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Fe2(SO4)3氧化脱除煤中无机硫的研究
引用本文:马岩,张望,黄胜,吴诗勇,吴幼青,高晋生.Fe2(SO4)3氧化脱除煤中无机硫的研究[J].医学教育探索,2014(5):568-572.
作者姓名:马岩  张望  黄胜  吴诗勇  吴幼青  高晋生
作者单位:华东理工大学资源与环境工程学院,煤气化及能源化工教育部重点实验室,上海 200237;华东理工大学资源与环境工程学院,煤气化及能源化工教育部重点实验室,上海 200237;华东理工大学资源与环境工程学院,煤气化及能源化工教育部重点实验室,上海 200237;华东理工大学资源与环境工程学院,煤气化及能源化工教育部重点实验室,上海 200237;华东理工大学资源与环境工程学院,煤气化及能源化工教育部重点实验室,上海 200237;华东理工大学资源与环境工程学院,煤气化及能源化工教育部重点实验室,上海 200237
基金项目:国家重点基础研究发展(973)计划(2012CB214903)
摘    要:以3种高硫煤为对象,考察了反应温度、反应时间、Fe2(SO4)3溶液浓度和原煤粒度等因素对Fe2(SO4)3溶液热处理脱硫效果的影响,并对脱硫前后原煤理化性质的变化进行了研究。结果表明:在Fe2(SO4)3溶液浓度为1 mol/L,反应温度为90 ℃,反应时间为4 h,煤粒度小于0.096 mm的条件下,原煤中黄铁矿硫的脱除率高达67%,而煤中的有机硫含量并无明显的变化;升高反应温度,增加Fe2(SO4)3溶液浓度,延长反应时间以及减小原煤粒径均可在一定程度上提高原煤的黄铁矿硫和全硫的脱硫率;经Fe2(SO4)3溶液处理后原煤的黏结性均出现了不同程度的下降,其中新峪煤完全失去了黏结性;Fe2(SO4)3溶液脱除原煤中无机硫主要是通过Fe3+的强氧化性将黄铁矿硫氧化为SO2-4进而脱除。

关 键 词:    脱硫    硫酸铁    黄铁矿
修稿时间:2013/10/28 0:00:00

Removal of Inorganic Sulfur from Coal by Fe2(SO4)3 Oxidation Method
MA Yan,ZHANG Wang,HUANG Sheng,WU Shi-yong,WU You-qing and GAO Jin-sheng.Removal of Inorganic Sulfur from Coal by Fe2(SO4)3 Oxidation Method[J].Researches in Medical Education,2014(5):568-572.
Authors:MA Yan  ZHANG Wang  HUANG Sheng  WU Shi-yong  WU You-qing and GAO Jin-sheng
Institution:Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, School of Resource and Environmental Engineering, East China University of Science and Technology, Shanghai 200237, China;Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, School of Resource and Environmental Engineering, East China University of Science and Technology, Shanghai 200237, China;Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, School of Resource and Environmental Engineering, East China University of Science and Technology, Shanghai 200237, China;Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, School of Resource and Environmental Engineering, East China University of Science and Technology, Shanghai 200237, China;Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, School of Resource and Environmental Engineering, East China University of Science and Technology, Shanghai 200237, China;Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, School of Resource and Environmental Engineering, East China University of Science and Technology, Shanghai 200237, China
Abstract:
Keywords:coal  desulfurization  ferric sulfate  pyrite
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