Effect of Boron-Doped Diamond Interlayer on Cutting Performance of Diamond Coated Micro Drills for Graphite Machining

Thin boron doped diamond (BDD) film is deposited from trimethyl borate/acetone/hydrogen mixture on Co-cemented tungsten carbide (WC-Co) micro drills by using the hot filament chemical vapor deposition (HFCVD) technique. The boron peak on Raman spectrum confirms the boron incorporation in diamond film. This film is used as an interlayer for subsequent CVD of micro-crystalline diamond (MCD) film. The Rockwell indentation test shows that boron doping could effectively improve the adhesive strength on substrate of as deposited thin diamond films. Dry drilling of graphite is chosen to check the multilayer (BDD + MCD) film performance. For the sake of comparison, machining tests are also carried out under identical conditions using BDD and MCD coated micro drills with no interlayer. The wear mechanism of the tools has been identified and correlated with the criterion used to evaluate the tool life. The results show that the multilayer (BDD + MCD) coated micro drill exhibits the longest tool life. Therefore, thin BDD interlayer is proved to be a new viable alternative and a suitable option for adherent diamond coatings on micro cutting tools.     

Tribological Properties of Solid Solution Strengthened Laser Cladded NiCrBSi/WC-12Co Metal Matrix Composite Coatings

NiCrBSi, WC-12Co and NiCrBSi with 30, 40 and 50 wt.% WC-12Co coatings were produced on low carbon steel by laser cladding with an Nd:YAG laser with a multi-jet coaxial cladding-nozzle. The microstructure properties after WC-12Co alloying were investigated by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), electron backscatter diffraction (EBSD) and Vickers hardness tests. The resulting microstructures consisted of a γ-Ni and Ni₃B matrix, strengthened with Co and W, Ni₃Si, CrB, Cr₇C3, Cr₂₃C₆, WC/W₂C phases. In coatings with 30, 40 and 50 wt.% WC-12Co, a solid solution, strengthened multi-matrix NiCrWCo phase formed, which yielded a higher matrix hardness. Wear tests that monitored the friction coefficients were performed with a tribometer that contained a ball-on-disc configuration, Al₂O₃ counter-body and reciprocal sliding mode at room temperature. The major wear mode on the NiCrBSi coatings without the WC-12Co was adhesive with a high wear rate and visible material loss by flaking, delamination and micro-ploughing. The addition of WC-12Co to the NiCrBSi coating significantly increased the wear resistance and changed the major wear mechanism from adhesion to three-body abrasion and fatigue wear.     

Synthesis and Characterization of Multilayered Diamond Coatings for Biomedical Implants

With incredible hardness and excellent wear-resistance, nanocrystalline diamond (NCD) coatings are gaining interest in the biomedical community as articulating surfaces of structural implant devices. The focus of this study was to deposit multilayered diamond coatings of alternating NCD and microcrystalline diamond (MCD) layers on Ti-6Al-4V alloy surfaces using microwave plasma chemical vapor deposition (MPCVD) and validate the multilayer coating's effect on toughness and adhesion. Multilayer samples were designed with varying NCD to MCD thickness ratios and layer numbers. The surface morphology and structural characteristics of the coatings were studied with X-ray diffraction (XRD), Raman spectroscopy, and atomic force microscopy (AFM). Coating adhesion was assessed by Rockwell indentation and progressive load scratch adhesion tests. Multilayered coatings shown to exhibit the greatest adhesion, comparable to single-layered NCD coatings, were the multilayer samples having the lowest average grain sizes and the highest titanium carbide to diamond ratios.     

Boron Doped Diamond for Real-Time Wireless Cutting Temperature Monitoring of Diamond Coated Carbide Tools

Among the unique opportunities and developments that are currently being triggered by the fourth industrial revolution, developments in cutting tools have been following the trend of an ever more holistic control of manufacturing processes. Sustainable manufacturing is at the forefront of tools development, encompassing environmental, economic, and technological goals. The integrated use of sensors, data processing, and smart algorithms for fast optimization or real time adjustment of cutting processes can lead to a significant impact on productivity and energy uptake, as well as less usage of cutting fluids. Diamond is the material of choice for machining of non-ferrous alloys, composites, and ultrahard materials. While the extreme hardness, thermal conductivity, and wear resistance of CVD diamond coatings are well-known, these also exhibit highly auspicious sensing properties through doping with boron and other elements. The present study focuses on the thermal response of boron-doped diamond (BDD) coatings. BDD coatings have been shown to have a negative temperature coefficient (NTC). Several approaches have been adopted for monitoring cutting temperature, including thin film thermocouples and infrared thermography. Although these are good solutions, they can be costly and become impractical for certain finishing cutting operations, tool geometries such as rotary tools, as well as during material removal in intricate spaces. In the scope of this study, diamond/WC-Co substrates were coated with BDD by hot filament chemical vapor deposition (HFCVD). Scanning electron microscopy, Raman spectroscopy, and the van der Pauw method were used for morphological, structural, and electrical characterization, respectively. The thermal response of the thin diamond thermistors was characterized in the temperature interval of 20–400 °C. Compared to state-of-the-art temperature monitoring solutions, this is a one-step approach that improves the wear properties and heat dissipation of carbide tools while providing real-time and in-situ temperature monitoring.     

Experimental Study on High-Speed Milling of SiCf/SiC Composites with PCD and CVD Diamond Tools

Silicon carbide fiber reinforced silicon carbide ceramic matrix composite (SiC_f/SiC composite) is characterized by a high strength-to-density ratio, high hardness, and high temperature resistance. However, due to the brittleness of the matrix material and the anisotropy of the reinforcing phase, it is a huge challenge for machining of the material. The milling method has advantages of a high material removal rate and applicability to complex surface geometry. However, no published literature on milling of SiC_f/SiC composite has been found up to now. In this paper, high-speed milling of SiC_f/SiC composites was carried out under dry conditions and cryogenic cooling using liquid nitrogen, respectively. Polycrystalline diamond (PCD) and chemical vapor deposition (CVD) diamond cutting tools were used for the milling work. The cutting performance of the two kinds of tools in high-speed milling of SiC_f/SiC composites was studied. Tool failure modes and mechanisms were analyzed. The effects of the cooling approach on tool wear and machined surface quality were also investigated. The experimental results showed that under identical cutting parameters and cooling approaches, the PCD tool yielded better cutting performance in terms of a longer tool life and better surface quality than that of the CVD diamond tool. In dry machining, the failure modes of the CVD diamond tool were a large area of spalling on the rake face, edge chipping and severe tool nose fracture, whereas for the PCD tool, only a small area of spalling around the tool nose took place. Compared to the dry machining, the wear magnitudes of both PCD and CVD diamond tools were decreased in cryogenic machining. Additionally, the surface quality also showed significant improvements. This study indicates that the PCD tool is highly suitable for machining of SiC_f/SiC composite, and that the cryogenic method can improve machining efficiency and surface quality.     

Study of PVD AlCrN Coating for Reducing Carbide Cutting Tool Deterioration in the Machining of Titanium Alloys

The manufacture of medical and aerospace components made of titanium alloys and other difficult-to-cut materials requires the parallel development of high performance cutting tools coated with materials capable of enhanced tribological and resistance properties. In this matter, a thin nanocomposite film made out of AlCrN (aluminum–chromium–nitride) was studied in this research, showing experimental work in the deposition process and its characterization. A heat-treated monolayer coating, competitive with other coatings in the machining of titanium alloys, was analyzed. Different analysis and characterizations were performed on the manufactured coating by scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM-EDXS), and X-ray diffraction (XRD). Furthermore, the mechanical behavior of the coating was evaluated through hardness test and tribology with pin-on-disk to quantify friction coefficient and wear rate. Finally, machinability tests using coated tungsten carbide cutting tools were executed in order to determine its performance through wear resistance, which is a key issue of cutting tools in high-end cutting at elevated temperatures. It was demonstrated that the specimen (with lower friction coefficient than previous research) is more efficient in machinability tests in Ti6Al4V alloys. Furthermore, the heat-treated monolayer coating presented better performance in comparison with a conventional monolayer of AlCrN coating.     

Impact of Deposition of the (TiBx/TiSiyCz) x3 Multilayer on M2 HSS on the Cutting Force Components and Temperature Generated in the Machined Area during the Milling of 316L Steel

High-speed steel (HSS) tools account for 20 percent of the cutting tools materials’ global market. This is due to both their significant toughness and resistance to cracking, compared to cemented carbides. Covering steel tools with hard coatings clearly improves their mechanical properties, wear resistance, and significantly increases their durability. Physical vapor deposition methods are preferred for coating metal substrates, as they allow low temperature deposition. The most widely deposited coating materials are carbides, nitrides, and borides. They are combined with softer ones in the multilayer structure to promote increased resistance to cracking and delamination in comparison to monolayered structures. In this paper, the M2 steel end mills were coated by (TiB_x/TiSi_yC_z) x3 multilayer by the pulsed laser deposition method. Coated and uncoated tools were tested in the cylindrical down milling of AISI 316L steel. Components of the cutting force and temperature generated in the machined area during dry milling were measured under two variants of operating conditions: V1 and V2. Tool wear mechanism was examined using scanning electron microscopy (SEM), accompanied by EDS analysis of worn areas. It was found that milling with higher speed (variant V2) is accompanied by lower cutting force components and a lower temperature generated in cutting area. The presence of the coating allowed lower cutting forces and temperature in the case of variant V1. The temperature measured during milling did not exceed 200 °C. The SEM observation of the edges of cutting tools indicated that the main mechanism of wear for both types of tools was abrasion. The built-up edge formation was observed in the case of tools tested at the V1 cutting parameters variant. It was assumed that it was the reason for higher cutting forces measured during milling according to this variant. The chemical composition of built-up edges was different for coated and uncoated tools. Tribo-chemical reactions were responsible for the reduction of the cutting force and temperature components observed during milling with a coated tool at V1 variant. Boron and titanium were the elements of the coating that enabled the tribo-oxidation reactions thanks to which friction was reduced. Our results show that this beneficial effect occurs with (TiB_x/TiSi_yC_z) x3 coated tools, but can easily be lost with inadequately selected cutting parameters.     

Influence of Different Types of Cemented Carbide Blades and Coating Thickness on Structure and Properties of TiN/AlTiN and TiAlN/a-C:N Coatings Deposited by PVD Techniques for Machining of Wood-Based Materials

The influence of different types of cemented carbide blades and thickness of TiAlN/a-C:N and TiN/AlTiN protective coatings used in the wood industry on cutting performance has been studied. Three types of WC-Co cemented carbide blades with different cobalt content were used in the study. The thicknesses of both types of coatings were ~2 and ~5 µm. The structure, chemical and phase composition were studied using transmission and scanning electron microscopy (TEM, SEM), X-ray dispersion spectroscopy (EDX) and X-ray diffraction (XRD), respectively. The adhesion was evaluated by scratch test. Nanohardness and durability tests of uncoated and coated blades were performed. We found that the blades covered with 5 µm TiN/AlTiN coatings exhibited the best durability characteristic. The cutting distances were within the range ~6700-~7080 depending on the substrates in comparison with pure substrates (~4300–~4900) and 2 µm TiN/AlTiN coatings (~5400–~6600). The presence of a thin and soft outer a-C:N layer aggravates the nanohardness and durability of the coated blades.     

Investigation on Microstructure,Mechanical and Wear Properties of HVOF Sprayed Composite Coatings (WC–Co + CR) On Ductile Cast Iron

Recent work indicates that the high-velocity oxy-fuel (HVOF) thermal spraying WC–Co coatings have been used to enhance the wear resistance of various engineering components in a variety of industrial environments. In the present work, WC–Co powder, containing Cr particles in an amount of 10%, was deposited on ductile cast iron with the HVOF thermal spray coating technique. An investigation was conducted to determine the role of Cr particles in the WC–Co coating produced with the HVOF technique on microstructure, mechanical, and wear properties in a system of type: WC-Co coating/ductile cast iron. The microstructure of the HVOF-sprayed WC–Co + Cr coating was characterised by light microscopy, X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), and energy-dispersive X-ray spectroscopy (EDS). The analysis of the microstructure showed the formation of a coating with low porosity, compact structure, and good adhesion to the substrate with a typical lamellar structure composed of fine molten Cr particles and finely fragmented WC grains embedded in a Co matrix, reaching the size of nanocrystalline. The scratch test was applied for the analysis of the adhesion of coatings to the substrate. The erosion behaviour and mechanism of material removal was studied and discussed based on microstructural examinations. Moreover, the results were discussed in relation to the bending strength test, including cracks and delamination in the system of the WC–Co + Cr/ductile cast iron, as microhardness and erosion resistance of the coating. It was found that the addition of Cr particles to the WC–Co powder, which causes hardening of the binder phase is a key influence on increased mechanical and wear properties in the studied system. Additionally, due to the construction of nanostructured coatings, suitable proportion of hard and soft phases, the technique sprayed HVOF coatings have advantageous properties such as high density and good slurry erosion resistance.     

Improvement of the Adhesion and Diamond Content of Electrodeposited Cu/Microdiamond Composite Coatings by a Plated Cu Interlayer

Diamond-incorporated copper metal matrix layers were fabricated on brass substrates by using electrodeposition technology in this study. To improve the adhesion of the composite coatings on the brass substrate, a plated copper was applied as the interlayer between the multilayers and the substrate. The surface morphologies of the interlayer and the diamond-incorporated copper composite layers were studied by scanning electron microscopy. The effect of the copper interlayer on the incorporation and the distribution of the diamond content in the coatings was analyzed by surface roughness, electrochemical impedance spectroscopy, and cyclic voltammetry. The diamond content of the composite coating was measured by energy-dispersive X-ray. The film thickness was evaluated by the cross-sectional technique of focused ion beam microscopy. The element, composition, and crystallization direction of diamond with Cu matrix was measured by X-ray diffraction and transmission electron microscope. The adhesion of the multilayers was studied by scratch tests. The experiment results indicated that the diamond content and distribution of the coating were higher and more uniform with the Cu interlayer than that without one. The plated copper interlayer reduced the electrical double-layer impedance and enhanced the adsorption of diamond particles by the surrounding Cu ions, which promoted the diamond content in the composite coatings. The roughened surface caused by the plated Cu interlayer also improved the substrate’s mechanical interlock with the composite coating, which contributed to the strong adhesion between them.     

Influence of Fiber Orientation on Single-Point Cutting Fracture Behavior of Carbon-Fiber/Epoxy Prepreg Sheets

The purpose of this article is to investigate the influences of carbon fibers on the fracture mechanism of carbon fibers both in macroscopic view and microscopic view by using single-point flying cutting method. Cutting tools with three different materials were used in this research, namely, PCD (polycrystalline diamond) tool, CVD (chemical vapor deposition) diamond thin film coated carbide tool and uncoated carbide tool. The influence of fiber orientation on the cutting force and fracture topography were analyzed and conclusions were drawn that cutting forces are not affected by cutting speeds but significantly influenced by the fiber orientation. Cutting forces presented smaller values in the fiber orientation of 0/180° and 15/165° but the highest one in 30/150°. The fracture mechanism of carbon fibers was studied in different cutting conditions such as 0° orientation angle, 90° orientation angle, orientation angles along fiber direction, and orientation angles inverse to the fiber direction. In addition, a prediction model on the cutting defects of carbon fiber reinforced plastic was established based on acoustic emission (AE) signals.     

Effects of Different Substrates on the Formability and Densification Behaviors of Cemented Carbide Processed by Laser Powder Bed Fusion

Cemented carbide materials are widely applied in cutting tools, drill tools, and mold fabrication due to their superior hardness and wear resistance. Producing cemented carbide parts via the laser powder bed fusion (L-PBF) method has the advantage of fabricating complex structures with a rapid manufacturing speed; however, they were underdeveloped due to their low density and crack formation on the blocks. This work studied the effect of different substrates including 316L substrates, Ni200 substrates, and YG15 substrates on the forming quality of WC-17Co parts fabricated by L-PBF, with the aim of finding the optimal substrate for fabrication. The results revealed that the Ni200 substrates had a better wettability for the single tracks formation than other substrates, and bonding between the built block and the Ni200 substrate was firm without separation during processing with a large range of laser energy inputs. This guaranteed the fabrication of a relatively dense block with fewer cracks. Although the high laser energy input that led to fine crack formation on the blocks formed on the Ni200 substrate, it was found to be better suited to restricting cracks than other substrates.     

The Influence of Nanometals,Dispersed in the Electrophoretic Nanohydroxyapatite Coatings on the Ti13Zr13Nb Alloy,on Their Morphology and Mechanical Properties

In this work, nanohydroxyapatite coatings with nanosilver and nanocopper have been fabricated and studied. The presented results concern coatings with a chemical composition that has never been proposed before. The present research aims to characterize the effects of nanosilver and nanocopper, dispersed in nanohydroxyapatite coatings and deposited on a new, non-toxic Ti13Zr13Nb alloy, on the physical and mechanical properties of coatings. The coatings were obtained by a one-stage electrophoretic process. The surface topography, and the chemical and phase compositions of coatings were examined with scanning electron microscopy, atomic force microscopy, X-ray diffractometry, glow discharge optical emission spectroscopy, and energy-dispersive X-ray spectroscopy. The mechanical properties of coatings were determined by nanoindentation tests, while coatings adhesion was determined by nanoscratch tests. The results demonstrate that copper addition increases the hardness and adhesion. The presence of nanosilver has no significant influence on the adhesion of coatings.     

Influence of Preheating Temperature on Structural and Mechanical Properties of a Laser-Welded MMC Cobalt Based Coating Reinforced by TiC and PCD Particles

This article presents research on the structural and mechanical properties of an innovative metal matrix composite (MMC) coating designed for use in conditions of intense metal-mineral abrasive wear. The layer, which is intended to protect the working surface of drilling tools used in the oil and natural gas extraction sector, was padded using the multi-run technique on a sheet made of AISI 4715 low-alloy structural steel by Laser Direct Metal Deposition (LDMD) using a high-power fiber laser (FL). An innovative cobalt alloy matrix powder with a ceramic reinforcement of crushed titanium carbide (TiC) and tungsten-coated synthetic polycrystalline diamond (PCD) was used as the surfacing material. The influence of the preheating temperature of the base material on the susceptibility to cracking and abrasive wear of the composite coating was assessed. The structural properties of the coating were characterized by using methods such as optical microscopy, scanning electron microscopy (SEM), energy dispersion spectroscopy (EDS), transmission electron microscopy (TEM) and X-ray diffraction analysis (XRD). The mechanical properties of the hardfaced coating were assessed on the basis of the results of a metal-mineral abrasive wear resistance test, hardness measurement, and the observation of the abrasion area with a scanning laser microscope. The results of laboratory tests showed a slight dissolution of the tungsten coating protecting the synthetic PCD particles and the transfer of its components into the metallic matrix of the composite. Moreover, it was proved that an increase in the preheating temperature of the base material prior to welding has a positive effect on reducing the susceptibility of the coating to cracking, reducing the porosity of the metal deposit and increasing the resistance to abrasive wear.     

Wear Mechanism of Multilayer Coated Carbide Cutting Tool in the Milling Process of AISI 4340 under Cryogenic Environment

Cryogenic technique is the use of a cryogenic medium as a coolant in machining operations. Commonly used cryogens are liquid nitrogen (LN2) and carbon dioxide (CO₂) because of their low cost and non-harmful environmental impact. In this study, the effects of machining conditions and parameters on the wear mechanism were analysed in the milling process of AISI 4340 steel (32 HRC) under cryogenic conditions using a multilayer coated carbide cutting tool (TiAlN/AlCrN). A field emission scanning electron microscope with energy-dispersive X-ray analysis was used to examine the wear mechanisms comprehensively. At low machining parameters, abrasion and adhesion were the major wear mechanisms which occurred on the rake face. Machining at high machining parameters caused the removal of the coating material on the rake face due to the high temperature and cutting force generated during the cutting process. In addition, it was found that continuously adhered material on the rake face would lead to crater wear. Furthermore, the phenomenon of oxidation was also observed when machining at high cutting speed, which resulted in diffusion wear and increase in the crater wear. Based on the relationship between the cutting force and cutting temperature, it can be concluded that these machining outputs are significant in affecting the progression of tool wear rate, and tool wear mechanism in the machining of AISI 4340 alloy steel.     

The Effect of Surface Treatment on Structural Properties of CVD Diamond Layers with Different Grain Sizes Studied by Raman Spectroscopy

Extensive Raman spectroscopy studies combined with scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) measurements were performed to investigate structural and chemical changes in diamond layers deposited by chemical vapour deposition (CVD) upon post-growth treatment with hydrogen. The aim of this study is to characterize the changes in micro-structural properties of diamond layers with different grain sizes and different contents of sp² carbon phase. Hydrogenation or oxidization of diamond layer surface is often performed to modify its properties; however, it can also strongly affect the surface structure. In this study, the impact of hydrogenation on the structure of diamond layer surface and its chemical composition is investigated. Owing to their polycrystalline nature, the structural properties of CVD diamond layers can strongly differ within the same layer. Therefore, in this project, in order to compare the results before and after hydrogen treatment, the diamond layers are subjected to Raman spectroscopy studies in the vicinity of a T-shape marker fabricated on the surface of each diamond layer studied.     

Investigation of the Wear Performance of TiB2 Coated Cutting Tools during the Machining of Ti6Al4V Alloy

The machining of Ti6Al4V alloy, especially at low cutting speeds, is associated with strong Built-Up Edge (BUE) formation. The PVD coatings applied on cutting tools to machine such materials must have the necessary combination of properties to address such an underlying wear mechanism. The present work investigates and shows that TiB₂ PVD coating can be designed to have certain mechanical properties and tribological characteristics that improve machining in cases where BUE formation is observed. Three TiB₂ coatings were studied: one low hardness coating and two high hardness coatings with varied coating thicknesses. Wear performances for the various TiB₂ coated carbide tools were evaluated while rough turning Ti6Al4V. Tool wear characteristics were evaluated using tool life studies and the 3D wear volume measurements of the worn surface. Chip morphology analyses were done to assess the in-situ tribological performance of the coatings. The micro-mechanical properties of the coatings were also studied in detail to co-relate with the coatings’ performances. The results obtained show that during the rough turning of Ti6Al4V alloy with intensive BUE formation, the harder TiB₂ coatings performed worse, with coating delamination on the rake surface under operation, whereas the softer version of the coating exhibited significantly better tool life without significant coating failure.     

Characterization of Cobalt-Based Stellite 6 Alloy Coating Fabricated by Laser-Engineered Net Shaping (LENS)

The results of microstructure and mechanical properties evaluation of a Stellite 6 (Co-6) alloy deposited on X22CrMoV12-1 substrate by the laser-engineered net shaping (LENS^TM) technology are presented in this paper. The Stellite 6 alloy is widely used in industry due to its excellent wear resistance at elevated temperatures and corrosive environments. Specific properties of this alloy are useful in many applications, e.g., as protective coatings in steam turbine components. In this area, the main problems are related to the fabrication of coatings on complex-shaped parts, the low metallurgical quality of obtained coatings, and its insufficient adhesion to a substrate. The results of recently performed investigations proved that the LENS technology is one of the most effective manufacturing techniques of the Co-6 alloy coatings (especially deposited on complex-shaped turbine parts). The microstructural and phase analyses of obtained Stellite 6 coatings were carried out by light microscopy techniques and X-ray diffraction analysis. A chemical homogeneity of Co-6 based layers and a fluctuation of chemical composition in coating–substrate zone after the laser deposition were analyzed using an energy dispersive X-ray spectrometer coupled with scanning electron microscopy. The room temperature strength and ductility of the LENS processed layers were determined in static bending tests.     

Microstructure and Abrasive Wear Resistance of Metal Matrix Composite Coatings Deposited on Steel Grade AISI 4715 by Powder Plasma Transferred Arc Welding Part 2. Mechanical and Structural Properties of a Nickel-Based Alloy Surface Layer Reinforced with Particles of Tungsten Carbide and Synthetic Metal–Diamond Composite

The article is the continuation of a cycle of works published in a Special Issue of MDPI entitled “Innovative Technologies and Materials for the Production of Mechanical, Thermal and Corrosion Wear-Resistant Surface Layers and Coatings” related to tests concerning the microstructure and mechanical properties of innovative surface layers made using the Powder Plasma Transferred Arc Welding (PPTAW) method and intended for work surfaces of drilling tools and machinery applied in the extraction industry. A layer subjected to tests was a metal matrix composite, made using powder based on a nickel alloy containing spherical fused tungsten carbide (SFTC) particles, which are fused tungsten carbide (FTC) particles and spherical particles of tungsten-coated synthetic metal–diamond composite (PD-W). The layer was deposited on the substrate of low-alloy structural steel grade AISI 4715. The results showed that the chemical composition of the metallic powder as well as the content of the hard phase constituting the matrix enabled the making of a powder filler material characterised by very good weldability and appropriate melting. It was also found that the structure of the Ni-WC-PD-W layer was complex and that proper claddings (characterised by the uniform distribution of tungsten carbide (WC)) were formed in relation to specific cladding process parameters. In addition, the structure of the composite layer revealed the partial thermal and structural decomposition of tungsten carbide, while the particles of the synthetic metal–diamond composite remained coherent. The deposited surface layer was characterised by favourable resistance to moderate dynamic impact loads with a potential energy of 200 J, yet at the same time, by over 12 times lower metal–mineral abrasive wear resistance than the previously tested surface layer made of cobalt-based composite powder, the matrix of which contained the hard phase composed of TiC particles and synthetic metal–diamond composite. The lower abrasive wear resistance could result from a different mechanism responsible for the hardening of the spherical particles of the hard phase susceptible to separation from the metal matrix, as well as from a different mechanism of tribological wear.