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不对称电化学电容器的大电流充放电性能
引用本文:胡耀强,詹亮,杨俊和,张睿,梁晓怿,凌立成.不对称电化学电容器的大电流充放电性能[J].医学教育探索,2007(5):619-623.
作者姓名:胡耀强  詹亮  杨俊和  张睿  梁晓怿  凌立成
作者单位:华东理工大学化学工程联合国家重点实验室;上海应用技术学院材料科学与工程系;
基金项目:国家自然科学基金(50672025);;上海市科委资助项目
摘    要:采用Ni(OH)2和比表面积为1114 m2/g的活性炭分别作正、负电极材料,不对称电化学电容器(67 mm×20 mm×170 mm)在0.24 A/s的放电速率下,电容量达14000 F,6000次反复充放电的容量衰减为9.4%,72 h后的自放电为17%。分析表明:高比表面积活性炭的表面化学性质、杂质含量以及测试温度都将影响不对称电化学电容器的容量稳定性。

关 键 词:电化学电容器  不对称电极  活性炭  

Charge/Discharge Electrode Properties of Asymmetry Electrochemical Capacitor with High Currents
HU Yao-qiang,ZHAN Liang,YANG Jun-he,ZHANG Rui,LIANG Xiao-yi,LING Li-cheng.Charge/Discharge Electrode Properties of Asymmetry Electrochemical Capacitor with High Currents[J].Researches in Medical Education,2007(5):619-623.
Authors:HU Yao-qiang  ZHAN Liang  YANG Jun-he  ZHANG Rui  LIANG Xiao-yi  LING Li-cheng
Institution:1.State Key Laboratory of Chemical Engineering;East China University of Science and Technology;Shanghai 200237;China;2.Department of Materials Science and Engineering;Shanghai Institute of Technology;Shanghai 200235;China
Abstract:Electrochemical capacitor with 67 mm length,20 mm width and 170 mm height,was assembled with asymmetry electrode,in which Ni(OH)_2 and activated carbon was used as the anode and cathode electrode materials,respectively.High capacitance was given of 14 000 F with the high discharge velocity of 0.24 A/s if activated carbon with the specific surface area of 1 114 m~2/g was chosen. Moreover,its(capacitance) would keep high and decrease only 9.4% even if it was charged and discharged repeatedly from 1.6 to 0.8 V...
Keywords:electrochemical capacitor  asymmetry electrode  activated carbon  
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