Sulfate Freeze–Thaw Resistance of Magnesium Potassium Phosphate Cement Mortar

Concrete facilities in the severe-cold areas of western China (salt lake environments and heavy saline soils) are seriously damaged by the multiple corrosion effects of freeze–thaw cycles and sulfate corrosion. Magnesium phosphate cement (MPC) cement-based material has become an ideal concrete structural component because of its superior performance. Because concrete structural repair materials are used in heavy-corrosion environments, their durability in those environments should also be considered. Regarding the salt-freezing resistance of MPC, the existing studies have all used a NaCl solution as the heat transfer medium. In addition to chlorine salt, sulfate, especially Na₂SO₄, is also common in typical use environments such as oceans, salt lakes, and groundwater. To evaluate the sulfate freeze–thaw resistance of potassium magnesium phosphate cement (MKPC) mortar, in this study the strength development, weight loss, and water absorption of MKPC mortar specimens subjected to different freeze–thaw cycles were tested and compared with those for Portland cement (P.O) mortar specimens of the same strength grade. The results showed that the P.O mortar specimen completely lost its strength after 75 cycles of rapid water freezing and thawing and 50 cycles of sodium sulfate solution (5%) freezing and thawing. However, the residual strength rating of the MKPC mortar specimen after 75 cycles of water freezing and thawing and 100 cycles of sodium sulfate solution freezing and thawing was higher than 75%. After 50 rapid freeze–thaw cycles in water and a 5% Na₂SO₄ solution, the P.O mortar specimen’s mass loss exceeded the 5% failure standard, whereas the mass loss of the MKPC mortar specimens was much less than 5%. Before the freeze–thaw cycles, the water absorption of the P.O mortar specimen was close to 8 times that of the MKPC mortar specimen, and after 50 water freeze–thaw cycles and 25 sulfate solution freeze–thaw cycles, the water absorption reached 4.88% and 5.68%, respectively. However, after 225 freeze–thaw cycles in water and the sulfate solution, the water absorption rates of MKPC mortar specimens were 2.91% and 2.51% respectively. The test and analysis results show that the freeze–thaw resistance of MKPC mortar was much higher than that of Portland cement mortar specimens. Those results provide a prerequisite for applying and expanding the use of MKPC-based materials in severe-cold areas of western China (salt lake and heavily saline soil environments).     

Study on Deterioration of Gray Brick with Different Moisture Contents under Freeze–Thaw Environment

Generally, brick buildings are in the open-air environment year round, and damage to them is aggravated by the effect of repeated freezing and thawing cycles. In order to determine freeze–thaw damage and deterioration mechanism, the initial moisture content of gray brick specimens was set as 20%, 40%, 60%, 80%, 100%. The effects of moisture content and the number of freeze–thaw cycles on the quality, mechanical properties and microstructure of gray brick were investigated by uniaxial compression tests and scanning electron microscopy (SEM) tests. Numerical simulations were applied to model the freezing and thawing process. The results showed that: as the number of freeze–thaw cycles increased, the mass loss rate and peak strength reduction rate of gray brick both increased. The initial moisture content had a greater impact on damage to gray brick due to freeze–thaw; ω = 80% was defined as the limit moisture content of gray brick. Under the repeated action of freeze–thaw cycles, the areas affected by thermal stress were mainly concentrated in the center of the outer surface and the center of the side of gray bricks. The maximum thermal stress after 55 freeze–thaw cycles was 1.522 × 10⁻² MPa. This research results provide a theoretical basis for the prevention and protection of frost damage of brick buildings in a freeze–thaw environment.     

Concrete Durability after Load Damage and Salt Freeze–Thaw Cycles

To determine how the performance of concrete changes after initial load damage and salt freezing, concrete samples were first subjected to loading and unloading, and were then put into salt solutions to carry out rapid freeze–thaw cycle (FTC) experiments. Salt solutions were created based on the saline soil of western Jilin, China, for use in salt freeze–thaw testing. This determined the change law of the compressive strength and the dynamic elastic modulus (DEM). Additionally, low-field nuclear magnetic resonance technology and a scanning electron microscope were applied to investigate the pore characteristics and microstructure of concrete samples after FTCs. This study found that when the concrete specimens were subjected to an initial load of 0.3f under 50 FTCs, the loss in the compressive strength increased by 24% when the concrete was subjected to freeze–thaw cycles in freshwater and increased by 24% when concrete was subjected to freeze–thaw cycles in a 6.8% composite salt solution compared with the specimens without the initial load. When the concrete was subjected to FTCs in a 6.8% composite salt solution 50 times, the loss in the compressive strength increased by 110% for concrete without an initial load and increased by 109% when the concrete was subjected to an initial load of 0.3f compared with the specimens under FTCs in freshwater. The persistent effect of the FTCs also aggravated chloride ion erosion in the concrete, which gradually reduced the concrete’s permeability resistance. Internal pores in the concrete, especially the proportion of above-medium-sized pores, gradually increased along with the increase in the number of FTCs. There is a good linear correlation between the change rule of compressive mechanical properties and the change rules of mass, DEM, and pore characteristics inside the concrete under rapid FTCs in different salt solutions.     

Effects of Freeze–Thaw Cycles on the Internal Voids Structure of Asphalt Mixtures

Freeze–thaw cycle is one of the main distresses of asphalt pavement, and the law of freeze–thaw damage has always been an important topic. In this paper, X-ray computed tomography (CT) of asphalt mixture before and after freezing and thawing was carried out, and its two-dimensional (2D) digital image was recognized. Firstly, the eigenvalues of internal voids of asphalt mixture are extracted. Then the distribution of internal voids was analyzed. Finally, the evolution law of internal voids was summarized. The research results show that the characteristic mean value of the 9th cycle is the irreversible limit of freeze–thaw damage, and the non-resilience after the large void area increases is the fundamental reason for the accumulation of freeze–thaw damage. The source of void damage shifts from large voids to small voids, and the middle-stage is a critical stage of freeze–thaw damage. This work quantitatively evaluates the internal freeze–thaw damage process of asphalt mixture, and a morphological theory of the evolution of void damage based on an equivalent ellipse is proposed, which is helpful for better understanding the freezing–thawing damage law of asphalt pavement.     

Bond Behavior of Reinforced Concrete Considering Freeze–Thaw Cycles and Corrosion of Stirrups

In relatively cold environments, the combination of freeze–thaw and steel bar corrosion is a key factor affecting the durability of concrete. The adjustment of the stirrup ratio would change the mechanical performance of surrounding concrete, while the circumferential compressive stress can further improve the bonding performance. Hence, based on eccentrically tensioned specimens, the influence of corrosion of stirrups and freeze–thaw of concrete on bond properties is discussed in this paper. The monotonic pull-out test of reinforced concrete specimens is carried out to study the variation rules of bond strength and slip between steel bar and concrete under the coupling action of corrosion rate, freeze–thaw times and stirrup spacing. Based on the experimental data, the empirical formula for the ultimate bond strength is obtained, and a bond–slip constitutive model is established considering the stirrup spacing, stirrup corrosion rate and freeze–thaw times. Then, a refined finite element pull-out specimen model is established by ABAQUS simulation, and the numerical simulation results are compared with the real test ones, so as to make up for the deficiencies in the test and lay the foundation for further finite element analysis.     

Compressive Behavior,Microstructural Properties,and Freeze–Thaw Behavior of Tailing Recycled Aggregate Concrete with Waste Polypropylene Fiber Addition

To improve the high brittleness of recycled aggregate concrete containing iron ore tailings (TRAC), the feasibility of adding polypropylene fiber (PPF) to TRAC was studied by performing a compression stress–strain curve test, scanning electron microscope characterization, and a freeze–thaw cycle test. The results indicated that PPF had a beneficial impact on reducing the brittleness of TRAC. With the increase in PPF content, the peak strain increased, the elastic modulus decreased, and the peak stress and energy absorption capacity increased at first and then decreased. Furthermore, the microstructure investigation revealed that the interface friction between the PPF, aggregate, and cement matrix was the main source of energy dissipation. When the load acted on the concrete, the stress was dispersed to the fiber monofilaments, thus effectively enhancing the peak stress and peak strain of concrete and suppressing the generation and development of cracks in the concrete. In terms of freeze–thaw resistance, adding a small amount of PPF could reduce the negative effects of the freeze–thaw process on the cement matrix. On the premise of ensuring strength, the waste utilization should be as high as possible. Therefore, it was suggested that the content of PPF in fiber-reinforced tailings recycled aggregate concrete (TRAC-PP) should be 0.6%.     

Freeze–Thaw Effect on Road Concrete Containing Blast Furnace Slag: NMR Relaxometry Investigations

The present work investigates the effect of freeze–thaw cycles on the porosity of three mixtures of road concrete containing blast furnace slag in comparison with two mixtures made with conventional materials. The main technique used in our investigations is nuclear magnetic resonance (NMR) relaxometry. This permitted the extraction of information with respect to the freeze–thaw effect on pore-size distribution, which influences both the mechanical strength and the molecular transport through the material. Moreover, by using this technique, the structure of the air voids was analyzed for the entire pore system in the cement paste and the aggregate particles. The samples under study were first dried in a vacuum oven and then saturated with water or cyclohexane where the distribution of the transverse relaxation times of the protons was recorded. The NMR relaxation measurements were performed on samples extracted from specimens maintained at 300 freeze–thaw cycles and on control samples extracted from specimens kept in water during the freeze–thaw period. Scanning Electron Microscopy (SEM) was used to analyze the microstructure of concrete samples in order to obtain information about the pore sizes and the distance between them. The results from the NMR relaxation measurements were consistent with those obtained by using standard techniques for determining the porosity and the freeze–thaw resistances. The investigations made it possible to establish the optimal composition of blast furnace slag that can be incorporated into road concrete compositions. This non-invasive technique can also complete standard techniques for assessing the porosity and the progress of internal cracks during the freeze–thaw test.     

Sulfate Freeze–Thaw Resistance of Magnesium Potassium Phosphate Cement Mortar according to Hydration Age

Concrete structures can be degraded by exposure to environmental stressors such as freeze–thaw cycling and salt corrosion. Magnesium potassium phosphate cement (MKPC) mortar is useful for the rapid repair of such structures but must acquire environmental resistance rapidly. In this study, the freeze–thaw resistance of MKPC mortar specimens of different hydration ages was tested in water and a 5% Na₂SO₄ solution. The strength, volume deformation, and water absorption rates were compared with those of full-age MKPC mortar specimens (28 d). The phase composition and microscopic morphology of the MKPC mortar specimens before and after corrosion were observed, and the corrosion-resistance mechanism was analyzed. After 225 freeze–thaw cycles in water and sulfate solution, the strength residual rates of the early-age specimen (1 d) were higher than those of the full-age specimen (28 d). The degree of strength attenuation in the 1 d specimen was lower in the sulfate environment than in the water environment. After 225 freeze–thaw cycles, the volume expansion rates of 1 d specimens in water or sulfate were 0.487% and 0.518%, respectively, while those of 28 d specimens were 0.963% and 1.308%. The comparison shows that the 1 d specimen had significantly better deformation resistance under freeze–thaw than the 28 d specimen. After 225 freeze–thaw cycles, the water absorption rates of 1 d specimens were 1.95% and 1.64% in water and sulfate solution, respectively, while those of 28 d specimens were 2.20% and 1.83%. This indicates that freeze–thaw cycling has a greater effect on the pore structure of fully aged mortar than on early-age mortar (1 d). Therefore, MKPC mortar is suitable for the rapid repair of concrete structures in harsh environments. The results form a theoretical basis for winter emergency repair projects. They also further the understanding of the application of MKPC-based materials in extreme environments.     

Hybrid Lime–Pozzolan Geopolymer Systems: Microstructural,Mechanical and Durability Studies

This work studies the possibility of using geopolymer materials to enhance the mechanical and durability properties of hydrated lime–pozzolan mixtures, which gave rise to the so-called “hybrid systems”. Two different waste types were used as pozzolan in the lime–pozzolan system: rice husk ash (RHA) and spent fluid catalytic cracking (FCC). The geopolymer fabricated with FCC was activated with commercial reagents (NaOH and Na₂SiO₃), and also with alternative sources of silica to obtain a lower carbon footprint in these mixtures. The alternative silica sources were RHA and residual diatomaceous earth (RDE) from the beer industry. The geopolymer mixture substituted the lime–pozzolan mixture for 30% replacement in weight. The hybrid systems showed better mechanical strengths for the short and medium curing ages in relation to the lime–pozzolan mixtures. Thermogravimetric analyses were performed to characterise the types of products formed in these mixtures. In the durability studies, hybrid systems better performed in freeze–thaw cycles and obtained lower capillarity water absorption values.     

Impact of Freeze–Thaw Cycles on the Long-Term Performance of Concrete Pavement and Related Improvement Measures: A Review

Freeze–thaw damage is one of the most severe threats to the long-term performance of concrete pavement in cold regions. Currently, the freeze–thaw deterioration mechanism of concrete pavement has not been fully understood. This study summarizes the significant findings of concrete pavement freeze–thaw durability performance, identifies existing knowledge gaps, and proposes future research needs. The concrete material deterioration mechanism under freeze–thaw cycles is first critically reviewed. Current deterioration theories mainly include the hydrostatic pressure hypothesis, osmolarity, and salt crystallization pressure hypothesis. The critical saturation degree has been proposed to depict the influence of internal saturation on freeze–thaw damage development. Meanwhile, the influence of pore solution salinity on freeze–thaw damage level has not been widely investigated. Additionally, the deterioration mechanism of the typical D-cracking that occurs in concrete pavement has not been fully understood. Following this, we investigate the coupling effect between freeze–thaw and other loading or environmental factors. It is found that external loading can accelerate the development of freeze–thaw damage, and the acceleration becomes more evident under higher stress levels. Further, deicing salts can interact with concrete during freeze–thaw cycles, generating internal pores or leading to crystalline expansion pressure. Specifically, freeze–thaw development can be mitigated under relatively low ion concentration due to increased frozen points. The interactive mechanism between external loading, environmental ions, and freeze–thaw cycles has not been fully understood. Finally, the mitigation protocols to enhance frost resistance of concrete pavement are reviewed. Besides the widely used air-entraining process, the freeze–thaw durability of concrete can also be enhanced by using fiber reinforcement, pozzolanic materials, surface strengthening, Super Absorbent Polymers (SAPs), and Phase Change Materials. This study serves as a solid base of information to understand how to enhance the freeze–thaw durability of concrete pavement.     

An Empirical Dilatancy Model for Coarse-Grained Soil under the Influence of Freeze–Thaw Cycles

In the era of high-speed trains, it is very important to ensure the safety and stability of rail tracks under adverse conditions including seasonal freezing and thawing. Freeze–thaw cycles (FTCs) affecting the engineering performance of coarse-grained soil (CGS) is one of the major reasons for track deterioration. The reported results of a number of static freeze–thaw triaxial tests on the shear behaviour of CGS are analysed herein. It was observed that confining pressure (σ₃) and FTCs have a significant influence on the shear behaviour of CGS. In this paper, an empirical mathematical model has been proposed to capture the dilatancy of CGS subjected to FTCs during shearing. The empirical constants a, b, and c proposed in the model are a function of σ₃ and FTCs. The results of the model have been compared with the laboratory experiments and are found to be in good agreement.     

Pore Structure Characteristics and Strength Variation of Red Sandstone under Freeze–Thaw Cycles

To study pore structure characteristics and the strength of red sandstone under freeze–thaw cycles, the saturated red sandstone was studied by the combination of freeze–thaw cycle test, high-pressure mercury injection test, uniaxial compression test and theoretical analysis, and research shows that: with the increase of freeze–thaw cycles, the pores of red sandstone continue to expand and extend, macropore volume and the total pore volume increases gradually, and the pore size distribution curves become more continuous. Porosity of samples after 10, 30, 70 and 100 freeze–thaw cycles is 1.14 times, 1.17 times, 1.28 times and 1.44 times of that of 0 cycle, and the uniaxial compressive strength of samples is 0.68 times, 0.53 times, 0.26 times and 0.17 times of that of 0 cycle, respectively. With the increase of freeze–thaw cycles, freeze–thaw damage continues to accumulate, the crack propagation direction changes from axial through-through failure mode to transverse and axial simultaneous failure mode. Taken the change of porosity as a parameter, through the regression analysis of the test data, the functional relationship between uniaxial compressive strength and the change of porosity in red sandstone is established. The research results will provide a theoretical basis for stability research of slopes of railway subgrade in cold region.     

Advanced Evaluation of the Freeze–Thaw Damage of Concrete Based on the Fracture Tests

This paper presents the results of an experimental program aimed at the assessment of the freeze–thaw (F–T) resistance of concrete based on the evaluation of fracture tests accompanied by acoustic emission measurements. Two concretes of similar mechanical characteristics were manufactured for the experiment. The main difference between the C1 and C2 concrete was in the total number of air voids and in the A300 parameter, where both parameters were higher for C1 by about 35% and 52%, respectively. The evaluation of the fracture characteristics was performed on the basis of experimentally recorded load–deflection and load–crack mouth opening displacement diagrams using two different approaches: linear fracture mechanics completed with the effective crack model and the double-K model. The results show that both approaches gave similar results, especially if the nonlinear behavior before the peak load was considered. According to the results, it can be stated that continuous AE measurement is beneficial for the assessment of the extent of concrete deterioration, and it suitably supplements the fracture test evaluation. A comparison of the results of fracture tests with the resonance method and splitting tensile strength test shows that all testing methods led to the same conclusion, i.e., the C1 concrete was more F–T-resistant than C2. However, the fracture test evaluation provided more detailed information about the internal structure deterioration due to the F–T exposure.     

The Influence of Freeze–Thaw Cycles and Corrosion on Reinforced Concrete and the Relationship between the Evolutions of the Microstructure and Mechanical Properties

Freeze–thaw cycles (FTCs) and steel bar corrosion (SBC) are the most common service conditions of hydraulic concrete and have significant impacts on its durability. Using pullout and microscopic tests of different FTC and SBC rates, we selected the mass loss rate, ultrasonic velocity, bond strength and bond slip in order to describe the changes in the macro-properties, and also selected the porosity and pore size distribution as micro-parameters in order to explore the influence of FTCs and SBC on the mechanical properties of hydraulic concrete. The results showed that the bond strength decreased as the FTCs increased due to the microstructure damage caused by FTC and SBC, which affects the mechanical properties. A corrosion rate of ≤3% offset the damage caused by 50 FTCs. FTCs and SBC resulted in superimposed damage effects on the concrete. In addition, we established a bond strength damage model based on the joint FTCs and SBC and quantitatively described the degradation law of the macro-mechanical properties. The analysis shows that the influence of FTCs on the bond strength was greater than that of the SBC. These research results can provide a reference and experimental support for the frost-resistant design and durability prediction of hydraulic concrete structures in cold environments.     

Influence Factors and Prediction Model of Bond Strength of Tunnel Fireproof Coating under Freeze–Thaw Cycles

The freeze–thaw resistant performance of a tunnel fireproof coating (TFC) has an important impact on bonding property and durability. The influence of redispersible emulsion powder, polypropylene fiber and air-entraining agent on TFCs was studied. Transverse fundamental frequency and ultrasonic sound velocity were used to evaluate the damage degree of TFC, and the mechanism was revealed by SEM and pore structure. The results show that the most beneficial effect on bond strength of TFC is redispersible emulsion powder, followed by air-entraining agent, and then polypropylene fiber. After freeze–thaw cycles, the cumulative pore volume of micropores in the TFC increases obviously, while the porosity of macropores does not change significantly. A prediction model was proposed, which can calculate the bond strength from the damage degree of TFC under freeze–thaw cycles. The achievement can promote the application of TFC in cold regions.     

Effect of Biochar on Metal Distribution and Microbiome Dynamic of a Phytostabilized Metalloid-Contaminated Soil Following Freeze–Thaw Cycles

In the present paper the effectiveness of biochar-aided phytostabilization of metal/metalloid-contaminated soil under freezing–thawing conditions and using the metal tolerating test plant Lolium perenne L. is comprehensively studied. The vegetative experiment consisted of plants cultivated for over 52 days with no exposure to freezing–thawing in a glass greenhouse, followed by 64 days under freezing–thawing in a temperature-controlled apparatus and was carried out in initial soil derived from a post-industrial urban area, characterized by the higher total content of Zn, Pb, Cu, Cr, As and Hg than the limit values included in the classification provided by the Regulation of the Polish Ministry of Environment. According to the substance priority list published by the Toxic Substances and Disease Registry Agency, As, Pb, and Hg are also indicated as being among the top three most hazardous substances. The initial soil was modified by biochar obtained from willow chips. The freeze–thaw effect on the total content of metals/metalloids (metal(-loid)s) in plant materials (roots and above-ground parts) and in phytostabilized soils (non- and biochar-amended) as well as on metal(-loid) concentration distribution/redistribution between four BCR (community bureau of reference) fractions extracted from phytostabilized soils was determined. Based on metal(-loid)s redistribution in phytostabilized soils, their stability was evaluated using the reduced partition index (Ir). Special attention was paid to investigating soil microbial composition. In both cases, before and after freezing–thawing, biochar increased plant biomass, soil pH value, and metal(-loid)s accumulation in roots, and decreased metal(-loid)s accumulation in stems and total content in the soil, respectively, as compared to the corresponding non-amended series (before and after freezing–thawing, respectively). In particular, in the phytostabilized biochar-amended series after freezing–thawing, the recorded total content of Zn, Cu, Pb, and As in roots substantially increased as well as the Hg, Cu, Cr, and Zn in the soil was significantly reduced as compared to the corresponding non-amended series after freezing–thawing. Moreover, exposure to freezing–thawing itself caused redistribution of examined metal(-loid)s from mobile and/or potentially mobile into the most stable fraction, but this transformation was favored by biochar presence, especially for Cu, Pb, Cr, and Hg. While freezing–thawing greatly affected soil microbiome composition, biochar reduced the freeze–thaw adverse effect on bacterial diversity and helped preserve bacterial groups important for efficient soil nutrient conversion. In biochar-amended soil exposed to freezing–thawing, psychrotolerant and trace element-resistant genera such as Rhodococcus sp. or Williamsia sp. were most abundant.     

Damage Fracture Characterization of Asphalt Mixtures Considering Freeze–Thaw Cycling and Aging Effects Based on Acoustic Emission Monitoring

Freeze–thaw (F–T) cycling and aging effects are the main factors contributing to the deterioration of asphalt mixtures. The acoustic emission (AE) technique enables real-time detection regarding the evolution of internal damage in asphalt mixtures during the loading process. This study set out to investigate the effects of F–T cycling and aging on the damage characteristics of asphalt mixture under splitting loads. Firstly, the Marshall specimens were prepared and then exposed to various numbers of F–T cycles (one, three, five, and seven) and different durations of aging (short-term aging and long-term aging for 24, 72, 120 and 168 h), after which the specimens were loaded by means of indirect tensile (IDT) testing, and corresponding parameters were synchronously collected by the AE acquisition system during the fracture process. Finally, the energy, cumulative energy and peak frequency were selected to investigate the damage mechanisms of asphalt mixtures. The findings demonstrate that the AE parameters provided effective identification of the deterioration for all specimens in real-time, and that the F–T cycling and aging effects altered the damage characteristics of asphalt mixtures, causing early damage, exacerbating the formation of micro-cracks in the early stage, accelerating the expansion of macro-cracks and advancing the debonding between the asphalt and aggregates. The findings of this study provide further insight into the mechanism of F–T cycling and aging effects on the deterioration of asphalt mixture.     

Effects of Fiber and Surface Treatment on Airport Pavement Concrete against Freeze–Thawing and Salt Freezing

Airport pavement concrete often suffers from freeze–thawing damage in high latitude and cold areas. In addition, the use of aircraft deicer makes the airport pavement concrete suffer from salt-freezing damage. To improve the durability of airport pavement concrete, modified polyester synthetic fiber (FC), cellulose fiber (CF), and basalt fiber (BF) reinforced concrete were prepared in this paper. The mechanical strength, pore structure, and frost resistance (freeze–thawing and salt freezing) of fiber-reinforced concrete were investigated. The effects of the combined action of fiber (fiber type and content) and surface treatment methods (spraying silane and impregnating silane) on the frost resistance of concrete were investigated. The results show that the flexural strength of concrete is positively correlated with the elastic modulus of fiber, but has little effect on the compressive strength. Fiber can reduce mass loss and dynamic modulus loss of concrete subjected to frost damage. FC more effectively improved the frost resistance of concrete than CF. After 30 cycles of salt freezing, the spalling amount of concrete sprayed or soaked with silane was decreased by 65.5% and 55.5%, respectively. Adding fiber and impregnating silane reduced the spalled concrete by up to 70.5%. Spraying silane treatment is better than impregnating silane treatment in enhancing the frost resistance of concrete because a better silane condensation reaction is achieved with spraying silane.     

Frost Resistance and Pore Structure of Concrete Incorporated with Rubber Aggregates and Nano-SiO2

This paper aims to develop frost-resistant concretes, and investigate their pore structures and freeze–thaw damage mechanism. The frost-resistant concrete mixtures are designed by using rubber particles and nano-SiO₂ to partially replace sands. The chord lengths, specific surface areas, contents and spacing coefficients of the pores in the designed concretes are measured and analyzed. The results show that concrete mixture incorporated with 5% silanized rubber and 3% nanosilica shows good synergetic effect by considering both mass loss and relative dynamic modulus of elasticity (RDME). The freeze–thaw damage degree of the concrete could be reduced by adding high elastic rubber particles, due to filling and constraining pores, and resulting in better uniform pore distribution and smaller pore spacing coefficient. Furthermore, the correlations between frost resistance and pore are analyzed and proposed.     

Effect of Manufactured Sand with Different Quality on Chloride Penetration Resistance of High–Strength Recycled Concrete

High–strength manufactured sand recycled aggregate concrete (MSRAC) prepared with manufactured sand (MS) and recycled coarse aggregate (RCA) is an effective way to reduce the consumption of natural aggregate resources and environmental impact of concrete industry. In this study, high–, medium– and low–quality MS, which were commercial MS local to Changzhou and 100% by volume of recycled coarse aggregate, were used to prepare MSRAC. The quality of MS was determined based on stone powder content, methylene blue value (MBV), crushing value and soundness as quality characteristic parameters. The variation laws of compressive strength and chloride penetration resistance of high–strength MSRAC with different rates of replacement and different qualities of MS were explored. The results showed that for medium– and low–quality MS, the compressive strength of the MSRAC increased first and then decreased with increasing rate of replacement. Conversely, for high–quality MS, the compressive strength gradually increased with increasing rate of replacement. The chloride diffusion coefficient of MSRAC increased with decreasing MS quality and increasing rate of replacement. The chloride diffusion coefficient of MSRAC basically met the specifications for 50–year and 100–year design working life when the chloride environmental action was D and E. To prepare high–strength MSRAC, high–quality MS can 100% replace RS (river sand), while rates of replacement of 50–75% for medium–quality MS or 25–50% for low–quality MS are proposed. Scanning Electron Microscope (SEM) images indicated that an appropriate amount of stone powder is able to improve the compressive strength of RAC, but excessive stone powder content and MBV are unfavorable to the compressive strength and chloride penetration resistance of RAC.