Preparation and Study of Composite Materials of the NiAl-Cr-Mo-Nanoparticles (ZrO2, MgAl2O4) System

Materials based on the NiAl-Cr-Mo system with zirconium oxide or aluminum-magnesium spinel nanoparticle small additions were obtained by spark plasma sintering. Thermodynamic modeling was carried out to predict the phase formation in the NiAl-Cr-Mo system and its change depending on temperature, considering the presence of a small amount of carbon in the system. The phase composition and microstructure of materials were studied. NiAl (B2) and CrMo phases were found in the sintered samples. Bending strength measurements at different temperatures shows that nanoparticles of insoluble additives lead to an increase in bending strength, especially at high temperatures. A fractographic analysis of the sample’s fractures shows their hybrid nature and intercrystalline fracture, which is confirmed by the clearly visible matrix grains similar to cleavage. The maximum strength at 700 °C (475 MPa) was found for material with the addition of 0.1 wt.% zirconium oxide nanoparticles. In the study of internal friction, typical peaks of a nickel-aluminum alloy were found in the temperature ranges of 150–200 °C and 350–400 °C.