Fatigue Behavior of Additively Manufactured Stainless Steel 316L

316L stainless steel is the material of choice for several critical applications in which a combination of mechanical strength and resistance to corrosion is required, as in the biomedical field. Additive Manufacturing (AM) technologies can pave the way to new design solutions, but microstructure, defect types, and surface characteristics are substantially different in comparison to traditional processing routes, making the assessment of the long-term durability of AM materials and components a crucial aspect. In this paper a thorough review is presented of the relatively large body of recent literature devoted to investigations on fatigue of AM 316L, focusing on the comparison between different AM technologies and conventional processes and on the influence of processing and post-processing aspects in terms of fatigue strength and lifetime. Overall fatigue data are quite scattered, but the dependency of fatigue performances on surface finish, building orientation, and type of heat treatment can be clearly appreciated, as well as the influence of different printing processes. A critical discussion on the different testing approaches presented in the literature is also provided, highlighting the need for shared experimental test protocols and data presentation in order to better understand the complex correlations between fatigue behavior and processing parameters.     

Corrosion and Microstructural Investigation on Additively Manufactured 316L Stainless Steel: Experimental and Statistical Approach

The use of metal additive manufacturing (AM) has strongly increased in the industry during the last years. More specifically, selective laser melting (SLM) is one of the most used techniques due to its numerous advantages compared to conventional processing methods. The purpose of this study is to investigate the effects of process parameters on the microstructural and corrosion properties of the additively manufactured AISI 316L stainless steel. Porosity, surface roughness, hardness, and grain size were studied for specimens produced with energy densities ranging from 51.17 to 173.91 J/mm³ that resulted from different combinations of processing parameters. Using experimental results and applying the Taguchi model, 99.38 J/mm³ was determined as the optimal energy density needed to produce samples with almost no porosity. The following analysis of variance ANOVA confirmed the scanning speed as the most influential factor in reducing the porosity percentage, which had a 74.9% contribution, followed by the position along the building direction with 22.8%, and finally, the laser energy with 2.3%. The influence on corrosion resistance was obtained by performing cyclic potentiodynamic polarization tests (CPP) in a 3.5 wt % NaCl solution at room temperature for different energy densities and positions (Z axis). The corrosion properties of the AM samples were studied and compared to those obtained from the traditionally manufactured samples. The corrosion resistance of the samples worsened with the increase in the percentage of porosity. The process parameters have consequently been optimized and the database has been extended to improve the quality of the AM-produced parts in which microstructural heterogeneities were observed along the building direction.     

Tensile Properties and Deformation of AISI 316L Additively Manufactured with Various Energy Densities

Additive manufacturing (AM) is an emerging fabrication technology that offers unprecedented potential for manufacturing end-to-end complex shape customized products. However, building products with high performance by AM presents a technological challenge. Inadequate processing parameters, fabrication environment or changes in powder properties may lead to high defect density in the part and poor mechanical properties. Microstructure, defect structure, and mechanical properties of AISI 316L stainless steel pieces, additively manufactured by the laser powder bed fusion method using three different volume energy densities (VEDs), were investigated and compared with those of a commercial wrought AISI 316L sheet. Scanning and transmission electron microscopies were employed for characterization of grain and defect structures, and mechanical properties were determined by tensile testing. It was found that the number of defects such as pores and lack of fusion in AM specimens did not affect the strength, but they impaired the post-uniform elongation, more significantly when processed with the low VED. Twinning was found to be an active deformation mechanism in the medium and high VED specimens and in the commercially wrought material in the later stage of straining, but it was suppressed in the low VED specimens presumably because the presence of large voids limited the strain attained in the matrix.     

Post-Processing and Surface Characterization of Additively Manufactured Stainless Steel 316L Lattice: Implications for BioMedical Use

Additive manufacturing of stainless steel is becoming increasingly accessible, allowing for the customisation of structure and surface characteristics; there is little guidance for the post-processing of these metals. We carried out this study to ascertain the effects of various combinations of post-processing methods on the surface of an additively manufactured stainless steel 316L lattice. We also characterized the nature of residual surface particles found after these processes via energy-dispersive X-ray spectroscopy. Finally, we measured the surface roughness of the post-processing lattices via digital microscopy. The native lattices had a predictably high surface roughness from partially molten particles. Sandblasting effectively removed this but damaged the surface, introducing a peel-off layer, as well as leaving surface residue from the glass beads used. The addition of either abrasive polishing or electropolishing removed the peel-off layer but introduced other surface deficiencies making it more susceptible to corrosion. Finally, when electropolishing was performed after the above processes, there was a significant reduction in residual surface particles. The constitution of the particulate debris as well as the lattice surface roughness following each post-processing method varied, with potential implications for clinical use. The work provides a good base for future development of post-processing methods for additively manufactured stainless steel.     

Impact of the Allowed Compositional Range of Additively Manufactured 316L Stainless Steel on Processability and Material Properties

This work aims to show the impact of the allowed chemical composition range of AISI 316L stainless steel on its processability in additive manufacturing and on the resulting part properties. ASTM A276 allows the chromium and nickel contents in 316L stainless steel to be set between 16 and 18 mass%, respectively, 10 and 14 mass%. Nevertheless, the allowed compositional range impacts the microstructure formation in additive manufacturing and thus the properties of the manufactured components. Therefore, this influence is analyzed using three different starting powders. Two starting powders are laboratory alloys, one containing the maximum allowed chromium content and the other one containing the maximum nickel content. The third material is a commercial powder with the chemical composition set in the middle ground of the allowed compositional range. The materials were processed by laser-based powder bed fusion (PBF-LB/M). The powder characteristics, the microstructure and defect formation, the corrosion resistance, and the mechanical properties were investigated as a function of the chemical composition of the powders used. As a main result, solid-state cracking could be observed in samples additively manufactured from the starting powder containing the maximum nickel content. This is related to a fully austenitic solidification, which occurs because of the low chromium to nickel equivalent ratio. These cracks reduce the corrosion resistance as well as the elongation at fracture of the additively manufactured material that possesses a low chromium to nickel equivalent ratio of 1.0. A limitation of the nickel equivalent of the 316L type steel is suggested for PBF-LB/M production. Based on the knowledge obtained, a more detailed specification of the chemical composition of the type 316L stainless steel is recommended so that this steel can be PBF-LB/M processed to defect-free components with the desired mechanical and chemical properties.     

Anisotropy of Mechanical Properties and Residual Stress in Additively Manufactured 316L Specimens

In the presented study, LPBF 316L stainless steel tensile specimens were manufactured in three different orientations for the analysis of anisotropy. The first set of specimens was built vertically on the build platform, and two other sets were oriented horizontally perpendicular to each other. Tensile test results show that mean Young’s modulus of vertically built specimens is significantly less then horizontal ones (158.7 GPa versus 198 GPa), as well as yield strength and elongation. A role of residual stress in a deviation of tensile loading diagrams is investigated as a possible explanation. Simulation of the build process on the basis of ABAQUS FEA software was used to predict residual stress in 316L cylindrical specimens. Virtual tensile test results show that residual stress affects the initial stage of the loading curve with a tendency to reduce apparent Young’s modulus, measured according to standard mechanical test methods.     

Multiscale Analysis of Surface Texture Quality of Models Manufactured by Laser Powder-Bed Fusion Technology and Machining from 316L Steel

The paper presents the results of tests aimed at evaluating the surface textures of samples manufactured from material based on 316L stainless steel. The analysis of the surface topography was conducted based on the classical approach in accordance with the current standard and with the use of multiscale methods; i.e., wavelet transformation and geometric via curvature. Selective laser melting 3D printing technology was used to produce samples for surface testing. Furthermore, additional assessment of surfaces created as result of milling was conducted. Statistical research demonstrated a differentiation in the distribution of particular morphological features in certain ranges of the analyzed scales.     

A Comparative Study on Laser Powder Bed Fusion of Differently Atomized 316L Stainless Steel

The significant growth of Additive Manufacturing (AM), visible over the last ten years, has driven an increase in demand for small gradation metallic powders of a size lower than 100 µm. Until now, most affordable powders for AM have been produced using gas atomization. Recently, a new, alternative method of powder production based on ultrasonic atomization with melting by electric arc has appeared. This paper summarizes the preliminary research results of AM samples made of two AISI 316L steel powder batches, one of which was obtained during Ultrasonic Atomization (UA) and the other during Plasma Arc Gas Atomization (PAGA). The comparison starts from powder particle statistical distribution, chemical composition analysis, density, and flowability measurements. After powder analysis, test samples were produced using AM to observe the differences in microstructure, porosity, and hardness. Finally, the test campaign covered an analysis of mechanical properties, including tensile testing with Digital Image Correlation (DIC) and Charpy’s impact tests. A comparative study of parts made of ultrasonic and gas atomization powders confirms the likelihood that both methods can deliver material of similar properties.     

Correlations of Geometry and Infill Degree of Extrusion Additively Manufactured 316L Stainless Steel Components

This study focuses on the effect of part geometry and infill degrees on effective mechanical properties of extrusion additively manufactured stainless steel 316L parts produced with BASF’s Ultrafuse 316LX filament. Knowledge about correlations between infill degrees, mechanical properties and dimensional deviations are essential to enhance the part performance and further establish efficient methods for the product development for lightweight metal engineering applications. To investigate the effective Young’s modulus, yield strength and bending stress, standard testing methods for tensile testing and bending testing were used. For evaluating the dimensional accuracy, the tensile and bending specimens were measured before and after sintering to analyze anisotropic shrinkage effects and dimensional deviations linked to the infill structure. The results showed that dimensions larger than 10 mm have minor geometrical deviations and that the effective Young’s modulus varied in the range of 176%. These findings provide a more profound understanding of the process and its capabilities and enhance the product development process for metal extrusion-based additive manufacturing.     

Effect of Phase Transformation on Stress Corrosion Behavior of Additively Manufactured Austenitic Stainless Steel Produced by Directed Energy Deposition

The present study aims to evaluate the stress corrosion behavior of additively manufactured austenitic stainless steel produced by the wire arc additive manufacturing (WAAM) process. This was examined in comparison with its counterpart, wrought alloy, by electrochemical analysis in terms of potentiodynamic polarization and impedance spectroscopy and by slow strain rate testing (SSRT) in a corrosive environment. The microstructure assessment was performed using optical and scanning electron microscopy along with X-ray diffraction analysis. The obtained results indicated that in spite of the inherent differences in microstructure and mechanical properties between the additively manufactured austenitic stainless steel and its counterpart wrought alloy, their electrochemical performance and stress corrosion susceptibility were similar. The corrosion attack in the additively manufactured alloy was mainly concentrated at the interface between the austenitic matrix and the secondary ferritic phase. In the case of the counterpart wrought alloy with a single austenitic phase, the corrosion attack was manifested by uniform pitting evenly scattered at the external surface. Both alloys showed ductile failure in the form of “cap and cone” fractures in post-SSRT experiments in corrosive environment.     

The Effect of Severe Shot Peening on Fatigue Life of Laser Powder Bed Fusion Manufactured 316L Stainless Steel

Severe shot peening (SSP) was used on additive manufactured 316L by laser powder bed fusion. The effect of the post processing on the surface features of the material was analyzed through residual stress measurements, tensile testing, hardness-depth profiles, and fatigue testing by flexural bending. The results showed that SSP can be utilized to form residual stresses up to −400 MPa 200 μm below the surface. At the same time, a clear improvement on the surface hardness was achieved from 275 HV to near 650 HV. These together resulted in a clear improvement on material strength which was recorded at 10% improvement in ultimate tensile strength. Most significantly, the fatigue limit of the material was tripled from 200 MPa to over 600 MPa and the overall fatigue strength raised similarly from a low to high cycle regime.     

Design and Validation of Additively Manufactured Metallic Cellular Scaffold Structures for Bone Tissue Engineering

Bone-related defects that cannot heal without significant surgical intervention represent a significant challenge in the orthopedic field. The use of implants for these critical-sized bone defects is being explored to address the limitations of autograft and allograft options. Three-dimensional cellular structures, or bone scaffolds, provide mechanical support and promote bone tissue formation by acting as a template for bone growth. Stress shielding in bones is the reduction in bone density caused by the difference in stiffness between the scaffold and the surrounding bone tissue. This study aimed to reduce the stress shielding and introduce a cellular metal structure to replace defected bone by designing and producing a numerically optimized bone scaffold with an elastic modulus of 15 GPa, which matches the human’s cortical bone modulus. Cubic cell and diagonal cell designs were explored. Strut and cell dimensions were numerically optimized to achieve the desired structural modulus. The resulting scaffold designs were produced from stainless steel using laser powder bed fusion (LPBF). Finite element analysis (FEA) models were validated through compression testing of the printed scaffold designs. The structural configuration of the scaffolds was characterized with scanning electron microscopy (SEM). Cellular struts were found to have minimal internal porosity and rough surfaces. Strut dimensions of the printed scaffolds were found to have variations with the optimized computer-aided design (CAD) models. The experimental results, as expected, were slightly less than FEA results due to structural relative density variations in the scaffolds. Failure of the structures was stretch-dominated for the cubic scaffold and bending-dominated for the diagonal scaffold. The torsional and bending stiffnesses were numerically evaluated and showed higher bending and torsional moduli for the diagonal scaffold. The study successfully contributed to minimizing stress shielding in bone tissue engineering. The study also produced an innovative metal cellular structure that can replace large bone segments anywhere in the human body.     

Wall Fabrication by Direct Energy Deposition (DED) Combining Mild Steel (ER70) and Stainless Steel (SS 316L): Microstructure and Mechanical Properties

Direct energy deposition is gaining much visibility in research as one of the most adaptable additive manufacturing technologies for industry due to its ease of application and high deposition rates. The possibility of combining these materials to obtain parts with variable mechanical properties is an important task to be studied. The combination of two types of steel, mild steel ER70-6 and stainless steel SS 316L, for the fabrication of a wall by direct energy deposition was studied for this paper. The separate fabrication of these two materials was studied for the microstructurally flawless fabrication of bimetallic walls. As a result of the application of superimposed and overlapped strategies, two walls were fabricated and the microstructure, mechanical properties and hardness of the resulting walls are analyzed. The walls obtained with both strategies present dissimilar regions; the hardness where the most present material is ER70-6 is around 380 HV, and for SS 316L, it is around 180 HV. The average values of ultimate tensile strength (UTS) are 869 and 628 MPa, yield strength (YS) are 584 and 389 MPa and elongation at break are 20% and 36%, respectively, in the cases where we have more ER70-6 in the sample than SS 316L. This indicates an important relationship between the distribution of the materials and their mechanical behavior.     

Mechanical and Microstructural Anisotropy of Laser Powder Bed Fusion 316L Stainless Steel

This paper aims at an in-depth and comprehensive analysis of mechanical and microstructural properties of AISI 316L austenitic stainless steel (W. Nr. 1.4404, CL20ES) produced by laser powder bed fusion (LPBF) additive manufacturing (AM) technology. The experiment in its first part includes an extensive study of the anisotropy of mechanical and microstructural properties in relation to the built orientation and the direction of loading, which showed significant differences in tensile properties among samples. The second part of the experiment is devoted to the influence of the process parameter focus level (FL) on mechanical properties, where a 48% increase in notched toughness was recorded when the level of laser focus was identical to the level of melting. The FL parameter is not normally considered a process parameter; however, it can be intentionally changed in the service settings of the machine or by incorrect machine repair and maintenance. Evaluation of mechanical and microstructural properties was performed using the tensile test, Charpy impact test, Brinell hardness measurement, microhardness matrix measurement, porosity analysis, scanning electron microscopy (SEM), and optical microscopy. Across the whole spectrum of samples, performed analysis confirmed the high quality of LPBF additive manufactured material, which can be compared with conventionally produced material. A very low level of porosity in the range of 0.036 to 0.103% was found. Microstructural investigation of solution annealed (1070 °C) tensile test samples showed an outstanding tendency to recrystallization, grain polygonization, annealing twins formation, and even distribution of carbides in solid solution.     

316L Stainless Steel Powders for Additive Manufacturing: Relationships of Powder Rheology,Size, Size Distribution to Part Properties

Laser-Powder Bed Fusion (L-PBF) of metallic parts is a highly multivariate process. An understanding of powder feedstock properties is critical to ensure part quality. In this paper, a detailed examination of two commercial stainless steel 316L powders produced using the gas atomization process is presented. In particular, the effects of the powder properties (particle size and shape) on the powder rheology were examined. The results presented suggest that the powder properties strongly influence the powder rheology and are important factors in the selection of suitable powder for use in an additive manufacturing (AM) process. Both of the powders exhibited a strong correlation between the particle size and shape parameters and the powder rheology. Optical microscope images of melt pools of parts printed using the powders in an L-PBF machine are presented, which demonstrated further the significance of the powder morphology parameters on resulting part microstructures.     

Experimental Validation and Evaluation of the Bending Properties of Additively Manufactured Metallic Cellular Scaffold Structures for Bone Tissue Engineering

The availability of additive manufacturing enables the fabrication of cellular bone tissue engineering scaffolds with a wide range of structural and architectural possibilities. The purpose of bone tissue engineering scaffolds is to repair critical size bone defects due to extreme traumas, tumors, or infections. This research study presented the experimental validation and evaluation of the bending properties of optimized bone scaffolds with an elastic modulus that is equivalent to the young’s modulus of the cortical bone. The specimens were manufactured using laser powder bed fusion technology. The morphological properties of the manufactured specimens were evaluated using both dry weighing and Archimedes techniques, and minor variations in the relative densities were observed in comparison with the computer-aided design files. The bending modulus of the cubic and diagonal scaffolds were experimentally investigated using a three-point bending test, and the results were found to agree with the numerical findings. A higher bending modulus was observed in the diagonal scaffold design. The diagonal scaffold was substantially tougher, with considerably higher energy absorption before fracture. The shear modulus of the diagonal scaffold was observed to be significantly higher than the cubic scaffold. Due to bending, the pores at the top side of the diagonal scaffold were heavily compressed compared to the cubic scaffold due to the extensive plastic deformation occurring in diagonal scaffolds and the rapid fracture of struts in the tension side of the cubic scaffold. The failure in struts in tension showed signs of ductility as necking was observed in fractured struts. Moreover, the fractured surface was observed to be rough and dull as opposed to being smooth and bright like in brittle fractures. Dimple fracture was observed using scanning electron microscopy as a result of microvoids emerging in places of high localized plastic deformation. Finally, a comparison of the mechanical properties of the studied BTE scaffolds with the cortical bone properties under longitudinal and transverse loading was investigated. In conclusion, we showed the capabilities of finite element analysis and additive manufacturing in designing and manufacturing promising scaffold designs that can replace bone segments in the human body.     

Base Plate Preheating Effect on Microstructure of 316L Stainless Steel Single Track Deposition by Directed Energy Deposition

The microstructural morphology in additive manufacturing (AM) has a significant influence on the building structure. High-energy concentric heat source scanning leads to rapid heating and cooling during material deposition. This results in a unique microstructure. The size and morphology of the microstructure have a strong directionality, which depends on laser power, scanning rate, melt pool fluid dynamics, and material thermal properties, etc. The grain structure significantly affects its resistance to solidification cracking and mechanical properties. Microstructure control is challenging for AM considering multiple process parameters. A preheating base plate has a significant influence on residual stress, defect-free AM structure, and it also minimizes thermal mismatch during the deposition. In the present work, a simple single track deposition experiment was designed to analyze base plate preheating on microstructure. The microstructural evolution at different preheating temperatures was studied in detail, keeping process parameters constant. The base plate was heated uniformly from an external heating source and set the stable desired temperature on the surface of the base plate before deposition. A single track was deposited on the base plate at room temperature and preheating temperatures of 200 °C, 300 °C, 400 °C, and 500 °C. Subsequently, the resulting microstructural morphologies were analyzed and compared. The microstructure was evaluated using electron backscattered diffraction (EBSD) imaging in the transverse and longitudinal sections. An increase in grain size area fraction was observed as the preheating temperature increased. Base plate preheating did not show influence on grain boundary misorientation. An increase in the deposition depth was noticed for higher base plate preheating temperatures. The results were convincing that grain morphology and columnar grain orientation can be tailored by base plate preheating.     

Tribological Performance of Additively Manufactured AISI H13 Steel in Different Surface Conditions

Additive manufacturing of metallic tribological components offers unprecedented degrees of freedom, but the surface roughness of most as-printed surfaces impedes the direct applicability of such structures, and postprocessing is necessary. Here, the tribological performance of AISI H13 steel samples was studied. These were additively manufactured through laser powder bed fusion (L-PBF), also referred to as selective laser melting (SLM). Samples were tested in four different surface conditions: as-printed, polished, ground and polished, and laser-surface-textured (LST) with round dimples. Friction experiments were conducted in a pin-on-disk fashion against bearing steel disks under lubrication with an additive-free mineral base oil for sliding speeds between 20 and 170 mm/s. Results demonstrated that, among the four surface treatments, grinding and polishing resulted in the lowest friction coefficient, followed by the as-printed state, while both polishing alone and laser-surface texturing increased the friction coefficient. Surprisingly, direct correlation between surface roughness and friction coefficient, i.e., the rougher the surface was, the higher the friction force, was not observed. Wear was minimal in all cases and below what could be detected by gravimetrical means. These results highlight the need for an adequate post-processing treatment of additively manufactured parts that are to be employed in tribological systems.     

Comparison of Different Additive Manufacturing Methods for 316L Stainless Steel

In additive manufacturing (AM), the technology and processing parameters are key elements that determine the characteristics of samples for a given material. To distinguish the effects of these variables, we used the same AISI 316L stainless steel powder with different AM techniques. The techniques used are the most relevant ones in the AM of metals, i.e., direct laser deposition (DLD) with a high-power diode laser and selective laser melting (SLM) using a fiber laser and a novel CO₂ laser, a novel technique that has not yet been reported with this material. The microstructure of all samples showed austenitic and ferritic phases, which were coarser with the DLD technique than for the two SLM ones. The hardness of the fiber laser SLM samples was the greatest, but its bending strength was lower. In SLM with CO₂ laser pieces, the porosity and lack of melting reduced the fracture strain, but the strength was greater than in the fiber laser SLM samples under certain build-up strategies. Specimens manufactured using DLD showed a higher fracture strain than the rest, while maintaining high strength values. In all the cases, crack surfaces were observed and the fracture mechanisms were determined. The processing conditions were compared using a normalized parameters methodology, which has also been used to explain the observed microstructures.     

Affecting Microstructure and Properties of Additively Manufactured AISI 316L Steel by Rotary Swaging

The presented work focused on the development of the microstructural and mechanical properties of a AISI 316L stainless steel workpiece prepared through additive manufacturing and subsequently processed by hot rotary swaging. In order to characterize the effects of swaging on the structural development, samples were taken for electron microscopy scanning and microhardness measurements were taken after each swaging reduction. The as-built and final swaged pieces were also subjected to tensile testing at room temperature and at 900 °C. The structural analyses showed that the hot swaging introduced a substructural formation; low angle grain boundaries prevailed over high angle ones after each pass. The swaging also imparted an almost complete elimination of the porosity and significant grain size; the average grain area decreased from the original value of 365.5 µm² to 4.4 µm² after the final swaging pass. The changes in the texture between the passes were negligible, however, the grain refinement went hand in hand with the microhardness increase (up to almost 300 HV1). The results of the tensile testing confirmed that the mechanical properties of the swaged pieces which improved dramatically and remained favorable up to high temperatures.