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中温加压下镁基吸附剂CO2吸附和再生性能研究
引用本文:魏彬,商春芳,黄胜,吴诗勇,吴幼青,高晋生.中温加压下镁基吸附剂CO2吸附和再生性能研究[J].医学教育探索,2014(5):573-578.
作者姓名:魏彬  商春芳  黄胜  吴诗勇  吴幼青  高晋生
作者单位:华东理工大学煤气化及能源化工教育部重点实验室,上海 200237;华东理工大学煤气化及能源化工教育部重点实验室,上海 200237;华东理工大学煤气化及能源化工教育部重点实验室,上海 200237;华东理工大学煤气化及能源化工教育部重点实验室,上海 200237;华东理工大学煤气化及能源化工教育部重点实验室,上海 200237;华东理工大学煤气化及能源化工教育部重点实验室,上海 200237
基金项目:SHELL GLOBAL SOLUTIONS INTERNATIONAL B.V.项目(SSR 166)
摘    要:以一种镁基前驱物和一种矿物黏结剂为原料,采用湿混法经煅烧及水合制备得到镁基吸附剂,考察了吸附温度和吸附压力对其CO2吸附性能的影响,并利用XRD、SEM和BET对其理化性质进行了表征。结果表明:镁基吸附剂经水合后的活性组分为Mg(OH)2,当吸附温度为300 ℃、吸附压力为2 MPa时其CO2穿透吸附量达3.93 mmol/g;吸附剂水合过程中生成叶蛇纹石,降低了Mg的利用率,吸附过程中在吸附剂表面生成的块状产物层阻碍了CO2内扩散的进行;在中温加压条件下此吸附剂能够达到稳定的18次吸附 再生循环,适用于整体煤气化联合循环发电(IGCC)系统中CO2的脱除。

关 键 词:镁基吸附剂    CO2捕集    穿透吸附量    再生
修稿时间:2014/2/24 0:00:00

CO2 Adsorption and Regeneration Properties of a Magnesium Based Sorbent under Moderate Temperature and Pressured Condition
WEI Bin,SHANG Chun-fang,HUANG Sheng,WU Shi-yong,WU You-qing and GAO Jin-sheng.CO2 Adsorption and Regeneration Properties of a Magnesium Based Sorbent under Moderate Temperature and Pressured Condition[J].Researches in Medical Education,2014(5):573-578.
Authors:WEI Bin  SHANG Chun-fang  HUANG Sheng  WU Shi-yong  WU You-qing and GAO Jin-sheng
Institution:Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, East China University of Science and Technology, Shanghai 200237, China;Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, East China University of Science and Technology, Shanghai 200237, China;Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, East China University of Science and Technology, Shanghai 200237, China;Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, East China University of Science and Technology, Shanghai 200237, China;Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, East China University of Science and Technology, Shanghai 200237, China;Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, East China University of Science and Technology, Shanghai 200237, China
Abstract:
Keywords:Key words: magnesium based sorbent  CO2 capture  breakthrough capacity  regeneration
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