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1.
Tooth decay is a prevalent disease that initiates when the oral pH becomes acidic. Fluoride and/or bioactive glass (NovaMin) were used to regenerate/repair teeth that had been decalcified. In this present study, we investigated the effect of fluoride and/or bioactive glass (NovaMin) on remineralization of hydroxyapatite (HA) discs, which mimic the enamel surface of natural teeth. HA discs were etched with phosphoric acid and treated with one of the following toothpastes: (1) Sensodyne toothpaste with fluoride; (2) Sensodyne toothpaste with fluoride and bioactive glass (NovaMin); (3) Tom’s toothpaste without fluoride or bioactive glass (NovaMin); and (4) Tom’s toothpaste with bioactive glass (NovaMin). The toothpastes were applied on the etched discs for two minutes, once a day for 15 days. Scanning electron microscopy (SEM) was used to analyze surface morphologies and X-ray photoelectron spectroscopy (XPS) was used to analyze surface compositions. Tom’s toothpaste with only NovaMin demonstrated the most remineralization potential compared with the other groups. In conclusion, incorporating bioactive glass (NovaMin) into toothpastes could benefit the repair and remineralization of teeth.  相似文献   

2.
Abrasive blasting is a process widely used in dentistry. One of the uses is the development of metal surfaces for connections with ceramics in fixed prosthetic restorations. The purpose of this paper was to check how the rough surface profile (width, height, and depth on unevenness) impacts the surface’s condition, like its wettability and percentage of stuck abrasives. The Ni-Cr alloy surface was abrasive blasted by silicon carbide with the various pressure parameters (0.2, 0.4, and 0.6 MPa) and abrasive particle sizes (50, 110, and 250 µm). Cleaned surfaces were examined for roughness, wettability, and percentage of stuck abrasive particles on the surface. The surface after abrasive blasting using 110 µm of abrasive size and 0.4 MPa pressure has the best wettability results. The width of unevenness may cause it. When the unevenness has too small or too large width and depth, the fluids may not cover the entire cavities because of locking the air. The surface condition of dental alloys directly affects metal–ceramic connection strength. The knowledge about the impact of the abrasive blasting parameters on the bond strength will allow one to create durable dental restorations.  相似文献   

3.
This randomized, double-blind, 12 h clinical study tested the effect of a single brushing with two Zn-containing toothpastes on volatile sulfur compound (VSC) levels in morning breath. The following toothpastes were each tested by all 28 participants: A-Zn toothpaste, B--experimental toothpaste (Zn citrate + PVM/MA copolymer) and C--control toothpaste without Zn. The evening prior to test days participants brushed their teeth for 2 min with 1 g toothpaste. 12 h later and prior to eating or performing oral hygiene, morning breath levels of VSC (H(2)S, CH(3)SH) were analysed by gas chromatography. Subjects then rinsed for 30 s with 5 ml cysteine and breath samples were analysed for H(2)S (H(2)S(cys)). Median VSC (area under the curve) values were compared for A, B and C and the effects of A and B on VSC were compared with C. Toothpaste B was more effective than both toothpastes A and C in reducing H(2)S, CH(3)SH and H(2)S(cys) (p < 0.05). Compared with toothpaste C, toothpastes A and B reduced H(2)S by 35% and 68%, respectively (p = 0.003), and CH(3)SH by 12% and 47%, respectively (p = 0.002). Toothpaste B reduced H(2)S(cys) by 48% compared with toothpaste C (p = 0.001). It is suggested that the superior effect of the experimental toothpaste was most likely due to a higher Zn concentration combined with longer retention of Zn due to the PVM/MA copolymer.  相似文献   

4.
The procedure generally used to remove bacterial biofilm adhering to the surface of titanium on dental implants is implantoplasty. This treatment is based on the machining of the titanium surface to remove bacterial plaque. In this study, we used 60 grade 4 titanium implants and performed the implantoplasty protocol. Using X-ray diffraction, we determined the stresses accumulated in each of the as-received, machined and debris implants. The resistance to corrosion in open circuit and potentiodynamically in physiological medium has been determined, and the corrosion potentials and intensities have been determined. Tests have been carried out to determine ion release by ICP-MS at different immersion times. The results show that the corrosion resistance and the release of titanium ions into the medium are related to the accumulated energy or the degree of deformation. The titanium debris exhibit compressive residual stresses of −202 MPa, the implant treated with implantoplasty −120 MPa, and as-received −77 MPa, with their corrosion behavior resulting in corrosion rates of 0.501, 0.77, and 0.444 mm/year, respectively. Debris is the material with the worst corrosion resistance and the one that releases the most titanium ions to the physiological medium (15.3 ppb after 21 days vs. 7 ppb for as-received samples). Pitting has been observed on the surface of the debris released into the physiological environment. This behavior should be taken into account by clinicians for the good long-term behavior of implants with implantoplasty.  相似文献   

5.
In this paper, we used two mass-produced industrial technologies, namely, thermal spraying and anodization methods, to enhance the surface characteristics of AISI 1045 medium carbon steel for use in special environments or products. The anodic film can effectively improve the surface properties of carbon steel. A sequence of treatments of the carbon steel substrate surface that consist of sandblasting, spraying the aluminum film, annealing, hot rolling, cleaning, grinding, and polishing can increase the quality of the anodized film. This paper proposes an anodization process for the surface of carbon steel to increase the corrosion resistance, hardness, color diversification, and electrical resistance. The resulting surface improves the hardness (from 170 HV to 524 HV), surface roughness (from 1.26 to 0.15 μm), coloring (from metal color to various colors), and corrosion resistance (from rusty to corrosion resistant). The electrochemical corrosion studies showed that the AISI 1045 steel surface with a hard anodized film had a lower corrosion current density of 105.9 A/cm2 and a higher impedance of 9000 ohm than those of naked AISI 1045 steel (10−4.2 A/cm2 and 150 ohm) in HCl gas.  相似文献   

6.
Background: In this study, we assess the effect produced on roughness and gloss of full-body bulk-fill materials by different finishing and polishing systems. Methods: Four full-body bulk-fill materials were tested: SonicFill2 (SF), Filtek Bulk Fill Posterior Restorative (FB), Tetric EvoCeram bulk-fill (EC), and Fill-Up! (FU). Sixty discs per material (2 mm in thickness and 7 mm in diameter) were obtained and randomly assigned (n = 15) to four finishing and polishing methods: Sof-Lex Spiral Wheels (SW), HiLusterPLUS (HL), Astropol (AP), and Opti1Step (OS). Surface roughness and gloss were then measured. Results: For roughness, material and surface treatment were significant factors (p < 0.001) with SF = FB = EC < FU and AP < SW < HL = OS. Material and surface treatment had a significant effect also on gloss (p < 0.001), with SF > FB = EC > FU and SW > AP > HL > OS. Conclusions: The tested combinations of bulk-fill and polishing systems provided clinically acceptable results with regard to roughness, while the outcome was poor for gloss. Multistep finishing/polishing systems were able to produce smoother surfaces on full-body bulk-fill materials compared to simplified ones.  相似文献   

7.
Changes of titanium surface roughness and surface free energy may influence protein absorption that increases cell differentiation through activation of focal adhesion kinase related pathways. However, the influence of titanium surface roughness and hydrophilicity on fibroblast behavior is not well understood. The aim of this study was to investigate the influence of topography and hydrophilicity on fibroblast attachment, spreading, morphology, intracellular signaling, proliferation, and collagen I mRNA levels. Using a cellular FAK knockout (FAK−/−) model and wild-type (WT) controls, we also investigated the contribution of adhesion in fibroblasts cultured on smooth (PT), sand-blasted, large grit, acid-etched (SLA) and hydrophilic SLA topographies. Loss of FAK did not significantly affect fibroblast attachment to any surface, but SLA and hydrophilic SLA surface attenuated spreading of WT cells significantly more than FAK−/− fibroblasts. Both FAK−/− and WT cells formed numerous focal adhesions on PT surfaces, but significantly less on SLA and hydrophilic SLA surfaces. In WT cells, phosphorylation levels of FAK were lower on SLA and hydrophilic SLA in comparison with PT 24 h post seeding. Labeling of cells with antibodies to cortactin showed that FAK−/− cells contained significantly more cortactin-rich focal adhesion in comparison with WT cells on PT surfaces, but not on SLA or hydrophilic SLA. ERK 1/2 phosphorylation was highest in WT cells on all surfaces which correlated with collagen I expression levels. We conclude that fibroblasts are sensitive to changes in surface roughness and hydrophilicity, with adhesive interactions mediated through FAK, an important modulator of fibroblast response.  相似文献   

8.
Oral dysfunction due to peri-implantitis and shortened life of implants has become a major concern. Self-care and removal of oral biofilms by professional mechanical tooth cleaning (PMTC) are indispensable for its prevention. However, if the surface roughness of the implant is increased, it may result in the adhesion of biofilm in the oral cavity. Therefore, the PMTC method can serve for long-term implant management. Calcium carbonate (CaCO3) has been used as a cleaning method for implant surfaces; however, there is concern that the implant surface roughness could increase due to particle collision. Therefore, in this study, to establish a blasting cleaning method that does not adversely affect the implant surface, a new blasting cleaning method using agar particles was devised and its practical application examined. When the simulated stains were blasted with white alumina (WA) abrasive grains and CaCO3 particles, the simulated stains were almost removed, the surface roughness changed to a satin-finished surface—which was thought to be due to fine scratches—and the surface roughness increased. Most of the simulated stains were removed on the surface of the sample blasted with glycine particles and agar particles. Conversely, the gloss of the sample surface was maintained after cleaning, and the increase in surface roughness was slight.  相似文献   

9.
Selective laser sintering (SLS) is being developed for dental applications. This study aimed to investigate the properties of Ti-6Al-4V and pure titanium specimens fabricated using the SLS process and compare them with casting specimens. Besides, the effect of the building direction on the properties of the SLS specimens was also investigated. Specimens were prepared by SLS using Ti-6Al-4V powder or pure titanium powder. Casting specimens were also prepared using Ti-6Al-4V alloys and pure titanium. The mechanical properties (tensile strength and elongation), physical properties (surface roughness, contact angle, and Vickers hardness); corrosion resistors (color difference and corrosion), and surface properties (chemical composition and surface observation) were examined. Both Ti-6Al-4V and pure titanium specimens produced using the SLS process had comparable or superior properties compared with casting specimens. In comparing the building directions, specimens fabricated horizontally to the printing platform showed the greatest tensile strength, and the surface roughness scanned in the horizontal direction to the platform showed the smallest. However, there was no significant effect on other properties. Thus, the SLS process with Ti-6Al-4V powder and pure titanium powder has great performance for the fabrication of dental prosthesis, and there is a possibility for it to take the place of conventional methods.  相似文献   

10.
The present paper focuses on the fabrication of coatings based on vinyltrimethoxysilane and the influence of various corrosion media on the coatings produced. Coatings were deposited on two substrate materials, namely, titanium Grade 2 and titanium alloy Ti13Nb13Zr, by immersion in a solution containing vinyltrimethoxysilane, anhydrous ethyl alcohol, acetic acid and distilled water. The obtained coatings were characterized in terms of surface morphology, adhesion to the substrate and corrosion resistance. As corrosion solutions, four different simulated physiological fluids, which differed in the contents of individual ions, and a 1 mol dm−3 NaBr solution were used. The chloride ions contained in the simulated physiological fluids did not lead to pitting corrosion of titanium Grade 2 and titanium alloy Ti13Nb13Zr. This investigation shows that titanium undergoes pitting corrosion in a bromide ion medium. It is demonstrated that the investigated coatings slow down corrosion processes in all corrosion media examined.  相似文献   

11.
Titanium alloys have now become the first choice of tubing material used in the harsh oil- and gas-exploitation environment, while the interaction of force and medium is a serious threat to the safety and reliability of titanium alloy in service. In this paper, different stresses were applied to TC4 titanium alloy by four-point bending stress fixture, and the corrosion behavior of TC4 titanium alloy was studied by high-temperature and high-pressure simulation experiments and electrochemical techniques, and the microscopic morphologies and chemical composition of the surface film layer on the specimen were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray energy-dispersive spectroscopy (EDS), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS), to reveal the corrosion-resistance mechanism of TC4 titanium alloy under different stress-loading conditions. The results showed that the pits appeared on the specimens loaded with elastic stress, but the degree of pitting corrosion was still lighter, and the surface film layer showed n-type semiconductor properties with cation selective permeability. While the pits on the specimens loaded with plastic stress were deeper and wider in size, and the semiconductor type of the surface film layer changed to p-type, it was easier for anions such as Cl and CO32− to adsorb on, destroy, and pass through the protective film and then to contact with the matrix, resulting in a decrease in corrosion resistance of TC4 titanium alloy.  相似文献   

12.
4145H steel is a commonly used material for downhole tools. However, up to now the wear behavior of 4145H drilling tool steel under real drilling fluid environment conditions is still not clear. In this work, this was investigated using a modified ASTM B611 rubber ring wet grinding test system, in which six kinds of abrasives (talc, dolomite or fluorite, as well as their mixed abrasive with quartz) with metal hardness-to-abrasive hardness ratios (H/HA) ranging from 0.25 to 6.25 were used in the drilling fluid for experiments. The results show that the H/HA value determined the wear mechanism of 4145H steel. When a single soft abrasive was used (with H/HA higher than 1.3–1.5), polishing was the dominantly observed mechanism. While mixed abrasives were applied, a microcutting mechanism due to the ploughing of hard abrasive particles on the steel surface was also observed. The increase in mass fraction of the soft abrasives has little effect on the wear rate of 4145H steel, but its wear rate will significantly increase as the mass fraction of hard abrasives increases. Therefore, in order to extend the life of drilling tools and reduce downhole accidents, the mass fraction of hard particles in the drilling fluid should be reduced as much as possible.  相似文献   

13.
This work presents the analysis of functional relationships between fraction size of abrasives and geometric parameters of surfaces after rotary cleaning. The influence of an abrasive type on the effectiveness of rotary cleaning of machine parts with complex geometric features was determined as well. The process of mechanical cleaning, using a rotational method, of clutch springs was performed in the proprietary device for rotational cleaning, which was followed by the computer-aided analysis of the obtained results. The research process was carried out using abrasive materials such as grinding stone, sand, basalt, glass, and fine gravel, and the test samples were clutch springs after eight years of operation. Based on calculated three-dimensional (3D) roughness values of the cleaned samples’ surfaces, qualitative classification of abrasives was determined. The most effective material turned out to be fine gravel, while the worst results were related to basalt usage.  相似文献   

14.
The goal of this study was to evaluate the effectiveness of the toothpaste Tooth Mousse compared to conventional fluoride-based versions in the prevention of enamel and dentin demineralization. Human enamel and dentin samples (n = 120 each) were exposed to artificial demineralization at pH 4.92. During the demineralization process, the samples in the test groups were periodically treated with Tooth Mousse (TM) containing casein-phosphopeptide -amorphous-calcium-phosphate (CPP-ACP) and Tooth Mousse Plus (TMP) containing amorphous-calcium-fluoride-phosphate (CPP-ACPF) to evaluate their protective properties. Fluoride toothpastes containing 1400 ppm amine fluoride (AmF) and 1450 ppm sodium fluoride (NaF) were applied in the positive control groups. Treatment with distilled water (group C-W) or demineralization without treatment (group C-D) served as negative controls. After the demineralization and treatment process, all samples were cut longitudinally and lesion depths were determined at six locations using polarized light microscopy. In TM/TMP groups (enamel: 80/86 µm, dentin: 153/156 µm) lesion depths were significantly smaller compared to the negative control groups C-W/C-D (enamel: 99/111 µm, dentin: 163/166 µm). However, TM and TMP compared to the positive controls AmF/NaF (enamel: 58/63 µm, dentin: 87/109 µm) showed higher lesion depths. The application of TM/TMP (89%/78%) during demineralization led to a reduced number of severe lesions compared to the negative controls C-W/C-D (100%/95%). In this study we demonstrate that Tooth Mousse is less effective regarding prevention of enamel and dentin demineralization compared to fluoride containing toothpastes.  相似文献   

15.
The surface of titanium (Ti) dental implants must be modified to improve their applicability, owing to the biological inertness of Ti. This study aims to use sandblasting as a pretreatment method and prepare a hydroxyapatite (HA) coating on Ti to improve its biocompatibility and induce bone bonding and osteogenesis. In this paper, sandblasted Ti discs were coated with α-tricalcium phosphate (α-TCP) via Er:YAG pulsed laser deposition (Er:YAG-PLD). An HA coating was then obtained via the hydrothermal treatment of the discs at 90 °C for 10 h. The surface characteristics of the samples were evaluated by SEM, SPM, XPS, XRD, FTIR, and tensile tests. Rat bone marrow mesenchymal stem cells were seeded on the HA-coated discs to determine cellular responses in vitro. The surface characterization results indicated the successful transformation of the HA coating with a nanorod-like morphology, and its surface roughness increased. In vitro experiments revealed increased cell attachment on the HA-coated discs, as did the cell morphology of fluorescence staining and SEM analysis; in contrast, there was no increase in cell proliferation. This study confirms that Er:YAG-PLD could be used as an implant surface-modification technique to prepare HA coatings with a nanorod-like morphology on Ti discs.  相似文献   

16.
Single-crystal sapphire (α-Al2O3) is an important material and widely used in many advanced fields. The semi-fixed abrasive grain processing method based on solid-phase reaction theory is a prominent processing method for achieving ultra-precision damage-free surfaces. In order to develop the proposed method for polishing sapphire, the basic characteristics of the semi-fixed abrasive grains polishing tool for polishing sapphire were determined. Weight analysis was used to study the influence rules of parameters on surface roughness and material removal rates using an orthogonal experiment. Then, the optimized polishing tool was obtained through a mixture of abrasive particle sizes to reduce the difficulty in molding the polishing tool. Finally, polishing experiments using different polishing tools were carried out to investigate polishing performance by considering the surface roughness, material removal rate and the surface morphology during polishing. The results showed that (1) external load affects the surface roughness and material removal rate the most, followed by abrasive particle size, sand bond ratio, revolution speed of the workpiece and he polishing tool; (2) the difficulty in manufacturing the polishing tool could be reduced by mixing larger abrasive particles with small abrasive particles; (3) the polishing tool with 200 nm and 1 μm particle sizes performed best in the first 210 min polishing.  相似文献   

17.
High-entropy alloys are a new generation of materials that have attracted the interest of numerous scientists because of their unusual properties. It seems interesting to use these alloys in biomedical applications. However, for this purpose, the basic condition of corrosion resistance must be fulfilled. In this article, selected corrosion properties of self-composed high-entropy alloys are investigated and compared with conventional biomedical alloys, that is titanium alloys and stainless steels. Corrosive parameters were determined using the potentiodynamic method. X-ray diffraction studies were performed to characterize the crystal structures. Microstructures of the prepared materials were examined using a scanning electron microscope, and surface hardness was measured by the Vickers method. The results show that investigated high-entropy alloys are characterized by simple structures. Three out of four tested high-entropy alloys had better corrosion properties than conventional implant alloys used in medicine. The Al0.7CoCrFeNi alloy was characterized by a corrosion potential of −224 mV and a corrosion current density of 0.9 μA/cm2; CoCrFeNiCu by −210 mV and 1.1 μA/cm2; TiAlFeCoNi by −435 mV and 4.6 μA/cm2; and Mn0.5TiCuAlCr by −253 mV and 1.3 μA/cm2, respectively. Therefore, the proposed high-entropy alloys can be considered as potential materials for biomedical applications, but this requires more studies to confirm their biocompatibility.  相似文献   

18.
Three titanium (Ti) targets with different purities were used to prepare Ti films on polyimide substrates by DC magnetron sputtering. The microstructures of Ti films were characterized by a metallographic microscope, X-ray diffractometer, field emission scanning electron microscope and three-dimensional surface topography instrument. In this study, we investigated the effects of Ti target purity and microstructure on film deposition rate, surface roughness, microstructure and resistivity. The results show that the deposition rate increased with increasing Ti target purity. Ti film deposited by the high-purity (99.999%) Ti target has fewer surface particles with smaller size, lower surface roughness and lower resistivity when compared to that prepared by the Ti target of low purity (99.7%). The surface roughness of Ti film prepared by the high-purity Ti target was Sa = 121 nm, the deposition rate was 16.3 nm/min and the resistivity was 6.9 × 10−6 Ω·m. For Ti targets of the same purity, the performance of Ti film prepared by a target with equiaxed α-phase grains is better than that of Ti film prepared by a target with twins and β-phase grains.  相似文献   

19.
This study evaluated the effects of different simulated chairside grinding and polishing protocols on the physical and mechanical properties of surface roughness, hardness, and flexural strength of monolithic zirconia. Sintered monolithic zirconia specimens (15 mm × 3 mm × 3 mm) were abraded using three different burs: diamond bur, modified diamond bur (zirconia specified), and tungsten carbide bur, along with a group of unprepared specimens that served as a control group. The study was divided into two phases, Phase 1 and Phase 2. Surface roughness, surface hardness, and flexural strength were assessed before and after the grinding procedure to determine the ‘best test group’ in Phase 1. The best abrasive agent was selected for Phase 2 of the study. The specimens in Phase 2 underwent grinding with the best abrasive agent selected. Following the grinding, the specimens were then polished using commercially available diamond polishing paste, a porcelain polishing kit, and an indigenously developed low-temperature sintered zirconia slurry. The physical and mechanical properties were again assessed. Results were analyzed using one-way ANOVA test. Specimens were observed under scanning electron microscopy (SEM) and X-ray diffraction (XRD) for their microstructure and crystalline phases, respectively. Grinding with diamond burs did not weaken zirconia (p > 0.05) but produced rougher surfaces than the control group (p < 0.05). Tungsten carbide burs did not significantly roughen the zirconia surface. However, specimens ground by tungsten carbide burs had a significantly reduced mean flexural strength (p < 0.05) and SEM revealed fine surface cracks. Phase transformation was not detected by XRD. Polishing with commercially available polishing agents, however, restored the surface roughness levels to the control group. Dental monolithic zirconia ground with tungsten carbide burs had a significantly reduced flexural strength and a smooth but defective surface. However, grinding with diamond burs roughened the zirconia surface. These defects may be reduced by polishing with commercially available polishing agents. The use of tungsten carbide burs for grinding dental zirconia should not be advocated. Grinding with diamond abrasives does not weaken zirconia but requires further polishing with commercially available polishing agents.  相似文献   

20.
Although some reports suggest that taper-slip cemented stems may be associated with a higher periprosthetic femoral fractures rate than composite-beam cemented stems, few studies have focused on the biomaterial effect of the polished material on the stem–cement interface. The purpose of this study was to investigate the relationship between surface roughness of materials and bone cement. Four types of metal discs—cobalt-chromium-molybdenum alloy (CoCr), stainless steel alloy 316 (SUS), and two titanium alloys (Ti-6Al-4V and Ti-15Mo-5Zr-3Al)—were prepared. Five discs of each material were produced with varying degrees of surface roughness. In order to evaluate surface wettability, the contact angle was measured using the sessile drop method. A pin was made using two bone cements and the frictional coefficient was assessed with a pin-on-disc test. The contact angle of each metal increased with decreasing surface roughness and the surface wettability of metal decreased with higher degrees of polishing. With a surface roughness of Ra = 0.06 μm and moderate viscosity bone cement, the frictional coefficient was significantly lower in CoCr than in SUS (p = 0.0073). In CoCr, the low adhesion effect with low frictional coefficient may result in excessive taper-slip, especially with the use of moderate viscosity bone cement.  相似文献   

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