|
|||||
|
|
| 苯偶氮基萘自组装膜特性的研究 | |
| 引用本文： | 苯偶氮基萘自组装膜特性的研究[J]. 中国药科大学学报, 1999, (4): 71-73. |
| 作者姓名： | 钟文英 顾建华 |
| 作者单位： | 中国药科大学分析化学教研室!南京210009(钟文英)，中国药科大学分析化学教研室!南京210009 (梁宏暸)，东南大学分子电子学实验室!南京210096(顾建华，陆祖宏) |
| 摘 要： | 用自组装技术将１ 巯基 ６ ［１ （４ 苯偶氮基萘氧基 ）］ 己烷自发吸附到透明金膜表面，形成稳定的自组装单层膜（ Ｓ Ａ Ｍ） 。用紫外 可见吸收光谱检测自组装过程，可以看出自组装过程分两个阶段：最初的快速吸附和随后的慢速重组过程。用循环伏安法对膜的电化学性质进行了研究，结果表明，自组装单层分子是定向排布，但并不是紧密堆积的。 |
| 关 键 词： | 巯基化苯偶氮基萘 自组装单层 紫外-可见吸收光谱 电化学 |
Study on Properties of Phenylazonaphthalene Based on Self asse m bled Monolayer |
|
| Study on Properties of Phenylazonaphthalene Based on Self asse m bled Monolayer[J]. Journal of China Pharmaceutical University, 1999, (4): 71-73. | |
| Authors: | Zhong Wenying Liang Hongxi Gu Jianhu Lu Zuhong |
| Affiliation: | Zhong Wenying,Liang Hongxi,Gu Jianhua,Lu Zuhong Department of Analytical Chemistry,China Pharm aceutical University,Nanjing 210009 , 1 National Laboratory of Molecular and Bio molecular Electronics,Southeast University,Nanji |
| Abstract: | By self assembly technology , 1 mercapto 6 [ 1 (4 phenylazonaphthoxy)] hexane was spontaneouslyabsorbed on optically transparent gold . It formed a stable self assembled monolayer( S A M) . The self assembly coursewas monitored by U V visible absorption spectra which gave direct evidence for the self assembly mechanism ,i .e .,adsorbed firstly ,then came through a long time orientation . Meanwhile , Cyclic Voltam mogram was employed to studythe electrochemical properties of S A M. It showed that S A M was well molecular orientation ,but not densely packing . |
| Keywords: | Thiol terminated phenylazonaphthalene Self assembled Monolayer U V visible spectra Electroche mistry |
| 本文献已被 CNKI 维普 等数据库收录！ | |
| 点击此处可从《中国药科大学学报》浏览原始摘要信息 | |
| 点击此处可从《中国药科大学学报》下载全文 | |