Osteoblast-like Cell Proliferation,ALP Activity and Photocatalytic Activity on Sintered Anatase and Rutile Titanium Dioxide

This study aimed to create a biomaterial from titanium dioxide (TiO₂), which has been known to have photocatalytic and bone formation promoting effects. I expected that anatase titanium dioxide-based implants could promote bone augmentation and induce bone formation. Powdery anatase TiO₂ was compression molded and sintered at 700, 800, 900, and 1000 °C to prepare sintered compact samples. X-ray diffraction and scanning electron microscopy were used to observe the surface of these samples. Furthermore, mouse osteoblast-like cells (MC3T3-E1 cell line) were seeded on the samples sintered at different temperatures, and cell proliferation was observed to evaluate the cell proliferation of the samples. The sample sintered at 700 °C was composed of anatase TiO₂. The samples sintered at 800 °C and 900 °C were confirmed to consist of a mixture of anatase and rutile TiO₂ crystalline phases. Moreover, the sample sintered at 700 and 800 °C, which contained anatase TiO₂, showed remarkable photocatalytic activity. Those samples sintered at 1000 °C were transformed to the rutile TiO₂. The cell proliferation after 7–14-days culturing revealed that cells cultured on the 700 °C sample decreased in number immediately after initiation of culturing. The cells cultured on TiO₂ sintered at 900 °C markedly proliferated over time with an increase in the alkaline phosphatase activity, showing good MC3T3-E1 cell compatibility of the samples. The sample sintered at 1000 °C, which is rutile TiO₂, showed the highest increase.     

Photocatalytic Performance Evaluation of Titanium Dioxide Nanotube-Reinforced Cement Paste

Considering the increase in research regarding environmental pollution reduction, the utilization of cementitious material, a commonly used construction material, in photocatalysts has become a desirable research field for the widespread application of photocatalytic degradation technology. Nano-reinforcement technology for cementitious materials has been extensively researched and developed. In this work, as a new and promising reinforcing agent for cementitious materials, the photocatalytic performance of titanium dioxide nanotube (TNT) was investigated. The degradation of methylene blue was used to evaluate the photocatalytic performance of the TNT-reinforced cement paste. In addition, cement paste containing micro-TiO₂ (m-TiO₂) and nano-TiO₂ (n-TiO₂) particles were used for comparison. Moreover, the effect of these TiO₂-based photocatalytic materials on the cement hydration products was monitored via X-ray diffraction (XRD) and thermogravimetric analysis (TG). The results indicated that all the TiO₂ based materials promoted the formation of hydration products. After 28 days of curing, the TNT-reinforced cement paste contained the maximum amount of hydration products (Ca(OH)₂). Furthermore, the cement paste containing TNT exhibited better photocatalytic effects than that containing n-TiO₂, but worse than that containing m-TiO₂.     

Prospects of Synthesized Magnetic TiO2-Based Membranes for Wastewater Treatment: A Review

Global accessibility to clean water has stressed the need to develop advanced technologies for the removal of toxic organic and inorganic pollutants and pathogens from wastewater to meet stringent discharge water quality limits. Conventionally, the high separation efficiencies, relative low costs, small footprint, and ease of operation associated with integrated photocatalytic-membrane (IPM) technologies are gaining an all-inclusive attention. Conversely, photocatalysis and membrane technologies face some degree of setbacks, which limit their worldwide application in wastewater settings for the treatment of emerging contaminants. Therefore, this review elucidated titanium dioxide (TiO₂), based on its unique properties (low cost, non-toxicity, biocompatibility, and high chemical stability), to have great potential in engineering photocatalytic-based membranes for reclamation of wastewater for re-use. The environmental pathway of TiO₂ nanoparticles, membranes and configuration types, modification process, characteristics, and applications of IPMs in water settings are discussed. Future research and prospects of magnetized TiO₂-based membrane technology is highlighted as a viable water purification technology to mitigate fouling in the membrane process and photocatalyst recoverability. In addition, exploring life cycle assessment research would also aid in utilizing the concept and pressing for large-scale application of this technology.     

Pilot-Scale Studies of WO3/S-Doped g-C3N4 Heterojunction toward Photocatalytic NOx Removal

Due to the rising concentration of toxic nitrogen oxides (NO_x) in the air, effective methods of NO_x removal have been extensively studied recently. In the present study, the first developed WO₃/S-doped g-C₃N₄ nanocomposite was synthesized using a facile method to remove NOx in air efficiently. The photocatalytic tests performed in a newly designed continuous-flow photoreactor with an LED array and online monitored NO₂ and NO system allowed the investigation of photocatalyst layers at the pilot scale. The WO₃/S-doped-g-C₃N₄ nanocomposite, as well as single components, were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer–Emmett–Teller surface area analysis (BET), X-ray fluorescence spectroscopy (XRF), X-ray photoemission spectroscopy method (XPS), UV–vis diffuse reflectance spectroscopy (DR/UV–vis), and photoluminescence spectroscopy with charge carriers’ lifetime measurements. All materials exhibited high efficiency in photocatalytic NO₂ conversion, and 100% was reached in less than 5 min of illumination under simulated solar light. The effect of process parameters in the experimental setup together with WO₃/S-doped g-C₃N₄ photocatalysts was studied in detail. Finally, the stability of the composite was tested in five subsequent cycles of photocatalytic degradation. The WO₃/S-doped g-C₃N₄ was stable in time and did not undergo deactivation due to the blocking of active sites on the photocatalyst’s surface.     

Synthesis of Selected Mixed Oxide Materials with Tailored Photocatalytic Activity in the Degradation of Tetracycline

The elimination of antibiotics occurring in the natural environment has become a great challenge in recent years. Among other techniques, the photocatalytic degradation of this type of pollutant seems to be a promising approach. Thus, the search for new photoactive materials is currently of great importance. The present study concerns the sol–gel synthesis of mono, binary and ternary TiO₂-based materials, which are used as active photocatalysts. The main goal was to evaluate how the addition of selected components—zirconium dioxide (ZrO₂) and/or zinc oxide (ZnO)—during the synthesis of TiO₂-based materials and the temperature of thermal treatment affect the materials’ physicochemical and photocatalytic properties. The fabricated mixed oxide materials underwent detailed physicochemical analysis, utilizing scanning-electron microscopy (SEM), X-ray diffraction (XRD), diffuse reflectance spectroscopy (DRS), energy-dispersive X-ray spectroscopy (EDS), low-temperature N₂ sorption (BET model), X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR). The synthesized mixed oxide materials were used as photocatalysts in the heterogeneous photodegradation of tetracycline (TC). The physicochemical properties of the fabricated photocatalysts, including morphology, crystalline and textural structure, as well as the pH of the reaction system in the photocatalytic tests, were taken into account in determining their photo-oxidation activity. LC–MS/MS analysis was used to identify the possible degradation products of the selected antibiotic.     

Improved Methane Production by Photocatalytic CO2 Conversion over Ag/In2O3/TiO2 Heterojunctions

In this work, the role of In₂O₃ in a heterojunction with TiO₂ is studied as a way of increasing the photocatalytic activity for gas-phase CO₂ reduction using water as the electron donor and UV irradiation. Depending on the nature of the employed In₂O₃, different behaviors appear. Thus, with the high crystallite sizes of commercial In₂O₃, the activity is improved with respect to TiO₂, with modest improvements in the selectivity to methane. On the other hand, when In₂O₃ obtained in the laboratory, with low crystallite size, is employed, there is a further change in selectivity toward CH₄, even if the total conversion is lower than that obtained with TiO₂. The selectivity improvement in the heterojunctions is attributed to an enhancement in the charge transfer and separation with the presence of In₂O₃, more pronounced when smaller particles are used as in the case of laboratory-made In₂O₃, as confirmed by time-resolved fluorescence measurements. Ternary systems formed by these heterojunctions with silver nanoparticles reflect a drastic change in selectivity toward methane, confirming the role of silver as an electron collector that favors the charge transfer to the reaction medium.     

Decomposition Characteristics of the TTIP (Tetraisopropyl Orthotitanate) Precursor for Atomic Layer Deposition

The decomposition of tetraisopropyl orthotitanate (TTIP), a representative precursor used in the atomic layer deposition (ALD) of titanium dioxide (TiO₂) film, and the resulting changes in the thin film properties of the TiO₂ film were investigated. TTIP was evaluated after exposure to thermal stress in an enclosed container. The vapor pressure results provide reasonable evidence that impurities are generated by the decomposition of TTIP under thermal stress. These impurities led to changes in the thermal properties of TTIP and changes in the growth rate, morphology, and composition of the thin film; in particular, these impurities increased the unstable oxidation states of Ti²⁺ (TiO) content in the TiO₂ film. The changes in the properties of the TiO₂ film resulting from the changes in the physical properties of TTIP led to a change in the properties of the device. We proved that the thermal stability of the precursor is a factor that can determine the reliability of the ALD process and the resulting thin film. Additionally, systematic evaluation of the precursor can provide useful information that can improve the development of the precursor and the consistency of the process.     

Performance of Nanocomposites of a Phase Change Material Formed by the Dispersion of MWCNT/TiO2 for Thermal Energy Storage Applications

Thermal energy storage technology is an important topic, as it enables renewable energy technology to be available 24/7 and under different weather conditions. Phase changing materials (PCM) are key players in thermal energy storage, being the most economic among those available with adjustable thermal properties. Paraffin wax (PW) is one of the best materials used in industrial processes to enhance thermal storage. However, the low thermal conductivity of PW prevents its thermal application. In this study, we successfully modified PW based on multi-walled carbon nanotubes (MWCNT) with different concentrations of TiO₂—3, 5 and 7 wt.%. The morphology of PCM and its relationship with the chemical structure and stability were characterized using scanning electron microscopy (SEM), Fourier transform infrared (FTIR) and Thermogravimetric analysis (TGA). As a result, the composites achieved a highest latent heat enthalpy of 176 J/g, in addition to enhanced thermal stability after 15 thermal cycles, and reliability, with a slight change in latent heat observed when using a differential scanning calorimeter (DSC). The thermal conductivity of the composites could significantly be enhanced by 100%. Compared to pure paraffin, the PCM composites developed in this study exhibited an excellent preference for thermal energy storage and possessed low cost, high reliability, and phase change properties.     

Irradiance-Controlled Photoassisted Synthesis of Sub-Nanometre Sized Ruthenium Nanoparticles as Co-Catalyst for TiO2 in Photocatalytic Reactions

Photoassisted synthesis is as a highly appealing green procedure for controlled decoration of semiconductor catalysts with co-catalyst nanoparticles, which can be carried out without the concourse of elevated temperatures, external chemical reducing agents or applied bias potential and in a simple slurry reactor. The aim of this study is to evaluate the control that such a photoassisted method can exert on the properties of ruthenium nanoparticles supported on TiO₂ by means of the variation of the incident irradiance and hence of the photodeposition rate. For that purpose, different Ru/TiO₂ systems with the same metal load have been prepared under varying irradiance and characterized by means of elemental analysis, transmission electron microscopy and X-ray photoelectron spectroscopy. The photocatalytic activity of the so-obtained materials has been evaluated by using the degradation of formic acid in water under UV-A light. Particles with size around or below one nanometer were obtained, depending on the irradiance employed in the synthesis, with narrow size distribution and homogeneous dispersion over the titania support. The relation between neutral and positive oxidation states of ruthenium could also be controlled by the variation of the irradiance. The obtained photocatalytic activities for formic acid oxidation were in all cases higher than that of undecorated titania, with the sample obtained with the lowest irradiation giving rise to the highest oxidation rate. According to the catalysts characterization, photocatalytic activity is influenced by both Ru size and Ru⁰/Ru^δ+ ratio.     

Enhanced Photocatalytic Degradation of Methyl Orange Dye under the Daylight Irradiation over CN-TiO2 Modified with OMS-2

In this study, CN-TiO₂ was modified with cryptomelane octahedral molecular sieves (OMS-2) by the sol-gel method based on the self-assembly technique to enhance its photocatalytic activity under the daylight irradiation. The synthesized samples were characterized by X-ray diffraction (XRD), UV-vis spectroscopy, Fourier transform infrared spectroscopy (FT-IR) and porosimeter analysis. The results showed that the addition of OMS-2 in the sol lead to higher Brunauer-Emmett-Teller (BET) surface area, pore volume, porosity of particle after heat treatment and the specific surface area, porosity, crystallite size and pore size distribution could be controlled by adjusting the calcination temperature. Compared to the CN-TiO₂-400 sample, CN-TiO₂/OMS-2-400 exhibited greater red shift in absorption edge of samples in visible region due to the OMS-2 coated. The enhancement of photocatalytic activity of CN-TiO₂/OMS-2 composite photocatalyst was subsequently evaluated for the degradation of the methyl orange dye under the daylight irradiation in water. The results showed that the methyl orange dye degradation rate reach to 37.8% for the CN-TiO₂/OMS-2-400 sample under the daylight irradiation for 5 h, which was higher than that of reference sample. The enhancement in daylight photocatalytic activities of the CN-TiO₂/OMS samples could be attributed to the synergistic effects of OMS-2 coated, larger surface area and red shift in adsorption edge of the prepared sample.     

Photocatalytic Reduction of Carbon Dioxide on TiO2 Heterojunction Photocatalysts—A Review

The photocatalytic reduction of carbon dioxide to renewable fuel or other valuable chemicals using solar energy is attracting the interest of researchers because of its great potential to offer a clean fuel alternative and solve global warming problems. Unfortunately, the efficiency of CO₂ photocatalytic reduction remains not very high due to the fast recombination of photogenerated electron–hole and small light utilization. Consequently, tremendous efforts have been made to solve these problems, and one possible solution is the use of heterojunction photocatalysts. This review begins with the fundamental aspects of CO₂ photocatalytic reduction and the fundamental principles of various heterojunction photocatalysts. In the following part, we discuss using TiO₂ heterojunction photocatalysts with other semiconductors, such as C₃N₄, CeO₂, CuO, CdS, MoS₂, GaP, CaTiO₃ and FeTiO₃. Finally, a concise summary and presentation of perspectives in the field of heterojunction photocatalysts are provided. The review covers references in the years 2011–2021.     

Supercritical Phase Inversion to Produce Photocatalytic Active PVDF-coHFP_TiO2 Composites for the Degradation of Sudan Blue II Dye

TiO₂-loaded poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-coHFP) membranes were produced by supercritical CO₂-assisted phase inversion. Three different TiO₂ loadings were tested: 10, 20, and 30 wt% with respect to the polymer. Increasing the TiO₂ amount from 10 wt% to 20 wt% in the starting solution, the transition from leafy-like to leafy-cellular morphology was observed in the section of the membrane. When 30 wt% TiO₂ was used, the entire membrane section showed agglomerates of TiO₂ nanoparticles. These polymeric membranes were tested to remove Sudan Blue II (SB) dye from aqueous solutions. The adsorption/photocatalytic processes revealed that membrane morphology and TiO₂ cluster size were the parameters that mainly affected the dye removal efficiency. Moreover, after five cycles of exposure of these membranes to UV light, SB removal was higher than 85%.     

Analysis for DC and RF Characteristics Recessed-Gate GaN MOSFET Using Stacked TiO2/Si3N4 Dual-Layer Insulator

The self-heating effects (SHEs) on the electrical characteristics of the GaN MOSFETs with a stacked TiO₂/Si₃N₄ dual-layer insulator are investigated by using rigorous TCAD simulations. To accurately analyze them, the GaN MOSFETs with Si₃N₄ single-layer insulator are conducted to the simulation works together. The stacked TiO₂/Si₃N₄ GaN MOSFET has a maximum on-state current of 743.8 mA/mm, which is the improved value due to the larger oxide capacitance of TiO₂/Si₃N₄ than that of a Si₃N₄ single-layer insulator. However, the electrical field and current density increased by the stacked TiO₂/Si₃N₄ layers make the device’s temperature higher. That results in the degradation of the device’s performance. We simulated and analyzed the operation mechanisms of the GaN MOSFETs modulated by the SHEs in view of high-power and high-frequency characteristics. The maximum temperature inside the device was increased to 409.89 K by the SHEs. In this case, the stacked TiO₂/Si₃N₄-based GaN MOSFETs had 25%-lower values for both the maximum on-state current and the maximum transconductance compared with the device where SHEs did not occur; R_on increased from 1.41 mΩ·cm² to 2.56 mΩ·cm², and the cut-off frequency was reduced by 26% from 5.45 GHz. Although the performance of the stacked TiO₂/Si₃N₄-based GaN MOSFET is degraded by SHEs, it shows superior electrical performance than GaN MOSFETs with Si₃N₄ single-layer insulator.     

Eu-Doped Zeolitic Imidazolate Framework-8 Modified Mixed-Crystal TiO2 for Efficient Removal of Basic Fuchsin from Effluent

Zeolitic imidazolate framework-8 (ZIF-8) was doped with a rare-earth metal, Eu, using a solvent synthesis method evenly on the surface of a mixed-crystal TiO₂(Mc-TiO₂) structure in order to produce a core–shell structure composite ZIF-8(Eu)@Mc-TiO₂ adsorption photocatalyst with good adsorption and photocatalytic properties. The characterisation of ZIF-8(Eu)@Mc-TiO₂ was performed via X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), Brunauer–Emmett–Teller analysis (BET) and ultraviolet–visible light differential reflectance spectroscopy (UV-DRs). The results indicated that Eu-doped ZIF-8 was formed evenly on the Mc-TiO₂ surface, a core–shell structure formed and the light-response range was enhanced greatly. The ZIF-8(Eu)@Mc-TiO₂ for basic fuchsin was investigated to validate its photocatalytic performance. The effect of the Eu doping amount, basic fuchsin concentration and photocatalyst dosage on the photocatalytic efficiency were investigated. The results revealed that, when 5%-Eu-doped ZIF-8(Eu)@Mc-TiO₂ (20 mg) was combined with 30 mg/L basic fuchsin (100 mL) under UV irradiation for 1 h, the photocatalytic efficiency could reach 99%. Further, it exhibited a good recycling performance. Thus, it shows certain advantages in its degradation rate and repeatability compared with previously reported materials. All of these factors suggested that, in an aqueous medium, ZIF-8(Eu)@Mc-TiO₂ is an eco-friendly, sustainable and efficient material for the photocatalytic degradation of basic fuchsin.     

The Preparation of {001}TiO2/TiOF2 via a One-Step Hydrothermal Method and Its Degradation Mechanism of Ammonia Nitrogen

{001}TiO₂/TiOF₂ photocatalytic composites with a high activity {001} crystal plane were prepared by one-step hydrothermal methods using butyl titanate as a titanium source and hydrofluoric acid as a fluorine source. X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), raman spectroscopy, N₂ adsorption-desorption curve (BET), UV-Vis diffuse absorption spectroscopy (UV-Vis DRS), X-ray photoelectron spectroscopy (XPS), and fluorescence spectroscopy (PL) were used to evaluate the structure, morphology, specific surface area, optical properties, and photocarrier separation ability of {001}TiO₂/TiOF₂. Ammonia nitrogen was taken as the target pollutant, and the degradation performance of the catalyst was investigated. The results show that hydrofluoric acid improves the content of {001} crystal plane of TiO₂ with high activity; it also improves the specific surface area and dispersion of the composite material and adjusts the ratio of {001}TiO₂ to TiOF₂ in the composite material to enhance the absorption capacity of the composite material and reduce the band gap width of the composite material. The degradation rate of ammonia nitrogen by 100 mg F15 is 93.19% when the initial concentration of ammonia nitrogen is 100 mg/L and pH is 10. Throughout the reaction process, the {001}TiO₂/TiOF₂ composite produces superoxide anion radical (·O₂⁻) and hydroxyl radical (·OH) to oxidize NH₃·H₂O and generate N₂ accompanied by a small amount of NO₃⁻ and NO₂⁻.     

Influence of TiO2 Nanoparticles on the Resistance of Cementitious Composite Materials to the Action of Fungal Species

The development of mold films on the cement surfaces of buildings is a health and safety problem for the population, aesthetic but also in terms of their durability. The use of specific performance of cementitious composites containing TiO₂ nanoparticles, photoactivated by UV radiation, can be a viable solution to mitigate to eliminate these problems. The experimental studies presented aim to analyze the capacity to inhibit the development of mold type Aspergillus and Penicillium on the surface of composite materials with nano-TiO₂ content and the identification of the optimal range of nanomaterial addition. The identification and analysis of the inhibition halo (zone with a biological load of maximum 1–10 colonies of microorganisms) confirmed the biocidal capacity of the cementitious composites, but also indicated the possibility that an excess of TiO₂ nanoparticles in the mixture could induce a development of cell resistance, which would be unfavorable both in terms of behavior and in terms of cost.     

Removal of Aniline and Benzothiazole Wastewaters Using an Efficient MnO2/GAC Catalyst in a Photocatalytic Fluidised Bed Reactor

This work presents an efficient method for treating industrial wastewater containing aniline and benzothiazole, which are refractory to conventional treatments. A combination of heterogeneous photocatalysis operating in a fluidised bed reactor is studied in order to increase mass transfer and reduce reaction times. This process uses a manganese dioxide catalyst supported on granular activated carbon with environmentally friendly characteristics. The manganese dioxide composite is prepared by hydrothermal synthesis on carbon Hydrodarco^® 3000 with different active phase ratios. The support, the metal oxide, and the composite are characterised by performing Brunauer, Emmett, and Teller analysis, transmission electron microscopy, X-ray diffraction analysis, X-ray fluorescence analysis, UV–Vis spectroscopy by diffuse reflectance, and Fourier transform infrared spectroscopy in order to evaluate the influence of the metal oxide on the activated carbon. A composite of MnO₂/GAC (3.78% in phase α-MnO₂) is obtained, with a 9.4% increase in the specific surface of the initial GAC and a 12.79 nm crystal size. The effect of pH and catalyst load is studied. At a pH of 9.0 and a dose of 0.9 g L⁻¹, a high degradation of aniline and benzothiazole is obtained, with an 81.63% TOC mineralisation in 64.8 min.     

Efficient Adsorption-Assisted Photocatalysis Degradation of Congo Red through Loading ZIF-8 on KI-Doped TiO2

Zeolitic imidazolate framework-8 (ZIF-8) was evenly loaded on the surface of TiO₂ doped with KI, using a solvent synthesis method, in order to produce a ZIF-8@TiO₂ (KI) adsorption photocatalyst with good adsorption and photocatalytic properties. The samples were characterized by XRD, SEM, EDX, XPS, BET and UV-Vis. The photocatalytic efficiency of the material was obtained by photocatalytic tests. The results indicate that the doping with I inhibited the grain growth and reduced the crystallite size of TiO₂, reduced the band gap width and improved the utilization rate for light. TiO₂ (KI) was a single crystal of anatase titanium dioxide. The combination of ZIF-8 and TiO₂ (KI) improved the specific surface area and increased the reaction site. The ZIF-8@TiO₂ (KI) for Congo red was investigated to validate its photocatalytic performance. The optimal concentration of Congo red solution was 30 mg/L, and the amount of catalyst was proportional to the degradation efficiency. The degradation efficiency of ZIF-8@TiO₂ (5%KI) was 76.42%, after being recycled four times.     

Study on Photocatalytic Performance of Ag/TiO2 Modified Cement Mortar

In this paper, Ag-TiO₂ photocatalysts with different Ag contents (1 mol%–5 mol%) were prepared and applied to cement mortar. The photocatalytic performance of Ag-TiO₂ and photocatalytic cement mortar under UV light and simulated solar light was evaluated. The results showed that Ag loading on the surface of TiO₂ could reduce its band gap width and increase its absorbance in the visible region, and 2% Ag-TiO₂ had the highest photocatalytic activity under UV light, the degradation rate of methyl orange (MO) was 95.5% at 30 min, and the first-order reaction constant k was 0.0980 min⁻¹, which was 61.7% higher than that of TiO₂, and 5% Ag-TiO₂ had the highest photocatalytic activity under solar light, the degradation rate of methylene blue (MB) was 69.8% at 40 min, and the first-order reaction constant k was 0.0294 min⁻¹, which was 90.9% higher than that of TiO₂. The photocatalytic mortar prepared by the spraying method has high photocatalytic performance, The MO degradation rate of sample S2 under UV light was 87.5% after 120 min, MB degradation rate of sample S5 under solar light was 75.4% after 120 min. The photocatalytic reaction conforms to the zero-order reaction kinetics, which was 1.5 times–3.3 times higher than that of the mixed samples and has no effect on the mechanical properties of mortar.