首页 | 本学科首页   官方微博 | 高级检索  
检索        

煤燃烧过程中痕量元素溴和碘的释放行为
引用本文:高运川,吴晓伟,孙明星,高勤芬,刘勇弟.煤燃烧过程中痕量元素溴和碘的释放行为[J].医学教育探索,2010(4):482-487.
作者姓名:高运川  吴晓伟  孙明星  高勤芬  刘勇弟
作者单位:华东理工大学资源与环境工程学院环境工程系,上海 200237; 上海师范大学生命与 环境科学学院,上海 200234;上海师范大学生命与环境科学学院,上海 200234;上海市出入境检验检疫局,上海 200135;浙江省质量技术监督检测研究院,杭州 310013;华东理工大学资源与环境工程学院环境工程系,上海 200237
摘    要:以小型管式炉模拟煤燃烧过程,采用电感耦合等离子质谱法(ICPMS)分析测定煤燃烧过程中气相、颗粒相及底渣中溴和碘的含量,考察了燃烧温度、燃烧气氛对溴、碘释放的影响以及溴、碘的释放行为。结果表明:溴、碘的释放程度随燃烧温度升高而增加,随燃烧气氛中氧气浓度的增加而降低。在实验条件下,碘几乎全部分布于气相中;溴主要分布在气相和颗粒相,在底渣中也有分布;固体添加剂可以在燃烧过程中对溴和碘进行有效捕捉。

关 键 词:    煤燃烧            痕量元素    电感耦合等离子质谱法

Behavior of Trace Elements Bromine and Iodine during Coal Combustion Process
GAO Yun chuan,WU Xiao wei,SUN Ming xing,GAO Qin fen and LIU Yong di.Behavior of Trace Elements Bromine and Iodine during Coal Combustion Process[J].Researches in Medical Education,2010(4):482-487.
Authors:GAO Yun chuan  WU Xiao wei  SUN Ming xing  GAO Qin fen and LIU Yong di
Institution:School of Resources and Environmental Engineering, East China University of Science and Technology, Shanghai 200237, China; College of Life and Environmental Sciences, Shanghai Normal University, Shanghai 200234, China;College of Life and Environmental Sciences, Shanghai Normal University, Shanghai 200234, China;Shanghai Entry Exit Inspection & Quarantine Bureau, Shanghai 200135, China;Zhejiang Test Academy of Quality and Technical Supervision, Hangzhou 310013, China;School of Resources and Environmental Engineering, East China University of Science and Technology, Shanghai 200237, China
Abstract:A sampling and inductively coupled plasma mass spectrometry(ICP MS) analysis procedure was described for determining bromine and iodine concentrations of vapor phase, particulate matter and residue in the simulative combustion in a small stove. The effects of the combustion temperature and combustion atmosphere on the release of bromine and iodine were investigated. Experimental results showed that the release of bromine and iodine increased with an increase of temperature, decreased with the increase of oxygen concentration. At the given experimental condition, iodine was observed almost entirely in the vapor phase, while bromine was observed dominantly in the vapor phase and particulate matter, as well as in residue, respectively. Solid additives could capture bromine and iodine effectively during coal combustion process.
Keywords:coal  coal combustion  bromine  iodine  trace element  ICP MS
点击此处可从《医学教育探索》浏览原始摘要信息
点击此处可从《医学教育探索》下载免费的PDF全文
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号