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1.
Various types of fiber reinforced cementitious composites (FRCCs) were experimentally studied to evaluate their self-healing capabilities regarding their watertightness and mechanical properties. Cracks were induced in the FRCC specimens during a tensile loading test, and the specimens were then immersed in static water for self-healing. By water permeability and reloading tests, it was determined that the FRCCs containing synthetic fiber and cracks of width within a certain range (<0.1 mm) exhibited good self-healing capabilities regarding their watertightness. Particularly, the high polarity of the synthetic fiber (polyvinyl alcohol (PVA)) series and hybrid fiber reinforcing (polyethylene (PE) and steel code (SC)) series showed high recovery ratio. Moreover, these series also showed high potential of self-healing of mechanical properties. It was confirmed that recovery of mechanical property could be obtained only in case when crack width was sufficiently narrow, both the visible surface cracks and the very fine cracks around the bridging of the SC fibers. Recovery of the bond strength by filling of the very fine cracks around the bridging fibers enhanced the recovery of the mechanical property.  相似文献   

2.
This paper investigates the effectiveness of a specific crystalline waterproofing admixture (CWA) in concrete as a function of a water–binder ratio. Four concrete mixes with and without CWA were prepared; two of them with a water–binder ratio of 0.45 and two of them with a water–binder ratio of 0.55. Water permeability and compressive strength were tested on hardened concrete specimens and self-healing of cracks over time was observed. Cement paste and CWA paste were prepared to clarify the results obtained on the concrete specimens. SEM and EDS and XRD and FTIR were performed on the hardened pastes to explain the mechanism of CWA working. The results show that the addition of CWA had no significant effect on the compressive strength of the concrete, but reduced the water penetration depth in the concrete, and the reduction was more effective for mixes with lower water–binder ratio. Regarding the self-healing effect, it can be concluded that the addition of CWA improves the crack healing in concrete, but the efficiency of self-healing is highly dependent on the initial crack width. The mechanisms involved in the reduction of water penetration depth and crack healing in concrete can be explained by different mechanisms; one is creation of the CSH gel from unreacted clinker grains, then formation carbonate, and additional mechanism is gel formation (highly expansive Mg-rich hydro-carbonate) from magnesium based additives. The presence of sodium silicate, which would transform into carbonate/bicarbonate, also cannot be excluded.  相似文献   

3.
The phase composition of self-healing products generated in cracks affects self-healing performance. This study investigated the self-healing products of cementitious materials using supplementary cementitious materials (SCMs), a calcium sulfoaluminate (CSA) expansion agent, and crystalline additives (CAs). Ground-granulated blast-furnace slag (GGBFS), fly ash (FA), and silica fume (SF) were used as SCMs, and anhydrite, Na2SO4, Na2CO3, and MgCO3 were used as crystalline additives (CAs). An artificial crack method was used to collect the self-healing products in the crack of the paste. The phase composition of the self-healing products was analyzed through X-ray diffraction (XRD)/Rietveld refinements and thermogravimetry/differential thermogravimetry (TG/DTG) analysis, and their morphology and ion concentration were examined through scanning electron microscopy with energy dispersive spectroscopy (SEM–EDS). From the results, the main compound of self-healing products was found to be calcite. GGBFS and FA decreased the content of portlandite, and the use of CAs led to the formation of alkali sulfate and alkali carbonate. The SEM–EDS analysis results showed that when GGBFS and FA were used, a large proportion of the self-healing products contained C-S-H and C-A-H, and the use of CSA led to the formation of monosulfate and ettringite.  相似文献   

4.
Waste ceramic concrete (WOC) made from waste ceramic floor tiles has several economic and environmental benefits. Fire is one of the most common disasters in buildings, and WOC is a brittle construction material; therefore, the mechanical properties of WOC structures under high temperatures should be considered. According to previous studies, hybrid fiber can further reduce damage to concrete under high temperatures. Meanwhile, crack width and propagation are among the key characteristics of concrete materials that need to be considered, but few studies have focused on their behavior when subjected to elevated temperatures. The new concrete materials proposed by the authors are WOC and WOC-Hybrid. WOC was prepared with Natural Coarse Aggregates (NCA), Natural Fine Aggregate (NFA), Ordinary Portland Cement (OPC 43 grade), and ceramic waste tiles with 20% replacements for coarse aggregates, 10% replacements for fine aggregates, and 10% replacement for cement. In contrast, WOC-Hybrid was prepared with the addition of hybrid fiber (1% crimped steel fiber and 1% polyvinyl alcohol fiber) in WOC. The specimens were exposed to temperatures of 100–300 °C, and then the specimens were tested for tensile and compressive strength. The present study aims to find a new method to improve concrete resistance to elevated temperatures at the lowest costs by experimental and computational analysis via machine learning models. The application of machine learning models such as artificial neural networks (ANN) and multiple linear regression (MLR) was employed in this study to predict the compressive and tensile strength of concrete. The linear coefficient correlation (R2) and mean square error (MSE) were evaluated to investigate the performance of the models. Based on the experimental analysis, the results show that the effect of hybrid fiber on the crack width and propagation is greater than that on the crack width and propagation of WOC and PC after exposure to high temperatures. However, the enhanced effect of hybrid fiber on the mechanical properties, rack width, and propagation decreases after subjecting it to a high-temperature treatment, owing to the melting and ignition of hybrid fibers at high temperatures. Regarding the computational analysis, it was found that the developed MLR model shows higher efficiency than ANN in predicting the compressive and tensile strength of PC, WOC, and WOC-Hybrid concrete.  相似文献   

5.
Concrete and cement-based materials inherently possess an autogenous self-healing capacity. Despite the huge amount of literature on the topic, self-healing concepts still fail to consistently enter design strategies able to effectively quantify their benefits on structural performance. This study aims to develop quantitative relationships through statistical models and artificial neural network (ANN) by establishing a correlation between the mix proportions, exposure type and time, and width of the initial crack against suitably defined self-healing indices (SHI), quantifying the recovery of material performance. Furthermore, it is intended to pave the way towards consistent incorporation of self-healing concepts into durability-based design approaches for reinforced concrete structures, aimed at quantifying, with reliable confidence, the benefits in terms of slower degradation of the structural performance and extension of the service lifespan. It has been observed that the exposure type, crack width and presence of healing stimulators such as crystalline admixtures has the most significant effect on enhancing SHI and hence self-healing efficiency. However, other parameters, such as the amount of fibers and Supplementary Cementitious Materials have less impact on the autogenous self-healing. The study proposes, through suitably built design charts and ANN analysis, a straightforward input–output model to quickly predict and evaluate, and hence “design”, the self-healing efficiency of cement-based materials.  相似文献   

6.
Colloidal silica can quickly seep through sand and then form silica gels to cement sand particles. To improve the strength of sand seeped by colloidal silica, carbon nanotubes were dispersed in the colloidal silica to form carbon-nanotube-reinforced sand-gel composites. Then triaxial tests were performed to explore how carbon nanotube content affects shear strength. The test results showed that: (1) with the increase of colloidal silica concentration, the shear strength significantly increased with the same carbon nanotube content (especially the low concentration of 10 wt. % colloidal silica, which showed almost no reinforcing effect with carbon nanotubes) while 40 wt. % colloidal silica plus 0.01 wt. % carbon nanotube caused the maximum increase of shear strength by up to 93.65%; (2) there was a concentration threshold of colloidal silica, above which the shear strength first increased to the peak value and then decreased with increasing carbon nanotube content (and we also established a formula to predict such phenomenon); and (3) SEM images showed that carbon nanotubes were connected as several ropes in the micro-cracks of the silica gel, resulting in greater macroscopic shear strength. Our new method of mixing carbon nanotubes and colloidal silica to seep through sand can contribute to sandy ground improvement.  相似文献   

7.
The purpose of this study was to investigate the relationship between strength and strain in manufacturing controlled low strength materials to recycle incineration bottom ash. Laboratory tests for controlled low strength materials with bottom ash and recycled in-situ soil have been carried out. The optimum mixing ratios were 25%–45% of in-situ soil, 30% of bottom ash, 10%–20% of fly ash, 0%–3% of crumb rubber, 3% of cement, and 22% of water. Each mixture satisfied the standard specifications: a minimum 20 cm of flowability and 127 kPa of unconfined compressive strength. The average secant modulus (E50) was (0.07–0.08) qu. The ranges of the internal friction angle and cohesion for mixtures were 36.5°–46.6° and 49.1–180 kPa, respectively. The pH of all of the mixtures was over 12, which is strongly alkaline. Small-scale chamber tests for controlled low strength materials with bottom ash and recycled in-situ soil have been carried out. Vertical deflection of 0.88–2.41 mm and horizontal deflection of 0.83–3.72 mm were measured during backfilling. The vertical and horizontal deflections of controlled low strength materials were smaller than that of sand backfill.  相似文献   

8.
In this study, an investigation of the shear behavior of full-scale reinforced concrete (RC) beams affected from alkali–silica reactivity damage is presented. A detailed finite element model (FEM) was developed and validated with data obtained from the experiments using several metrics, including a force–deformation curve, rebar strains, and crack maps and width. The validated FEM was used in a parametric study to investigate the potential impact of alkali–silica reactivity (ASR) degradation on the shear capacity of the beam. Degradations of concrete mechanical properties were correlated with ASR expansion using material test data and implemented in the FEM for different expansions. The finite element (FE) analysis provided a better understanding of the failure mechanism of ASR-affected RC beam and degradation in the capacity as a function of the ASR expansion. The parametric study using the FEM showed 6%, 19%, and 25% reduction in the shear capacity of the beam, respectively, affected from 0.2%, 0.4%, and 0.6% of ASR-induced expansion.  相似文献   

9.
The purpose of this study was to develop a microcapsule-type self-healing coating system that could self-heal cracks and then maintain the healed state even upon crack expansion. Mixtures consisting of a photoinitiator and two methacrylate components, bismethacryloxypropyl-terminated polydimethylsiloxane (BMT-PDMS) and monomethacryloxypropyl-terminated PDMS (MMT-PDMS), were transformed into viscoelastic semi-solids through photoreaction. The viscoelasticity of the reacted mixtures could be controlled by varying the mass ratio of the two methacrylates. Through a stretchability test, the optimal composition mixture was chosen as a healing agent. Microcapsules loaded with the healing agent were prepared and dispersed in a commercial undercoating to obtain a self-healing coating formulation. The formulation was applied onto mortar specimens, and then cracks were generated in the coating by using a universal testing machine (UTM). Cracks with around a 150-μm mean width were generated and were allowed to self-heal under UV light. Then, the cracks were expanded up to 650 μm in width. By conducting a water sorptivity test at each expanded crack width, the self-healing efficiency and capability of maintaining the healed state were evaluated. The B-M-1.5-1-based coating showed a healing efficiency of 90% at a 150-μm crack width and maintained its healing efficiency (about 80%) up to a 350-μm crack width. This self-healing coating system is promising for the protection of structural materials that can undergo crack formation and expansion.  相似文献   

10.
The effect of combining filler (carbon black) and fibrous materials (steel fiber and polypropylene fiber) with various sizes of coarse particles on the post-cracking behavior of conductive concrete was investigated in this study. Steel fibers (SF) and carbon black (CB) were added as monophasic, diphasic, and triphasic materials in the concrete to enhance the conductive properties of reinforced concrete. Polypropylene fiber (PP) was also added to steel fiber and carbon to improve the post-cracking behavior of concrete beams. This research mainly focused on the effects of macro fibers on toughness parameters and energy absorption capacity, as well as enhancing the self-sensing of multiple cracks and post-cracking behavior. Fractional changes in resistance and crack opening displacement (COD-FCR) and the relationship of load-deflection-FCR with different coarse aggregates of (5–10 mm and 15–20 mm) sizes were investigated, and the law of resistance signal changes with single and multiple cracking through load-time-FCR curves was explored. Results indicated that the smaller size coarse aggregates (5–10 mm) showed higher compressive strength: up to 8.3% and 14.83% with diphasic (SF + CB), respectively. The flexural strength of PC-10 increased 22.60 and 51.2%, respectively, with and without fibers, compared to PC-20. The diphasic and triphasic conductive material with the smaller size of aggregates (5–10 mm) increased the FCR values up to 38.95% and 42.21%, respectively, as compared to those of greater size coarse aggregates (15–20 mm). The hybrid uses of fibrous and filler materials improved post-cracking behavior as well as the self-sensing ability of reinforced concrete.  相似文献   

11.
This paper presents an efficient method of microbial-induced calcite precipitation (MICP) for cementation of sand particles. First, the influence of initial pH value of the culture medium on the growth of bacteria was discussed. Then, the compressive strength and calcium carbonate content of cemented sand columns with different sand particle sizes were measured to indicate the cementation effectiveness. The microstructure of cemented sand columns as well as the mineral composition and distribution of calcium carbonate were characterised by means of scanning electron microscopy-energy dispersive spectrometer (SEM-EDS) and X-ray diffraction (XRD). The results showed that the urease-producing bacteria S. pasteurii can be cultured at the initial pH values of 7–10, while a higher pH (e.g., 11) would hinder its growth and decrease its urease activity. The injection method of MICP with high standing time can cement sand columns effectively. Small average sand particle size of sand columns and high injection cycles can facilitate the gain of compressive strength, while calcium carbonate content of sand column higher than 8% can promote the increase of compressive strength. XRD results indicate that the fine grains generated on the surface of sand particles are calcite. The distribution of calcite on sand particles’ surface is broad and uniform. First, calcite was precipitated on the surface of sand particles, and then a precipitation layer was formed, which would connect sand particles through its high enough thickness and contribute to the development of compressive strength of the whole sand column.  相似文献   

12.
Fiber reinforcement is currently most often used in floors, railway sleepers, prefabricated structural elements such as slabs, beams and tanks, and in small architecture elements. Designing elements or structures made of fiber-reinforced concrete requires knowledge of its basic mechanical parameters. In the case of concretes with metallic fibers, the literature can find many tests and standard guidelines regarding compressive, flexural, tensile strength and fracture energy. The properties of concretes with non-metallic fibers are slightly less recognized, especially concretes with new types of polymer fibers. Additionally, the lack of standardized methods of testing concrete with polymer fibers make their application much more difficult. In the article, the possibility of using the EN 14651 standard to assess the flexural tensile strength of concrete with the addition of 2.0 and 3.0 kg/m3 of synthetic fibers with different geometry and form was presented. There was a 5.5–13.5% increase in the flexural tensile strength depending on the mixture type. Moreover, in the case of fiber-reinforced concretes, the ductility was enhanced and the samples were characterized by significant residual flexural tensile strengths. Additionally, from the workability tests it was concluded that after the incorporation of fibers, the consistency class decreased by one, two or three. Nevertheless, the compressive strengths of concrete with and without fibers were very similar to each other, and varied from 58.05 to 61.31 MPa. Moreover, it was concluded that results obtained from three-point bending tests significantly differed from empirical formulas for the calculation of the flexural tensile strength of fiber-reinforced concretes with dispersed steel fibers present in the literature. As a result, the new formula determined by the authors was proposed for concrete with polymer fibers with a nominal fiber content ≤1.0% and slenderness of up to 200. It must be mentioned that the formula gave a very good agreement with studies presented in different literature positions. In addition, an attempt was made to evaluate the strengths of tested mixes in accordance with the Model Code 2010. However, it occurred that the proposed fiber-reinforced concrete mixtures would not be able to replace traditional reinforcement in a form of steel bars. Furthermore, in uniaxial tensile tests, it was not possible to determine the σ–w graphs, and received results for maximum tensile strength did not show the clear influence of fibers incorporation on concrete. Then, the fracture energy enhancement (from about 16 to 22 times) and dependencies: crack mouth opening displacement–deflection; crack mouth opening displacement–crack tip opening displacement; and crack tip opening displacement–deflection were analyzed. Finally, the results from flexural tensile tests were compared with measurements of the surface displacement field obtained through the Digital Image Correlation technique. It was concluded that this technique can be successfully used to determine the crack mouth and crack tip opening displacements with very high accuracy.  相似文献   

13.
In cemented sand, the influences of the sampling factors (i.e., the curing time, cement–sand ratio, and initial void ratio) on the triaxial shear behavior were investigated using discrete element method. Cemented sand samples with different initial conditions were prepared and subjected to the consolidated drained triaxial shearing test. In the simulations, the peak strength, residual strength, and pre-peak stiffness of cemented sand were enhanced by increasing the curing time and cement–sand ratio, and the enhancements could be explained by the increases in bond strength and bond number. Resulting from the increases of these two sampling factors, bond breakage emerged at a greater axial strain but lower intensity. However, some uncommon phenomena were generated; that is, the contractive but strain-softening response occurred in the sample with a curing time of 3 days, and the shear band and the strain-hardening behavior coexisted in the sample with a cement–sand ratio of 1%. The peak strength and pre-peak stiffness were also enhanced by decreasing the initial void ratio, more distinctly than by increasing the curing time and cement–sand ratio. However, the residual strength, bond breakage, and failure pattern with the persistence of shear band were insensitive to this change.  相似文献   

14.
Usually, C30/37 strength class concrete is used to construct concrete pavements on a rigid, semi-rigid or flexible base. Concrete with such a strength delivers essential design characteristics: flexural strength and tensile splitting strength are between 4.5–5.4 MPa and 2.8–3.7 MPa, respectively. Design characteristics can be significantly increased by densifying the concrete mixture, i.e., adding silica fume, steel or polypropylene macro fibers. As high-performance concrete characteristics are 20–60% higher than those for standard concrete (C30/37), new possibilities to reduce the thickness of concrete pavement slabs appear. The theoretical analysis of concrete pavement structures with high-performance concrete mixtures (C40/50, C45/55 and C50/60) showed that slab thickness could be reduced by 6–39% compared to a standard concrete pavement structure depending on the concrete properties and design method. From all those pavement structures, three concrete mixtures were determined as the most rational ones in terms of PCP thickness reduction and total pavement cost: (i) with 49.5 kg/m3 of steel fibers and 25.2 kg/m3 of silica fume; (ii) with 10.0 kg/m3 of polypropylene fibers (type A); (iii) with 49.5 kg/m3 of steel fibers.  相似文献   

15.
Lime quartz samples in which ground quartz sand was gradually substituted with waste glass powder (GP) were obtained under hydrothermal conditions to determine the influence of GP addition on the microstructure (observed by SEM), phase composition (analyzed by XRD), and compressive strength of autoclaved building materials. An additional series containing analytical grade NaOH and no GP was formed to evaluate the effect of sodium ions on tobermorite formation and its impact on the mechanical properties of the samples. GP addition hindered the formation of tobermorite during autoclaving. Instead, a higher amount of an amorphous and semi-crystalline C–S–H phase formed, leading to the densification of the composite matrix. Nevertheless, tobermorite-like structures were found during both XRD and SEM analyses, proving that the presence of small amounts of Al3+ ions allowed, to an extent, for the stabilization of the phase despite the high sodium content. The compressive strength values indicate that the presence of alkali in the system and the resulting formation of additional portions of C–S–H have a beneficial influence on the mechanical properties of autoclaved composites. However, the effect fades with increasing glass powder content which, together with a slight expansion of the samples, suggests that at high sand substitution levels, an alkali–silica reaction takes place.  相似文献   

16.
The carburizing–quenching–tempering process is generally conducted on heavy-duty gear in order to obtain favorable comprehensive mechanical performance. Different mechanical properties could be produced by carbon partition and precipitation. In this study, the carburizing–quenching–tempering process was carried out on low-carbon alloy steel in order to investigate the influence of microstructure evolution and precipitate transition on mechanical behavior and wear resistance under different carburizing/tempering durations. Favorable comprehensive mechanical property and wear resistance could be obtained in favor of long durations of carburizing/tempering. A fatigue-wear model was proposed to describe fatigue crack evolution and damage mechanism on the basis of wear features.  相似文献   

17.
Supplementary cementitious materials (SCMs) and chemical additives (CA) are incorporated to modify the properties of concrete. In this paper, SCMs such as fly ash (FA), ground granulated blast furnace slag (GGBS), silica fume (SF), rice husk ash (RHA), sugarcane bagasse ash (SBA), and tire-derived fuel ash (TDFA) admixed concretes are reviewed. FA (25–30%), GGBS (50–55%), RHA (15–20%), and SBA (15%) are safely used to replace Portland cement. FA requires activation, while GGBS has undergone in situ activation, with other alkalis present in it. The reactive silica in RHA and SBA readily reacts with free Ca(OH)2 in cement matrix, which produces the secondary C-S-H gel and gives strength to the concrete. SF addition involves both physical contribution and chemical action in concrete. TDFA contains 25–30% SiO2 and 30–35% CaO, and is considered a suitable secondary pozzolanic material. In this review, special emphasis is given to the various chemical additives and their role in protecting rebar from corrosion. Specialized concrete for novel applications, namely self-curing, self-healing, superhydrophobic, electromagnetic (EM) wave shielding and self-temperature adjusting concretes, are also discussed.  相似文献   

18.
Recognizing that steel fibers can supplement the brittle tensile characteristics of concrete, many studies have been conducted on the shear performance of steel fiber reinforced concrete (SFRC) members. However, previous studies were mostly focused on the shear strength and proposed empirical shear strength equations based on their experimental results. Thus, this study attempts to estimate the strains and stresses in steel fibers by considering the detailed characteristics of steel fibers in SFRC members, from which more accurate estimation on the shear behavior and strength of SFRC members is possible, and the failure mode of steel fibers can be also identified. Four shear behavior models for SFRC members have been proposed, which have been modified from the softened truss models for reinforced concrete members, and they can estimate the contribution of steel fibers to the total shear strength of the SFRC member. The performances of all the models proposed in this study were also evaluated by a large number of test results. The contribution of steel fibers to the shear strength varied from 5% to 50% according to their amount, and the most optimized volume fraction of steel fibers was estimated as 1%–1.5%, in terms of shear performance.  相似文献   

19.
Self-healing concrete designs can protect against deterioration and improve durability. However, there is no unified conclusion regarding the effective preparation and mechanical properties of self-healing concrete. In this paper, microcapsules are used in cement-based materials, the reasonable dosage of microcapsules is determined, and the self-healing performance of the microcapsule self-healing system under different curing agents is explored. The microcapsules and curing agent are shown to enhance the flexural and compressive strength of mortar specimens at relatively low contents. The optimal microcapsule content in terms of compressive strength is 1–3%. When the content of the microcapsule reaches 7%, the strength of the specimen decreases by approximately 30%. Sodium fluorosilicate is better-suited to the microcapsule self-healing cement-based system than the other two fluorosilicates, potassium fluorosilicate and magnesium, which have similarly poor healing performance as curing agents. Healing time also appears to significantly influence the microcapsule self-healing system; mortar specimens that healed for 28 days are significantly higher than those that healed for 7 days. This work may provide a valuable reference for the design and preparation of self-healing cementitious composite structures.  相似文献   

20.
The cyclic tensile behavior of steel-reinforced high strain-hardening ultrahigh-performance concrete (HSHUHPC) was investigated in this paper. In the experimental program, 12 HSHUHPC specimens concentrically placed in a single steel reinforcement under cyclic uniaxial tension were tested, accompanied by acoustic emission (AE) source locating technology, and 4 identical specimens under monotonic uniaxial tension were tested as references. The experimental variables mainly include the loading pattern, the diameter of the embedded steel rebar, and the level of target strain at each cycle. The tensile responses of the steel-reinforced HSHUHPC specimens were evaluated using multiple performance measures, including the failure pattern, load–strain response, residual strain, stiffness degradation, and the tension-stiffening behavior. The test results showed that the enhanced bond strength due to the inclusion of steel fibers transformed the failure pattern of the steel-reinforced HSHUHPC into a single, localized macro-crack in conjunction with a sprinkling of narrow and closely spaced micro-cracks, which intensified the strain concentration in the embedded steel rebar. Besides, it was observed that the larger the diameter of the embedded steel rebar, the smaller the maximum accumulative tensile strain under cyclic tension, which indicated that the larger the diameter of the embedded steel rebar, the greater the contribution to the tensile stiffness of steel-reinforced HSHUHPC specimens in the elastic–plastic stage. In addition, it was found that a larger embedded steel rebar appeared to reduce the tension-stiffening effect (peak tensile strength) of the HSHUHPC. Moreover, the residual strain and the stiffness of the steel-reinforced HSHUHPC were reduced by increasing the number of cycles and finally tended toward stability. Nevertheless, different target strain rates in each cycle resulted in different eventual cumulative tensile strain rates; hence the rules about failure pattern, residual strain, and loading stiffness were divergent. Finally, the relationship between the accumulative tensile strain and the loading stiffness degradation ratio under cyclic tension was proposed and the tension-stiffening effect was analyzed.  相似文献   

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