Voltammetric lability of multiligand complexes: the case of ML2 |
| |
| Authors: | Jaume Puy Joan Cecilia Josep Galceran Raewyn M. Town Herman P. van Leeuwen |
| |
| Affiliation: | 1. Departament de Qu??mica, Universitat de Lleida (UdL), Av. Rovira Roure, 191. E-25198 Lleida, Catalonia, Spain;2. Departament de Matemàtica, Universitat de Lleida (UdL), Av. Rovira Roure, 191. E-25198 Lleida, Catalonia, Spain;3. School of Chemistry, The Queen''s University of Belfast, Belfast BT9 5AG, UK;4. Laboratory of Physical Chemistry and Colloid Science, Wageningen University, P.O. Box 8038, Dreijenplein 6, 6703 HB Wageningen, The Netherlands |
| |
| Abstract: | ![]()
The voltammetric lability of a complex system, where a metal ion M and a ligand L form the species ML and ML2, is examined. Together with the rigorous numerical simulation of the problem, two limiting cases are analysed for the overall process ML2 → M: (i) the most common case for aqueous complexes, where ML → M is the kinetically limiting step and (ii) the case where ML2 → ML is limiting. In both cases, analytical expressions for the lability criteria are provided which show good agreement with the results obtained from the rigorous numerical simulation of the problem. |
| |
| Keywords: | Voltammetry Lability Reaction layer Kinetic currents |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
