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1.
This article presents an assessment of indoor air quality at a bus terminal. For this purpose, field surveys were conducted, and air samples were collected and analyzed for the presence of selected indoor air quality indicators. Mathematical modeling was performed to simulate bus emission rates, occupational exposure, and ventilation requirements to maintain acceptable indoor air quality. A sensitivity analysis based on literature-derived emission rates estimates was conducted to evaluate the effect of seasonal temperature changes within the terminal. Control measures to improve indoor air quality at the terminal are also outlined. While carbon monoxide concentrations were below the corresponding American Conference of Governmental Industrial Hygienists' (ACGIH) standards under normal operating conditions, they exceeded the 8-hr recommended average standard at peak hours and the World Health Organization (WHO) standard at all times. Total suspended particulates levels, on the other hand, were above the 24-hr American Society of Heating, Refrigerating and Air Conditioning Engineers' (ASHRAE) standard. Carbon monoxide emission rates that were estimated using the transient mass balance model correlated relatively well with those reported in the literature. Modeling results showed that the natural ventilation rate should be at least doubled for acceptable indoor air quality. While pollutant exposure levels depended on the individual activity patterns and the pollutant concentration, pollutant emissions rates within the terminal were affected mostly by the temperature with a 20-25 percent variation in carbon monoxide levels due to changes in seasonal temperatures.  相似文献   

2.
The evaporation of formaldehyde from cadavers in gross anatomy laboratories can produce high exposures among students and instructors. To understand the system that produces exposures and to plan for implementing control options, the generation of formaldehyde vapors must be characterized. A gross anatomy laboratory with 47 dissecting tables was studied during 15 lab sessions over a period of 16 weeks. Area concentrations were measured using National Institute of Occupational Safety and Health (NIOSH) method 3500. Average daily area concentrations in the laboratory ranged from 0.635 to 1.82 mg/m3. The ventilation was characterized on three separate days. The laboratory had a general ventilation rate of 9.8 air changes per hour. There was no local exhaust ventilation. The concentration measurements were used in a mass balance model along with ventilation rates to determine formaldehyde emission rates. The daily average formaldehyde emission rate from all sources in the laboratory ranged from 95.2-274 mg/min, with an average of 148 mg/min over the course of the study. This total emission rate was used along with the number of dissecting tables to develop an emission factor of 3.15 mg/min per table. The emission factor is a generalizable tool that can be used in laboratories of various sizes to predict emission rates and develop control strategies. This emission factor is applicable where the cadavers are prepared with similar embalming fluid consisting of approximately 10 percent formaldehyde.  相似文献   

3.
Predicting the space-time evolution of a gaseous or particulate pollutant concentration in a ventilated room where a process operation is performed is imperative in hazardous activities, such as chemical or nuclear ones. This study presents a prediction of the space-time evolution of airborne pollutant dispersion following the accidental rupture of a containment enclosure (fume cupboard, glove box, pressurized gas duct, etc.). The final model is written as correlations inspired by the free turbulent jet theory, giving the space-time evolution of a pollutant concentration c (x,y,z,t) that has been formulated as a correlated function of various parameters: leak geometry (slot or round opening), emission type (continuous or transient), emission duration and initial emission velocity. These correlations are based on gas tracing experiments and on multidimensional simulations using computational fluid dynamics (CFD) tools. An instrumented experimental facility was used to simulate pressurized gas industrial failure, and the measurements performed gave the real-time evolution of a tracer gas concentration. Transient leak simulations were run in parallel with a CFD code. Comparisons between experimental and numerical results largely agree. A semiempirical model was built using a methodical parametric study of all the simulation results. This model is easy to use in safety evaluations of radioactive material containment and radiological protection inside nuclear facilities and for evaluating toxic gaseous compounds in the chemical industry.  相似文献   

4.
To evaluate the efficacy of engineering controls in reducing worker exposure to metalworking fluids, an evaluation of an enclosure for a machining center during face milling was performed. The enclosure was built around a vertical metal machining center with an attached ventilation system consisting of a 25-cm diameter duct, a fan, and an air-cleaning filter. The evaluation method included using sulfur hexafluoride (SF6) tracer gas to determine the ventilation system's flow rate and capture efficiency, a respirable aerosol monitor (RAM) to identify aerosol leak locations around the enclosure, and smoke tubes and a velometer to evaluate air movement around the outside of the enclosure. Results of the tracer gas evaluation indicated that the control system was approximately 98% efficient at capturing tracer gas released near the spindle of the machining center. This result was not significantly different from 100% efficiency (p = 0.2). The measured SF6 concentration when released directly into the duct had a relative standard deviation of 2.2%; whereas, when releasing SF6 at the spindle, the concentration had a significantly higher relative standard deviation of 7.8% (p = 0.016). This increased variability could be due to a cyclic leakage at a small gap between the upper and lower portion of the enclosure or due to cyclic stagnation. Leakage also was observed with smoke tubes, a velometer, and an aerosol photometer. The tool and fluid motion combined to induce a periodic airflow in and out of the enclosure. These results suggest that tracer gas methods could be used to evaluate enclosure efficiency. However, smoke tubes and aerosol instrumentation such as optical particle counters or aerosol photometers also need to be used to locate leakage from enclosures.  相似文献   

5.
Recent studies have shown that a reverse flow often occurs in a unidirectional airflow in push-pull ventilation and may transport contaminants from the source into a worker's breathing zone. The same problem may arise in local exhaust ventilation when the contaminant source is located in the worker's wake region. In this study, organic solvent work with local exhaust ventilation was duplicated in a laboratory and the details of the reverse flow around the worker's body produced by the ventilation were experimentally investigated. In order to evaluate the influence of the reverse flow on the exposure of the worker, experiments with a mock-up mannequin (dummy worker) and a local ventilation system which was equipped with an exterior type hood and an enclosure type hood were conducted. The exposure level and the contaminant leakage from the hoods in several conditions were measured by means of a smoke test and tracer gas method. Ethanol vapor was used as a tracer gas. With the exterior type hood, the reverse flow visualized by the smoke was observed in front of the standing dummy worker but could not be observed when the dummy worker was seated. From the tracer gas measurements, it was proved that the exposure due to the reverse flow was not so serious at a capture velocity of > 0.4 m/s, but < 10 ppm contaminant leakage from the exterior hood had been recognized independently of the capture velocity. With the enclosure type hood, exposure due to the reverse flow could be controlled with a capture velocity of > 0.8 m/s. Although the contaminant leakage from the hood due to the reverse flow was not obvious with the enclosure type in any condition, caution should be exercised to prevent exposure when the worker is seated. Regardless of the hood type, the increase in the capture velocity was effective in decreasing exposure due to the reverse flow.  相似文献   

6.
A method is introduced for evaluating recirculation in a building ventilation system from pollutant emissions in or near the building. Tracer was released at a known rate at the point of pollutant emission. Using measured tracer concentrations, the tracer release rate, and an estimate of the pollutant release rate, pollutant concentrations were estimated at the locations in the building where the tracer was measured. The method can be used to test whether a ventilation system is adequate for maintaining an acceptable work environment before work with a hazardous substance begins. In a case study presented to illustrate the technique, initial attempts to correct a problem of recirculation of sulfuric acid from a fume hood in a chemistry laboratory were shown to be inadequate, prompting the ventilation contractor to make further repairs before work with sulfuric acid could be resumed.  相似文献   

7.
摘要:目的 研究典型空气污染物(SO2、NO2、CO、PM10、O3)与慢性阻塞性肺炎的相关性,为疾病预防和污染治理提供依据。方法 依托于地理信息系统操作平台,通过遥感影像反演结果与地面实测浓度的插值,得到研究区内5种污染物浓度的分布趋势;利用统计学原理,求平均、数理统计、建立回归分析等,得到最适宜于研究两者之间关系的模型;利用SPSS,分别以5种污染物月平均浓度为自变量,以每月的慢性阻塞性肺炎患者数量为因变量,进行相关性分析、建立散点图和函数模型,并比较各自参数。结果 各污染物浓度分布与患者分布情况趋于一致:浓度高的区域,患者分布密集;SO2、NO2、PM10、CO、O3浓度与患者数量的相关性因子分别为0.681、0.576、0.755、0.611、0.519。结论 空气污染越严重,即污染物浓度越高,病患分布越为密集;PM10浓度与病患数量之间函数模型的相关性因子最大,两者相关性最强。  相似文献   

8.
To assist validation of numerical simulations of urban pollution, air quality in a street canyon was investigated using a wind tunnel as a research tool under neutral atmospheric conditions. We used tracer gas techniques from a line source without buoyancy. Ethylene (C(2)H(4)) was used as the tracer gas. The street canyon model was formed of six parallel building rows of the same length. The flow and dispersion field was analyzed and measured using a hot-wire anemometer with split fiber probe and fast flame ionization detector. The diffusion flow field in the boundary layer within the street canyon was examined at different locations, with varying building orientations (θ=90°, 112.5°, 135° and 157.5°) and street canyon aspect ratios (W/H=1/2, 3/4 and 1) downwind of the leeward side of the street canyon model. Results show that velocity increases with aspect ratio, and with θ>90°. Pollutant concentration increases as aspect ratio decreases. This concentration decreases exponentially in the vertical direction, and decreases as θ increases from 90°. Measured pollutant concentration distributions indicate that variability of building orientation and aspect ratio in the street canyon are important for estimating air quality in the canyon. The data presented here can be used as a comprehensive database for validation of numerical models.  相似文献   

9.
The ventilation rate within a negatively pressurized room is usually determined by measuring the exhaust air flow rate. This method does not account for air mixing factors and gives limited information on ventilation efficiency within the room. Effective ventilation rates have been determined using tracer gases such as sulfur hexafluoride (SF6). The objective of this study was to determine whether artificially generated airborne particles could be used as a tracer to directly measure ventilation efficiency. We monitored the decay of artificially generated particles within negatively pressurized rooms. Separate trials were conducted at air exhaust rates ranging from about 6 to 20 room air changes per hour. Particles were generated to a minimum of 20 times the ambient concentration using a simple ventilation smoke bottle and measured with handheld light-scattering airborne particle counters. Data were obtained for aerodynamic particle size ranges of: 0.5 micron (microM) and larger, and 1.0 microM and larger. The time rate of decay of particles was plotted after subtracting the background concentrations. Results were compared with simultaneously conducted tracer gas decay analyses (ASTM method E741-95) using SF6. Particle concentrations followed an exponential decay (R2 = 0.98-0.99+) and mirrored the decay curve of the tracer gas. The air change rates predicted by the particle count procedure differed from the tracer gas results by a mean of 4.0 percent (range 0%-12%). The particle count procedure was substantially simpler and less expensive than the SF6 tracer gas method. Additional studies are needed to further refine this procedure and to explore its range of applicability.  相似文献   

10.
Several approaches can be taken to estimate or classify total personal exposures to air pollutants. While personal exposure monitoring (PEM) provides the most direct measurements, it is usually not practical for extended time periods or large populations. This paper describes the use of indirect approaches to estimate total personal exposure for NO2 and particulate matter (PM), summarizes the distributions of these estimates, and compares the effectiveness of these estimates with microenvironmental concentrations for evaluating effects on respiratory function and symptoms. Pollutant concentrations were measured at several indoor and outdoor locations for over 400 households participating in an epidemiological study in Tucson, Arizona. Central site monitoring data were significantly correlated with samples collected directly outside homes, but the former usually had higher pollutant concentrations. Integrated indices of daily total personal exposure were calculated using micro-environmental (ME) measurements or estimates and time-budget diary information. Peak expiratory flow rates (PEFR) were measured for up to four times a day during two-week study periods. In thirty children (ages 6-15 years) with current diagnosed asthma, a significant reduction in PEFR was associated with NO2 levels measured outside of their homes. Additional decrements of morning PEFR were found in those children sleeping in bedrooms with higher measured NO2 levels. Morning and noon PEFR decrements were also linked to higher morning NO2 levels that were measured at central monitoring stations. Effects of PM were also found, but were limited to morning PEFR. No effects were found in non-asthmatic children. The relationship of PEFR to the calculated indices of daily average total exposure were weaker than to the microenvironment concentrations. This suggests that diary and ME monitoring data need to yield better time resolution in order to incorporate short-term average exposures to higher concentrations into the exposure indices and into the analysis of within day health responses.  相似文献   

11.
According to the Machinery Directive 2006/42/EC, one of the essential requirements relating to occupational safety and health hazards is to prevent dust pollution emitted by machinery during the implementation processes. Research on evaluation of emissions from machinery, according to the method of test bench using tracer gases, are currently being conducted in CIOP-PIB. This article presents some aspects of dust emission and efficiency of local exhaust ventilation (LEV) during metal grinding. Studies were performed with 10 sources of dust emissions during grinding. To evaluate the pollutants emission in the process of grinding metal products sulfur hexafluoride (SF(6)) was selected as a tracer gas. The results show that wherever dust is emitted, the LEV should be supported by the general ventilation. Ensure good interaction between all elements of modifying the air flow and the spread of pollutants in the surroundings of the LEV is essential to effective protection of human working zone against pollutants. We used five variants of ventilation: ventilation turned off, the LEV, one-way general ventilation, mixed general ventilation and displacement general ventilation. An increase in the efficiency of dust capture depending on the source of emission by 2.5-14% was observed. This confirms that characteristics of flow resulting from the operation of ventilation is important in the spread of pollutants in the room.  相似文献   

12.
A middle school (grades 6 to 8) in a residential section of Springfield, Illinois, with no known air quality problems, was selected for a baseline indoor air quality survey. The study was designed to measure and evaluate air quality at the middle school with the objective of providing a benchmark for comparisons with measurements in schools with potential air quality problems. The focus of this article is on the development of emission factors for particulate matter and bioaerosols. The school was characterized as having no health complaints and good maintenance schedules. Four indoor locations including the cafeteria, a science classroom, an art classroom, the lobby outside the main office, and one outdoor location were sampled for various environmental comfort and pollutant parameters for one week in February 1997. Integrated samples (eight-hour sampling time) for respirable and total particulate matter, and short-term measurements (two-minute samples, three times per day) for bioaerosols were collected on three consecutive days at each of the sampling sites. Continuous measurements of carbon dioxide were logged at all locations for five days. Continuous measurements of respirable particulate matter were also collected in the lobby area. A linear relationship between occupancy and corresponding carbon dioxide and particle concentrations was seen. A completely mixed space, one compartment mass balance model with estimated CO2 generation rates and actual CO2 and particulate matter concentrations was used to model ventilation and pollutant emission rates. Emission factors for occupancy were represented by the slope of emission rate versus occupancy scatter plots. The following particle and bioaerosol emission factors were derived from the indoor measurements: total particles: 1.28 mg/hr/person-hr; respirable particles: 0.154 g/hr/person-hr; total fungi: 167 CFU/hr/person-min; thermophilic fungi: 35.8 CFU/hr/person-min; mesophilic fungi: 119 CFU/hr/person-min; total bacteria: 227 CFU/hr/person-min; gram-negative bacteria: 69.5 CFU/hr/person-min; gram-positive bacteria: 191 CFU/hr/person-min; Aspergillus: 17.0 CFU/hr/person-min; Penicillium: 161 CFU/hr/person-min; and yeasts: 16.4 CFU/hr/person-min.  相似文献   

13.
Inhalation of airborne nanoparticles is a well-known source of potentially health-hazardous occupational exposures. Effective mitigation measures are necessary to reduce exposure, but also challenging to implement due to the different characteristics of each individual emission source and industrial scenario. The present paper describes four different exposure case studies in the ceramic industry and quantifies the effectiveness of mitigation strategies implemented during: ceramic tile processing by thermal spraying, laser ablation, the use of diesel engines, and tile firing. The mitigation measures for exposure reduction were tailored to each industrial scenario. The NP removal efficiency of source enclosure (partial/full) combined with local exhaust ventilation (LEV) were quantified to range between 65 and 85% when the enclosure was partial. The efficiency reached 99% with full enclosure and vigorous ventilation (Air Change per Hour; ACH = 132 h−1). The elimination of the source was the optimal strategy to minimize exposure in the case of diesel forklifts use. The conventional ceramic kilns used intensively (>10 years) generated high NP exposure concentrations (>106/cm3). Appropriate maintenance and enhanced sealing enabled the reduction of exposure down to 52% of the initial value. It must be added that technologically advanced kilns, enabled even greater NP reductions (down to 84%), compared to the conventional ones. This proves technological improvements can lead to significant reduction of work exposures. This work evidences the need for tailored mitigation measures due to the broad variety of potential sources and activities in industrial scenarios. The quantitative efficiency rates reported here may be valuable for the adequate parametrization of exposure prediction and risk assessment models.  相似文献   

14.
The effect of displacement flow on the distribution of aerosol concentration was investigated in an industrial hall. According to the displacement ventilation principle, vertical upflow is accomplished by introducing fresh air, cooler than room air, into the occupied zone near floor level. The fresh air is introduced from low-velocity devices and heated by warm processes. This technique allows warm air contaminants to rise to the ceiling, and the rising plume is then exhausted close to the ceiling. This study presents the results of a field study conducted in an industrial environment. The aerosol properties and behavior, especially the vertical gradients, are characterized in a displacement flow field. The results indicate that the fine particles, less than 1 microm in diameter, are transported away from the breathing zone by the ventilation process. However, the air quality is significantly influenced by the emission source, and therefore the number concentration of fine and ultrafine (smaller than 0.1 microm in diameter) aerosol particles in the breathing zone was clearly elevated compared to that of the incoming clean air. The vertical gradients displayed clear size dependence; the strongest gradients were found for particles between 0.003 and 0.015 microm in diameter.  相似文献   

15.
This article describes a new method for measuring and mapping pollutants in air in real-time which can be used for visualizing the flow of gases and vapors in both indoor industrial and outdoor environmental applications. This method uses open-path Fourier Transform Infrared (OP-FTIR) spectrometry and computed tomography for real-time mapping of concentrations of chemicals in air. These maps may be used to evaluate human exposures, source emissions and air dispersion models; thus, this method can be used for both industrial and environmental sampling. It is being developed using computer simulations, and chamber and field studies. Computer simulations used simulated test concentration data to create maps; the original maps of concentrations were compared with the tomographic reconstructed maps. In the chamber studies, tracer gas was released into the chamber and measurements from a tomographic system were compared with point sample measurements taken at the same time. When sulfur hexafluoride was injected in a stable flow field position in the chamber, the concentrations reconstructed by the concentration maps were within +/- 15.9 percent of the measured point samples; overall, they were within +/- 27 percent of the measured point samples. On a 12-foot by 14-foot grid of cells used to model the chamber, the average peak location error was within one foot. The peak location error refers to the error involved in locating the point of highest concentration in the plume. For the field study, field-generated tomographic maps were compared with concentrations estimated using the Industrial Source Complex-Short Term (ISCST) model. Fairly good correlation (R2 = 0.67) was found between the five-minute overall-average cell concentrations in the tomographic and ISCST model maps. Overall, the tomographic map concentrations over-predicted the ISCST model concentrations by 24 percent. Optical remote sensing and computed tomography shows promise as a method to produce spatially and temporally resolved two-dimensional concentration maps indoors and outdoors. These maps would provide near real-time visualization of contaminant generation, movement, concentrations, and emission rates for multiple chemicals simultaneously at low limits of detection.  相似文献   

16.
A method to measure the emission rate of an airborne pollutant source using a tracer gas was tested in the case of an aerosol source. The influence of particle deposition on the walls of a test room of 72 m3 was studied. The deposition rate of an aerosol of MgCl2 was determined by means of two methods: one based on measuring the aerosol concentration decay inside the ventilated room, the other based on calculation of the material mass balance. The concentration decay was monitored by optical counting and the aerosol mass concentration determined by means of sampling on a filter and analysis of the mass deposited by atomic absorption spectrometry. Four series of measurements were carried out. The curve giving the deposition rate according to the particle aerodynamic diameter (d(ae)) was established and shows deposition rates higher than those predicted using the model of Corner. The decay method gives the best results. The study carried out has shown that the phenomenon of deposition has little effect on the measurement of the aerosol source emission rate using a tracer gas for particles of aerodynamic diameter < 5 microm (underestimation < 25%). For particles of a greater diameter, wall deposition is an extremely limiting factor for the method, the influence of which can, however, be limited by using a test booth of small volume and keeping the sampling duration as short as possible.  相似文献   

17.
This article presents a method that enables the generation rate from one or /more particle sources to be estimated, using far-field concentration measurements. The method is made up of two distinct steps; a calibration phase, followed by an estimation phase. The calibration phase makes it possible to create a transfer relationship between a known source (“reference source”) and the measurement of the far-field concentration. The second step consists of estimating unknown source generation rates by inverting the transfer relationship and using measurements of far-field concentrations resulting from these unknown sources. In addition, this article presents a technique to improve the positioning of the sensors in the room in which the sources are situated.

A numerical study using computational fluid dynamics was first conducted to theoretically validate the estimation method and assist with choosing the sensor positions in the experimental rig. The study established that, with ideal sensors, the difference between the real and estimated generation rates can be accurate to within 0.1%. The method was then deployed on an experimental case. The results confirmed that it is possible to estimate an isolated source. However, the quality of the estimation deteriorated when the source to be estimated was significantly different from the reference source, from an aerodynamic perspective.  相似文献   


18.
Radiation exposures due to patient sources, a pneumatic transport system, and gas lines in a positron emission tomography imaging facility are estimated for heavy clinical work loads. For simple source approximations and estimated study activities and times, exposure rates are computed that are larger than those anticipated in traditional nuclear medical imaging facilities. Measurements of exposure rates indicate that such an approach will result in conservative estimates of exposure by a factor of 1.2-6.3. Exposure rates due to gas lines may be kept at reasonable levels by careful planning of the routing of the line and by using high flow rates and small bore tubing. If reasonable care is taken to maintain the system so that only a limited number of failures occur, the doses due to pneumatic transport system operation are also small. The nonextremity doses to personnel and other individuals not involved in radiotracer preparation are estimated to be highest due to exposure to the patient sources. Shielding for 511 keV photons may help to minimize exposure. Several practical suggestions are given for further reducing exposure to personnel.  相似文献   

19.
A measuring method of the emission rate of an atmospheric pollutant source, based on the use of a tracer gas (helium) and developed in the case of a gaseous source, was tested for an aerosol source. The influence of both particle sedimentation and wall depositions was studied. The transport coefficients of the tracer gas and of alumina particles of various particle sizes (MMAD from 8 to 36 microns) were measured on a vertical axis close to the source, in a 71 m3 room swept by a piston flow. The measurements clearly demonstrated the predominant influence of sedimentation in the case of particles with aerodynamic diameters greater than 10 microns. Particle wall deposition was determined by measuring the gas and particle concentration decay in the ventilated room. To do this, a new tracing method using a fluorescent aerosol was developed. The measured aerosol deposition rates are much higher than those calculated from the formula of Corner for a cubical volume. Aerosol sedimentation and wall deposition are two phenomena limiting the use of a tracer gas to measure the aerosol emission rate. The chemical substances and materials used in work premises are likely to be released into the atmosphere and lead to the formation of pollutants. These emissions stem from either physical or chemical processes (evaporation of a solvent) or from mechanical processes (dispersion of oil droplets at the source of mists).  相似文献   

20.
Understanding the inhalation, transport and deposition of smoke particles during fire missions are important to evaluating the health risks for firefighters. In this study, measurements from Underwriters Laboratories' large-scale fire experiments on smoke particle size distribution and concentration in three residential fire scenes were incorporated into models to investigate the fate of inhaled toxic ultrafine particulates in a realistic firefighter nasal cavity model. Deposition equations were developed, and the actual particle dosimetry (in mass, number and surface area) was evaluated. A strong monotonic growth of nasal airway dosages of simulated smoke particles was identified for airflow rates and fire duration across all simulated residential fire scene conditions. Even though the “number” dosage of arsenic in the limited ventilation living room fire was similar to the “number” dosage of chromium in the living room, particle mass and surface area dosages simulated in the limited living room were 90–200 fold higher than that in the ventilated living room. These were also confirmed when comparing the dosimetry in the living room and the kitchen. This phenomenon implied that particles with larger size were the dominant factors in mass and surface area dosages. Firefighters should not remove the self-contained breathing apparatus (SCBA) during fire suppression and overhaul operations, especially in smoldering fires with limited ventilation.  相似文献   

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