| 含氧和氮的四氯化钛络合物催化双环戊二烯开环移位聚合反应的研究 |
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| 引用本文： | 多诺·克莱伯特,黄吉玲,马海燕,钱延龙. 含氧和氮的四氯化钛络合物催化双环戊二烯开环移位聚合反应的研究[J]. 医学教育探索, 1999, 0(4) |
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| 作者姓名： | 多诺·克莱伯特 黄吉玲 马海燕 钱延龙 |
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| 作者单位： | 华东理工大学金属有机化学研究室 |
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| 摘 要： | 报道了ＴｉＣｌ４·２［Ｃ６Ｈ８Ｏ］（１）；ＴｉＣｌ４·２［Ｃ８Ｈ１１Ｎ］（２）；ＴｉＣｌ４·２［Ｏ（ＣＨ２）４ＣＨ２］（３）；ＴｉＣｌ４·２［Ｃ６Ｈ７Ｎ］（４）；ＴｉＣｌ４·２［Ｃ５Ｈ５Ｎ］（５）；ＴｉＣｌ４·２［Ｃ４Ｈ８Ｏ２］（６）催化双环戊二烯开环移位聚合反应并对６个影响因素进行了讨论，由此得到了优化的反应条件。
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| 关 键 词： | 双环戊二烯（DCPD）；开环移位聚合反应；四氯化钛络合物 |
Ring Opening Metathesis Polymerisation of Dicyclopentadiene=Catalysed by Titanium Tetracloride Adduct Complexes=Containing Nitrogen or Oxygen Ligand |
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| Keleypette Dono,Huang Jiling,Ma Haiyan and Qian Yanlong. Ring Opening Metathesis Polymerisation of Dicyclopentadiene=Catalysed by Titanium Tetracloride Adduct Complexes=Containing Nitrogen or Oxygen Ligand[J]. Researches in Medical Education, 1999, 0(4) |
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| Authors: | Keleypette Dono Huang Jiling Ma Haiyan Qian Yanlong |
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| Abstract: | The ring opening metathesis polymerisation of dicyclopentadiene (DCPD) catalysed by TiCl42 ( 1 ):TiCl4211N]( 2 );TiCl42 ( 3 );TiCl42 ( 4 );TiCl42 (5 );TiCl42 ( 6Z) is reported.These catalysis appear to exhibit good catalytic activity in the polymerisation reaction.After a detailed investigation of some influencing parameters,the optimised reaction conditions were obtained. |
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| Keywords: | ring opening metathesis polymerisation (ROMP) dicyclopentadiene (DCPD) titanium tetrachloride adduct complexes |
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