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1.
Biochar application has been reported to improve the physical, chemical, and hydrological properties of soil. However, the information about the size fraction composition of the applied biochar as a factor that may have an impact on the properties of soil-biochar mixtures is often underappreciated. Our research shows how sunflower husk biochar (pyrolyzed at 650 °C) can modify the water retention characteristics of arable sandy soil depending on the biochar dose (up to 9.52 wt.%) and particle size (<50 µm, 50–100 µm, 100–250 µm). For comparison, we used soil samples mixed with biochar passed through 2 mm sieve and an unamended reference. The addition of sieved biochar to the soil caused a 30% increase in the available water content (AWC) in comparing to the soil without biochar. However, the most notable improvement (doubling the reference AWC value from 0.078 m3 m−3 to 0.157 m3 m−3) was observed at the lowest doses of biochar (0.95 and 2.24 wt.%) and for the finest size fractions (below 100 µm). The water retention effects on sandy soil are explained as the interplay between the dose, the size of biochar particles, and the porous properties of biochar fractions.  相似文献   

2.
The study investigates effect of the additive consisting of natural zeolite (clinoptilolite) and soda lime glass powder on the hydration, mechanical properties and porosity of Portland cement concrete. The effect of mineral additive on the technological, physical-mechanical properties and porosity of the mortar was investigated by increasing the content of natural zeolite and glass powder added to the mortar up to 20% by weight of cement in increments of 5% and different particles size of natural zeolite. The mixes with the best technological and mechanical properties were identified and further studies were conducted by replacing 10% and 15% of cement with natural zeolite and soda lime glass with an average grain size of 59.3 μm, 29.0 μm or 3.6 μm of zeolite, and 29.6 μm of glass powder. The hydration process and microstructure of hardened cement paste modified with the aforementioned mineral additives was analysed by microcalorimetry, X-ray diffraction tests and thermogravimetric analysis. The optimal composition of cement paste and particle size distribution of natural zeolite were determined to achieve the higher flexural and compressive strength and lower open porosity. The mixture of mineral additives has the highest effect in terms of flexural and compressive strength and open porosity when added at the proportion 75:15:10 (cement:natural zeolite:soda lime glass) and when zeolite with an average particle size of about 3.6 μm is used  相似文献   

3.
A nitrogen fertilizer slow-release membrane was proposed using polyvinyl alcohol (PVA), polyvinylpyrrolidone (PVP), epoxy resin, and zeolite as raw materials. The effects of the water-based copolymer (PVA:PVP) solution ratio A (A1–A4) and zeolite amount B (B1–B4) on the water absorption rate (XS), water permeability (TS), fertilizer permeability (TF), tensile strength (KL), elongation at break (DSL), and viscosity (ND) of the membrane were explored using the swelling method, a self-made device, and a universal testing machine. The optimal combination of the water-based copolymer and zeolite amount was determined by the coefficient-of-variation method. The results show that the effects of the decrease in A on KL and the increase in B on KL and DSL are promoted first and then inhibited. DSL and ND showed a negative response to the A decrease, whereas XS, TS, and TF showed a positive response. The effect of increasing B on ND, TS, and TF showed a zigzag fluctuation. In the condition of A1–A3, XS showed a negative response to the B increase, whereas in the condition of A4, XS was promoted first and then inhibited. Adding PVP and zeolite caused the hydroxyl stretching vibration peak of PVA at 3300 cm−1 to widen; the former caused the vibration peak to move to low frequencies, and the latter caused it to move to high frequencies. The XRD pattern shows that the highest peak of zeolite is located at 2θ = 7.18° and the crystallization peak of the composite membrane increases with the rise in the proportion of zeolite. Adding PVP made the surface of the membrane smooth and flat, and adding a small amount of zeolite improved the mechanical properties of the membrane and exhibited good compatibility with water-based copolymers. In the evaluation model of the physicochemical properties of sustained-release membrane materials, the weight of all indicators was in the following order: TF > ND > TS > KL > XL > DSL. The optimal membrane material for comprehensive performance was determined to be A2B3.  相似文献   

4.
Torrefaction is one of the methods of thermal treatment of biomass, which allows obtaining a product of better quality in the form of biochar. The aim of the paper was to analyze the possibility of using goldenrod (Solidago canadensis, Solidago gigantea) for the production of biochar. The torrefaction process involved the vegetative and generative parts as well as the whole plant at temperatures of 250 °C and 275 °C, for 3 h. Next, the physicochemical properties of the raw material and biochar were determined, namely moisture content, ash content, volatile matter content, calorific value, and heat of combustion. The bulk density of raw biomass and biochar was also determined. It was found that after biomass torrefaction, the ash content, calorific value, and heat of combustion increased, while volatile matter content decreased. It has been observed that in both the case of raw biomass and biochar, the plant species and the sampled parts have a significant impact on the ash content, volatile matter content, calorific value, and heat of combustion.  相似文献   

5.
Due to the special geographical location, climatic characteristics, special soil properties and the flood zone of the Yellow River in Kaifeng, the groundwater level in the lower reaches of the river basin is high and contains much salt. The matrix suction and surface free energy of the Kaifeng city wall earthen site changed under capillary action, resulting in cracking, peeling and efflorescence to varying degrees. In order to reduce the deterioration of the Kaifeng city wall caused by environmental erosion, a select lime with excellent mechanical properties and waterproof methanesiliconic acid sodium salt with excellent water resistance were chosen to reinforce the earthen sites. In this paper, 0%, 3%, 5% and 7% lime, and 0%, 1%, 2% and 3% waterproof materials were selected to determine four types of imitation site soil with 16 different mix proportion samples. Further, samples with different mixing ratios were subjected to direct shear, a disintegration test, and a microscopic scanning electron microscope test. The results show that under different normal stresses, with the increase in waterproof material content, the growth rate of shear strength of imitation site soil ranges from 1.82% to 10.81%. With the increase in lime content, the shear strength of imitation site soil increases rapidly, up to 38.16%. Both materials can improve the shear strength of the soil site. Under reinforcement with the two materials, the cohesive force of the imitation site soil can be improved at a maximum rate of 59.23%, and the internal friction angle changes in the range of 36.72°–41.61°. Compared with the sample without waterproof material, the mass water absorption rate of the sample with waterproof material decreases in the range of 2.76–27.77, and with the increase in waterproof material, the mass water absorption rate of the sample gradually decreases. The chemical reaction products of the waterproof materials and lime can play a filling role in silty clay; filling micro-pores and micro-cracks between soil particles.  相似文献   

6.
Illitic clays are the commonly used material in building ceramics. Zeolites are microporous, hydrated crystalline aluminosilicates, they are widely used due to their structure and absorption properties. In this study, illitic clay (Füzérradvány, Hungary) was mixed with natural zeolite (Nižný Hrabovec, Slovakia) with up to 50 wt.% of zeolite content. The samples were submitted to thermal analyses, such as differential thermal analysis, differential scanning calorimetry, thermogravimetry, and dilatometry. In addition, the evolution of thermal diffusivity, thermal conductivity, and specific heat capacity in the heating stage of firing were measured and discussed. The amount of the physically bound water in the samples increased along with the amount of zeolite. The temperature of the illite dehydroxylation (peak temperature) was slightly shifted to lower temperatures, from 609 °C to 575 °C (for sample IZ50). On the other hand, the mass loss and the shrinkage of the samples significantly increased with the zeolite content in the samples. Sample IZ50 reached 10.8% shrinkage, while the sample prepared only from the illitic clay contracted by 5.8%. Nevertheless, the temperature of the beginning of the sintering (taken from the dilatometric curves) decreased from 1021 °C (for illitic clay) to 1005 °C (for IZ50). The thermal diffusivity and thermal conductivity values decreased as the amount of zeolite increased in the samples, thus showing promising thermal insulating properties.  相似文献   

7.
Diatomite is a non-metallic mineral resource rich in SiO2, which can be used to modify coastal cement soil. In order to explore the mechanical modification effect of diatomite on coastal cement soil at the age of 7 days, based on coastal cement soil with cement content of 5 % (mass fraction), diatomite of 0 %, 5 %, 10 %, 15 % and 20% (mass fraction) was mixed for modification. Through the unconfined compressive strength test, the triaxial unconsolidated undrained test, backscattered electron imaging (BSE), and energy-dispersive spectroscopy (EDS) technology, the influence of diatomite content and confining pressure on the peak strength of modified coastal cement soil was explored. The empirical formula between the peak strength of the DE specimen and the content of diatomite and confining pressure was established by curve fitting, and the fitting effect was ideal. When diatomite was mixed with coastal cement soil, the optimal dosage of diatomite was 5% from the perspective of mechanical properties and economic benefits of the maximum growth rate of compression and shear. The unconfined compressive strength test showed that the peak strength and elastic modulus of the modified coastal cement soil with 5% diatomite content were 37% and 57% higher than those of cement soil, respectively. The triaxial unconsolidated undrained test showed that the internal friction angle of the modified coastal cement soil was stable at about 30°, and cohesion of DE-5, DE-10, DE-15, and DE-20 increased by 28%, 48%, 78%, and 97%, respectively, compared to cement soil. The microscopic test found that the pore distribution of modified coastal cement soil is closely related to the strength change. The results show that the addition of diatomite can effectively improve the mechanical properties of soil-cement.  相似文献   

8.
The surface modification of titanium substrates and its alloys in order to improve their osseointegration properties is one of widely studied issues related to the design and production of modern orthopedic and dental implants. In this paper, we discuss the results concerning Ti6Al4V substrate surface modification by (a) alkaline treatment with a 7 M NaOH solution, and (b) production of a porous coating (anodic oxidation with the use of potential U = 5 V) and then treating its surface in the abovementioned alkaline solution. We compared the apatite-forming ability of unmodified and surface-modified titanium alloy in simulated body fluid (SBF) for 1–4 weeks. Analysis of the X-ray diffraction patterns of synthesized coatings allowed their structure characterization before and after immersing in SBF. The obtained nanolayers were studied using Raman spectroscopy, diffuse reflectance infrared Fourier transform spectroscopy (DRIFT), and scanning electron microscopy (SEM) images. Elemental analysis was carried out using X-ray energy dispersion spectroscopy (SEM EDX). Wettability and biointegration activity (on the basis of the degree of integration of MG-63 osteoblast-like cells, L929 fibroblasts, and adipose-derived mesenchymal stem cells cultured in vitro on the sample surface) were also evaluated. The obtained results proved that the surfaces of Ti6Al4V and Ti6Al4V covered by TiO2 nanoporous coatings, which were modified by titanate layers, promote apatite formation in the environment of body fluids and possess optimal biointegration properties for fibroblasts and osteoblasts.  相似文献   

9.
To enhance the conductivity and volume expansion during the charging and discharging of transition metal oxide anode materials, rGO-SnO2-Fe2O3 composite materials with different contents of rGO were prepared by the in situ hydrothermal synthesis method. The SEM morphology revealed a sphere-like fluffy structure, particles of the 0.4%rGO-10%SnO2-Fe2O3 composite were smaller and more compact with a specific surface area of 223.19 m2/g, the first discharge capacity of 1423.75 mAh/g, and the specific capacity could be maintained at 687.60 mAh/g even after 100 cycles. It exhibited a good ratio performance and electrochemical reversibility, smaller charge transfer resistance, and contact resistance, which aided in lithium-ion transport. Its superior electrochemical performance was due to the addition of graphene, which made the spherical particle size distribution more uniform, effectively lowering the volume expansion during the process of charging and discharging and improving the electrochemical cycle stability of the anode materials.  相似文献   

10.
This study aimed to determine the effect of circulating fluidised bed bottom ash (CFB-BA) content on the mechanical properties and drying shrinkage of cement-stabilised soil. Experiments were performed to study the changes in unconfined compressive strength and expansibility of cement-stabilised soil with different CFB-BA contents and the underlying mechanisms based on microscopic properties. The results show that CFB-BA can effectively increase the unconfined compressive strength of the specimen and reduce the amount of cement in the soil. When the combined content of CFB-BA and cement in the soil was 30%, the unconfined compressive strength of the specimen with C/CFB = 2 after 60 days of curing was 10.138 MPa, which is 1.4 times that of the pure cement specimen. However, the CFB-BA does not significantly improve the strength of the soil and cannot be added alone as a cementing material to the soil. Additionally, swelling tests showed that the addition of CFB-BA to cement-stabilised soil can significantly reduce the drying shrinkage. This research project provides reference values for the application of CFB-BA in cement–soil mixing piles, including compressive strength and the reduction in the shrinkage deformation of specimens.  相似文献   

11.
Rendering mortars with lightweight zeolite aggregates were designed and tested. The effect of the type of binder used was also researched. For the hardened mortars, macrostructural parameters, mechanical characteristics, hygric and thermal properties were assessed. Specific attention was paid to the analysis of the salt crystallization resistance of the developed rendering mortars. Quartz sand was fully replaced in the composition of mortars with zeolite gave materials with low density, high porosity, sufficient mechanical strength, high water vapor permeability and high water absorption coefficient, which are technical parameters required for repair rendering mortars as prescribed in the WTA directive 2-9-04/D and EN 998-1. Moreover, the zeolite enhanced mortars exhibit good thermal insulation performance and high sorption capacity. The examined rendering mortars were found to be well durable against salt crystallization, which supports their applicability in salt-laden masonry. Based on the compatibility of the repair materials with those originally used, the lime and natural hydraulic lime zeolite mortars can be used as rendering mortars for the repair of historical and heritage buildings. The cement-lime zeolite render is applicable for repair purposes only in the case of the renewal of masonry in which Portland cement-based materials were originally used.  相似文献   

12.
This work provides valuable information about unexplored catalytic systems tested in the transesterification reaction of vegetable oil with methanol. It was demonstrated that natural zeolite treatment leads to enhanced catalytic activity and yield of biodiesel production. The activation of the catalytic material in a mixture of 5% H2–95% Ar resulted in an improvement of the values of the TG conversion and fatty acid methyl esters (FAME) yield. In addition, it was proven that the incorporation of CaO, MgO and SrO oxides onto the natural zeolite surface improves the TG conversion and FAME yield values in the transesterification reaction.  相似文献   

13.
Groundwater treatment residuals (GWTRs) are safe waste materials generated during drinking water treatment. GWTRs are mainly deposited in landfills, but the preferred solution should be reused or utilized for some components. To ensure proper sludge management, it is important to provide quality, chemical composition, and texture characteristics of GWTRs. Therefore, in this study, we aimed to investigate and compare the features of GWTRs collected from four water treatment plants. GWTRs were characterized by X-ray diffraction (XRD); scanning electron microscopy (SEM) with energy dispersion spectroscopy (EDS); Fourier transform infrared spectroscopy (FTIR); thermogravimetric, differential thermogravimetric, and differential thermal analysis (TG, DTG, and DTA, respectively); X-ray fluorescence (XRF); inductively coupled plasma optical emission spectrometry (ICP-OEP); specific surface area (SBET) measurement; and determination of the isoelectric point (pHIEP). According to the results, GWTRs are poor crystalline materials that are predominantly composed of ferrihydrite with minor calcite and quartz admixture. They formed heterogeneously mixed particles with irregular shapes. They were mainly composed of iron oxides (32–55%), silica (4–28%), calcium oxide (4–17%), and manganese oxides (0.3–4.0%). They were found to be mesoporous with a large specific surface area. Due to their composition and texture characteristics, GWTRs demonstrate good adsorption properties toward different compounds such as heavy metals and metalloids.  相似文献   

14.
The study aimed to evaluate the influence of the manipulation surfaces on the physical properties of one-step self-etch adhesives (1-SEAs). Scotchbond Universal (SBU), Clearfil Universal Bond Quick ER (UBQ), and an experimental adhesive (UBQexp) were manipulated on different surfaces: manufacturer’s Teflon-based dispensing dish (TD) or hydroxyapatite plate (HA). After manipulation of the adhesives, the pH of each 1-SEA was measured. Samples of each adhesive/manipulation surface were prepared and subjected to water sorption (WS)/solubility (SL) and flexural strength tests. The modulus of elasticity (E) was measured in dry and wet conditions before and after 24 h water storage, and the percentage of variation of E (ΔE) was calculated. Results were analyzed using the t-test with Bonferroni corrections (α = 0.05). When adhesives were manipulated on the HA plate, there was a significant increase in the adhesives’ pH. WS and SL of all 1-SEAs decreased when the HA was used. Only SBU showed higher flexural strength when manipulated on the HA compared to the manipulation on TD under dry and wet conditions. For each 1-SEA, the use of HA resulted in significantly higher E in dry and wet conditions. ΔE of all adhesives was smaller with the manipulation on HA than on TD. It was concluded that the manipulation of 1-SEA on a hydroxyapatite plate considerably affected the adhesives’ properties.  相似文献   

15.
Bovine bone grafts (BBX) require protein removal as part of the manufacturing process to reduce antigenicity and, in consequence, to be safely used in humans. Deproteinisation may have direct effects on the characteristics of the bone material and on in vivo material performance. This research aimed to comprehensively study the physicochemical and mechanical properties of BBX processed at low deproteinisation processing temperatures. Cubes of bovine bone (8 mm3) were treated with temperatures between 100 °C and 220 °C at 30 °C intervals and with pressures ranging from 1.01 to 24.58 Bar. The samples were characterised topographically and mechanically using scanning electron microscopy (SEM), atomic force microscopy (AFM), and uniaxial bending tests. The organic content and the chemical composition were determined using thermogravimetric analysis (TGA) and Fourier-transform infrared spectroscopy (FTIR). X-ray diffraction (XRD) and FTIR were also used to quantitatively determine the specimen crystallinity. Increasing temperature/pressure was associated with decreasing protein levels and compressive strength and increasing surface irregularities and crystallinity. The findings suggest that low-temperature processed bone is likely to exhibit a rapid in vivo degradation rate. The deproteinisation temperature can be adjusted to tailor the graft properties for specific applications.  相似文献   

16.
Nowadays, a great attention is directed into development of innovative multifunctional composites which may support bone tissue regeneration. This may be achieved by combining collagen and hydroxyapatite showing bioactivity, osteoconductivity and osteoinductivity with such biocompatible polymers as polyvinylpyrrolidone (PVP) and poly(vinyl alcohol) (PVA). Here PVA/PVP-based composites modified with hydroxyapatite (HAp, 10 wt.%) and collagen (30 wt.%) were obtained via UV radiation while two types of collagen were used (fish and bovine) and crosslinking agents differing in the average molecular weight. Next, their chemical structure was characterized using Fourier transform infrared (FT-IR) spectroscopy, roughness of their surfaces was determined using a stylus contact profilometer while their wettability was evaluated by a sessile drop method followed by the measurements of their surface free energy. Subsequently, swelling properties of composites were verified in simulated physiological liquids as well as the behavior of composites in these liquids by pH measurements. It was proved that collagen-modified composites showed higher swelling ability (even 25% more) compared to unmodified ones, surface roughness, biocompatibility towards simulated physiological liquids and hydrophilicity (contact angles lower than 90°). Considering physicochemical properties of developed materials and a possibility of the preparation of their various shapes and sizes, it may be concluded that developed materials showed great application potential for biomedical use, e.g., as materials filling bone defects supporting their treatments and promoting bone tissue regeneration due to the presence of hydroxyapatite with osteoinductive and osteoconductive properties.  相似文献   

17.
Commercial Yttria-tetragonal zirconia polycrystalline (Y-TZP) was subjected to surface treatments, and the bond strength of dual resin cement to Y-TZP and failure modes were evaluated. Disks (12 mm × 2 mm), cylinders (7 mm × 3.3 mm), and bars (25 mm × 5 mm × 2 mm) were milled from Y-TZP CAD-CAM blocks, divided into seven groups, and subjected to different surface treatments; silicatization was used as control. On the basis of the literature, this study evaluated modifications with films containing SiO2 nanoparticles and silane; SiO2+ZrO2—SiO2 (50%) and ZrO2 (50%) nanoparticles, SiO2+ZrO2/Silane-SiO2 (50%) and ZrO2 (50%) nanoparticles, and silane. Specimens were analyzed by wettability (n = 3), surface free energy (n = 3), X-ray diffraction (n = 1), Fourier transform infrared spectroscopy (FTIR) (n = 1), roughness (n = 5), shear bond test (n = 10), and dynamic modulus (n = 3). Specimens treated with hydrofluoric acid—HF 40% presented significantly higher contact angle and lowest surface free energy (p < 0.05). The SiO2/Silane presented crystalline SiO2 on the surface. The surface roughness was significantly higher for groups treated with nanofilms (p < 0.05). Shear bond strength was significantly higher for silicatization, HF 40%/silicatization, SiO2/Silane, and SiO2+ZrO2/Silane groups. The proposed treatments with nanofilms had potentially good results without prejudice to the physicochemical characteristics of zirconia. Generally, groups that underwent silica surface deposition and silanization had better bond strength (p < 0.005).  相似文献   

18.
Biochar is a versatile carbon-rich organic material originating from pyrolyzed biomass residues that possess the potential to stabilize organic carbon in the soil, improve soil fertility and water retention, and enhance plant growth. For the utilization of biochar as a soil conditioner, the mutual interconnection of the physicochemical properties of biochar with the production conditions used during the pyrolysis (temperature, heating rate, residence time) and the role of the origin of used biomass seem to be crucial. The aim of the research was focused on a comparison of the properties of biochar samples (originated from oat brans, mixed woodcut, corn residues and commercial compost) produced at different temperatures (400–700 °C) and different residence times (10 and 60 min). The results indicated similar structural features of produced biochar samples; nevertheless, the original biomass showed differences in physicochemical properties. The morphological and structural analysis showed well-developed aromatic porous structures for biochar samples originated from oat brans, mixed woodcut and corn residues. The higher pyrolysis temperature resulted in lower yields; however, it provided products with higher content of organic carbon and a more developed surface area. The lignocellulose biomass with higher contents of lignin is an attractive feedstock material for the production of biochar with potential agricultural applications.  相似文献   

19.
Soil amendments are substances added to the soil for moisture increment or physicochemical soil process enhancement. This study aimed to assess the water conservation efficiency of available organic soil amendments like bentonite, attapulgite, biochar and inorganics like superabsorbent polymer, and nonwoven geotextile in relation to the newly developed water absorbing geocomposite (WAG) and its biodegradable version (bioWAG). Soil amendments were mixed with loamy sand soil, placed in 7.5 dm3 pots, then watered and dried in controlled laboratory conditions during 22-day long drying cycles (pot experiment). Soil moisture was recorded in three locations, and matric potential was recorded in one location during the drying process. The conducted research has confirmed that the addition of any examined soil amendment in the amount of 0.7% increased soil moisture, compared to control, depending on measurement depth in the soil profile and evaporation stage. The application of WAG as a soil amendment resulted in higher soil moisture in the centre and bottom layers, by 5.4 percent point (p.p.) and 6.4 p.p. on day 4 and by 4.5 p.p. and 8.8 p.p. on day 7, respectively, relative to the control samples. Additionally, an experiment in a pressure plate extractor was conducted to ensure the reliability of the obtained results. Soil density and porosity were also recorded. Samples containing WAG had water holding capacity at a value of −10 kPa higher than samples with biochar, attapulgite, bentonite, bioWAG and control by 3.6, 2.1, 5.7, 1 and 4.5 percentage points, respectively. Only samples containing superabsorbent polymers and samples with nonwoven geotextiles had water holding capacity at a value of −10 kPa higher than WAG, by 14.3 and 0.1 percentage points, respectively. Significant changes were noted in samples amended with superabsorbent polymers resulting in a 90% soil sample porosity and bulk density decrease from 1.70 g∙cm−3 to 1.14 g∙cm−3. It was thus concluded that the water absorbing geocomposite is an advanced and most efficient solution for water retention in soil.  相似文献   

20.
Stabilized soils are commonly used as part of pavement construction in highway engineering. The everyday use of this material makes it necessary to classify it. One of the basic methods of determining the mechanical properties of a material is the unconfined compressive strength (UCS) test, from which the material elasticity can be determined. The scope of the research included the design and making of soil mixtures stabilized with polypropylene fibers modified cement. This paper presents the effect of the amount of dispersed reinforcement on the maximum compressive strength, the secant modulus at half the ultimate stress (E50), the secant modulus at the ultimate stress (Es), and the tangent modulus (Et). The materials chapter characterizes the soil, cement, and dispersed reinforcement used. The test methods section describes the tests performed and the procedure for interpreting the results. The results section describes the relationship between elastic modulus and compressive strength. The discussion section compares the obtained results with the works of other authors. The work is concluded with a summary containing the most important conclusions resulting from the work.  相似文献   

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