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1.
Carbonaceous composites with tailored porous architectures and magnetic Fe3O4 components derived from walnut shells were fabricated by a solvothermal method and used as effective microwave absorbers. The porous composites were obtained by two carbonization processes at different temperatures and an etching process using potassium hydroxide. The introduction of a developed porous architecture inside the resulting materials distinctly improved the microwave absorption performance. Moreover, investigations revealed that the Fe3O4 nanoparticles were chemically bonded and uniformly decorated on the porous framework without aggregation. Owing to the combined advantages of the lightweight conductive biochar-like porous framework with a favorable dielectric loss and Fe3O4 nanoparticles with magnetic loss features, these newly fabricated porous carbonaceous composites exhibited excellent microwave absorption performance. A reflection loss (RL) of −51.6 dB was achieved at a frequency of 13.6 GHz. Besides, the effective absorption (below −10 dB) bandwidth reached 5.8 GHz (from 11.9 to 17.7 GHz) at an absorber thickness of only 2 mm. These results indicated that this type of porous Fe3O4–biochar composite derived from biomass substances and prepared via an easy-to-handle process can be considered as attractive candidates for the design and manufacture of high-efficiency microwave-absorbing materials.A novel type of Fe3O4/WPC-600 with a tailored porous architecture and magnetic components has been facilely fabricated for significantly enhanced microwave absorption performance. 相似文献
2.
The NiCo2O4 nanowires and reduced graphene oxide (rGO) hybrid nanostructure has been constructed on carbon fibers (NiCo2O4/rGO/CF) via a hydrothermal method. The effects of graphene oxide (GO) concentration on the structure and performance of the NiCo2O4/rGO/CF were investigated in detail to obtain the optimized electrode. When the GO concentration was 0.4 mg ml−1, the rGO/NiCo2O4/CF composite exhibited a maximum specific capacitance of 931.7 F g−1 at 1 A g−1, while that of NiCo2O4/CF was 704.9 F g−1. Furthermore, the NiCo2O4/rGO/CF//AC asymmetric supercapacitor with a maximum specific capacitance of 61.2 F g−1 at 1 A g−1 was fabricated, which delivered a maximum energy density (24.6 W h kg−1) and a maximum power density (8477.7 W kg−1). Results suggested that the NiCo2O4/rGO/CF composite would be a desirable electrode for flexible supercapacitors.The NiCo2O4 nanowires and rGO hybrid nanostructure was constructed on carbon fibers (NiCo2O4/rGO/CF) via a hydrothermal method. 相似文献
3.
Interconnected mesoporous sheet-like ZnCo2O4 nanomaterials directly grown on a three-dimensional (3D) graphene film (GF) coated on Ni foam (NF) have been successfully synthesized via an effective chemical vapor deposition (CVD) method combined with a subsequent hydrothermal route. When the ZnCo2O4@3DGF@NF composite material with a high surface area of 46.06 m2 g−1 is evaluated as a binder-free anode material for lithium ion batteries, it exhibits a superior electrochemical performance with a high discharge capacity (1223 mA h g−1 at a current density of 500 mA g−1 after 240 cycles), and an excellent reversibility (coulombic efficiency of 97–99%). Such an outstanding electrochemical performance may be attributed to its unique mesoporous sheet-like nanostructure with a 3DGF supporting, which can facilitate the electrolyte penetration and accelerate the ion/electron transport, as well as buffer the volume variation during charge/discharge processes.Mesoporous ZnCo2O4 nanomaterials grown on a three-dimensional (3D) graphene film (GF) coated on Ni foam (NF) have been synthesized via an effective chemical vapor deposition (CVD) method combined with a subsequent hydrothermal route. 相似文献
4.
Ayesha Khan Tareen Karim Khan Waqas Ahmad Muhammad Farooq Khan Qudrat Ullah Khan Xinke Liu 《RSC advances》2021,11(31):19316
A MnO–CrN composite was obtained via the ammonolysis of the low-cost nitride precursors Cr(NO3)3·9H2O and Mn(NO3)2·4H2O at 800 °C for 8 h using a sol–gel method. The specific surface area of the synthesized powder was measured via BET analysis and it was found to be 262 m2 g−1. Regarding its application, the electrochemical sensing performance toward hydrogen peroxide (H2O2) was studied via applying cyclic voltammetry (CV) and amperometry (i–t) analysis. The linear response range was 0.33–15 000 μM with a correlation coefficient (R2) value of 0.995. Excellent performance toward H2O2 was observed with a limit of detection of 0.059 μM, a limit of quantification of 0.199 μM, and sensitivity of 2156.25 μA mM−1 cm−2. A short response time of within 2 s was achieved. Hence, we develop and offer an efficient approach for synthesizing a new cost-efficient material for H2O2 sensing.A MnO–CrN composite was obtained via the ammonolysis of the low-cost nitride precursors Cr(NO3)3·9H2O and Mn(NO3)2·4H2O at 800 °C for 8 h using a sol–gel method. 相似文献
5.
Activated carbon@Fe3O4 composites with good electromagnetic wave absorption performances in the low frequency range were synthesized via the hydrothermal method. The crystal structure, microstructure, magnetization properties, frequency-dependent electromagnetic properties and microwave absorption properties of the as-prepared composites were characterized via XRD, VSM, SEM, TEM and VNA, respectively. The results indicated that the electromagnetic wave absorption performance of the composites can be adjusted through the addition of activated carbon. A suitable loading content of Fe3O4 NPs on activated carbon can also enhance the microwave absorption performance of the composites. The synergy of dielectric and magnetic loss is the main electromagnetic wave absorption mechanism, and the maximum RL of −10.08 dB at 1.75 GHz with a −5 dB bandwidth over the frequency range of 1.55 GHz (1.07–2.62 GHz) is obtained when the percentage of Fe3O4 NPs and the thickness of the composites are 74 wt% and 5 mm, respectively. Hence, the composite reported in this study can be used as a promising microwave absorbing material in the low frequency range of 0.5–3 GHz.Activated carbon@Fe3O4 composites with good electromagnetic wave absorbing performances in the low frequency range were synthesized via a hydrothermal method. 相似文献
6.
Tingting Liu Shuai Zhou Xuehan Yu Chao Mao Yujie Wei Xinyong Yu Lei Chen Xin Zhao Guoxing Tian Ling Chen 《RSC advances》2022,12(7):4029
NiCo2O4@reduced graphene oxide (rGO)/nickel foam (NF) composites were prepared via a hydrothermal method followed by annealing assisted by hexadecyl trimethyl ammonium bromide (CTAB). NiCo2O4@rGO/NF nanoneedle arrays grew directly on Ni foam (NF) without using a binder. The effect of graphene oxide (GO) concentration on the electrochemical properties of the composite was studied. When the GO concentration was 5 mg L−1, the as-prepared NiCo2O4@rGO/NF reaches the highest specific capacitance of 1644 F g−1 at a current density of 1 A g−1. Even at 15 A g−1, the specific capacitance is still 1167 F g−1 and the capacitance retention rate is 89% after 10 000 cycles at 10 A g−1. Furthermore, a NiCo2O4@rGO/NF//graphene hydrogel (GH) asymmetric supercapacitor cell (ASC) device was assembled and exhibits a high specific capacitance of 84.13 F g−1 at 1 A g−1 and excellent cycle stability (113% capacitance retention) after 10 000 charge/discharge cycles at 10 A g−1. This provides potential for application in the field of supercapacitors due to the outstanding specific capacitance, rate performance and cycle stability of NiCo2O4@rGO/NF.Anisotropic NiCo2O4 nanoneedle arrays grew directly on Ni foam in the presence of rGO via the hydrothermal method followed by annealing assisted by hexadecyl trimethyl ammonium bromide (CTAB). 相似文献
7.
Hierarchical NiO/Ni3V2O8 nanoplatelet arrays (NPAs) grown on Ti foil were prepared as free-standing anodes for Li-ion batteries (LIBs) via a simple one-step hydrothermal approach followed by thermal treatment to enhance Li storage performance. Compared to the bare NiO, the fabricated NiO/Ni3V2O8 NPAs exhibited significantly enhanced electrochemical performances with superior discharge capacity (1169.3 mA h g−1 at 200 mA g−1), excellent cycling stability (570.1 mA h g−1 after 600 cycles at current density of 1000 mA g−1) and remarkable rate capability (427.5 mA h g−1 even at rate of 8000 mA g−1). The excellent electrochemical performances of the NiO/Ni3V2O8 NPAs were mainly attributed to their unique composition and hierarchical structural features, which not only could offer fast Li+ diffusion, high surface area and good electrolyte penetration, but also could withstand the volume change. The ex situ XRD analysis revealed that the charge/discharge mechanism of the NiO/Ni3V2O8 NPAs included conversion and intercalation reaction. Such NiO/Ni3V2O8 NPAs manifest great potential as anode materials for LIBs with the advantages of a facile, low-cost approach and outstanding electrochemical performances.Hierarchical NiO/Ni3V2O8 nanoplatelet arrays (NPAs) grown on Ti foil were prepared as free-standing anodes for Li-ion batteries (LIBs) via a simple one-step hydrothermal approach followed by thermal treatment to enhance Li storage performance. 相似文献
8.
Metal–organic framework-derived materials are now considered potential next-generation electrode materials for supercapacitors. In this present investigation, Co3O4@MnO2 nanosheets are synthesized using ZIF-67, which is used as a sacrificial template through a facile hydrothermal method. The unique vertically grown nanosheets provide an effective pathway for rapidly transporting electrons and ions. As a result, the ZIF-67 derived Co3O4@MnO2-3 electrode material shows a high specific capacitance of 768 C g−1 at 1 A g−1 current density with outstanding cycling stability (86% retention after 5000 cycles) and the porous structure of the material has a good BET surface area of 160.8 m2 g−1. As a hybrid supercapacitor, Co3O4@MnO2-3//activated carbon exhibits a high specific capacitance (82.9 C g−1) and long cycle life (85.5% retention after 5000 cycles). Moreover, a high energy density of 60.17 W h kg−1 and power density of 2674.37 W kg−1 has been achieved. This attractive performance reveals that Co3O4@MnO2 nanosheets could find potential applications as an electrode material for high-performance hybrid supercapacitors.Metal–organic framework-derived materials are now considered potential next-generation electrode materials for supercapacitors. 相似文献
9.
Xinyang Zhang Ziqing Zhang Shuanggan Sun Yunpeng Wu Qiushi Sun Xiaoyang Liu 《RSC advances》2018,8(27):15222
In this contribution, NiFe2O4@NiFe2O4 nanosheet arrays (NSAs) with three-dimensional (3D) hierarchical core–shell structures were synthesized by a facile one-step hydrothermal method and they were used as electrode materials for supercapacitors (SCs). The NiFe2O4@NiFe2O4 composite electrode showed a high specific capacitance of 1452.6 F g−1 (5 mA cm−2). It also exhibited a superior cycling stability (93% retention after 3000 cycles). Moreover, an asymmetric supercapacitor (ASC) was constructed utilizing NiFe2O4@NiFe2O4 NSAs and activated carbon (AC) as the positive and negative electrode, respectively. The optimized ASC shows extraordinary performances with a high energy density of 33.6 W h kg−1 at a power density of 367.3 W kg−1 and an excellent cycling stability of 95.3% capacitance retention over 3000 cycles. Therefore, NiFe2O4@NiFe2O4 NSAs have excellent pseudocapacitance properties and are good electrode materials for high energy density.Hierarchical NiFe2O4@NiFe2O4 core–shell nanosheet arrays synthesized via one-step hydrothermal method with a successive annealing exhibited outstanding electrochemical performance. 相似文献
10.
In order to realize the characteristics of new types of wave-absorbing materials, such as strong absorption, broad bandwidth, low weight and small thickness, a hollow-structured flower-like Fe3O4@MoS2 composite was successfully prepared by simple solvothermal and hydrothermal methods in this paper. The structural properties were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Besides, the microwave properties and magnetic properties were measured using a vector network analyzer and via a hysteresis loop. SEM and TEM images revealed that MoS2 nanosheets grew on the surface of hollow nanospheres. The results showed that the composite exhibited excellent absorbing property. When the molar ratio of Fe3O4 and MoS2 was 1 : 18, the minimum reflection loss value reached −49.6 dB at 13.2 GHz with a thickness of 2.0 mm and the effective absorption bandwidth was 4.24 GHz (11.68–15.92 GHz). Meanwhile, the effective absorption in the entire X-band (8–12 GHz) and part of the C-band (4–8 GHz) and Ku-band (12–18 GHz) could be achieved by designing the sample thickness. In addition, the hollow structure effectively reduced the density of the material, which was in line with the current development trend of absorption materials. It could be predicted that the hollow core–shell structure composite has a potential application prospect in the field of microwave absorption.A hollow-structured flower-like Fe3O4@MoS2 composite was synthesized. The minimum reflection loss value reached −49.6 dB at 13.2 GHz with a thickness of 2.0 mm and the effective absorbing bandwidth was 4.24 GHz (11.68–15.92 GHz). 相似文献
11.
Orthorhombic phase V2O5 nanosheets with a high V4+ content (V-V2O5) have been fabricated via a facile sol–gel method and freeze-drying technology followed with a vacuum annealing process. XPS tests demonstrated that the content of V4+ in the as-prepared V-V2O5 sample was 7.4%, much higher than that (4.7%) in the V2O5 sample annealed in air. Compared with the V2O5 annealed in air, the V-V2O5 sample exhibited better cycling stability, higher lithium storage activity, and smaller electrochemical reaction resistance when evaluated as a cathode active material for lithium ion batteries. For example, the specific capacity of the V-V2O5 and V2O5 electrodes after 100 cycles at 200 mA g−1 are 224.7 and 199.2 mA h g−1, respectively; after 200 cycles at 3 A g−1 are 150 and 136.7 mA h g−1, respectively.Orthorhombic phase V2O5 nanosheets with a high V4+ content (V-V2O5) have been fabricated via a facile sol–gel method and freeze-drying technology followed with a vacuum annealing process. 相似文献
12.
Hongliang Zhao Zhifan Song Hanxi Gao Biqian Li Tao Hu Fengqin Liu Hong Yong Sohn 《RSC advances》2020,10(68):41403
Graphene sheets that contain porous iron oxides including Fe2O3 and FeOOH nanorods were synthesized via a one-step hydrothermal route. A novel mechanism for controlling the structure of graphene-based composites was developed. Porous FeOOH nanorods with a high capacity for electron- and ion-transport were synthesized by controlling the composition of GO dispersion. The synthesized graphene/FeOOH composite anode exhibited an excellent electrochemical performance in which a reversible capacity of 304 mA h g−1 was reached with nearly 100% coulombic efficiency after 1000 cycles of charge and discharge under a high current rate of 5 A g−1.GO acts as a structure-directing template in the crystal growth of FeOOH and Fe2O3. 相似文献
13.
Gorkshnath H. Gote Mansi Pathak Mahendra A. More Dattatray J. Late Chandra Sekhar Rout 《RSC advances》2019,9(56):32573
Pristine and Au-decorated Bi2O3/Bi2WO6 nanocomposites were synthesized via a facile hydrothermal method. Characterization techniques such as XRD, FESEM, HRTEM and XPS were used to explore the structural, morphological and electronic properties. Furthermore, electrochemical characterizations including cyclic voltammetry (CV), the galvanostatic charge–discharge (GCD) method, and electrochemical impedance spectroscopy (EIS) were performed to investigate the supercapacitance behaviour of the synthesized materials. Interestingly, the Au-decorated Bi2O3/Bi2WO6 nanocomposite showed a higher capacitance of 495.05 F g−1 (1 M aqueous KOH electrolyte) with improved cycling stability (99.26%) over 2000 cycles, measured at a current density of 1 A g−1, when compared to the pristine Bi2O3/Bi2WO6 composite (capacitance of 148.81 F g−1 and good cycling stability (95.99%) over 2000 cycles at a current density of 1 A g−1). The results clearly reveal that the decoration of the Bi2O3/Bi2WO6 composite with Au nanoparticles enhances its supercapacitance behaviour, which can be attributed to an increase in electrical conductivity, good electrical contact between the electrode and electrolyte, and an increase in effective area. The Au-decorated Bi2O3/Bi2WO6 nanocomposite can be considered as an electrode material for supercapacitor application.Pristine and Au-decorated Bi2O3/Bi2WO6 nanocomposites were synthesized via a facile hydrothermal method, and find its application in supercapacitor. 相似文献
14.
ZnCo2O4 nanosheets were successfully arrayed on a Ni foam surface with graphene using a hydrothermal method followed by annealing treatment; then MnO2 nanoparticles were electrodeposited on the ZnCo2O4 nanosheets to obtain a synthesized composite binder-free electrode named MnO2/ZnCo2O4/graphene/Ni foam (denoted as MnO2/ZnCo2O4/G/NF). After testing the binder-free composite electrode of MnO2/ZnCo2O4/G/NF via cyclic voltammetry, galvanostatic charge–discharge and electrochemical impedance spectroscopy testing, we found that it exhibited ultrahigh electrochemical properties, with a high specific areal capacitance of 3405.21 F g−1 under a current density of 2 A g−1, and wonderful cycling stability, with 91.2% retention after 5000 cycles. Moreover, an asymmetric supercapacitor (ASC) based on MnO2/ZnCo2O4/G/NF//G/NF was successfully designed. When tested, the as-designed ASC can achieve a maximum energy density of 46.85 W h kg−1 at a power density of 166.67 W kg−1. Finally, the ASC we assembled can power a commercial red LED lamp successfully for more than 5 min, which proves its practicability. All these impressive performances indicate that the MnO2/ZnCo2O4/graphene composite material is an outstanding electrode material for electrochemical capacitors.Schematic illustration of formation process of MnO2/ZnCo2O4/G/NF composite electrode. 相似文献
15.
Jianwei Zhou Chubei Wang Chen Zhou Fangfang Duo Liangliang Chu Mingliang Zhang 《RSC advances》2022,12(51):33449
Two-dimensional vertically aligned Bi2O3 nanosheets over carbon paper (CP) were prepared via an in situ growth approach. Bi2O3/CP exhibits a robust photocatalytic activity, as well as renewability and flexibility. With Rhodamine B and 2,4-dichlorophenol used as target pollutants, the rate constant of Bi2O3/CP was 3.72 × 10−3 min−1 and 6.93 × 10−3 min−1 under visible-light irradiation for 2 h, respectively. The improved activity was attributed to the synergistic effects of the hierarchical structure of Bi2O3 and the conductive substrate, CP; the former provided efficient catalytic sites for the pollutants and absorbed more of the light scattered among the nanosheets, while the latter is beneficial to the photogenerated electron transfer.Two-dimensional vertically aligned Bi2O3 nanosheets over carbon paper (CP) were prepared via an in situ growth approach. 相似文献
16.
Hongyuan Shen Binbin Liu Zanxiang Nie Zixuan Li Shunyu Jin Yuan Huang Hang Zhou 《RSC advances》2021,11(24):14408
The high specific capacity, low cost and environmental friendliness make manganese dioxide materials promising cathode materials for zinc-ion batteries (ZIBs). In order to understand the difference between the electrochemical behavior of manganese dioxide materials with different valence states, i.e., Mn(iii) and Mn(iv), we investigated and compared the electrochemical properties of pure MnO2 and Mn2O3 as ZIB cathodes via a combined experimental and computational approach. The MnO2 electrode showed a higher discharging capacity (270.4 mA h g−1 at 0.1 A g−1) and a superior rate performance (125.7 mA h g−1 at 3 A g−1) than the Mn2O3 electrode (188.2 mA h g−1 at 0.1 A g−1 and 87 mA h g−1 at 3 A g−1, respectively). The superior performance of the MnO2 electrode was ascribed to its higher specific surface area, higher electronic conductivity and lower diffusion barrier of Zn2+ compared to the Mn2O3 electrode. This study provides a detailed picture of the diversity of manganese dioxide electrodes as ZIB cathodes.MnO2 and Mn2O3 cathodes for zinc ion batteries were experimentally and computationally explored. 相似文献
17.
In this study, ultrahigh electrochemical performance for interconnected meso/macro-porous 2D C@α-Fe2O3 synthesized via sucrose-assisted microwave combustion is demonstrated. Hematite (α-Fe2O3) synthesized via the same approach gave an encouraging electrochemical performance close to its theoretical value, justifying its consideration as a potential supercapacitor electrode material; nonetheless, its specific capacitance was still low. The pore size distribution as well as the specific surface of bare α-Fe2O3 improved from 145 m2 g−1 to 297.3 m2 g−1 after it was coated with sucrose, which was endowed with ordered symmetric single-layer graphene (2D graphene). Accordingly, the optimized hematite material (2D C@α-Fe2O3) showed a specific capacitance of 1876.7 F g−1 at a current density of 1 A g−1 and capacity retention of 95.9% after 4000 cycles. Moreover, the material exhibited an ultrahigh energy density of 93.8 W h kg−1 at a power density of 150 W kg−1. The synergistic effect created by carbon-coating α-Fe2O3 resulted in modest electrochemical performance owing to extremely low charge transfer resistance at the electrode–electrolyte interface with many active sites for ionic reactions and efficient diffusion process. This 2D C@α-Fe2O3 electrode material has the capacity to develop into a cost-effective and stable electrode for future high-energy-capacity supercapacitors.In this study, ultrahigh electrochemical performance for interconnected meso/macro-porous 2D C@α-Fe2O3 synthesized via sucrose-assisted microwave combustion is demonstrated. 相似文献
18.
Gold nanoclusters (Au NCs), which have the characteristics of small size, near infrared (NIR) absorption and long triplet excited lifetime, have been used as a new type of photosensitizer for deep tissue photodynamic therapy (PDT). However, the therapeutic efficiency of the nano-system based on Au NCs still needs to be improved. Herein, we proposed a strategy using Mito-Au25@MnO2 nanocomposites to achieve enhanced PDT. Au25(Capt)18− nanoclusters were applied as photosensitizers and further modified with peptides to target mitochondrial and MnO2 nanosheets to consume glutathione (GSH). In the presence of GSH, Mito-Au25@MnO2 dis-integrated and Mito-Au25 nanoparticles realized accurate mitochondrial targeting. Under the irradiation of 808 nm light, the nanocomposite ensured highly efficient PDT both in vitro and in vivo via oxidation pressure elevation and mitochondrial targeting in cancer cells.This is the first example of mitochondrial targeting Au NCs capable of improving the efficiency of photodynamic therapy. Mito-Au25@MnO2 can be activated by consuming GSH and elevating oxidation pressure in cancer cells. 相似文献
19.
Srinivasa N. Shreenivasa L. Prashanth S. Adarakatti Jack P. Hughes Samuel J. Rowley-Neale Craig E. Banks Ashoka S. 《RSC advances》2019,9(43):24995
We present a rapid, environmentally benign one-pot synthesis technique for the production of a NiCo2O4/CoO and graphite composite that demonstrates efficient electrocatalysis towards the Oxygen Evolution Reaction (OER), in 1.0 M KOH. The NiCo2O4/CoO/graphitic carbon composite that displayed optimal OER catalysis was synthesized by nitrate decomposition in the presence of citric acid (synthesized glycine and sucrose variants displayed inferior electro kinetics towards the OER). Screen-printed electrodes modified with ca. 530 μg cm−2 of the citric acid NiCo2O4/CoO/graphite variant displayed remarkable OER catalysis with an overpotential (η) of +323 mV (vs. RHE) (recorded at 10 mA cm−2), which is superior to that of IrO2 (340 mV) and RuO2 (350 mV). The composite also exhibited a large achievable current density of 77 mA cm−2 (at +1.5 V (vs. RHE)), a high O2 turnover frequency of 1.53 × 10−2 s−1 and good stability over the course of 500 repeat cycles. Clearly, the NiCo2O4/CoO composite has the potential to replace precious metal based catalysts as the anodic material within electrolysers, thereby providing a reduction in the associated costs of hydrogen production via water splitting.A facile synthesis technique for the production of NiCo2O4/CoO and graphite composites that demonstrate efficient electrocatalysis towards the oxygen evolution reaction. 相似文献
20.
Uniform pea-like yolk–shell (PLYS) structured magnetic TiO2(PLYS-Fe3O4@TiO2) nanosheets have been prepared via a combined kinetics-controlled mechanical force-driven and hydrothermal etching assisted crystallization method and characterized. The resulting PLYS-Fe3O4@TiO2 nanosheets possess well defined yolk–shell structures with a large BET surface area (∼187.26 m2 g−1) and a strong magnetic susceptibility (∼17.4 emu g−1). The reaction rate constant was 24.2 × 10−2 min−1 as a result of oxidative decomposition of BPA using UV/PLYS-Fe3O4@TiO2/H2O2 system. This is 1.1 and 8.34 times faster than the BPA decomposition reaction rate constant in UV/TiO2/H2O2 and UV/Fe3O4/H2O2 systems, respectively. The synthesized catalyst also exhibited excellent recycle capability and excellent acid decomposition performance.Uniform pea-like yolk–shell (PLYS) structured magnetic TiO2(PLYS-Fe3O4@TiO2) nanosheets have been prepared via a combined kinetics-controlled mechanical force-driven and hydrothermal etching assisted crystallization method and characterized. 相似文献