Clean Electrochemical Synthesis of Pd–Pt Bimetallic Dendrites with High Electrocatalytic Performance for the Oxidation of Formic Acid

Pd–Pt bimetallic catalysts with a dendritic morphology were in situ synthesized on the surface of a carbon paper via the facile and surfactant-free two step electrochemical method. The effects of the frequency and modification time of the periodic square-wave potential (PSWP) on the morphology of the Pd–Pt bimetallic catalysts were investigated. The obtained Pd–Pt bimetallic catalysts with a dendritic morphology displayed an enhanced catalytic activity of 0.77 A mg⁻¹, almost 2.5 times that of the commercial Pd/C catalyst reported in the literature (0.31 A mg⁻¹) in acidic media. The enhanced catalytic activity of the Pd–Pt bimetallic catalysts with a dendritic morphology towards formic acid oxidation reaction (FAOR) was not only attributed to the large number of atomic defects at the edges of dendrites, but also ascribed to the high utilization of active sites resulting from the “clean” electrochemical preparation method. Besides, during chronoamperometric testing, the current density of the dendritic Pd–Pt bimetallic catalysts for a period of 3000 s was 0.08 A mg⁻¹, even four times that of the commercial Pd/C catalyst reported in the literature (about 0.02 A mg⁻¹).     

Investigation of the Process Conditions for Hydrogen Production by Steam Reforming of Glycerol over Ni/Al2O3 Catalyst Using Response Surface Methodology (RSM)

In this work; a response surface methodology (RSM) was implemented to investigate the process variables in a hydrogen production system. The effects of five independent variables; namely the temperature (X₁); the flow rate (X₂); the catalyst weight (X₃); the catalyst loading (X₄) and the glycerol-water molar ratio (X₅) on the H₂ yield (Y₁) and the conversion of glycerol to gaseous products (Y₂) were explored. Using multiple regression analysis; the experimental results of the H₂ yield and the glycerol conversion to gases were fit to quadratic polynomial models. The proposed mathematical models have correlated the dependent factors well within the limits that were being examined. The best values of the process variables were a temperature of approximately 600 °C; a feed flow rate of 0.05 mL/min; a catalyst weight of 0.2 g; a catalyst loading of 20% and a glycerol-water molar ratio of approximately 12; where the H₂ yield was predicted to be 57.6% and the conversion of glycerol was predicted to be 75%. To validate the proposed models; statistical analysis using a two-sample t-test was performed; and the results showed that the models could predict the responses satisfactorily within the limits of the variables that were studied.