Carbon paste electrodes of the mixed oxide SiO2/Nb2O5 prepared by the sol–gel method: dissolved dioxygen sensor

A carbon paste of SiO₂/Nb₂O₅ material was used as the electrode in the development of a dissolved dioxygen sensor in 1.0 mol l^?1 KCl solution at pH 6.2. The material was prepared by the sol–gel method. In the investigation of its electrochemical properties, linear and cyclic voltammetric and chronoamperometric techniques were employed. Dioxygen reduction, which was diffusion controlled, occurred at ?280 mV vs. SCE by a two electron mechanism, producing peroxide. A linear response between the cathodic peak current intensity and the dissolved O₂ concentration was obtained for the region between 1.0 and 13.6 mg l^?1. The stability proved to be very good over successive voltammetric cycles. The electrode response time was about 5 s. The electron transfer reactions were explained as being to an n-type semiconductor of niobia dispersed in the silica surface.