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1.
Interventions in concrete heritage deal with challenges related to conservation, and must be performed from an integrated restoration perspective. In addition to the material technical performance, the aesthetic compatibility between the repair and the structure, in terms of colour and texture, needs to be ensured. Therefore, the characterisation of the restoration mortar concerning colour match and aging, and the mechanical and durability performances, is essential. In this article, the long-term behaviour of restoration mortar, previously designed and produced by the addition of pigments to white and grey cement-based reference mortar, is evaluated. The durability properties, colour change due to aging, and service life are estimated and analysed. An experimental program is performed to characterise the following properties: (i) water capillary absorption; (ii) accelerated carbonation; (iii) migration of chloride ions; (iv) electrical resistivity; and (v) shrinkage. The colour evolution, when exposed to carbonation, is measured through image processing. The obtained results allow the establishment of a correlation between durability and design parameters. Finally, service life considering deterioration due to steel corrosion is estimated, considering the carbonation resistance and the chloride diffusion values. It is concluded that the W/C ratio influences not only most of the characterised parameters, but also the type and content of the pigment. Furthermore, no colour variation due to carbonation is detected.  相似文献   

2.
Under corrosive environments, concrete material properties can deteriorate significantly, which can seriously affect structural safety. Therefore, it has important engineering applications to improve the durability performance at a lower economic cost. This paper proposes a new, highly durable concrete using inexpensive construction materials such as basalt fiber, sodium methyl silicate, and inorganic aluminum salt waterproofing agent. With the massive application of sewage treatment projects, the problem of concrete durability degradation is becoming more and more serious. In this paper, five types of concrete are developed for the sewage environment, and the apparent morphology and fine structure of the specimens after corrosion in sewage were analyzed. The density, water absorption, and compressive strength were measured to investigate the deterioration pattern of concrete properties. It was found that ordinary concrete was subject to significant corrosion, generating large deposits of algae on the surface and accompanied by sanding. The new concrete showed superior corrosion resistance compared to conventional concrete. Among other factors, the inorganic aluminum salt waterproofing agent effect was the most prominent. The study found that the strength of ordinary concrete decreased by about 15% in the test environment, while the new concrete had a slight increase. Comprehensive evaluation showed that the combination of basalt fiber and inorganic aluminum salt waterproofing agent had the best effect. Its use is recommended.  相似文献   

3.
The macroscopic mechanical properties and frost resistance durability of concrete are closely related to the changes in the internal pore structure. In this study, the two-dimensional and three-dimensional ICT (Industrial Computerized Tomography) pore characteristics of C30 concrete specimens before and after freezing and thawing in clean water, 5 wt.% NaCl, 5 wt.% CaCl2, and 5 wt.% CH3COOK solution environments are obtained through concrete frost resistance durability test and ICT scanning technology. The effects of pore structure changes on concrete frost resistance, durability, and compressive strength mechanical properties after freezing and thawing cycles in different salt solution environments are analyzed. This paper provides new means and ideas for the study of concrete pores. The results show that with the increase in the freezing and thawing times, the concrete porosity, two-dimensional pore area, three-dimensional pore volume, and pore number generally increase in any solution environment, resulting in the loss of concrete compressive strength, mortar spalling, and the decrease in the relative dynamic elastic modulus. Among them, the CH3COOK solution has the least influence on the concrete pore changes; the NaCl solution has the greatest influence on the change in the concrete internal porosity. The damage of CaCl2 solution to concrete is second only to the NaCl solution, followed by clean water. The increase in the concrete internal porosity from high to low is NaCl, CaCl2, clean water, and CH3COOK. The change in the pore volume of 0.1 to 1 mm3 after the freeze–thaw cycle is the main factor for reducing concrete strength. The test results have certain guiding value for the selection of deicing salt in engineering.  相似文献   

4.
The improved performance of recycled aggregate has an important impact on its use in engineering. In this study, to improve the weak surface properties, recycled aggregates were treated by nano-silica slurry and applied to concrete beam specimens. Under the action of cracks caused by continuous load and drying-wetting cycles with chloride ingress, the effects of different recycled aggregate additions, nano-silica contents and crack widths on the self-healing performance of cracks and the resistance to chloride ingress of the recycled concrete beams were investigated. It was found that the self-healing rate of cracks increased first and then decreased with increased nano-silica content, reaching a maximum when the content reached 0.4%. Greater amounts of additive in the recycled aggregate increased the concentration of free chloride ions in cracks. However, this concentration was found to be weakened in nano-reinforced aggregate. From a comprehensive perspective, the relative chloride ion concentration can be effectively reduced by controlling the crack width to be smaller than 0.12 mm and using improved recycled aggregates treated with 0.2% nano-silica material. This study provides a reference for the application of recycled aggregate concrete under severe environmental and load conditions.  相似文献   

5.
The influence of a chloride-ion adsorption agent (Cl agent in short), composed of zeolite, calcium aluminate hydrate and calcium nitrite, on the ingress of chloride ions into concrete and mortar has been experimentally studied. The permeability of concrete was measured, and the chloride ion content in mortar was tested. The experimental results reveal that the Cl agent could adsorb chloride ions effectively, which had penetrated into concrete and mortar. When the Cl agent was used at a dosage of 6% by mass of cementitious materials in mortar, the resistance to the penetration of chloride ions could be improved greatly, which was more pronounced when a combination of the Cl agent and fly ash or slag was employed. Such an effect is not the result of the low permeability of the mortar, but might be a result of the interaction between the Cl agent and the chloride ions penetrated into the mortar. There are two possible mechanisms for the interaction between the Cl agent and chloride ion ingress. One is the reaction between calcium aluminate hydrate in the Cl agent and chloride ions to form Friedel’s salt, and the other one is that calcium aluminate hydrate reacts with calcium nitrite to form AFm during the early-age hydration of mortar and later the NO2 in AFm is replaced by chloride ions, which then penetrate into the mortar, also forming Friedel’s salt. More research is needed to confirm the mechanisms.  相似文献   

6.
The wastewater from ready-mixed concrete plants is currently being recycled as concrete mixing water. It has attracted significant attention from the construction industry and researchers since it promotes sustainable development through environmental protection, energy-saving, and emissions reduction. This article review first introduces the nature of wastewater in ready-mixed concrete plants in different regions. Then the effects of solid content in water on various properties of concrete, including working performance, durability and microscopic properties, are reviewed, respectively, when concrete is mixed with wastewater instead of tap water. Furthermore, the microscopic mechanism of action in concrete mixing with wastewater is discussed, and future work is recommended. This review provides fundamentals on the study of the properties of concrete after wastewater is mixed into concrete.  相似文献   

7.
Cement mortar can be colored using color additive technology to give colorful facades to the surfaces of buildings, and to beautify the environment. In this study, weight ratios of color powder/cement at 1:80, 1:40, and 1:27, and polyacrylic emulsion/cement at a ratio of 1:5 were added as pigments to cement mortar; the fresh properties, slump, slump flow, hardened properties, compressive strength, flexural strength, ultrasonic pulse velocity, durability, surface electrical resistivity and thermal conductivity of the colored cement mortar were then examined. The results showed that adding color powder/cement at 1:80 and polyacrylic emulsion/cement at 1:5 gives the best water/cement (W/C) ratio, which equals 0.5; this can effectively improve the hardness and durability of colored cement mortar. At 28 days of aging, the strength of the various colored cement mortars was maintained at 33.1–36.8 MPa. The acrylic-based emulsion significantly improved the flexural strength of the specimen. At 91 days of aging, all of the cement mortars exceeded the control group, with an anti-bay strength of 19.9–21.7 MPa, and the strength increased with aging. Adding appropriate amounts of inorganic color powder and mixing water can effectively enhance the fresh and hardened properties and durability of the colored cement mortar, while polyacrylic emulsion may significantly improve the test pieces and flexural strength, which increases with age. Moreover, natural α-Fe2O3 (rust layer) is formed on the surface of the colored cement mortar samples through the addition of inorganic color powder that contains Fe(III) ion; this prevents the intrusion of noxious ions and thus increases the durability. All of the test pieces of colored cement mortar in this study had a surface resistance of over 20 kΩ-cm on the seventh day of the test period, meaning good surface compactness. In addition, because the thermal conductivity of the added inorganic color powder was higher than that of cement, the thermal conductivity was significantly improved.  相似文献   

8.
With the increasing importance of offshore wind turbines, a critical issue in their construction is the high-performance concrete (HPC) used for grouting underwater foundations, as such materials must be better able to withstand the extremes of the surrounding natural environment. This study produced and tested 12 concrete sample types by varying the water/binder ratio (0.28 and 0.30), the replacement ratios for fly ash (0%, 10%, and 20%) and silica fume (0% and 10%), as substitutes for cement, with ground granulated blast-furnace slag at a fixed proportion of 30%. The workability of fresh HPC is discussed with setting time, slump, and V-funnel flow properties. The hardened mechanical properties of the samples were tested at 1, 7, 28, 56, and 91 days, and durability tests were performed at 28, 56, and 91 days. Our results show that both fly ash (at 20%) and silica fume (at 10%) are required for effective filling of interstices and better pozzolanic reactions over time to produce HPC that is durable enough to withstand acid sulfate and chloride ion attacks, and we recommend this admixture for the best proportioning of HPC suitable for constructing offshore wind turbine foundations under the harsh underwater conditions of the Taiwan Bank. We established a model to predict a durability parameter (i.e., chloride permeability) of a sample using another mechanical property (i.e., compressive strength), or vice versa, using the observable relationship between them. This concept can be generalized to other pairs of parameters and across different parametric categories, and the regression model will make future experiments less laborious and time-consuming.  相似文献   

9.
《Materials》2022,15(8)
The topic of sustainability of reinforced concrete structures is strictly related with their durability in aggressive environments. In particular, at equal environmental impact, the higher the durability of construction materials, the higher the sustainability. The present review deals with the possible strategies aimed at producing sustainable and durable reinforced concrete structures in different environments. It focuses on the design methodologies as well as the use of unconventional corrosion-resistant reinforcements, alternative binders to Portland cement, and innovative or traditional solutions for reinforced concrete protection and prevention against rebars corrosion such as corrosion inhibitors, coatings, self-healing techniques, and waterproofing aggregates. Analysis of the scientific literature highlights that there is no preferential way for the production of “green” concrete but that the sustainability of the building materials can only be achieved by implementing simultaneous multiple strategies aimed at reducing environmental impact and improving both durability and performances.  相似文献   

10.
Over the vast Northwest China, arid desert contains high concentrations of sulfate, chloride, and other chemicals in the ground water, which poses serious challenges to infrastructure construction that routinely utilizes portland cement concrete. Rapid industrialization in the region has been generating huge amounts of mineral admixtures, such as fly ash and slags from energy and metallurgical industries. These industrial by-products would turn into waste materials if not utilized in time. The present study evaluated the suitability of utilizing local mineral admixtures in significant quantities for producing quality concrete mixtures that can withstand the harsh chemical environment without compromising the essential mechanical properties. Comprehensive chemical, mechanical, and durability tests were conducted in the laboratory to characterize the properties of the local cementitious mineral admixtures, cement mortar and portland cement concrete mixtures containing these admixtures. The results from this study indicated that the sulfate resistance of concrete was effectively improved by adding local class F fly ash and slag, or by applying sulfate resistance cement to the mixtures. It is noteworthy that concrete containing local mineral admixtures exhibited much lower permeability (in terms of chloride ion penetration) than ordinary portland cement concrete while retaining the same mechanical properties; whereas concrete mixtures made with sulfate resistance cement had significantly reduced strength and much increased chloride penetration comparing to the other mixtures. Hence, the use of local mineral admixtures in Northwest China in concrete mixtures would be beneficial to the performance of concrete, as well as to the protection of environment.  相似文献   

11.
In this paper, supplementary cementitious materials are used as a substitute for cement to decrease carbon dioxide emissions. A by-product of the iron manufacturing industry, ground granulated blast-furnace slag (GGBS), known to improve some performance characteristics of concrete, is used as an effective cement replacement to manufacture mortar samples. Here, the influence of curing conditions on the durability of samples including various amounts of GGBS is investigated experimentally and numerically. Twelve high-strength Portland cement CEM I 52.5 N samples were prepared, in which 0%, 45%, 60%, and 80% of cement were substituted by GGBS. In addition, three curing conditions (standard, dry, and cold curing) were applied to the samples. Durability aspects were studied through porosity, permeability, and water absorption. Experimental results indicate that samples cured in standard conditions gave the best performance in comparison to other curing conditions. Furthermore, samples incorporating 45% of GGBS have superior durability properties. Permeability and water absorption were improved by 17% and 18%, respectively, compared to the reference sample. Thereafter, data from capillary suction experiments were used to numerically determine the hydraulic properties based on a Bayesian inversion approach, namely the Markov Chain Monte Carlo method. Finally, the developed numerical model accurately estimates the hydraulic characteristics of mortar samples and greatly matches the measured water inflow over time through the samples.  相似文献   

12.
A significant part of reinforced concrete structures is subjected to intensive environmental impact during operation. This can cause local destruction and failure of buildings if obligatory measures are not taken to protect them from corrosion. This is especially true for industrial buildings, where the environment could be contaminated with aggressive products or waste. An important issue is the development of methods for calculating the load-bearing capacity and serviceability of reinforced concrete structures with corrosion damage. The main reason for this is the necessity to determine the durability and reliability of buildings and structures and the estimation of their safe operation time. As corrosion damages of concrete are a critical issue, more detailed experimental studies are needed. This paper presents experimental studies of concrete prisms under the simultaneous action of an aggressive environment and a constant level of compressive force. In total, 32 prisms under different loading conditions and in different aggressive medium were tested. Samples were divided in series, for which different load levels were chosen (0.25fck, 0.35fck, 0.45fck). Additionally, control samples in the air and immersed in water were tested. During the experiment, different parameters were monitored and recorded: decrease of cross-sectional size, the temperature and environmental humidity. Results of the study showed that destruction occurred due to the presence of corrosion damages of concrete and a reduction of the cross-sectional area. The stresses in the concrete at the destruction stage were less than the value of the prism strength by 10–12%. It was established that along the contour of the section, there is a partially degraded layer of concrete of 1.5–3.7 mm thickness, with corrosion microcracks and corrosion products. Additionally, experimental and theoretical diagrams of concrete with corrosion damages were obtained and compared. The ultimate deformations of concrete with corrosion damage, which correspond to the prismatic strength of concrete, in comparison with undamaged concrete were lower by 11–18%. Therefore, the concrete strength is decreased during exploitation under loading in an aggressive environment, which needs to be taken into account during calculations.  相似文献   

13.
The objective of this research was to study the effect of an optimal mechanical treatment method to reduce the mortar adhered on recycled aggregates (RCA) on the long-term mechanical properties and durability of concretes containing RCA at different replacement levels. It was found that concretes incorporating treated RCA exhibited sharper and more significant increase on 90- and 365-day compressive strengths than any other investigated mixture. The same mixtures also benefitted from a ‘shrinkage-controlling’ effect, where strains and mass losses were reduced by almost 15% and 10%, respectively, compared to the reference concrete. While sulfate resistance and carbonation resistance are predominantly defined by the hydration products available within the cement paste and not to a large extent by the aggregate type and quality, the incorporation of either treated or untreated RCA in concrete did not appear to expose RACs to significant durability threats.  相似文献   

14.
In this study, the potential application of slag-fly ash-based geopolymers as stabilizers for soft soil in sulfate erosion areas was investigated to promote environmental protection and waste residue recycling. The changes in the physical and mechanical properties and microstructure characteristics of cement-stabilized soil/geopolymer-stabilized soil under sulfate erosion were comparatively studied through tests such as appearance change, mass change, strength development, and microscopic examination. The results show that the sulfate resistance of stabilized soil is significantly affected by the stabilizer type. In the sulfate environment, the cement-stabilized soil significantly deteriorates with erosion age due to the expansion stress induced by AFt, while the geopolymer-stabilized soil exhibits excellent sulfate resistance. The slag-fly ash ratio (10:0, 9:1, 8:2 and 7:3) is an important factor affecting the sulfate resistance of geopolymer-stabilized soils, and the preferred value occurs at 9:1 (G-2). When immersed for 90 d, the unconfined compressive strength value of G-2 is 7.13 MPa, and its strength retention coefficient is 86.6%. The N-A-S-H gel formed by the polymerization in the geopolymer contributes to hindering the intrusion of sulfate ions, thereby improving the sulfate resistance of stabilized soil. The research results can provide a reference for technology that stabilizes soil with industrial waste in sulfate erosion areas.  相似文献   

15.
Polymer-modified concrete and fiber concrete are two excellent paving materials that improve the performance of some concrete, but the performance of single application material is still limited. In this paper, polymer-modified concrete with strong deformation and fiber concrete with obvious crack resistance and reinforcement effect were compounded by using the idea of composite material design so as to obtain a high-performance pavement material. The basic mechanical properties of high-content hybrid fiber–polymer-modified concrete, such as workability, compression, flexural resistance, and environmental durability (such as sulfate resistance) were studied by using the test regulations of cement concrete in China. The main results were as follows. (1) The hybrid fiber–polymer concrete displayed reliable working performance, high stiffness, and a modulus of elasticity as high as 35.93 GPa. (2) The hybrid fiber–polymer concrete had a compressive strength of 52.82 MPa, which was 31.2% higher than that of the plain C40 concrete (40.25 MPa); the strength of bending of the hybrid concrete was 11.51 MPa, 191.4% higher than that of the plain concrete (3.95 MPa). (3) The corrosion resistance value of the hybrid fiber–polymer concrete was 81.31%, indicating its adjustability to sulfate attack environments. (4) According to cross-sectional scanning electron microscope (SEM) images, the hybrid fiber–polymer concrete was seemingly more integrated with a dense layer of cementing substance on its surface along with fewer microholes and microcracks as when compared to the ordinary concrete. The research showed that hybrid fiber–polymer concrete had superior strength and environmental erosion resistance and was a pavement material with superior mechanical properties.  相似文献   

16.
The use of a high volume of industrial solid waste mineral admixture and hybrid fiber can greatly reduce the amount of cement in mortar or concrete, improve its performance, ensure the service properties of mortar or concrete, and reuse industrial solid waste to reduce the environmental burden, which has significant research significance. In this paper, the mechanical properties, wear resistance and microstructure of hybrid fiber-reinforced mortar (HFRM) with a high content of industrial solid waste mineral admixture were systematically studied under different water/binder ratios. Mineral admixtures include fly ash, silica fume and granulated blast furnace slag (slag). The total content of hybrid glass fiber (GF) and polypropylene fiber (PPF) was 2% by volume fractions, and six different water/binder ratios ranging from 0.27 to 0.62 were used. The following conclusions were drawn: fibers have a significant negative effect on the properties of mortars with a low water/binder ratio (w/b = 0.27) and high content of mineral admixtures. In general, the effect of adding hybrid fiber on improving the wear resistance of mortar is more obvious. The average residual weight of hybrid fiber-reinforced mortar is the highest after the wear resistance test. Comprehensively considering the compressive strength, flexural strength, wear resistance and microstructure of the mortar samples, G8PP2-0.40 is the optimal mix ratio. At this time, the replacement rates of fly ash, silica fume and slag are: 20%, 5% and 30%, the water/binder ratio is 0.40, and the content of GF and PPF is 1.6% and 0.4%, respectively.  相似文献   

17.
TiMoN coatings with different Mo contents on a SS316L substrate are deposited by using closed field unbalanced magnetron sputtering ion plating (CFUMSIP) technology to enhance the corrosion resistance and durability of stainless steel (SS) bipolar plates (BPs) in proton exchange membrane fuel cell (PEMFC) during the start-up/shut-down process. The electrochemical test results illustrate that TiMoN-4A coating has extremely good corrosion resistance compared to other coatings. The potentiostat polarization (+0.6 VSCE) tests indicate that the corrosion current density (Icorr) of TiMoN-4A coating is 5.22 × 10−7A cm−2, which meets the department of energy 2020 targets (DOE, ≤1 × 10−6 A cm−2). Otherwise, TiMoN-4A coating also exhibits the best corrosion resistance and stability in potentiostatic polarization, electrochemical impedance spectroscopy (EIS), and high potential (+1.2VSCE) polarization tests. The interfacial contact resistance (ICR) measurement results show that TiMoN-4A coating has the minimum ICR of 9.19 mΩ·cm2, which meets the DOE 2020 targets (≤10 mΩ·cm2).  相似文献   

18.
Concrete, as one of the essential construction materials, is responsible for a vast amount of emissions. Using recycled materials and gray water can considerably contribute to the sustainability aspect of concrete production. Thus, finding a proper replacement for fresh water in the production of concrete is significant. The usage of industrial wastewater instead of water in concrete is considered in this paper. In this study, 450 concrete samples are produced with different amounts of wastewater. The mechanical parameters, such as slump, compressive strength, water absorption, tensile strength, electrical resistivity, rapid freezing, half-cell potential and appearance, are investigated, and a specific concentration and impurities of wastewater that cause a 10% compressive strength reduction were found. The results showed that the usage of industrial wastewater does not significantly change the main characteristics of concrete. Although increasing the concentration of wastewater can decrease the durability and strength features of concrete nonlinearly, the negative effects on durability tests are more conspicuous, as utilizing concentrated wastewaters disrupt the formation of appropriate air voids, pore connectivity and pore-size distribution in the concrete.  相似文献   

19.
Ultra-high-performance concrete (UHPC) is a new type of high-performance cement-based composite. It is widely used in important buildings, bridges, national defense construction, etc. because of its excellent mechanical properties and durability. Freeze thaw and salt erosion damage are one of the main causes of concrete structure failure. The use of UHPC prepared with multi-walled carbon nanotubes (MWCNTs) is an effective method to enhance the durability of concrete structures in complex environments. In this work, the optimal mix proportion based on mechanical properties was obtained by changing the content of MWCNTs and water binder ratio to prepare MWCNTs UHPC. Then, based on the changes in the compressive strength, mass loss rate, and relative dynamic modulus of elasticity (RDME), the damage degree of concrete under different salt erosion during 1500 freeze-thaw (FT) cycles was analyzed. The changes in the micro pore structure were characterized by scanning electron microscope (SEM) and nuclear magnetic resonance (NMR). The test results showed that the optimum mix proportion at the water binder ratio was 0.19 and 0.1% MWCNTs. At this time, the compressive strength was 34.1% higher and the flexural strength was 13.6% higher than when the MWCNTs content was 0. After 1500 salt freezing cycles, the appearance and mass loss of MWCNTs-UHPC prepared according to the best ratio changed little, and the maximum mass loss was 3.18%. The higher the mass fraction of the erosion solution is, the lower the compressive strength and RDME of concrete after FT cycles. The SEM test showed that cracks appeared in the internal structure and gradually increased due to salt freezing damage. However, the microstructure of the concrete was still relatively dense after 1500 salt freezing cycles. The NMR test showed that the salt freezing cycle has a significant influence on the change in the small pores, and the larger the mass fraction of the erosion solution, the smaller the change in the proportion of pores. After 1500 salt freezing cycles, the samples did not fail, which shows that MWCNTs UHPC with a design service life of 150 years has good salt freezing resistance under the coupling effect of salt corrosion and the FT cycle.  相似文献   

20.
This numerical study investigates the structural performance of railway sleepers made of ultra high-performance concrete (UHPC). First, numerical concrete sleepers are developed, and the tensile stress-strain relationship obtained from the direct tension test on the UHPC coupons is used for the tensile constitutive model after applying a fiber orientation reduction factor. The numerical sleeper models are validated with the experimental data in terms of the force and crack-width relationship. Second, using the developed models, a parametric study is performed to investigate the performance of the UHPC sleepers while considering various design/mechanical/geometrical parameters: steel fiber contents, size of the cross-section, and diameter and strength of prestressing (PS) tendons. The simulation results indicate that the size of the cross-section has the most impacts on the performance, while the effect of yielding strengths of PS tendons is minimal among all the parameters. Engineers need to pay attention to efficiency and an economical factor when using a larger cross-section, since sleepers with larger cross-sections can be an over-designed sleeper. This study suggests an economical design factor for engineers to evaluate what combination of parameters would be economical designs.  相似文献   

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