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Urceolatol,a tetracyclic bromobenzaldehyde dimer from Polysiphonia urceolata
Authors:Q.-W. Liu  C.-H. Tan  T. Zhang  S.-J. Zhang  L.-J. Han  X. Fan
Affiliation:1. Graduate School of the Chinese Academy of Sciences , Beijing, 100039, China;2. Shanghai Institute of Materia Medica, Shanghai Institutes for Biological Sciences, Chinese Academy of Sciences, State Key Laboratory of Drug Research , Shanghai, 201203, China;3. Shandong Engineering Research Center for Natural Drugs , Yantai, 264003, China;4. Institute of Oceanology, Chinese Academy of Sciences , Qingdao, 266071, China
Abstract:
Urceolatol (1), a novel bromobenzaldehyde dimer, together with one known bromophenol, 3-bromo-4,5-dihydroxy-benzaldehyde (2), were isolated from the red alga Polysiphonia urceolata. The structure and absolute stereochemistry of 1 were elucidated to be (5R,10R)-2,7-dibromo-3,8-dihydroxy-5,10-dimethoxyl-5,10-dihydrochromeno[5,4,3-cde]chromene, on the basis of spectroscopic techniques and X-ray diffraction analysis.
Keywords:Urceolatol  Polysiphonia urceolata  Rhodomelaceae  Red alga
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