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1.
稻秆热解的目的是为了脱除氧元素,增加能量密度,并将热解的固体产物作为生物质气流床气化原料,从而提高气化合成气的热值。稻秆在管式电阻炉中以5℃/min和15℃/min的升温速率进行慢速热解,热解温度为200~800℃。利用自动量热仪和元素分析仪对热解后固体产物进行热值和元素分析。结果表明:同一热解温度下,升温速率越快,半焦的热值越高;碳元素的含量随着热解温度的升高逐渐增加,而氢和氧两种元素的含量随着热解温度的升高逐渐降低。同时,推导出热值与半焦中各元素含量的关系式。  相似文献   

2.
烟煤快速加氢热解,除获取轻质烃和甲烷等气,液产品外,还得到半焦,焦油和水,半焦中残留挥发分。在氢气氛中快速热解生成半焦中的挥发分低于氮气氛,残留挥发分的多少是衡量快速热解反应程度的标志。加氢热解后生成半焦的堆密度仅为原煤的1/3.5,活性半焦直接加氢反应生成甲烷是引起半焦密度减小的主要原因之一。轻质烃产率与焦油生成量有关,焦油加氢二次反应是轻质烃生成的主要途径。氢气氛中热解生成的水多于氮气氛,气相  相似文献   

3.
借助化学分析和FTIR光谱分析对我国煤化程度不同的18 种煤中官能团的研究表明:煤中官能团含量与煤化程度有关;煤中羧基、羟基及醚键等其他含氧官能团的含量与热解生成物CO2、H2O 和CO 的产率有关,脂肪—CH 的含量与甲烷和焦油的产率相关联,芳香—CH 的含量与热解半焦产率有关。煤的热解生成物主要是煤中官能团的断裂所致。  相似文献   

4.
借助化学分析和FTIR光谱分析对我国煤化程度不同的18种煤中官能团的研究表明:煤中官能团含量与煤化程度有关;煤中羧基、羟基及醚键等其他含氧官能团的含量与热解生成物CO2、H2O和CO的产率有关,脂肪-CH的含量与甲烷和焦油的产率相关联,芳香-CH的含量与热解半焦产率有关。煤的热解生成物主要是煤中官能团的断裂所致。  相似文献   

5.
研究表明,PVC在氧气、空气、氢气、氮气以及水蒸气中的脱氯可分3个阶段,低温缓和脱除期、中温快速脱除期和高温缓和脱除期。快速脱氯期的大致温度为180-240℃,其中70%~80%的氯离子在其间被脱除。气氛对脱氯率有显著的影响,氧气氛最有利于PVC材料的热解,随氧气分压的提高,脱氯率相应增加;与氮气相比,氢气也有利于热解;而在水蒸气中的脱氯率最小。各种改性PVC材料的热解性能不尽一致,通过对添加剂邻苯二甲酸二辛脂和硬脂酸钙与PVC树脂混合后的热解研究表明,脱氯性能的差异是由于添加剂的组分和含量的不同造成的。  相似文献   

6.
对我国18种具有代表性的不同煤化程度的煤(Φ3mm),在氢气氛、0.1MPa和900℃条件下进行了热解实验研究。考察了煤化程度对热解转化率和热解产物产率的影响;煤中挥发分与甲烷产率的关系;煤中氧含量与CO、CO2产率的关系以及煤种对热解气热值的影响,得到了描述热解气产率与煤中挥发分的关系式。  相似文献   

7.
生物质延迟焦化技术是一种新型的生物质热解技术,其中生物质颗粒在渣油中的传热是很重要的一个过程,本文构建了生物质颗粒在渣油延迟焦化过程中的传热模型,采用节点数值解法考察了颗粒半径、渣油升温速率以及生物质颗粒与渣油的表面换热系数对颗粒温差的影响,并分析了颗粒内部的温度分布.研究结果表明:颗粒内部最大温差与颗粒半径的平方和渣油升温速率成正比,颗粒壁面与渣油温差和换热系数成反比.  相似文献   

8.
采用吡啶 (Py)、四氢呋喃 (THF) 和CS2作为单一溶剂分别对淮南煤 (HN) 进行了溶胀处理。根据热解气析出速率、组成及热解半焦、焦油、热解水等产物分布,结合热重分析,系统考察了溶胀煤的热解行为。实验结果表明,溶胀煤的热解产物分布有显著改善,热解气体积和热解焦油有不同程度的增加,热解水产率降低;CS2和THF溶胀煤的热解气析出速率明显增大,Py溶胀煤的热解焦油产率最高,比HN原煤热解时产率提高了5.99%(质量分数,干燥无灰基),这表明溶剂和煤结构间有交互作用,从而提高溶胀煤的热解焦油产率。  相似文献   

9.
利用热解炉-高分辨飞行时间质谱联用仪和热解炉-同步辐射光电离飞行时间质谱仪检测不同含硫量的煤IBC105和C22650在热解过程中释放的8种含硫气体,并对这8种含硫气体的释放规律进行了分析.实验结果表明,在200℃—400℃的热解区间内含硫气体释放相对较多,表明硫元素大部分是以有机态的形式在煤中赋存,而且芳香硫相对于脂肪硫含量较多;同时含硫量较高的煤IBC105中噻吩硫的热解释放量,较煤C22650多;由于煤中芳香性有机物的裂解多以苄基的形式出现,因此在两种煤中二苄基硫醚释放量都较噻吩或者苯并噻吩多.  相似文献   

10.
生物质水解残渣中主要含有木质素和少量未水解完全的纤维素和半纤维素。研究了木屑以及水解残渣在氮气氛围下的TG和DTG曲线,着重探索残渣的裂解特性,并与木屑的热解特性作了比较,给出残渣热裂解一级平行动力学模型及其频率因子和活化能。研究表明:木质素是木质纤维素类热裂解产生焦碳的主要来源。随着升温速率的提高,生物质热裂解温度和速率明显提高。  相似文献   

11.
CASE HISTORY A female patient, 46 years old, head of the foreign affairs department of a certain university in Beijing, paid her first visit on October 9, 2006, with the chief complaint of vomiting for one month. She got vomiting after meals in early September. Before that, she had discomfortable sensation in the stomach due to angry with others, but she didn't pay much attention. Later, it developed into vomiting after eating. After the vomiting, the discomfort would be relieved, but with slight hypodynamia. She was once diagnosed as having 'neurogenic vomiting'. Having taken some western and Chinese drugs, the above symptoms were a little bit improved, but she would have nausea upon eating and with regurgitation. Because of the fear for vomiting, she did not dare to have food intake, with body weight reduction of 6 kilos in one month.  相似文献   

12.
Radiotherapy and chemotherapy are the important modern medical therapies for malignant tumors,yet they can also bring about serious local and systemic toxic side reactions so to decrease the patient;'s life quality,manifested by a series of consumptive symptoms.Having engaged in the combined work of Chinese and western medicine for nearly 50 years,the research fellow Qiu Baoguo in Henan Provincial Academy of TCM has developed his unique views on the TCM study of consumptive syndromes.The author of this essay had once the fortune tO follow Dr.Qiu in clinic,and specially would like to introduce in the following Dr.Qiu's experience in treating consumptive syndromes after radio-chemotherapies for patients with malignant tumor.  相似文献   

13.
OBJECTIVE: To observe therapeutic effects of the comprehensive therapy of acupuncture-moxibustion and Chinese Tuina for treatment of insomnia due to deficiency of both the heart and spleen. METHODS: 92 cases were divided randomly into the treatment group (treated by acupuncture-moxibustion and Chinese Tuina) and the control group (treated by acupuncture-moxibustion). RESULTS: The therapeutic effect of the treatment group was obviously superior to that of the control group (the CHI2 test showed P < 0.01). CONCLUSIONS: The comprehensive therapy of acupuncture-moxibustion and Chinese Tuina can give marked therapeutic effects for treatment of insomnia due to deficiency of both the heart and spleen.  相似文献   

14.
15.
Objective: To investigate if there are the CK-19, PDX-1, Nestin, Ngn3 positive cells in the donor islets of different purity in rats. Methods: Thirty male adult SD rats were randomly divided into 3 groups. Islets were isolated using digestion by ductal injection of collagenase. Group Ⅰ (n=10): Separating cell preparations were not purified, Group Ⅱ(n=10): Islet sediment was purified with 25% Ficoll400 ,Group Ⅲ (n=10): Islet sediment was purified with 25% and 11% Ficoll-400. The levels of protein of CK-19, PDX-1, Nestin and Ngn3 were detected by immunohistochemistry and the mRNA of CK-19, PDX-1, Nestin, Ngn3 was amplified by RT-PCR. Results: After two different purification methods applied, three islet preparations of different purities were obtained. The difference of islet purity was significant among various groups (P<0.05). Compared with group Ⅱ and group Ⅲ,the protein and mRNA of CK-19, PDX-1, Nestin,Ngn3 were both higher in group Ⅰ; group Ⅲ was poorly expressed. Conclusions: The three different islet purity donor islet have different CK-19, PDX-1, Nestin, Ngn3 positive cells within them, indicating that there are some islet stem cells in the purified donor islet.  相似文献   

16.
Objective:To investigate the optimum screening conditions of associated proteins in human psoriasis vulgaris by serum proteomics technique, and to screen the different expression proteins related with psoriasis vulgaris. Methods:Serum samples of peripheral blood were collected from newly diagnosed psoriasis vulgaris patients in the clinic, and 20 matched healthy persons. Serum albumin IgG was removed by filtering with ProteoExtract Albumin/IgG. After comparative proteomics analysis the different protein spots were identified using 2-DE and MS. Results :Electrophoresis figures with high resolution and reproducibility were obtained. Three different expression proteins were found only in the serum from psoriasis vulgaris patients, while nine other different proteins expressing from healthy volunteers. Conclusion:The protein expression was different in the serum between the psoriasis vulgaris patients and healthy volunteers. It was hoped that we could find the biomarkers related to psoriasis vulgaris by using proteomics.  相似文献   

17.
PYTOBEZOARS are common bezoars in gastrontestinal tract, commonly seen in stomach and mall intestine,1but huge disopyrobezoars are  相似文献   

18.
CASE HISTORY A male,a retired officer of 61 years old,paid his first visit on May 12,2006.The patient stated that 2 weeks before he suddenly got paroxysmal precordial choking pain,with irregular attacks.Each attack would last several seconds to several minutes.The attack was accompanied with heavy oppressed sensation in the precordial region,palpitation,lassitude,and in severe cases,sweating,which was once diagnosed by a hospital as'coronary heart disease'.Recalling the case history,the patient said that several days before he got angry with others because of some affairs in work,and he was not so used to the life pattern since he had just retired from his busy working post.At usual times,he was quick tempered and peevish.In recent days,he had poor appetite,and loose stool.  相似文献   

19.
The English edition of Chinese Journal of Integrative Medicine is edited and published by the Chinese Journal of Integrated Traditional and Western Medicine Press.Original scientific papers of advanced clinical and experimental medicine in the field of complementary/alternative medicine or integrative medicine are expected.  相似文献   

20.
<正>As culture is the soul of a nation,the three books,"History of Chinese Philosophy,""History of Chinese Culture"and"History of Chinese Science and Technology"have demonstrated the superiority of our great Chinese culture,and its significant impact in the field of international culture.Both core value and practical value of the Chinese culture are very clear,reflected in the views of universe,nature,life,health,disease,and therapy and related considerations,concepts,and technical methods.  相似文献   

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