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满山香化学成分的研究
引用本文:陈业高,秦国伟,谢毓元. 满山香化学成分的研究[J]. 中国中药杂志, 2001, 26(10): 694-697
作者姓名:陈业高  秦国伟  谢毓元
作者单位:1. 云南师范大学化学系,
2. 中国科学院上海药物研究所,
摘    要:目的 :从满山香茎藤中分离鉴定化学成分。方法 :溶剂提取及柱色谱法分离 ,光谱技术鉴定结构。结果 :分得 6个联苯环辛二烯木脂素 ,tigloylgomisinP(1) ,angeloylgomisinO(2) ,angeloylisogomisinO(3) ,kadsulignanL(4) ,(±) 5,8-epoxyl-6 ,7-dimethyl-2′ ,3′ ,2″ ,3″-dimethylenedioxy-4′ ,1″-dimethyl-1,2∶3,4-dibenzo-1,3-cyclooctadiene(5)和五味子丙素 (6)。结论 :化合物 4和 5为首次自五味子属植物中发现的6 ,9位形成氧桥环的木脂素 ,其余化合物均系首次自本植物中分得。

关 键 词:满山香  五味子科  联苯环辛二烯木脂素  kadsulignan L  tigloylgomisin P
文章编号:1001-5302(2001)10-0694-03
收稿时间:2000-09-04
修稿时间:2000-09-04

Studies on Chemical Constituents of Schisandra propinqua (Wall.) Hook. f. et Thoms
CHEN Ye gao ;QIN Guo wei ;XIE Yun yuan. Studies on Chemical Constituents of Schisandra propinqua (Wall.) Hook. f. et Thoms[J]. China Journal of Chinese Materia Medica, 2001, 26(10): 694-697
Authors:CHEN Ye gao   QIN Guo wei   XIE Yun yuan
Affiliation:Department of Chemistry, Yunnan Normal University, Kunming 650092, Yunnan, China.
Abstract:OBJECTIVE: To isolate and characterize compounds from the stems of Schisandra propinqua. METHOD: Extracting with solvent, isolating by column chromatography and identifying by the spectroscopic methods. RESULT: Six dibenzocyclooctadiene lignans were isolated and identified as tigloylgomisin P(1), angeloylgomisin O(2), angeloylisogomisin O(3), kadsulignan L(4), (+/-) 5,8-epoxyl-6, 7-dimethyl-2',3',2",3"-dimethylenedioxy-4', 1"-dimethyl-1,2:3,4-dibenzo-1, 3-cyclooctadiene(5) and wuweizisu C(6). CONCLUSION: Compounds 4 and 5 were the first two dibenzocyclooctadiene lignans with an 6,9-epoxy bridge cycle discovered in the genus Schisandra. The others were originally isolated from S. propinqua.
Keywords:Schisandra propinqua  Schisandraceae  dibenzocyclooctadiene lignans  kadsulignan L  tigloylgomisin P
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