Strength Properties of Sustainable Mortar Containing Waste Steel Slag and Waste Clay Brick: Effect of Temperature

The use of waste streams for the production of sustainable cement-based materials cannot be overemphasized. This study investigates the feasibility of reusing waste steel slag (WSS) and waste clay brick (WCB) as a replacement for natural sand (NS) in mortar. Numerous studies have reported mainly the compressive strength of concrete/mortar, while limited research is available that focuses on the tensile and flexural strength of mortar, and especially the performance at elevated temperature. Hence, this study investigates the tensile and flexural strength of mortar with three different replacement percentages (0, 50 and 100% by volume of NS) of NS by WSS and WCB at normal temperature (without thermal treatment) and after exposure to elevated temperatures (250, 400 and 600 °C). At ambient condition, both tensile and flexural strength were enhanced as the WSS content increased (76 and 68%, respectively, at 100% WSS). In comparison, the strength increased at 50% WCB (25 and 37%, accordingly) and decreased at 100% WCB (23 and 20%, respectively) compared to 100% NS. At elevated temperatures, both the tensile and flexural strength of mortar mixes decreased significantly at 600 °C.     

Evaluating the Feasibility of Using Brick Powder and Clay Powder in Cement Replacement

The cement industry generates very large amounts of CO₂ into the atmosphere. In recent years, there has been a search for alternative cementitious materials and micro-fillers that could partially or fully replace cement in cement composites without compromising their durability. This paper investigates the possibility of using brick powder (BP) and clay powder (CP) as a partial replacement for cement (up to 20% by weight) in cement paste. The raw materials were characterized, and the physical and mechanical properties of the modified cement pastes were studied, as well as their resistance to a short-term thermal shock at 250 °C. The study was supplemented by intelligent modelling of compressive strength using the support vector machine (SVM) algorithms. The results indicated a significant increase in tensile strength (up to 100%) and an increase in thermal resistance of cement pastes modified with BP and CP. The proposed SVM model had high accuracy (R² = 0.90), indicating its suitability to predict the compressive strength of the modified cement matrix. This study complements the knowledge in the field of inter alia, the effect of a short-term thermal shock at elevated temperature on the properties of BP and CP modified cement paste, and the effect of BP, which, due to its grain size, plays more the role of a microfiller than a pozzolanic additive.     

Properties of Titanium Zirconium Molybdenum Alloy after Exposure to Indium at Elevated Temperatures

Titanium zirconium molybdenum (TZM) is a high strength at high temperature alloy with favorable properties for use in high temperature structural applications. Use of TZM in high pressure, gas-containing autoclave systems was recently demonstrated for the ammonothermal method. Use of indium (In) in the system is desired, though there is a general lack of literature and understanding on the corrosion and impact of In on the mechanical properties of TZM. This study reports for the first time the mechanical properties of TZM after exposure to metallic In at temperatures up to 1000 °C. Static corrosion testing of TZM in In were performed at 750 °C and 1000 °C for 14 days. A microstructure analysis was performed suggesting no visible alteration of the grain structure. Differential thermal analysis (DTA) was performed to investigate compound formation between In and the primary constituents of TZM yielding no measurable reactions and hence no noticeable compound formation. X-ray energy dispersive spectroscopy (EDS) line scans across the TZM-In interface revealed no measurable mass transport of In into the TZM matrix. These results were confirmed using X-ray diffraction (XRD). Given the apparent inertness of TZM to In, mechanical properties of TZM after exposure to In were measured at test temperatures ranging from 22 °C to 800 °C and compared to unexposed, reference TZM samples from the same material stock. Tensile properties, including ultimate tensile strength, yield strength and total elongation, were found to be comparable between In-exposed and unexposed TZM samples. Impact fracture toughness testing (Charpy) performed at temperatures ranging from −196 °C to 800 °C showed that TZM is unaffected upon exposure to In. Tensile testing indicated ductile behavior at room temperature (slow strain rate) whereas impact testing (high strain rate) suggested a ductile to brittle transition temperature between 100 °C and 400 °C. Given these results, TZM appears to be a promising candidate for use as a force bearing material when exposed to In at high temperature.     

Low-Carbon and Fundamental Properties of Eco-Efficient Mortar with Recycled Powders

Using recycled powders from solid waste is accepted as an effective strategy to realize the sustainable development of the construction industry. In our study, the cement was substituted by two kinds of recycled powders, i.e., spontaneous combustion gangue powder (SCGP) and recycled concrete powder (RCP), with a certain replacement ratio of 30%. The experimental variables were mainly the type of replacement powder (e.g., SCGP, RCP, and SCGP + RCP) and the grinding time of RCP (e.g., 25 min, 50 min, and 75 min). The fundamental properties, including mechanical properties, long-term properties, and carbon emission, were analyzed for all the mortar mixtures. Experimental results indicate that incorporation of RCP contributes to enhancing the toughness and dry shrinkage resistance of eco-efficient mortar, while SCGP positively affects the compressive strength and chloride resistance. The grinding process improves the activity of RCP to a certain extent, while a long grinding time leads to fusion and aggregation between powders. Investigation on CO₂ emission demonstrates that carbon emission from cement production accounts for the largest proportion, 80~95%, in the total emission from mortar production. Combined with the AHP model, eco-efficient mortar containing 15% RCP ground for 50 min and 15% SCGP displays optimal fundamental properties.     

Fundamental Properties and Self-Healing Performance of Repair Mortar with Solid Capsules Made Using Inorganic Reactive Powder

Self-healing cement composites are generally produced by using materials such as inorganic powders, bacteria pellets, and microcapsules. Among them, inorganic powder-type healing materials tend to decrease in healing performance over time because they react relatively quickly. Accordingly, this study encapsulated self-healing inorganic reactive powders in solid capsules (SC) in order to delay their reaction. The capsule surface was coated with a membrane to prevent moisture from permeating it. SC were utilized to provide the self-healing effect to the repair mortar. SC were mixed at three rates (0%, 5%, and 10%) by the binder mass of the repair mortar. The fundamental properties, including rheology, table flow, strength, and length change, and the self-healing performance of the self-healing repair mortar mixes were investigated. It was found that the rheological and mechanical properties of the repair mortar decreased slightly as the amount of SC increased. On the other hand, for a crack width of 0.25 mm and crack inducing age of 28 days, the healing performance of repair mortar specimens containing SC was at least 20 pt% better than that of plain repair mortar after a healing period of 28 days.     

Strength and Water-Repelling Properties of Cement Mortar Mixed with Water Repellents

In this study, the compressive strength and water contact angle of mortar specimens prepared by mixing two types of water repellent with ordinary Portland cement (OPC) and rapid-hardening cement mortar were measured before and after surface abrasion. In addition, the hydration products and chemical bonding of cement mortar with the repellents were examined using X-ray diffraction (XRD), thermogravimetry-differential thermal analysis (TG-DTA), and Fourier-transform infrared spectroscopy (FT-IR) to evaluate the performance of these cement mortar mixtures as repair materials. We found that the fast-hardening cement mortar mixture containing the oligomer water repellent showed the best performance with a high compressive strength and large water contact angle. With the oligomer water repellent, the rapid-hardening cement mortar mixture showed contact angles of 131° and 126° even after a 2 mm abrasion, thereby confirming that the water repellent secured hydrophobicity through strong bonding with the entire cement mortar as well as its surface. The compressive strengths were found to be 34.5 MPa at 3 h and 54.8 MPa at 28 days, confirming that hydration occurred well despite the addition of water repellent.     

Experimental Research on Mechanical Properties of Carbon Fiber-Reinforced Reactive Powder Concrete after Exposure to Cryogenic Temperatures

This study aims to evaluate the mechanical properties of carbon fiber-reinforced reactive powder concrete (CFRPC) after exposure to cryogenic temperature. The mechanical properties of plain RPC and CFRPC with carbon fiber volume contents of 0, 0.5%, 1.0%, and 1.5% were examined after exposure to 20 °C, −5 °C, −15 °C, and −25 °C for 72 h. The effect of fiber contents and exposure temperatures on the cubic and axial compressive strength, splitting tensile strength, elastic modulus, and peak strain were systematically reported and analyzed. The results showed adding carbon fiber to RPC could significantly enhance the strength and slightly improve ductility performance. Additionally, CFRPC with 1.0% fiber content showed the best mechanical properties. The maximum increases in cubic and axial compressive strength and tensile strength were 26.0%, 25.7%, and 21.8%, the elastic modulus was 13.2%, and the peak strain was 13.0% over the plain RPC. Additionally, all mechanical properties continued to degrade with decreasing temperature. After exposure to −25 °C, the cubic, axial compressive strength, and tensile strength of CFRPC degraded to 82.2–84.9%, 80.7–87.5%, and 72.7–73.7% of the normal temperature strength, respectively. In addition, the linear relationship equation between the discount factor of each mechanical property and the temperature was established. Finally, the equation for the stress–strain ascending curve of CFRPC described by a quadratic polynomial was proposed, which fitted well with the experimental results.     

Influence of Silica Modulus and Curing Temperature on the Strength of Alkali-Activated Volcanic Ash and Limestone Powder Mortar

This present study evaluates the effect of silica modulus (M_s) and curing temperature on strengths and the microstructures of binary blended alkali-activated volcanic ash and limestone powder mortar. Mortar samples were prepared using mass ratio of combined Na₂SiO_3(aq)/10 M NaOH_(aq) of 0.5 to 1.5 at an interval of 0.25, corresponding to M_s of 0.52, 0.72, 0.89, 1.05 and 1.18, respectively, and sole 10 M NaOH_(aq). Samples were then subjected to ambient room temperature, and the oven-cured temperature was maintained from 45 to 90 °C at an interval of 15 °C for 24 h. The maximum achievable 28-day strength was 27 MPa at M_s value of 0.89 cured at 75 °C. Samples synthesised with the sole 10 M NaOH_(aq) activator resulted in a binder with a low 28-day compressive strength (15 MPa) compared to combined usage of Na₂SiO_3(aq)/10 M NaOH_(aq) activators. Results further revealed that curing at low temperatures (25 °C to 45 °C) does not favour strength development, whereas higher curing temperature positively enhanced strength development. More than 70% of the 28-day compressive strength could be achieved within 12 h of curing with the usage of combined Na₂SiO_3(aq)/10 M NaOH_(aq). XRD, FTIR and SEM + EDX characterisations revealed that activation with combined Na₂SiO_3(aq)/10 M NaOH_(aq) leads to the formation of anorthite (CaAl₂Si₂O₈), gehlenite (CaO.Al₂O₃.SiO₂) and albite (NaAlSi₃O₈) that improve the amorphosity, homogeneity and microstructural density of the binder compared to that of samples synthesised with sole 10 M NaOH_(aq).     

Mixture Design and Mechanical Properties of Recycled Mortar and Fully Recycled Aggregate Concrete Incorporated with Fly Ash

Recycled aggregate concrete (RAC) is a sort of green, low carbon, environmental protection building material, its application is of great significance to the low carbonization of the construction industry. The performance and strength of RAC are much lower than natural aggregate concrete (NAC), which are the key factors restricting its application. Class F fly ash is a cementitious material that is considered environmentally hazardous. In this paper, appropriate water-binder (w/b) ratios were found through a mortar expansion test at first. The compressive strength of recycled mortar incorporated with class F fly ash was further studied. On this basis, the mechanical properties of nine groups of fully recycled aggregate concrete (FRAC) with a w/b ratio of 0.3, 0.35, and 0.4, and fly ash replacement ratios of 0, 20%, and 40%, were studied. The influence of the w/b ratio and fly ash replacement ratio on mechanical properties was analyzed and compared with previous research results. In addition, the conversion formulas between the splitting tensile strength, flexural strength, and compressive strength of FRAC were fitted and established. The research results have a certain guiding significance for the mixture design of FRAC and further application of class F fly ash.     

Microstructure Development and Properties of the Two-Component Melt-Spun Ni55Fe20Cu5P10B10 Alloy at Elevated Temperatures

The aim of this work was to investigate the features of microstructure, phase composition, mechanical properties, and thermal stability of the two-component melt-spun Ni55Fe20Cu5P10B10 alloy. The development of the microstructure after heating to elevated temperatures was studied using scanning electron microscope and in situ high temperature X-ray diffraction. The high-temperature behavior of the two-component melt-spun Ni55Fe20Cu5P10B10 alloy and Ni40Fe40B20, Ni70Cu10P20, and Ni55Fe20Cu5P10B10 alloys melt-spun from single-chamber crucible was investigated using differential scanning calorymetry at different heating rates and by dynamic mechanical thermal analysis. The results show that band-like microstructure of the composite alloy is stable even at 800 K, although coarsening of bands forming the microstructure of the ribbons is observed above 550 K. Plastic deformation is observed in the composite previously heated to temperatures of 600–650 K. The properties of the composite alloy are generally different than the properties obtained for the melt-spun alloy of the same average nominal composition produced traditionally. Additionally, the mechanical and the thermal properties in this composite are inherited from the amorphous state of alloys that are precursors for two-component melt spinning (TCMS) processing.     

Metaheuristic Prediction of the Compressive Strength of Environmentally Friendly Concrete Modified with Eggshell Powder Using the Hybrid ANN-SFL Optimization Algorithm

The aim of this article is to predict the compressive strength of environmentally friendly concrete modified with eggshell powder. For this purpose, an optimized artificial neural network, combined with a novel metaheuristic shuffled frog leaping optimization algorithm, was employed and compared with a well-known genetic algorithm and multiple linear regression. The presented results confirm that the highest compressive strength (46 MPa on average) can be achieved for mix designs containing 7 to 9% of eggshell powder. This means that the strength increased by 55% when compared to conventional Portland cement-based concrete. The comparative results also show that the proposed artificial neural network, combined with the novel metaheuristic shuffled frog leaping optimization algorithm, offers satisfactory results of compressive strength predictions for concrete modified using eggshell powder concrete. Moreover, it has a higher accuracy than the genetic algorithm and the multiple linear regression. This finding makes the present method useful for construction practice because it enables a concrete mix with a specific compressive strength to be developed based on industrial waste that is locally available.     

Fresh,Mechanical, and Durability Properties of Self-Compacting Mortar Incorporating Alumina Nanoparticles and Rice Husk Ash

This paper presents a comprehensive evaluation on self-compacting (SC) mortars incorporating 0, 1, 3, and 5% alumina nanoparticles (NA) as well as 0% and 30% rice husk ash (RHA) used as Portland cement replacement. To evaluate the workability, mechanical, and durability performance of SC mortars incorporating NA and RHA, the fresh properties (slump flow diameter and V-funnel flow time), hardened properties (compressive strength, flexural strength, and ultrasonic pulse velocity), and durability properties (water absorption, rapid chloride permeability, and electrical resistivity) were determined. The results indicated that the addition of NA and RHA has negligible effect on the workability and water absorption rate of the SC mortars. However, significant compressive and flexural strength development was observed in the SC mortars treated with NA or the combination of NA and RHA. The introduction of RHA and NA also reduced the rapid chloride permeability and enhanced the electrical resistivity of the SC mortars significantly. It is concluded that the coexistence of 30% RHA and 3% NA as cement replacement in SC mortars can provide the best mechanical and durability performance.     

Microstructures and Tensile Properties of 9Cr-F/M Steel at Elevated Temperatures

Tensile properties and microstructure changes under different stress states of tempered 9Cr-F/M steel were characterized using a transmission electron microscope (TEM), electron backscatter diffraction (EBSD), scanning electron microscopy (SEM), Vickers hardness tester, and tensile tester. This tempered steel has a typical lath martensite structure with only a few polygonal ferrites embedded, and M₂₃C₆ and MX phases nucleated on the lath boundaries or within the sub-grains. At elevated temperatures, the strength of the steel decreases. However, the elongation at 400 °C is lower than that at room temperature. For the necking zone, tensile deformation made the grain elongated to the direction of applied stress and thus the grain’s cross-section becomes smaller. For samples with rectangular working area cross-section, the deformation in the TD direction was more severe than that in the ND direction, which made the grain elongated in the TD direction. These results can provide some guidance for composition optimization of the 9Cr-F/M steel and facilitate a better understanding of the fracture mechanism under different stress states.     

Experimental Study on the Properties of Mortar and Concrete Made with Tunnel Slag Machine-Made Sand

Machine-made sand is gradually replacing natural sand to achieve sustainable development. Experimental studies and gray-correlation analysis were used to study the properties of tunnel slag machine-made mortar and concrete. The properties of machine-made mortar with different stone powder content were analyzed through experiments. By analyzing the performance of machine-made sand concrete with equal amounts of cement replaced by stone powder, the optimum replacement ratio is obtained. Gray-correlation analysis was used to compare the degree of influence of fineness modulus and stone powder content on the performance of concrete. Scanning electron microscopy (SEM) and X-ray diffractometry (XRD) were used to analyze the microstructure of tunnel slag sand concrete. The test results showed that the flexural and compressive strengths of the machine-made sand concrete were greater than the standard sand with the same stone powder content. The 28-day flexural and compressive strengths had a maximum difference of more than 30%. The best stone powder content of the machine-made mortar is in the range of 5% to 8%. When the replacement cement content of stone powder is about 6%, the mechanical and working properties of machine-made sand concrete achieve the optimal state. The lower the stone powder content, the closer the mechanical and working properties of machine-made sand concrete and river sand concrete. The correlation between the performance of machine-made sand concrete and fineness modulus is the largest. When the stone powder content is low, it has almost no effect on the compressive strength of concrete. The results point out the direction for the quality control of tunnel slag machine-made sand concrete.     

Laser Beam Drilling of Inconel 718 and Its Effect on Mechanical Properties Determined by Static Uniaxial Tensile Testing at Room and Elevated Temperatures

Particularly in the aerospace industry and its applications, recast layers and microcracks in base materials are considered to be undesirable side effects of the laser beam machining process, and can have a significant influence on the resulting material behavior and its properties. The paper deals with the evaluation of the affected areas of the Inconel 718 nickel-base superalloy after its drilling by a laser beam. In addition, measurements and analyses of the mechanical properties were performed to investigate how these material properties were affected. It is supposed that the mechanical properties of the base material will be negatively affected by this accompanying machining process phenomenon. As a verification method of the final mechanical properties of the material, static uniaxial tension tests were performed on experimental flat shape samples made of the same material (Inconel 718) and three different thicknesses (0.5/1.0/1.6 mm) which best represented the practical needs of aerospace sheet metal applications. There was one hole that was drilled with an angle of under 70° in the middle of the sample length. Additionally, there were several sets of samples for each material thickness that were drilled by both conventional and nonconventional methods to emphasize the effect of the recast layer on the base material. In total, 192 samples were evaluated within the experiment. Moreover, different tensile testing temperatures (room as 23 °C and elevated as 550 °C) were determined for all the circumstances of the individual experiments to simulate real operation load material behavior. As a result, the dependencies between the amount of the recast layer and the length of the microcracks observed after the material was machined by laser beam, and the decrease in the mechanical properties of the base material, were determined.     

Effect of the Partial Replacement of Cement with Waste Granite Powder on the Properties of Fresh and Hardened Mortars for Masonry Applications

Granite is a well-known building and decorative material, and, therefore, the amount of produced waste in the form of granite powder is a problem. Granite powder affects the health of people living near landfills. Dust particles floating in the air, which are blown by gusts of wind, can lead to lung silicosis and eye infections, and can also affect the immune system. To find an application for this kind of waste material, it was decided to study the effect of partially replacing cement with waste granite powder on the properties of fresh and hardened mortars intended for masonry applications. The authors planned to replace 5%, 10%, and 15% of cement with waste material. Series of mortar with the addition of granite powder achieved 50% to 70% of the compressive strength of the reference series, and 60% to 76% of the bending strength of the reference series. The partial replacement of cement with the granite powder significantly increased the water sorption coefficient. The consistency of the fresh mortar, and its density and water absorption also increased when compared to the reference series. Therefore, Granite powder can be used as a partial replacement of cement in masonry mortars.     

Structure and Properties of Co-Cr-Mo Alloy Manufactured by Powder Injection Molding Method

Cobalt–chromium–molybdenum alloys samples were obtained by the powder injection molding method (PIM). PIM is dedicated to the mass production of components and can manufacture several grades of dental screws, bolts, stabilizers, or implants. As a skeleton component, ethylene–vinyl acetate (EVA copolymer) with a low temperature of processing and softening point was used. The choice of a low-temperature binder made it necessary to use a coarse ceramic powder as a mechanical support of the green sample during sintering. The injection-molded materials were thermally degraded in N₂ or Ar-5%H₂ and further sintered in N₂-5%H₂ or Ar-5%H₂ at 1300 or 1350 °C for 30 min. The structure of the obtained samples was characterized by X-ray diffraction and electron microscopy. Mechanical properties, including hardness and three-point bending tests, confirmed that a nitrogen-rich atmosphere significantly increases the bending strength compared to the material manufactured in Ar-5%H₂. This is due to the precipitation of numerous fine nitrides and intermetallic phases that strengthen the ductile γ-phase matrix.     

Microstructural Evolution and Surface Mechanical Properties of the Titanium Alloy Ti-13Nb-13Zr Subjected to Laser Shock Processing

As a progressive surface-hardening technology, laser shock processing (LSP) can enhance the mechanical properties and extend fatigue life for metallic components through laser-generated high-pressure plasma shock waves. In this work, LSP was used to treat titanium alloy Ti-13Nb-13Zr experimental coupons, and the microstructural response and surface mechanical properties of the Ti-13Nb-13Zr experimental coupons were investigated. After the LSP treatment, the X-ray diffraction (XRD) peaks were shifted without any new phase formation. The surface roughness of the experimental coupons increased, which can be explained by the LSP-induced severe plastic deformation. The LSP treatment effectively enhanced the surface compressive residual stress of Ti-13Nb-13Zr. Meanwhile, the microhardness of the Ti-13Nb-13Zr was also obviously increased after the LSP treatment. The experimental results also showed that the number of shocks times is an important factor in the improvement of surface mechanical properties. LSP treatment with multiple shocks can lead to more severe plastic deformation. The surface roughness, surface compressive residual stress and microhardness of the Ti-13Nb-13Zr experimental coupons shocked three times are higher than those after one shock. What is more, grain refinement accounts for the mechanical properties’ enhancements after the LSP treatment.     

Effect of Elevated Temperatures on the Mechanical Properties of a Direct Laser Deposited Ti-6Al-4V

In the present work, the mechanical properties of the DLD-processed Ti-6Al-4V alloy were obtained by tensile tests performed at different temperatures, ranging from 20 °C to 800 °C. Thereby, the process conditions were close to the conditions used to produce large-sized structures using the DLD method, resulting in specimens having the same initial martensitic microstructure. According to the obtained stress curves, the yield strength decreases gradually by 40% when the temperature is increased to 500 °C. Similar behavior is observed for the tensile strength. However, further heating above 500 °C leads to a significant increase in the softening rate. It was found that the DLD-processed Ti-6Al-4V alloy had a Young’s modulus with higher thermal stability than conventionally processed alloys. At 500 °C, the Young’s modulus of the DLD alloy was 46% higher than that of the wrought alloy. The influence of the thermal history on the stress relaxation for the cases where 500 °C and 700 °C were the maximum temperatures was studied. It was revealed that stress relaxation processes are decisive for the formation of residual stresses at temperatures above 700 °C, which is especially important for small-sized parts produced by the DLD method. The coefficient of thermal expansion was investigated up to 1050 °C.     

Physicochemical,Mechanical, and Esthetic Properties of the Composite Resin Manipulated with Glove Powder and Adhesive as a Modeling Liquid

Composite resins with low flowability are usually handled and manipulated before insertion into the tooth preparation with gloved hands and/or using an instrument covered with a little amount of adhesive to facilitate modeling. We investigated if the modeling techniques (combined or not) affected physicochemical and esthetic properties of a composite resin. Specimens were fabricated and divided into groups according to the handling/modeling technique: Gloved-hands (composite was hand-manipulated with powdered latex gloves); Adhesive (adhesive was used in between the composite layers); Gloved-hands + Adhesive; Control (no adhesive and no touch with gloved-hands). The highest values for flexural strength (MPa), modulus of elasticity (GPa), and fracture toughness (MPa.m^0.5) were obtained for Adhesive and Gloved-hands + Adhesive (p < 0.05); the lowest values were obtained for Control and Gloved-hands (p < 0.05). The Control group had the highest sorption. The Gloved-hands (p < 0.05) group had the highest solubility. Adhesive and Gloved-hands + Adhesive had a similar solubility (p > 0.05). The Control group (p < 0.05) had the lowest solubility. There was no statistical interaction between translucency vs. handling/modeling techniques and color stability vs. handling/modeling techniques. Adhesive as a modeling liquid protected the composite against sorption and solubility (if powdered gloves were used) and improved its physical/mechanical properties. Translucency and color stability were not correlated with modeling techniques.