Stereochemical aspects of diels-alder reaction of substituted penta-2,4-dienols and maleic anhydride derivatives |
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Authors: | Deukjoon Kim Moohi Yoo Kim |
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Affiliation: | 1. College of Pharmacy, Seoul National University, San 56-1, Shinrim-Dong, Kwanak-Ku, 151, Seoul, Korea 2. Central Research Institute, Dong-A Pharmaceutical Co., Ltd., 252, Yongdu-Dong, Dongdaemun-Ku, 131, Seoul, Korea
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Abstract: | Reaction of diene alcohol5 and maleic anhydride in benzene at either room temperature or reflux proceeds probably through a intermolecular Diels-Alder cycloaddition followed by lactone formation to give adduct6. |
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