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A new triterpenoid from Entodon okamurae Broth
Authors:Zhang Wen  Lou Hong-Xiang  Li Guang-Yao  Wu Hou-Ming
Institution:  a School of Pharmacy, Shandong University, Shandong Jinan, China b The State Key Laboratory of Bioorganic and Natural Product Chemistry, Shanghai Institute of Organic Chemistry, Shanghai, China
Abstract:One new triterpenoid, entokamurol (1), was isolated from Entodon okamurae Broth, together with other nine compounds, namely dryocrassol (2), chrysophamol (3), physcion (4), 10-nonacosamnol (5), n-hexadecanol (6), phthalic acid isodibutyl ester (7), curcumol (8), β-sitosterol (9) and daucosterol (10). Their structures were elucidated on the basis of extensive NMR (DEPT, DQF-COSY, HMQC, HMBC and NOESY), IR and MS studies. All the compounds were isolated and identified from the genus of Entodon for the first time, and it is also the first report of a guaiane-type sesquiterpenoid and compounds with anthraquinone skeleton in mosses.
Keywords:Broth  Entokamurol  Triterpenoid  Sesquiterpenoid  Anthraquinone
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