| Abstract: | Poly(enaminonitriles) containing flexible alkyl ether units were prepared by reacting p-bis(1-chloro-2,2-dicyanovinyl)benzene with various α,ω-bis(4-aminophenoxy)alkanes in N-methyl-2-pyrrolidone (NMP). All the polymers are soluble in polar aprotic solvents such as N,N-dimethylformamide (DMF), dimethyl sulfoxide (DMSO), N,N-dimethylacetamide (DMAc) and NMP as well as in common organic solvents such as tetrahydrofuran and acetone. High molecular weight polymers possessing inherent viscosities in the range of 0.82–1.20 dL/g were obtained and tough films were cast from a DMF solution. They showed a large exotherm around 340°C attributable to the chemical changes of the dicyanovinyl group. Thermogravimetric analyses exhibited a good thermal stability with a 10% weight loss around 450°C and 73–88% residual weight at 500°C under nitrogen. |
