Effect of Electroless Cu Plating Ti3AlC2 Particles on Microstructure and Properties of Gd2O3/Cu Composites

Ti₃AlC₂ presents a hexagonal layered crystal structure and bridges the gap between metallic and ceramic properties, and Gadolinia (Gd₂O₃) has excellent thermodynamic stability, which make them potentially attractive as dispersive phases for Cu matrix composites. In this paper, Cu@Ti₃AlC₂-Gd₂O₃/Cu composites, Ti₃AlC₂-Gd₂O₃/Cu composites, and Gd₂O₃/Cu composites were prepared by electroless Cu plating, internal oxidation, and vacuum hot press sintering. The microstructure and the effect of the Cu plating on the properties of the Cu@Ti₃AlC₂-Gd₂O₃/Cu composites were discussed. The results showed that a Cu plating with a thickness of about 0.67 μm was successfully plated onto the surface of Ti₃AlC₂ particles. The ex situ Ti₃AlC₂ particles were distributed at the Cu grain boundary, while the in situ Gd₂O₃ particles with a grain size of 20 nm were dispersed in the Cu grains. The electroless Cu plating onto the surface of the Ti₃AlC₂ particles effectively reduces their surfactivity and improves the surface contacting state between the Cu@Ti₃AlC₂ particles and the Cu matrix, and reduces electron scattering, so that the tensile strength reached 378.9 MPa, meanwhile, the electrical conductivity and elongation of the Cu matrix composites was maintained at 93.6 IACS% and 17.6%.     

Effect of Ti3SiC2 and Ti3AlC2 Particles on Microstructure and Wear Resistance of Microarc Oxidation Layers on TC4 Alloy

Microarc oxidation (MAO) layers were prepared using 8g/L Na₂SiO₃ + 6g/L (NaPO₃)₆ + 4g/L Na₂WO₄ electrolyte with the addition of 2g/L Ti₃SiC₂/Ti₃AlC₂ particles under constant-current mode. The roughness, porosity, composition, surface/cross-sectional morphology, and frictional behavior of the prepared MAO layers were characterized by 3D real-color electron microscopy, scanning electron microscopy, X-ray energy spectrometry, X-ray diffractometry, and with a tribo-tester. The results showed that the addition of Ti₃SiC₂ and Ti₃AlC₂ to the electrolyte reduced the porosity of the prepared layers by 9% compared with that of the MAO layer without added particles. The addition of Ti₃SiC₂/Ti₃AlC₂ also reduced the friction coefficient and wear rate of the prepared layers by 35% compared with that of the MAO layer without added particles. It was found that the addition of Ti₃AlC₂ particles to the electrolyte resulted in the lowest porosity and the lowest wear volume.     

A Novel Approach of Using Ground CNTs as the Carbon Source to Fabricate Uniformly Distributed Nano-Sized TiCx/2009Al Composites

Nano-sized TiC_x/2009Al composites (with 5, 7, and 9 vol% TiC_x) were fabricated via the combustion synthesis of the 2009Al-Ti-CNTs system combined with vacuum hot pressing followed by hot extrusion. In the present study, CNTs were used as the carbon source to synthesize nano-sized TiC_x particles. An attempt was made to correlate the effect of ground CNTs by milling and the distribution of synthesized nano-sized TiC_x particles in 2009Al as well as the tensile properties of nano-sized TiC_x/2009Al composites. Microstructure analysis showed that when ground CNTs were used, the synthesized nano-sized TiC_x particles dispersed more uniformly in the 2009Al matrix. Moreover, when 2 h-milled CNTs were used, the 5, 7, and 9 vol% nano-sized TiC_x/2009Al composites had the highest tensile properties, especially, the 9 vol% nano-sized TiC_x/2009Al composites. The results offered a new approach to improve the distribution of in situ nano-sized TiC_x particles and tensile properties of composites.     

Synthesis and Tribological Characterization of Ti3SiC2/ZnO Composites

Dense Ti₃SiC₂/ZnO composites were sintered at different temperatures by spark plasma sintering (SPS). The effects of sintering temperature on composition and mechanical properties of Ti₃SiC₂/ZnO composites were studied. The tribological behaviors of Ti₃SiC₂/ZnO composites/Inconel 718 alloy tribo-pairs at elevated temperature from 25 °C to 800 °C were discussed. The experimental results showed that the initial decomposition temperature of the Ti₃SiC₂/ZnO composite was 1150 °C, and Ti₃SiC₂ decomposed into TiC. When the decomposition temperature was higher than 1150 °C, the compositions of the Ti₃SiC₂/ZnO composites were Ti₃SiC₂, ZnO, and TiC. It was found that Ti₃SiC₂/ZnO composites had better self-lubricating performance than Ti₃SiC₂ at elevated temperature from 600 °C to 800 °C, which was owing to material transfers of tribo-pairs and sheared oxides generated by tribo-oxidation reactions.     

Microstructure and Mechanical Properties of Composites Obtained by Spark Plasma Sintering of Ti3SiC2-15 vol.%Cu Mixtures

Method of soft metal (Cu) strengthening of Ti₃SiC₂ was conducted to increase the hardness and improve the wear resistance of Ti₃SiC₂. Ti₃SiC₂/Cu composites containing 15 vol.% Cu were fabricated by Spark Plasma Sintering (SPS) in a vacuum. The effect of the sintering temperature on the phase composition, microstructure and mechanical properties of the composites was investigated in detail. The as-synthesized composites were thoroughly characterized by scanning electron micrography (SEM), optical micrography (OM) and X-ray diffractometry (XRD), respectively. The results indicated that the constituent of the Ti₃SiC₂/Cu composites sintered at different temperatures included Ti₃SiC₂, Cu₃Si and TiC. The formation of Cu₃Si and TiC originated from the reaction between Ti₃SiC₂ and Cu, which was induced by the presence of Cu and the de-intercalation of Si atoms Ti₃SiC₂. OM analysis showed that with the increase in the sintering temperature, the reaction between Ti₃SiC₂ and Cu was severe, leading to the Ti₃SiC₂ getting smaller and smaller. SEM measurements illustrated that the uniformity of the microstructure distribution of the composites was restricted by the agglomeration of Cu, controlling the mechanical behaviors of the composites. At 1000 °C, the distribution of Cu in the composites was relatively even; thus, the composites exhibited the highest density, relatively high hardness and compressive strength. The relationships of the temperature, the current and the axial dimension with the time during the sintering process were further discussed. Additionally, a schematic illustration was proposed to explain the related sintering characteristic of the composites sintered by SPS. The as-synthesized Ti₃SiC₂/Cu composites were expected to improve the wear resistance of polycrystalline Ti₃SiC₂.     

Microstructure and Mechanical Properties of Hybrid AZ91 Magnesium Matrix Composite with Ti and SiC Particles

In this paper, a new hybrid metal matrix composite, named AZ91/(SiC + Ti)_p, is presented. The commercial AZ91 magnesium alloy was chosen as the matrix. The composite was reinforced with both SiC and Ti particles. The investigated material was successfully fabricated using stir casting methods. Microstructure analyses were carried out by digital and scanning electron microscopy with an energy-dispersive X-ray spectrometer (SEM + EDX). Detailed investigations disclosed the presence (besides the reinforced particles) of primary dendrites of the α phase, α + γ eutectic and some part of discontinuous precipitates of the γ phase in the composite microstructure. The composite was characterised by uniform distribution of the Ti particles, whereas the SiC particles were revealed inside the primary dendrites of the α phase, on the Ti particles and in the interdendritic regions as a mixture with the α + γ eutectic. Both the tensile and compression strength as well as the yield strength of the composite were examined in both uniaxial tensile and compression tests at room temperature. The fabricated AZ91/(SiC + Ti)_p hybrid composite exhibited higher mechanical properties of all those investigated in comparison with the unreinforced AZ91 matrix alloy (cast in the same conditions). Additionally, analyses of the fracture surfaces of the AZ91/(SiC + Ti)_p hybrid composite carried out using scanning electron microscopy (SEM + EDX) were presented.     

Microstructure and Properties of TiB2 Composites Produced by Spark Plasma Sintering with the Addition of Ti5Si3

Titanium diboride (TiB₂) is a hard, refractory material, attractive for a number of applications, including wear-resistant machine parts and tools, but it is difficult to densify. The spark plasma sintering (SPS) method allows producing TiB₂-based composites of high density with different sintering aids, among them titanium silicides. In this paper, Ti₅Si₃ is used as a sintering aid for the sintering of TiB₂/10 wt % Ti₅Si₃ and TiB₂/20 wt % Ti₅Si₃ composites at 1600 °C and 1700 °C for 10 min. The phase composition of the initial powders and produced composites was analyzed by the X-ray diffraction method using CuK_α radiation. The microstructure was examined using scanning electron microscopy, accompanied by energy-dispersive spectroscopy (EDS). The hardness was determined using a diamond indenter of Vickers geometry loaded at 9.81 N. Friction–wear properties were tested in the dry sliding test in a ball-on-disc configuration, using WC as a counterpart material. The major phases present in the TiB₂/Ti₅Si₃ composites were TiB₂ and Ti₅Si_3. Traces of TiC were also identified. The hardness of the TiB₂/Ti₅Si₃ composites was in the range of 1860–2056 HV1 and decreased with Ti₅Si₃ content, as well as the specific wear rate W_v. The coefficient of friction for the composites was in the range of 0.5–0.54, almost the same as for TiB₂ sinters. The main mechanism of wear was abrasive.     

The Role of Sintering Temperature and Dual Metal Substitutions (Al3+, Ti4+) in the Development of NASICON-Structured Electrolyte

The aim of this study is to synthesize Li_1+xAl_xTi_xSn_2−2x(PO₄) sodium super ion conductor (NASICON) -based ceramic solid electrolyte and to study the effect of dual metal substitution on the electrical and structural properties of the electrolyte. The performance of the electrolyte is analyzed based on the sintering temperature (550 to 950 °C) as well as the composition. The trend of XRD results reveals the presence of impurities in the sample, and from Rietveld Refinement, the purest sample is achieved at a sintering temperature of 950 °C and when x = 0.6. The electrolytes obey Vegard′s Law as the addition of Al³⁺ and Ti⁴⁺ provide linear relation with cell volume, which signifies a random distribution. The different composition has a different optimum sintering temperature at which the highest conductivity is achieved when the sample is sintered at 650 °C and x = 0.4. Field emission scanning electron microscope (FESEM) analysis showed that higher sintering temperature promotes the increment of grain boundaries and size. Based on energy dispersive X-ray spectroscopy (EDX) analysis, x = 0.4 produced the closest atomic percentage ratio to the theoretical value. Electrode polarization is found to be at maximum when x = 0.4, which is determined from dielectric analysis. The electrolytes follow non-Debye behavior as it shows a variety of relaxation times.     

The Influence of SiO2 + SiC + Al (H2PO4)3 Coating on Mechanical and Dielectric Properties for SiCf/MWCNTS/AlPO4 Composites

SiC fiber-reinforced AlPO₄ matrix (SiC_f/MWCNTs/AlPO₄) composites were fabricated using a hot laminating process with multi-walled carbon nanotubes (MWCNTs) as the absorber. A coating prepared from SiO₂ + SiC + Al (H₂PO₄)₃ was applied to the surface of the SiC_f/MWCNTs/AlPO₄ composites prior to an anti-oxidation test at 1273 K in air for 40 h. The anti-oxidation effect was verified by a three-point bending test, scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and a dielectric property test. Anti-oxidation mechanism investigations revealed that the coating effectiveness could be attributed to three substances, i.e., SiO₂, SiP₂O_7, and SiO₂ + AlPO₄ solid solution from the reactions of SiC + O₂→SiO₂ + CO, SiO₂ + P₂O₅→SiP₂O₇ and SiO₂ + AlPO₄→solid solution, respectively.     

Tribo-oxide Competition and Oxide Layer Formation of Ti3SiC2/CaF2 Self-Lubricating Composites during the Friction Process in a Wide Temperature Range

Ti₃SiC₂/CaF₂ composites were prepared by the spark plasma sintering (SPS) process. Both the microstructure of Ti₃SiC₂/CaF₂ and the influence of test temperature on the tribological behavior of the Ti₃SiC₂/CaF₂ composites were investigated. The synergistic effect of friction and oxidation was evaluated by analyzing the worn surface morphology. The results showed that Ti₃SiC₂/CaF₂ were still brittle materials after adding CaF₂, which was in agreement with Ti₃SiC₂. The hardness, relative density, flexural strength and compressive strength of the Ti₃SiC₂/CaF₂ composites were slightly lower than those of Ti₃SiC₂, and the addition of CaF₂ decreased the decomposition temperature of Ti₃SiC₂ from 1350 to 1300 °C. Simultaneously, as the temperature of the test increased, the friction coefficient of Ti₃SiC₂/CaF₂ showed a downward trend (from 0.81 to 0.34), and its the wear rate was insensitive.     

Mg2+ Doping Effects on the Structural and Dielectric Properties of CaCu3Ti4O12 Ceramics Obtained by Mechanochemical Synthesis

In this study, ceramic CaCu₃Ti₄O₁₂ (CCTO) and CaCu_3−xMg_xTi₄O₁₂ solid solutions in which 0.1 ≤ x ≤ 0.5 were prepared by the mechanochemical method, realized by a high-energy ball milling technique. The effects of the Mg²⁺ ion concentration and sintering time on the dielectric response in the prepared ceramics were investigated and discussed. It was demonstrated that, by the use of a sufficiently high energy of mechanochemical treatment, it is possible to produce a crystalline product after only 2 h of milling the mixture of the oxide substrates. Both the addition of magnesium ions and the longer sintering time of the mechanochemically-produced ceramics cause excessive grain growth and significantly affect the dielectric properties of the materials. The X-ray diffraction (XRD) analysis showed that all of the as-prepared solid solutions, CaCu_3−xMg_xTi₄O₁₂ (0.0 ≤ x ≤ 0.5), regardless of the sintering time, exhibit a cubic perovskite single phase. The dielectric study showed two major contributions associated with the grains and the grain boundaries. The analysis of the electric modules of these ceramics confirmed the occurrence of Maxwell–Wagner type relaxation, which is dependent on the temperature.     

Microstructure and Tribological Properties of Spark-Plasma-Sintered Ti3SiC2-Pb-Ag Composites at Elevated Temperatures

Ti₃SiC₂-PbO-Ag composites (TSC-PA) were successfully prepared using the spark plasma sintering (SPS) technique. The ingredient and morphology of the as-synthesized composites were elaborately investigated. The tribological properties of the TSC-PA pin sliding against Inconel 718 alloys disk at room temperature (RT) to 800 °C were examined in air. The wear mechanisms were argued elaborately. The results showed that the TSC-PA was mainly composed of Ti₃SiC₂, Pb, and Ag. The average friction coefficient of TSC-PA gradually decreased from 0.72 (RT) to 0.3 (800 °C), with the temperature increasing from RT to 800 °C. The wear rate of TSC-PA showed a decreasing trend, with the temperature rising from RT to 800 °C. The wear rate of Inconel 718 exhibited positive wear at RT and negative wear at elevated temperatures. The tribological property of TSC-PA was related to the tribo-chemistry, and the abrasive and adhesive wear.     

Ceramic Matrix Composites Obtained by the Reactive Sintering of Boron Carbide with Intermetallic Compounds from the Ti-Si System

In this study, we investigated the effect of adding two different intermetallics, Ti₅Si₃ and TiSi₂, for the preparation of TiB₂-SiC-B₄C composites. As part of the research, stoichiometric composites consisting only of two phases TiB₂ and SiC were obtained. The TiB₂-SiC-B₄C composites were prepared via pressureless sintering. The presence of the phases in the sintered composites was confirmed using X-ray diffraction and scanning electron microscopy. The SEM-EDS examination revealed that the TiB₂ and SiC phases were formed during the composite process synthesis and were distributed homogeneously in the B₄C matrix. The obtained results allowed us to usually exceed 2000 °C and the use of specialized equipment for firing, that is, vacuum or protective atmosphere furnaces as well as control and measurement equipment. Such an approach generates high costs that are decisive for the economics of the technological processes. In the case of our compositions, it is possible to lower the temperature to 1650 °C. The TiB₂-SiC-B₄C composites were classified as UHTCs.     

Microstructure and Mechanical Properties of Alumina Composites with Addition of Structurally Modified 2D Ti3C2 (MXene) Phase

This study presents new findings related to the incorporation of MXene phases into ceramic. Aluminium oxide and synthesised Ti₃C₂ were utilised as starting materials. Knowing the tendency of MXenes to oxidation and degradation, particularly at higher temperatures, structural modifications were proposed. They consisted of creating the metallic layer on the Ti₃C₂, by sputtering the titanium or molybdenum. To prepare the composites, powder metallurgy and spark plasma sintering (SPS) techniques were adopted. In order to evaluate the effectiveness of the applied modifications, the emphasis of the research was placed on microstructural analysis. In addition, the mechanical properties of the obtained sinters were examined. Observations revealed significant changes in the MXenes degradation process, from porous areas with TiC particles (for unmodified Ti₃C₂), to in situ creation of graphitic carbon (in the case of Ti₃C₂-Ti/Mo). Moreover, the fracture changed from purely intergranular to cracking with high participation of transgranular mode, analogously. In addition, the results obtained showed an improvement in the mechanical properties for composites with Ti/Mo modifications (an increase of 10% and 15% in hardness and fracture toughness respectively, for specimens with 0.5 wt.% Ti₃C₂-Mo). For unmodified Ti₃C₂, enormously cracked areas with spatters emerged during tests, making the measurements impossible to perform.     

Gd/Mn Co-Doped CaBi4Ti4O15 Aurivillius-Phase Ceramics: Structures,Electrical Conduction and Dielectric Relaxation Behaviors

In this work, Gd/Mn co-doped CaBi₄Ti₄O₁₅ Aurivillius-type ceramics with the formula of Ca_1-xGd_xBi₄Ti₄O₁₅ + xGd/0.2wt%MnCO₃ (abbreviated as CBT-xGd/0.2Mn) were prepared by the conventional solid-state reaction route. Firstly, the prepared ceramics were identified as the single CaBi₄Ti₄O₁₅ phase with orthorhombic symmetry and the change in lattice parameters detected from the Rietveld XRD refinement demonstrated that Gd³⁺ was successfully substituted for Ca²⁺ at the A-site. SEM observations further revealed that all samples were composed of the randomly orientated plate-like grains, and the corresponding average grain size gradually decreased with Gd content (x) increasing. For all compositions studied, the frequency independence of conductivity observed above 400 °C showed a nature of ionic conduction behavior, which was predominated by the long-range migration of oxygen vacancies. Based on the correlated barrier hopping (CBH) model, the maximum barrier height W_M, the dc conduction activation energy E_dc, as well as the hopping conduction activation energy E_p were calculated for the CBT-xGd/0.2Mn ceramics. The composition with x = 0.06 was found to have the highest E_dc value of 1.87 eV, as well as the lowest conductivity (1.8 × 10⁻⁵ S/m at 600 °C) among these compositions. The electrical modules analysis for this composition further illustrated the degree of interaction between charge carrier β increases, with an increase in temperature from 500 °C to 600 °C, and then a turn to decrease when the temperature exceeded 600 °C. The value of β reached a maximum of 0.967 at 600 °C, indicating that the dielectric relaxation behavior at this temperature was closer to the ideal Debye type.     

Influence of Ti3C2Tx MXene and Surface-Modified Ti3C2Tx MXene Addition on Microstructure and Mechanical Properties of Silicon Carbide Composites Sintered via Spark Plasma Sintering Method

This article presents new findings related to the problem of the introduction of MXene phases into the silicon carbide matrix. The addition of MXene phases, as shown by the latest research, can significantly improve the mechanical properties of silicon carbide, including fracture toughness. Low fracture toughness is one of the main disadvantages that significantly limit its use. As a part of the experiment, two series of composites were produced with the addition of 2D-Ti₃C₂T_x MXene and 2D-Ti₃C₂T_x surface-modified MXene with the use of the sol-gel method with a mixture of Y₂O₃/Al₂O₃ oxides. The composites were obtained with the powder metallurgy technique and sintered with the Spark Plasma Sintering method at 1900 °C. The effect adding MXene phases had on the mechanical properties and microstructure of the produced sinters was investigated. Moreover, the influence of the performed surface modification on changes in the properties of the produced composites was determined. The analysis of the obtained results showed that during sintering, the MXene phases oxidize with the formation of carbon flakes playing the role of reinforcement. The influence of the Y₂O₃/Al₂O₃ layer on the structure of carbon flakes and the higher quality of the interface was also demonstrated. This was reflected in the higher mechanical properties of composites with the addition of modified Ti₃C₂T_x. Composites with 1 wt.% addition of Ti₃C₂T_x M are characterized with a fracture toughness of 5 MPa × m^0.5, which is over 50% higher than in the case of the reference sample and over 15% higher than for the composite with 2.5 wt.% addition of Ti₃C₂T_x, which showed the highest fracture toughness in this series.     

The Dielectric Constant of Ba6−3x(Sm1−yNdy)8+2xTi18O54 (x = 2/3) Ceramics for Microwave Communication by Linear Regression Analysis

The electronics related to the fifth generation mobile communication technology (5G) are projected to possess significant market potential. High dielectric constant microwave ceramics used as filters and resonators in 5G have thus attracted great attention. The Ba_6−3x(Sm_1−yNd_y)_8+2xTi₁₈O₅₄ (x = 2/3) ceramic system has aroused people’s interest due to its underlying excellent microwave dielectric properties. In this paper, the relationships between the dielectric constant, Nd-doped content, sintering temperature and the density of Ba_6−3x(Sm_1−yNd_y)_8+2xTi₁₈O₅₄ (x = 2/3) ceramics were studied. The linear regression equation was established by statistical product and service solution (SPSS) data analysis software, and the factors affecting the dielectric constant have been analyzed by using the enter and stepwise methods, respectively. It is found that the model established by the stepwise method is practically significant with Y = −71.168 + 6.946x₁ + 25.799x₃, where Y, x₁ and x₃ represent the dielectric constant, Nd content and the density, respectively. According to this model, the influence of density on the dielectric constant is greater than that of Nd doping concentration. We bring the linear regression analysis method into the research field of microwave dielectric ceramics, hoping to provide an instructive for the optimization of ceramic technology.     

Structure,Luminescence, and Magnetic Properties of Crystalline Manganese Tungstate Doped with Rare Earth Ion

The precursor prepared by co-precipitation method was sintered at various temperatures to synthesize crystalline manganese tungstate (MnWO₄). Sintered MnWO₄ showed the best crystallinity at a sintering temperature of 800 °C. Rare earth ion (Dysprosium; Dy³⁺) was added when preparing the precursor to enhance the magnetic and luminescent properties of crystalline MnWO₄ based on these sintering temperature conditions. As the amount of rare earth ions was changed, the magnetic and luminescent characteristics were enhanced; however, after 0.1 mol.%, the luminescent characteristics decreased due to the concentration quenching phenomenon. In addition, a composite was prepared by mixing MnWO₄ powder, with enhanced magnetism and luminescence properties due to the addition of dysprosium, with epoxy. To one of the two prepared composites a magnetic field was applied to induce alignment of the MnWO₄ particles. Aligned particles showed stronger luminescence than the composite sample prepared with unsorted particles. As a result of this, it was suggested that it can be used as phosphor and a photosensitizer by utilizing the magnetic and luminescent properties of the synthesized MnWO₄ powder with the addition of rare earth ions.     

Optical Properties of Mg,Fe, Co-Doped Near-Stoichiometric LiTaO3 Single Crystals

Mg, Fe co-doped near-stoichiometric lithium tantalite (SLT) single crystals were grown by employing the zone-leveling Czochralski (ZLCz) technique. The optical properties, holographic parameters, as well as the composition of the grown crystals were measured. It was found that the Li/Ta ratio decreased with the doping of Mg and Fe ions. A red shift was observed in absorption spectrum for the Mg, Fe co-doped crystals compared to the undoped and Mg-doped ones. The effect of the iron ions (Fe²⁺ and Fe³⁺) was further discussed based on the specified absorption bands. Moreover, the occupation mechanism for the defects was discussed by using the IR absorption spectrum, which was attributed to the Fe_Ta³⁻ defects in the highly Fe-doped crystal. In addition, the holographic parameters were also found to be improved with a higher Fe/Ta ratio in the crystals.     

In Situ Construction of TiC-Ti3SiC2 Gradient Hybrid Interphase Coated SiC Fibers for Suppression of Specular Reflection and Non-Specular Scattering

TiC-Ti₃SiC₂ gradient hybrid interphase on the surface of SiC fibers was successfully obtained through the molten salt method. The electromagnetic parameters of the prepared samples can be accurately controlled by adjusting the reaction temperature. A significant bimodal effect is observed in electromagnetic parameters patterns, corresponding to the double interface layer. TiC-Ti₃SiC₂ gradient hybrid interphase plays a dominant role in impedance matching, as well as in the attenuation layer through multi-interfacial polarization and conduction loss. Through the co-evaluation of the suppression of specular reflection and non-specular scattering properties of the samples, the SiC fiber with the TiC-Ti₃SiC₂ gradient hybrid interphase is expected to be a high temperature resistant radar absorbing material for future stealth aircraft.