Outperformance in Acrylation: Supported D-Glucose-Based Ionic Liquid Phase on MWCNTs for Immobilized Lipase B from Candida antarctica as Catalytic System

This study presents a highly efficient method of a synthesis of n-butyl acrylate via esterification of acrylic acid and n-butanol in the presence of supported ionic liquid phase (SILP) biocatalyst consisting of the lipase B from Candida antarctica (CALB) and multi-walled carbon nanotubes (MWCNTs) modified by D-glucose-based ionic liquids. Favorable reaction conditions (acrylic acid: n-butanol molar ratio 1:2, cyclohexane as a solvent, biocatalyst 0.150 g per 1 mmol of acrylic acid, temperature 25 °C) allowed the achievement of a 99% yield of n-butyl acrylate in 24 h. Screening of various ionic liquids showed that the most promising result was obtained if N-(6-deoxy-1-O-methoxy-α-D-glucopyranosyl)-N,N,N-trimethylammonium bis-(trifluoromethylsulfonyl)imide ([N(CH₃)₃GlcOCH₃][N(Tf)₂]) was selected in order to modify the outer surface of MWCNTs. The final SILP biocatalyst–CNTs-[N(CH₃)₃GlcOCH₃][N(Tf)₂]-CALB contained 1.8 wt.% of IL and 4.2 wt.% of CALB. Application of the SILP biocatalyst led to the enhanced activity of CALB in comparison with the biocatalyst prepared via physical adsorption of CALB onto MWCNTs (CNTs-CALB), as well as with commercially available Novozyme 435. Thus, the crucial role of IL in the stabilization of biocatalysts was clearly demonstrated. In addition, a significant stability of the developed biocatalytic system was confirmed (three runs with a yield of ester over 90%).     

Tomonaga–Luttinger Spin Liquid and Kosterlitz–Thouless Transition in the Spin-1/2 Branched Chains: The Study of Topological Phase Transition

In the present work, we provide a comprehensive numerical investigation of the magnetic properties and phase spectra of three types of spin-1/2 branched chains consisting of one, two and three side spins per unit block with intra-chain interaction and a uniform inter-chain interaction in the presence of an external magnetic field. In a specific magnetic field interval, the low-temperature magnetization of these chains shows a step-like behavior with a pronounced plateau depending on the strength and the type of intra-chain interaction being ferromagnetic or antiferromagnetic. We demonstrate that when inter-chain interaction J1 is antiferromagnetic and intra-chain interaction J2 is ferromagnetic, the magnetization of the models manifests a smooth increase without a plateau, which is evidence of the existence of a Luttinger-like spin liquid phase before reaching its saturation value. On the other hand, when J1 is ferromagnetic and J2 is antiferromagnetic, the low-temperature magnetization of the chain with two branches shows an intermediate plateau at one-half of the saturation magnetization that breaks a quantum spin liquid phase into two regions. The magnetization of the chain with three branches exhibits two intermediate plateaus and two regions of a quantum spin liquid. We demonstrate that the chains with more than one side spin illustrate in their ground-state phase diagram a Kosterlitz–Thouless transition from a gapful phase to a gapless spin liquid phase.     

Clean Electrochemical Synthesis of Pd–Pt Bimetallic Dendrites with High Electrocatalytic Performance for the Oxidation of Formic Acid

Pd–Pt bimetallic catalysts with a dendritic morphology were in situ synthesized on the surface of a carbon paper via the facile and surfactant-free two step electrochemical method. The effects of the frequency and modification time of the periodic square-wave potential (PSWP) on the morphology of the Pd–Pt bimetallic catalysts were investigated. The obtained Pd–Pt bimetallic catalysts with a dendritic morphology displayed an enhanced catalytic activity of 0.77 A mg⁻¹, almost 2.5 times that of the commercial Pd/C catalyst reported in the literature (0.31 A mg⁻¹) in acidic media. The enhanced catalytic activity of the Pd–Pt bimetallic catalysts with a dendritic morphology towards formic acid oxidation reaction (FAOR) was not only attributed to the large number of atomic defects at the edges of dendrites, but also ascribed to the high utilization of active sites resulting from the “clean” electrochemical preparation method. Besides, during chronoamperometric testing, the current density of the dendritic Pd–Pt bimetallic catalysts for a period of 3000 s was 0.08 A mg⁻¹, even four times that of the commercial Pd/C catalyst reported in the literature (about 0.02 A mg⁻¹).