys

The effect of iron and yttrium additions on glass forming ability and corrosion resistance of Al₈₈Y_8-xFe_4+x (x = 0, 1, 2 at.%) alloys in the form of ingots and melt-spun ribbons was investigated. The crystalline multiphase structure of ingots and amorphous-crystalline structure of ribbons were examined by a number of analytical techniques including X-ray diffraction, Mössbauer spectroscopy, and transmission electron microscopy. It was confirmed that the higher Fe additions contributed to formation of amorphous structures. The impact of chemical composition and structure of alloys on their corrosion resistance was characterized by electrochemical tests in 3.5% NaCl solution at 25 °C. The identification of the mechanism of chemical reactions taking place during polarization test along with the morphology and internal structure of the surface oxide films generated was performed. It was revealed that the best corrosion resistance was achieved for the Al₈₈Y₇Fe₅ alloy in the form of ribbon, which exhibited the lowest corrosion current density (j_corr = 0.09 μA/cm²) and the highest polarization resistance (R_p = 96.7 kΩ∙cm²).     

Striped Non-Uniform Corrosion Behavior of Non-Equiatomic FeMnCoCr High-Entropy Alloy Prepared by Laser Melting Deposition in 0.1 M H2SO4 Solution

The corrosion behavior of the Fe₅₀Mn₃₀Co₁₀Cr₁₀ high-entropy alloy (HEA) manufactured via laser melting deposition (LMD) was investigated using open circuit potential, potentiodynamic polarization, and electrochemical impedance spectroscopy measurements. The microstructure and morphology of LMD samples before and after the electrochemical tests were compared using X-ray diffraction, optical microscopy, scanning electron microscopy, and electron backscatter diffraction techniques. After the corrosion tests, a striped morphology was observed on the surface of the LMD HEA, which is mainly caused by the interval distribution of high-density and low-density grain-boundary regions. The corrosion performances varied with different planes of the LMD HEA sample, which is mainly controlled by the grain size at each plane. Local corrosion in this HEA is concentrated at the melt pool boundary, which may be due to the abundant metallurgical defects and stress concentration at this location.     

Erosion and Corrosion Resistance Performance of Laser Metal Deposited High-Entropy Alloy Coatings at Hellisheidi Geothermal Site

Geothermal process equipment and accessories are usually manufactured from low-alloy steels which offer affordability but increase the susceptibility of the materials to corrosion. Applying erosion-corrosion-resistant coatings to these components could represent an economical solution to the problem. In this work, testing of two newly developed laser metal deposited high-entropy alloy (LMD-HEA) coatings—CoCrFeNiMo_0.85 and Al_0.5CoCrFeNi, applied to carbon and stainless steels—was carried out at the Hellisheidi geothermal power plant. Tests in three different geothermal environments were performed at the Hellisheidi site: wellhead test at 194 °C and 14 bar, erosion test at 198 °C and 15 bar, and aerated test at 90 °C and 1 bar. Post-test microstructural characterization was performed via Scanning Eletron Microscope (SEM), Back-Scattered Electrons analysis (BSE), Energy Dispersive X-ray Spectroscopy (EDS), optical microscopy, and optical profilometry while erosion assessment was carried out using an image and chemical analysis. Both the CoCrFeNiMo_0.85 and Al_0.5CoCrFeNi coatings showed manufacturing defects (cracks) and were prone to corrosion damage. Results show that damage in the CoCrFeNiMo_0.85-coated carbon steel can be induced by manufacturing defects in the coating. This was further confirmed by the excellent corrosion resistance performance of the CoCrFeNiMo_0.85 coating deposited onto stainless steel, where no manufacturing cracks were observed.